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1.
Vegetable oils are a promising alternative among the different diesel fuel alternatives. However, the high viscosity, poor volatility and cold flow characteristics of vegetable oils can cause some problems such as injector coking, severe engine deposits, filter gumming, piston ring sticking and thickening of lubrication oil from long-term use in diesel engines. These problems can be eliminated or minimized by transesterification of the vegetable oils to form monoesters. These monoesters are known as biodiesel. The important advantages of biodiesel are lower exhaust gas emissions and its biodegradability and renewability compared with petroleum-based diesel fuel. Although the transesterification improves the fuel properties of vegetable oil, the viscosity and volatility of biodiesel are still worse than that of petroleum diesel fuel. The energy of the biodiesel can be released more efficiently with the concept of low heat rejection (LHR) engine. The aim of this study is to apply LHR engine for improving engine performance when biodiesel is used as an alternative fuel. For this purpose, a turbocharged direct injection (DI) diesel engine was converted to a LHR engine and the effects of biodiesel (produced from sunflower oil) usage in the LHR engine on its performance characteristics have been investigated experimentally. The results showed that specific fuel consumption and the brake thermal efficiency were improved and exhaust gas temperature before the turbine inlet was increased for both fuels in the LHR engine.  相似文献   

2.
非直喷式增压柴油机燃用生物柴油的性能与排放特性   总被引:36,自引:0,他引:36  
研究了非直喷式增压柴油机燃用柴油一生物柴油混合燃料的性能和排放特性。未对原机作任何调整和改动,研究了不同生物柴油掺混比例的混合燃料对功率、油耗、烟度和NOx排放的影响。结果表明:非直喷式柴油机燃用生物柴油后柴油机功率略有下降,油耗有所上升,烟度大幅下降,NOx排放增加明显。油耗、烟度和NOx的变化均与生物柴油掺混比例呈线性关系,合适的生物柴油掺混比例即可以保持柴油机的性能,又可有效地降低碳烟排放,且不引起NOx排放的显著变化。对于该增压柴油机,掺混生物柴油对外特性下的排放影响最大,影响最小的为标定转速下的负荷特性。不论是全负荷还是部分负荷,燃用生物柴油时低速下的烟度降低和NOx上升幅度均比高速时大,而同转速下高负荷时烟度降低和NOx上升更为明显。  相似文献   

3.
Recent concerns over the environment, increasing fuel prices and scarcity of its supply have promoted the interest in development of the alternative sources for petroleum fuels. At present, biodiesel is commercially produced from the refined edible vegetable oils such as sunflower oil, palm oil and soybean oil, etc. by alkaline-catalyzed esterification process. This process is not suitable for production of biodiesel from many unrefined non-edible vegetable oils because of their high acid value. Hence, a two-step esterification method is developed to produce biodiesel from high FFA vegetable oils. The biodiesel production method consists of acid-catalyzed pretreatment followed by an alkaline-catalyzed transesterification. The important properties of methyl esters of rubber seed oil are compared with other esters and diesel. Pure rubber seed oil, diesel and biodiesel are used as fuels in the compression ignition engine and the performance and emission characteristics of the engine are analyzed. The lower blends of biodiesel increase the brake thermal efficiency and reduce the fuel consumption. The exhaust gas emissions are reduced with increase in biodiesel concentration. The experimental results proved that the use of biodiesel (produced from unrefined rubber seed oil) in compression ignition engines is a viable alternative to diesel.  相似文献   

4.
Abstract

The purpose of this work is to investigate biodiesel production processes from vegetable oils. Biodiesel fuel can be made from new or used vegetable oils and animal fats, which are non-toxic, biodegradable, renewable resources. The vegetable oil fuels were not acceptable because they were more expensive than petroleum fuels. Biodiesel has become more attractive recently because of its environmental benefits. With recent increases in petroleum prices and uncertainties concerning petroleum availability, there is renewed interest in vegetable oil fuels for diesel engines. Dilution of oils with solvents and microemulsions of vegetable oils lowers the viscosity, and some engine performance problems still exist. The purpose of the transesterification process is to lower the viscosity of the oil. Pyrolysis produces more biogasoline than biodiesel fuel.  相似文献   

