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Characterisation of a laboratory electrochemical ozonation system and its application in advanced oxidation processes 总被引:1,自引:0,他引:1
Leonardo M. Da Silva Débora V. Franco Juliane C. Forti Wilson F. Jardim Julien F.C. Boodts 《Journal of Applied Electrochemistry》2006,36(5):523-530
An electrochemical reactor for oxygen/ozone production was developed using perforated planar electrodes. An electroformed
-PbO2 coating, deposited on a platinised titanium substrate, was employed as anode while the cathode was a platinised titanium substrate. The electrodes were pressed against a solid polymer electrolyte to minimise ohmic drop and avoid mixing of the gaseous products (H2 and O2/O3). Electrochemical ozone production (EOP) was investigated as function of current density, temperature and electrolyte composition. Electrochemical characterisation demonstrated ozone current efficiency, ΦEOP, ozone production rate (g h−1),
, and grams of O3 per total energy demand (g h−1 W−1), increase on decreasing electrolyte temperature and increasing current density. The best reactor performance for EOP was obtained with the base electrolyte (H2SO4 3.0 mol dm−3) containing 0.03 mol dm−3 KPF6. Degradation of reactive dyes used in the textile industry (Reactive Yellow 143 and Reactive Blue 264) with electrochemically-generated ozone was investigated in alkaline medium as function of ozone load (mg h−1) and ozonation time. This investigation revealed ozonation presents very good efficiency for both solution decolouration and total organic carbon (TOC) removal. 相似文献
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高级氧化处理有机污水技术进展 总被引:51,自引:1,他引:51
综述了高级氧化技术的原理,介绍了O3/UV、H2O2/UV、O3/H2O2组合过程及非均相TiO2光催化氧化等几种典型的高级氧化技术,阐述了高级氧化技术降解有机污水的机理以及在水处理中的应用进展。指出,高级氧化过程应用领域应扩展到水体中难降解的持久性有机污染物,并应加强高级氧化过程所需新型反应器的研制,以便进一步强化废水的5降解,提高其处理效率。 相似文献
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Francisco J. Real F. Javier Benitez Juan L. Acero Manuel Gonzalez 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2007,82(6):566-574
Diazinon is a widely used organophosphorus insecticide that is an important pollutant in aquatic environments. The chemical removal of diazinon has been studied using UV radiation, ozone, Fenton's reagent, UV radiation plus hydrogen peroxide, ozone plus hydrogen peroxide and photo‐Fenton as oxidation processes. In the photodegradation process the observed quantum yields had values ranging between 2.42 × 10?2 and 6.36 × 10?2 mol E?1. Similarly, the ozonation reaction gave values for the rate constant ranging between 0.100 and 0.193 min?1. In the combined systems UV/H2O2 and O3/H2O2 the partial contributions to the global oxidation reaction of the direct and radical pathways were deduced. In the Fenton's reagent and photo‐Fenton systems, the mechanism of reaction has been partially discussed, and the predominant role of the radical pathway pointed out. Additionally, the rate constant for the reaction between diazinon and the hydroxyl radicals was determined, with the value 8.4 × 109 L mol?1 s?1 obtained. A comparison of the different oxidation systems tested under the same operating conditions revealed that UV radiation alone had a moderate oxidation efficiency, which is enhanced in the case of ozone, while the most efficient oxidant is the photo‐Fenton system. Copyright © 2007 Society of Chemical Industry 相似文献
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F. Javier Rivas ngel Encinas Benito Acedo Fernando J. Beltrn 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(4):589-594
