新型太阳热反射涂料的组成与性能研究

对新型太阳热反射涂料的组成和性能进行了实验研究,结果表明：新型隔热填料中空微珠的添加量为20％时具有明显的隔热降温效果,同时对涂料的物理性能基本没有影响,所配的灰色涂层的隔热降温效果可达9～11℃;当漂浮型铝粉以不超过40％的添加量作为太阳热反射涂料用金属颜料时,显示良好的太阳热反射性能和隔热降温效果。     

无机复合颜料制备热反射甲板涂料

介绍了太阳热反射涂料的机理和热反射颜料的选取,研制出一种以丙烯酸聚氨酯为基体的具有一定热反射功能的甲板涂料,深灰色涂层在780～2500nm波段的太阳热反射率达到35％。对比了分光光度计法和美军标MILE46136A和46117A中规定的检测方法,指出了二者的不同之处。     

绿色太阳热反射涂料降温性能研究

介绍了绿色太阳热反射涂料的制备工艺和颜料配方。与普通外墙用绿色涂料、市售绿色涂料和军用绿色涂料进行比较,研究了自制的绿色太阳热反射涂料的降温性能。结果表明,相对其它涂料,涂覆自制的绿色太阳热反射涂料的涂层其降温效果最好,能使涂覆物的表面温度降低10~15℃,内部温度降低8~10℃;使油罐中油面10 cm处温度下降4~5℃。人工老化实验表明,自制的涂层具有优良的耐候性,适合于户外大型制件的涂饰。     

C.I.颜料红177颜料化的初步研究

本文论述了Ｃ．Ｉ．颜料红１７７的颜料化方法及其基本过程并采用添加表面处理剂对该颜料进行颜料化处理。此外,本文还以海泡石为核,对该颜料进行包核颜料初步研究,结果表明,该颜料在水中具有较好的分散性。     

还原染料类颜料及其颜料化技术

本文对还原染料类颜料特点、重要品种及合成工艺进行了讨论，较系统地论述了该类型颜料的颜料化方法，重点了各种不同的颜料表面改性处理的新进展。     

体质颜料

前言 过去对体质颜料的认识不够重视,对其仅作一般研究。事实上,它在大多数涂料中起着重要的作用。由于体质颜料的类型多且它们的性能有极大的差异,大多数的配方对其性能不能非常精确和有效的应用,所以需要重新定位,更确切地应用体质颜料来改良产品。     

发光颜料在硅橡胶中的应用

将发光颜料用于硅橡胶中制备发光硅橡胶制品。研究发光颜料粒径、用量及染色颜料对发光硅橡胶制品辉度的影响。结果表明。发光颜料的粒径越大，硅橡胶制品辉度也越大，但物理性能受到影响；采用PI，O-7c发光颜料可得到综合性能较好的制品；发光颜料的用量以10份为宜；为了染色而使用的染色颜料应尽量采用透明性颜料，且应尽量减小用量以减少对发光颜料的遮盖。     

效应颜料在涂料中应用的进展（Ⅰ）

介绍了效应颜料的定义、种类、性能和应用进展。对铝粉颜料、珠光颜料和超细二氧化钛三种效应颜料的分类、制造工艺、性能、品种牌号及在涂料中的应用作了详细的叙述。     

灰色颜料的配制及其太阳热反射性能的影响因素分析

基于三原色混色机理将不同的红、黄、蓝颜料混合,配制出不同的灰色颜料,并与纯丙乳液混合制成太阳热反射涂料。利用色差仪和紫外/可见/近红外分光光度计测试涂层的色空间值L*、a*、b*与太阳热反射率,考察了颜料组分、用量以及添加第二相粒子对涂层太阳热反射性能的影响。结果表明,类似色度下,着色力高的氧化铁红、钛铬棕的用量比着色力低的锆铁红、镨黄少;铁铬黑、钴黑这2种无机黑降低涂层明度的同时会严重减弱反射率。为获得反射率较高、明度较低的涂层,使用的颜料需折射率和反射率均较高且明度较低。     

谈谈铁系颜料的发展

氧化铁系颜料在无机彩色颜料中占有重要地位，其产量首屈一指，早在远古时代就开始使用氧化铁系颜料，至今仍不败落，究其原因是它具有优异的颜料性能，从低档天然矿物质颜料到高档合成的磁性颜料，品种多而用途广，价格低而无毒，所以得到大量的使用。1、氧化铁系颜料颜色丰富众所周知，氧化铁系颜料是以氧化铁红为主的系列颜料，色错很宽，可分黄、红、棕、黑四大类。细分则黄色按色相可由浅柠檬黄色到桔黄色，即由偏绿相的黄色到偏红相的黄色，其中间有无数个品种，可根据需要而定；红色可由桔红包到红紫色，即由偏黄相的红色到偏兰根的…     

陶瓷颜料调色机理初探

从颜料发色的基本光学原理出发,分析了利用陶瓷原料进行混合调色的机理,并就釉与颜料之间的关系,讨论了颜料在釉中的呈色情况。     

聚甲基丙烯酸甲酯／镉黄颜料色母粒的合成及其研究

采用亚硫酸氢钠、过氧化二苯甲酰作引发剂,在无机镉黄颜料水悬浮液中,引发甲基丙烯酸甲酯进行聚合反应,得到了镉黄颜料色母粒。对该种色母粒作了红外光谱及DTA、TG分析,并探讨了其反应机理。     

Surface coating properties of different shape and size pigment blends

The effect of different shape and size of pigments in blends on latex coating surface properties was investigated. Two pigment blends were compared. Both blends were made of plate-like kaolin pigment but with different size prismatic precipitated calcium carbonate at different volume ratios. All coatings were applied on absorbent as well as non-absorbent substrates. Surface coating properties investigated include surface morphology, surface chemistry and surface energy. Surface morphology was characterized by measuring gloss and roughness, surface chemistry was characterized by X-ray Photoelectron Spectroscopy and surface energy was estimated by Kaelable approach.     