5.
《Biomass & bioenergy》2003,24(2):141-149
Vegetable oils are produced from numerous oil seed crops. While all vegetable oils have high-energy content, most require some processing to assure safe use in internal combustion engines. Some of these oils already have been evaluated as substitutes for diesel fuels. With the exception of rape seed oil which is the principal raw material for biodiesel fatty acid methyl esters, sunflower oil, corn oil and olive oil, which are abundant in Southern Europe, along with some wastes, such as used frying oils, appear to be attractive candidates for biodiesel production. In this paper, fuel consumption and exhaust emissions measurements from a single cylinder, stationary diesel engine are described. The engine was fueled with pure marine diesel fuel and blends containing two types of biodiesel, at proportions up to 50%. The two types of biodiesel appeared to have equal performance, and irrespective of the raw material used for their production, their addition to the marine diesel fuel improved the particulate matter, unburned hydrocarbons, nitrogen oxide and carbon monoxide emissions.  相似文献   

6.
This article is a literature review on biodiesel production, combustion, performance and emissions. This study is based on the reports of about 130 scientists who published their results between 1980 and 2008. As the fossil fuels are depleting day by day, there is a need to find out an alternative fuel to fulfill the energy demand of the world. Biodiesel is one of the best available sources to fulfill the energy demand of the world. More than 350 oil-bearing crops identified, among which some only considered as potential alternative fuels for diesel engines. The scientists and researchers conducted tests by using different oils and their blends with diesel.A vast majority of the scientists reported that short-term engine tests using vegetable oils as fuels were very promising but the long-term test results showed higher carbon built up and lubricating oil contamination resulting in engine failure. They concluded that vegetable oils, either chemically altered or blended with diesel to prevent the engine failure. It was reported that the combustion characteristics of biodiesel are similar as diesel and blends were found shorter ignition delay, higher ignition temperature, higher ignition pressure and peak heat release. The engine power output was found to be equivalent to that of diesel fuel. In addition, it observed that the base catalysts are more effective than acid catalysts and enzymes.  相似文献   

7.

Biodiesel from transesterification of vegetable oils is an excellent alternative fuel. There is, however, a need to develop a direct process for conversion of vegetable oils into gasoline-competitive biodiesel and other petroleum products. Methyl esters of vegetable oils have several outstanding advantages among other new-renewable and clean engine fuel alternatives. The purpose of the transesterification process is to lower the viscosity of vegetable oil. Compared to No. 2 diesel fuel, all of the vegetable oils are much more viscous, whereas methyl esters of vegetable oils are slightly more viscous. The methyl esters are more volatile than those of the vegetable oils. Conversion of vegetable oils to useful fuels involves the pyrolysis and catalytic cracking of the oils into lower molecular products. Pyrolysis produces more biogasoline than biodiesel fuel. Soap pyrolysis products of vegetable oils can be used as alternative diesel engine fuel. The soaps obtained from the vegetable oils can be pyrolyzed into hydrocarbon-rich products. Zinc chloride catalyst contributed greatly to high amounts of hydrocarbons in the liquid product. The yield of ZnCl 2 catalytic conversion of the soybean oil reached the maximum 79.9% at 660 K.  相似文献   

8.
Renewable fuels produced from vegetable oils are an attractive alternative to fossil-based fuel. Different type of fuels can be derived from these triglycerides. One of them is biodiesel which is a mono alkyl ester of the vegetable oil. The biodiesel is produced by transesterification of the oil with an alcohol in the presence of a catalyst. Another kind of fuel (which is similar to petroleum-derived diesel) can be produced from the vegetable oil using hydroprocessing technique. This method uses elevated temperature and pressure along with a catalyst to produce a fuel termed as ‘renewable diesel’. The fuel produced has properties that are beneficial for the engine as well as the environment. It has high cetane number, low density, excellent cold flow properties and same materials can be used as are used for engine running on petrodiesel. It can effectively reduce NOx, PM, HC, CO emissions and unregulated emissions as well as greenhouse gases as compared to diesel. The fuel is also beneficial for the after-treatment systems. Trials in the field have shown that the volumetric fuel consumption of renewable diesel is higher than petrodiesel and nearly proportional to the volumetric heating value. The present review focuses on the hydroprocessing technique used for the renewable diesel production and the effect of different parameters such as catalyst, reaction temperature, hydrogen pressure, liquid hourly space velocity (LHSV) and H2/oil ratio on oil conversion, diesel selectivity, and isomerization. The review also summarizes the effect; renewable diesel has on combustion, performance, and emission characteristics of a compression ignition engine.  相似文献   

