共查询到20条相似文献,搜索用时 140 毫秒
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将模拟浓海水和NaOH直接沉淀制备的Mg(OH)2水热处理得到Mg(OH)2阻燃剂粉体,考察了矿化剂和温度对其晶体形貌、结晶性及分散性的影响. 结果表明,在实验温度范围内,碱类矿化剂对晶体形貌的改善优于氯盐矿化剂;矿化剂浓度和水热温度越高,对晶体形貌改善越好,晶体粒径及厚度增加越快,且可减小晶体极性和微观内应变,提高结晶度和分散性. 在水热时间8 h、温度200℃、4.0 mol/L NaOH溶液为矿化剂条件下,可制备出粒度分布均匀、平均粒径约为0.250 mm、厚度约61 nm、团聚指数约为10.95的阻燃型Mg(OH)2. 相似文献
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以工业Al(OH)3为原料,通过引入晶种和矿化剂,用水热法低温合成α-Al2O3粉体.研究了固相含量、原料粒度、水热温度、保温时间、晶种加入量、矿化剂种类等因素对α-Al2O3产率和产物晶粒形貌的影响.结果表明:随固相含量的增加,产物的收率增加,当固相含量增大到8%(质量分数,下同)时,产物的收率开始降低;原料粒度从16 μm减小到2.5μm时,产物的收率增大,当原料粒度减小到1.5μm,产物的收率变化不明显;随着水热温度的升高、水热时间的延长,α-Al2O3含量相对增多,晶粒发育渐趋完善:晶种的引入有效地降低了α-Al2O3成核的活化能,有利于α-Al2O3形成;矿化剂的种类对水热合成α-Al2O3的作用效果差别很大,加入矿化剂KBr更有利于α-Al2O3生成和晶体发育.发育完善的α-Al2O3呈六方柱状,晶体显露{0001}和{11 2 0}面族.最佳的实验工艺条件为:固相含量5%,反应温度390℃,保温时间2h,晶种加入量5%质量分数),填充度40%(体积分数),矿化剂KBr加入量0.5mol/L. 相似文献
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利用溶剂热法,以五水硫酸铜和氢氧化钠为原料,乙醇为还原剂,在乙醇与去离子水的混合溶剂中,140 ℃条件下溶剂热处理6~10 h制得了不同长径比的氧化亚铜纳米棒.利用X射线粉末衍射仪(XRD)及高分辨透射电镜(HRTEM)对合成产物进行了物相与形貌分析.检测结果显示合成的纳米棒结晶程度良好,尺寸较为均匀.在实验中还发现反应温度与溶剂中的含水量是影响乙醇还原性的主要因素. 相似文献
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本文以Sr(OH)2和TiO(OH)2作为水热合成SrTiO3晶体粉末的前驱物,讨论并选定制备前驱物的化工原料,并对水热合成SrTiO3晶体粉末的条件:KOH浓度、温度和时间进行了考察.结果表明150~200℃,1h均可有效合成.200℃下水热20~60min产物的X光衍射特征峰高无明显差别;水热介质中KOH浓度从0.1~1.0mol/L区域内对合成无大的影响;最后初步讨论了SrTiO3晶体粉末的合成机理并合理解释了实验结果. 相似文献
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采用水热法合成Zn_(0.95)Fe_(0.05)O稀磁半导体,通过试验及XRD、FE-SEM对合成的粉体进行分析,在水热合成法合成条件200℃保温24 h、矿化剂NaOH浓度3 mol/l、填充度为60%下,制备出的Zn_(0.95)Fe_(0.05)O纳米晶体发育完全,粒度分布均匀。是合成Zn_(0.95)Fe_(0.05)O纳米晶体的理想方法之一。 相似文献
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Two novel methods, one for preparation of porous α-Fe2O3 nanorod catalyst support and another for the deposition of gold (Au) particles on the catalyst support with high efficiency and high dispersion, were reported. In the former, FeO(OH) nanorods were first prepared by a mild hydrothermal synthesis using tetraethylammonium hydroxide (TEAOH) as the structure director. The FeO(OH) product was then converted to porous α-Fe2O3 nanorods via calcination at 300 °C. During this calcination, pores with a size distribution in the range of 1–5 nm were generated by removal of TEAOH molecules. By employing our invented Au colloid-based and sonication-assisted method, in which lysine was used as the capping agent and sonication was employed to facilitate the deposition of the Au particles, we were able to deposit very small Au particles (2–5 nm) into these pores. This method is rapid as the reaction/deposition is completed within 1 min. The prepared Au/α-Fe2O3-nanorod catalyst exhibited much higher catalytic activity than the Au/commercial α-Fe2O3 (Fluka) catalyst. 相似文献