关于红色陶瓷颜料

物理上的红色指波长为７００ｎｍ的单色光。本文综述了目前用于陶瓷生产的红色陶瓷颜料的品种，组成，特点，色调及应用现状，探讨提高颜料使用性能的途径，方法，对于红色陶瓷颜料，无毒化或降低毒性，增加对不同工艺条件的适应性，提高颜料的使用温度和稳定性，降低剧本，开发新的颜料品种将是今后生产和研究的重点，加强制备工艺条件的改善并对加工前后的粉为颗粒进行表面改性将有利于颜料性能的提高。     

彩色复合型反射隔热涂层的制备及性能

将空心微珠和二氧化钛为填料的涂层做底层,反射型颜料的涂层做表层,制备了阻隔-反射彩色复合型反射隔热涂层。采用紫外/可见/近红外分光光度计、红外发射率仪、精密色差仪和扫描电子显微镜对涂层性能进行表征,自制隔热性能测试装置考察涂层的隔热性能。结果表明,采用复合型涂层结构可显著提高涂层的太阳光反射比和隔热性能,铬绿、群青和铁铬黑颜料掺量分别为20%、20%和10%时,复合涂层的太阳光反射比较高,可达0.646 1、0.602 1和0.539 8,比相同颜料掺量的表层高40.82%、31.03%和58.67%,隔热性能比相同颜料掺量的表层高2.5、1.9和2.8℃,其主要应用性能符合相关标准。     

用铝锌系合金颜料制备阳极型强屏蔽涂料的研究

通过实验研究发现 ,把铝锌系合金颜料的锌含量提高到 35%～ 40 %、锡含量提高到 0 5%～ 1 0 %时 ,不仅可以充分降低颜料表面电阻 ,提高表面活性 ,使涂层下面的碳钢基体达到完全阴极保护电位 ,而且还可以使涂料的最佳颜料体积分数进一步降低     

铁铝红颜料的研制与生产探讨

铁铝红是一种发色鲜艳、生产稳定、价格低廉的颜料，为提高该颜料在基础釉中的适应性，文章通过对比实验数据分析，对颜料的配方和生产方法进行了探讨，并提出了实际性的生产方案。     

Relationship between surface chemistry and surface energy of different shape pigment blend coatings

The influence of pigment shapes and pigment blends on the surface energy was investigated and compared with the surface chemistry of pigmented latex coatings. The coatings were made of different volume ratios of two pigments: plate-like kaolin clay pigment and prismatic precipitated calcium carbonate (PCC) pigment. These were mixed together with carboxylated styrene–butadiene–acrylonitrile latex (SBA), and applied over nonabsorbent substrates as well as absorbent substrates. The composition of the surface of the coatings was investigated by X-ray photoelectron spectroscopy (XPS). Two approaches were used to estimate the total surface energy and the components of the coatings: a conventional approach—“the Kaelble approach”—and a more modern approach—“the van Oss approach.” Pigment blends with different shapes and increments caused a change in the surface chemistry and the surface energy of the latex coatings. As the prismatic PCC pigment particles increased in the kaolin/SBA coating system, the SBA latex content at the coating surface increased and the total surface energy of the coating decreased. This is valid for both nonabsorbent as well as absorbent substrates. It was found that there was a strong correlation between the surface energy and the surface composition. The surface energy of the coatings estimated by the Van Oss approach was always lower than that estimated by the Kaelble approach. Colloidal interactions between pigment–pigment and/or pigment–binder were thought to play an essential role in determining the final coating surface energy and its components. Changes in the surface latex content and the surface energy due to the different pigment blends investigated were found to fit straight-line equations.     

Preparation and characterization of Cr2O3-TiO2-Al2O3-V2O5 green pigment

Green pigments with high near infrared reflectance based on a Cr₂O₃-TiO₂-Al₂O₃-V₂O₅ composition have been synthesized. Cr₂O₃ was used as the host component and mixtures of TiO₂, Al₂O₃ and V₂O₅ were used as the guest components. TiO₂, Al₂O₃, and V₂O₅ were mixed into 39 different compositions. The spectral reflectance and the distribution of pigment powder were determined using a spectrophotometer and a scanning electron microscope, respectively. It was found that a pigment powder sample S9 with a Cr₂O₃-TiO₂-Al₂O₃-V₂O₅ composition of 80, 4, 14 and 2 wt%, respectively, gives a maximum near infrared solar reflectance of 82.8% compared with 49.0% for pure Cr₂O₃. The dispersion of pigment powders in a ceramic glaze was also studied. The results show that the pigment powder sample S9 is suitable for use as a coating material for ceramic-based roofs.     

食用天然石榴色素的性质及应用研究

对食用天然石榴色素的性质进行了研究。该色素对热、光照及发霉等具有稳定性，其红色色素溶液随ｐＨ值的改变而发生变化，变色灵敏且可逆。可做酸碱指示剂。并对其做了实用实验。