BACKGROUND: Endocrine disruptors, as in the case of bisphenol A (BPA), are increasingly found in aqueous effluents. The degree of mineralization of a bisphenol A (BPA) aqueous solution after applying several oxidation treatments has been investigated. RESULTS: UV‐C photolysis of BPA allowed calculation of the quantum yield, ϕλ=254 = 0.045 ± 0.005 mol Einstein−1 but only 15% of the initial organic carbon content (TOC) was eliminated. Better results (80% conversion) were obtained after TiO2 addition. Ozone inmediately reacts with BPA. Again, TiO2 addition in the presence of O3 was capable of increasing the mineralization level (60%). The photolytic ozonation of BPA was capable of completely eliminating TOC. The presence of activated carbon in the O3/UV and O3/UV/TiO2 systems significantly enhanced the TOC removal reaction rate (100% conversion in 20 min). CONCLUSIONS: Processes such as ozonation or photolysis are capable of efficiently removing BPA from water however, mineralization levels are rather low. Addition of TiO2 to O3 or UV‐C significantly enhances TOC removal. The remaining organics still account for an average 20–40% of the initial organic carbon. The combination of O3/UV‐C is capable of completely mineralizing BPA. Activated carbon and/or TiO2 addition to the system O3/UV‐C improves the TOC depletion rate. Copyright © 2008 Society of Chemical Industry 相似文献
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吲哚散发粪便恶臭气味,广泛存在于焦化、染料、化工、制药和农药等工业废水中。由于其特殊的双环稠合结构,靠传统的生物水解断环提高吲哚的降解效果难以为继。本文全面介绍了吲哚的来源、毒性、危害及传统生物降解技术的缺陷,特别论述了高级氧化法(AOPs)中·OH的形成反应及降解吲哚的作用机理。传统AOPs能够高效降解吲哚,但价格昂贵,操作复杂,且使用剂量常受到其他物质的干扰,易引入新的污染物,难以在大规模的水处理工程中应用。因此,认为将AOPs预氧化与生物处理技术进行高效耦合是降解吲哚经济有效的办法。本文最后介绍了硫酸根自由基的高级氧化技术(SR-AOPs)耦合厌氧生物技术降解吲哚的研究及其优点。这些研究对丰富AOPs耦合生物处理技术理论、含氮杂环污染物高效降解及资源化利用有一定的参考价值。 相似文献
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J Beltran J Torregrosa J
R Dominguez J
A Peres 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2001,76(12):1235-1242
The oxidation of p‐hydroxybenzoic acid in aqueous solution by UV radiation and by photo‐assisted ozonation (UV+O3) has been studied. The effects of temperature (10, 20, 30 and 40 °C), pH (2, 5, 7 and 9) and ozone partial pressure (0.10–0.38 kPa) on the conversion of p‐hydroxybenzoic acid were established. Experimental results indicated that the kinetics for both oxidation processes fit pseudo‐first‐order kinetics well. In the combined process, the overall kinetic rate constant was split into two components: direct oxidation by UV radiation (photolysis) and oxidation by free radicals (mainly OH·) generated in the system. The importance of these two reaction paths for each specific value of ozone partial pressure, temperature and pH was quantified. Lastly, a general expression is proposed for the reaction rate which takes into account the two reaction pathways and is a function of known operating variables. © 2001 Society of Chemical Industry 相似文献
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rGO-Fe3O4活化过硫酸盐处理酸性红73 总被引:2,自引:0,他引:2
采用共沉淀法制备了还原石墨烯纳米片和磁铁矿复合材料(rGO-Fe3O4)。利用X射线衍射(XRD)、X射线光电子能谱(XPS)和透射电镜(TEM)对其进行了表征。以酸性红73(AR73)为目标物,研究了rGO-Fe3O4活化过硫酸盐(PS)处理酸性红73的效能,考察了催化剂投加量、PS浓度、溶液初始pH以及反应温度的影响。结果表明,室温下催化剂投加量为1.0 g/L、PS的浓度为1.0 g/L及初始pH为6.9时,10 min内50 mg/L酸性红73的脱色率达到100%。淬灭实验结果表明rGO-Fe3O4/PS反应体系同时存在SO4-?、?OH和单线态氧1O2,其中1O2的氧化反应起主导作用。复合材料rGO-Fe3O4不但活性高,而且便于分离,应用前景良好。 相似文献
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实验研究了臭氧高级氧化-生化耦合技术处理低浓度有机污水。以某炼油厂乙烯废水为例,在低臭氧投加量1 5~2 0mg/L及其他一定条件下,出水CODCr平均不到33mg/L,石油类污染物平均去除率达到了67 2%,出水挥发酚最高质量浓度仅0 016mg/L,硫化物平均降解率为65 2%,氨氮去除率保持在87 9%以上,优于活性炭处理方法。实验还发现,低剂量臭氧投加量的影响不如废水流量及水质变化影响显著,前者既可提高有机物的可生化性,又不会对微生物产生抑制作用。 相似文献