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A novel method which is based on the hydrothermal reaction was employed to synthesize LiV3O8. First, the mixture solution of LiOH, V2O5, and NH4OH was subjected to the hydrothermal reaction. The hydrothermal treatment yielded a clear, homogeneous solution. The evaporation of this solution led to the formation of a precursor gel. The gel was then heated at different temperatures in the range of 300-600 °C. The characterization by X-ray diffraction (XRD), transmission electron microscopy (TEM), and Fourier transform infrared (FTIR) indicated that LiV3O8 nanorods have been obtained by this novel synthesis method. The electrochemical performance of the LiV3O8 nanorods have been investigated, which indicates that the highest discharge specific capacity of 302 mAh/g in the range of 1.8-4.0 V was obtained for the sample heated at 300 °C, and its capacity remained 278 mAh/g after 30 cycles. 相似文献
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《Ceramics International》2017,43(10):7881-7888
High quality pure and Fe-doped Gd(OH)3 nanorods were fabricated through a template-free hydrothermal method for the first time. Analysis of XRD indicates that Fe3+ was incorporating in the interstitial sites rather than occupying the substitutional sites, forming pure hexagonal structure of Gd(OH)3 without any other impurity phase. TEM characterizations show that all the samples perform uniform rod-like morphologies with similar diameter and length, which suggests that the Fe doping has little influence on the morphologies of samples. ICP and XPS spectra suggest that the dopant Fe3+ is incorporated into the inner body sites, not on the surface of nanorods. Magnetic studies show that the magnetic phase can be converted from paramagnetism to room-temperature ferromagnetism by doping Fe3+ ions into the Gd(OH)3 nanorods. The saturation magnetization (Ms) is sensitive to the amount of Fe dopants, and the Ms for Fe0.03Gd0.97(OH)3 nanorods reaches the maximum value of 0.184 emu/g. It is considered that the ferromagnetic ordering is possibly originated from the exchange interaction of Fe3+ through the oxygen vacancies, leading to the formation of point defect-mediated bound magnetic polarons (BMPs). Ruling out the affect of morphologies and secondary magnetic phase on the magnetic properties, the ferromagnetic ordering in uniform Fe-doped Gd(OH)3 nanorods, in which the dopant Fe3+ is incorporated into the inner body sites of nanorods, are of great importance to deeply understand the rare earth-based DMS/DMD systems and have potential applications in spintronic devices. 相似文献
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Piyaphan Pannasri Punnama Siriphannon Pathavuth Monvisade Jiti Nookaew 《Journal of Polymer Research》2011,18(6):2245-2254
Nano-ZnO synthesized by hydrothermal reaction were embedded in poly(methyl methacrylate-co-butyl acrylate) matrix (P(MMA-co-BA)) to produce the nano-ZnO/P(MMA-co-BA) nanocomposites via in-situ polymerization at 85 °C. The nano-ZnO/P(MMA-co-BA) nanocomposites were hydrothermal treated in the mixture solution of Zn(NO3)2·6H2O and NH4OH at 90 °C under various pH (i.e.7, 8, 9 and 10) and treatment time (i.e. 4, 6, 8, 10, 12 and 24 hrs). The nano-ZnO could