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Guopeng Wang Tao Wu Yujiang Li Dejun Sun Yan Wang Xinghai Huang Guochen Zhang Ruihong Liu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2012,87(5):623-628
BACKGROUND: The removal of antibiotic ampicillin sodium using H2O2 and modified granular activated carbon (GAC) is discussed. Two types of modified activated carbons were used in experiment to catalyze ·OH production from H2O2. One was modified with base (NaOH; called B‐GAC), the other was modified with Fe(NO3)3 (Fe‐GAC) and the nominal Fe metal loading was 5 wt%. In the experiment, pH, contact time, dosage of activated carbon and H2O2 and initial concentration of ampicillin sodium were investigated to determine their influence on the removal efficiency. The stability of Fe‐GAC was also evaluated. RESULTS: With an initial ampicillin sodium concentration of 200 mg L?1, 85.2% of chemical oxygen demand (COD) and 76.4% of total organic carbon (TOC) can be removed with 8.0 g L?1 of B‐GAC and 80 mg L?1 of H2O2 (at pH 5.0). For the Fe‐GAC/H2O2 process, with 5.0 g L?1 of activated carbon and 80 mg L?1 of H2O2, COD and TOC removal can be elevated to 91.2% and 79.5% (at pH 3.0), respectively. CONCLUSION: The integration of activated carbon and H2O2 treatment was more effective for the removal of ampicillin from aqueous solution than using activated carbon alone. In the process, adsorption played a dominant role and the addition of a small amount of H2O2 accelerated the reaction rate and improved the removal efficiency. pH also greatly affected removal efficiency. Copyright © 2011 Society of Chemical Industry 相似文献
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气液等离子体过程强化技术是20世纪80年代发展起来的一门新兴交叉学科,在高级氧化过程、液相化学合成和纳米材料制备等领域具有巨大的研究与应用价值。从化学工程的角度理解,气液等离子体过程强化技术的本质是特殊外场作用下的多相传递与反应过程,其中涉及高能电子碰撞、化学活性组分氧化、紫外光解和冲击波等多种物理与化学作用。由于气液等离子体过程强化技术本身的复杂性及多学科交叉性,对其复杂的物理与化学耦合机理还未得到充分认识,同时缺乏对气液等离子体反应器的系统研究及设计指导,从而极大程度地限制了该技术的进一步应用和发展。为全面认识气液等离子体过程强化技术,本文综述了近年来有关气液等离子体过程强化技术的诊断及机理研究进展,并剖析了气液等离子体反应器的设计思路,同时回顾和展望了气液等离子体高级氧化过程的最新研究进展,讨论了气液等离子体过程强化技术的研究方向。 相似文献
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Steven Van Geluwe Chris Vinckier Emil Bobu Christian Trandafir Jeroen Vanelslander Leen Braeken Bart Van der Bruggen 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2010,85(11):1480-1488
BACKGROUND: Membrane fouling by humic acids limits the water recovery of nanofiltration in drinking water production. This article investigates if membrane fouling can be reduced by decomposition of humic acids in the concentrate stream by O3 oxidation. RESULTS: At a specific O3 dose of 2.11 g O3 per g COD (17.0 g m?3 O3 (g) for 20 min), a COD reduction of 38% and a hydrophobic COD reduction of 69% is achieved. The membrane permeability of the ozonated solution by NF 270 membranes is higher (20.6 × 10?9 L s?1 m?2 Pa?1) than the permeability if the untreated solution is filtered (2.4 × 10?9 L s?1 m?2 Pa?1). The COD retention of the ozonated solution was similar to the retention of the untreated samples. The addition of H2O2 allows a better mineralization degree, i.e. UVA removal increased from 53% to 66% if H2O2 was added as from 10 min oxidation at the same molar flow rate as O3. CONCLUSION: O3 oxidation can substantially alleviate membrane fouling by humic acids in nanofiltration systems and the addition of H2O2 can slightly improve its decomposition. Copyright © 2010 Society of Chemical Industry 相似文献