act as seeding particles for hydrothermal growth of ZnO nanostructures on the surfaces of nanocomposites. The higher pH of
basic solutions used in the hydrothermal treatment, the higher amount of Zn(OH)42−nuclei would be created, leading to a modification of the ZnO morphology from nano-nuclei to nanorods, nanorods bushes (flower-like
nanostructure) and nanofibers with nanospine. The increase of hydrothermal treatment time resulted in the increases of amount
and length of multidirectional grown ZnO nanorods. Data of the contact angle measurement exhibited the increase of hydrophobicity
of the nano-ZnO/P(MMA-co-BA) nanocomposites after hydrothermal growth of ZnO nanostructures. The nanocomposites treated at pH = 10 for 24 hrs shows
the highest hydrophobicity with the contact angle of 121˚. In addition, the thermal stability of the nano-ZnO/P(MMA-co-BA) could be improved by the formation of hydrothermal grown ZnO nanostructure on the nanocomposite surface. 相似文献
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Andrea Pauline Ricasata Arazas Chia-Chen Wu Kao-Shuo Chang 《Ceramics International》2018,44(12):14158-14162
This paper reports the fabrication of vertically oriented BiFeO3 (BFO) nanorods on indium tin oxide/glass substrates through hydrothermal synthesis. Further, their piezotronic, piezophototronic, and piezophotocatalytic properties were analyzed. Various synthesis parameters were examined to modulate the morphology and alignment of BFO nanorods, including the ratios of precursors, the pH values, types of complex agents, and reaction times and temperatures. Transmission electron microscopy results demonstrated single crystallinity of the BFO nanorods. A band gap of approximately 2.3?eV was determined. The piezotronic and piezophototronic properties were observed through facile current–voltage measurement. The extended application of piezophotocatalysis under alternating external stress and visible-light irradiation, to decompose methylene blue solutions, was also ascertained. The piezophotocatalytic efficiency was improved by approximately 30% over photocatalysis in the first 30?min. Both O2?□and□·OH radicals were crucial for these activities. 相似文献
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应用水热合成法制备钛酸钡、钛酸锶、铁酸钙从钛酸铅晶体粉末,采用的技术路线分别以Ba(OH)2,Ca(OH)2,Sr(OH)2,Ph(OH)2及TiO(OH)2为水热合成钛酸盐的前驱物。研究了它们合成时的KOH浓度、温度和时间等影响因素。根据实验结果.按水热前驱物M(OH)2的特性分类.找出它们的共性和差异,提出了合成机理及MgTiO3和Al2(TiO3)3难以用水热合成的原因。 相似文献
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利用水热法合成了NaY(WO4)2:Dy3+上转换荧光粉. 通过XRD、SEM表征该荧光粉结构和形貌. 探讨了Dy3+浓度、pH值、反应温度及焙烧温度对NaY(WO4)2:Dy3+晶体结构、形貌及发光性能的影响,得到在Dy3+浓度为0.5%,pH=8,反应温度180℃,800℃焙烧条件下的样品具有最佳上转换发光性能. 利用776 nm近红外光激发NaY(WO4)2:Dy3+,观察到480 nm处的蓝光发射峰以及577 nm处的黄光发射峰. 其中蓝光来自Dy3+离子的4F9/2→6H15/2跃迁,黄光由Dy3+离子4F9/2→6H13/2跃迁产生. 相似文献
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钨酸锌纳米棒的水热合成条件对其荧光及光催化性能的影响 总被引:2,自引:2,他引:0
以硝酸锌和钨酸钠为原料,采用前驱体一水热法制得了钨酸锌纳米棒.X射线衍射、透射电镜和扫描电镜等分析结果表明:所得产物为直径约20nm,长度约200nm的ZnWO4纳米棒.详细研究了水热温度和水热时间对纳米棒的形成、荧光发射强度以及对有机染料罗丹明B(maodamine B,RhB)光催化降解的影响.结果表明:水热温度为200℃,反应时间为16h得到的产品直径小,形貌均一,结晶度高且对RhB的光催化降解效率与商用光催化剂二氧化钛(P-25)接近. 相似文献