9.
Vegetable oil is one of the main first generation liquid biofuels. The fuel characteristics of vegetable oil such as viscosity and atomization cannot be accommodated by existing diesel engines. An alternate process has been developed to improve the fuel characteristics of vegetable oils through the process of alcoholysis to produce a fuel called biodiesel. It can be used in engines as substitute for fossil fuel. This paper reviews the characteristics of different oils available for biodiesel production and the production technologies, engine performance using vegetable oil and biodiesel, and emission studies. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

10.
《Applied Thermal Engineering》2007,27(13):2314-2323
The scarce and rapidly depleting conventional petroleum resources have promoted research for alternative fuels for internal combustion engines. Among various possible options, fuels derived from triglycerides (vegetable oils/animal fats) present promising “greener” substitutes for fossil fuels. Vegetable oils, due to their agricultural origin, are able to reduce net CO2 emissions to the atmosphere along with import substitution of petroleum products. However, several operational and durability problems of using straight vegetable oils in diesel engines reported in the literature, which are because of their higher viscosity and low volatility compared to mineral diesel fuel.In the present research, experiments were designed to study the effect of reducing Jatropha oil’s viscosity by increasing the fuel temperature (using waste heat of the exhaust gases) and thereby eliminating its effect on combustion and emission characteristics of the engine. Experiments were also conducted using various blends of Jatropha oil with mineral diesel to study the effect of reduced blend viscosity on emissions and performance of diesel engine. A single cylinder, four stroke, constant speed, water cooled, direct injection diesel engine typically used in agricultural sector was used for the experiments. The acquired data were analyzed for various parameters such as thermal efficiency, brake specific fuel consumption (BSFC), smoke opacity, CO2, CO and HC emissions. While operating the engine on Jatropha oil (preheated and blends), performance and emission parameters were found to be very close to mineral diesel for lower blend concentrations. However, for higher blend concentrations, performance and emissions were observed to be marginally inferior.  相似文献   

11.
In order to meet the energy requirements, there has been growing interest in alternative fuels like biodiesels, methyl alcohol, ethyl alcohol, biogas, hydrogen and producer gas to provide a suitable diesel oil substitute for internal combustion engines. Vegetable oils present a very promising alternative to diesel oil since they are renewable and have similar properties. Vegetable oils offer almost the same power output with slightly lower thermal efficiency when used in diesel engine [Srivastava A, Prasad R. Triglycerides-based diesel fuels. Renew Sustain Energy Rev 2000;4:111–33. [1]; Vellguth G. Performance of vegetable oils and their monoesters as fuels for diesel engines. SAE 831358, 1983. [2]; Demirbas A. Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods. Int J Prog Energy Combust Sci 2005;31:466–87. [3]; Jajoo BN, Keoti RS. Evaluation of vegetable oils as supplementary fuels for diesel engines. In: Proceedings of the XV national conference on IC engines and combustion, Anna University Chennai, 1997. [4]; Altin R, Cetinkaya S, Yucesu HS. The potential of using vegetable oil fuels as fuel for diesel engines. Int J Energy Convers Manage 2000;42:529–38, 248. [5]; Gajendra Babu MK, Chandan Kumar Das LM. Experimental investigations on a Karanja oil methyl ester fuelled DI diesel engine. SAE 2006-01-0238, 2006. [6]; Agarwal D, Kumar Agarwal A. Performance and emission characteristics of a Jatropha oil (preheated and blends) in a direct injection compression ignition engine. Int J Appl Therm Eng 2007;27:2314–23. [7]]. Research in this direction with edible oils have yielded encouraging results, but their use as fuel for diesel engine has limited applications due to higher domestic requirement [Scholl Kyle W, Sorenson Spencer C. Combustion Analysis of soyabean oil methyl ester in a direct injection diesel engine. SAE 930934, 1993. [8]; Nwafor OMI. Effect of advanced injection timing on the performance of rapeseed oil in diesel engines. Int J Renew Energy 2000;21:433–44. [9]; Nwafor OMI. The effect of elevated fuel inlet temperature on performance of diesel engine running on neat vegetable oil at constant speed conditions. Renew Energy 2003;28:171–81. [10]]. In view of this, Honge oil (Pongamia Pinnata Linn) being non-edible oil could be regarded as an alternative fuel for CI engine applications. The viscosity of Honge oil is reduced by transesterification process to obtain Honge oil methyl ester (HOME).Gasification is a process in which solid biomass is converted into a mixture of combustible gases, which complete their combustion in an IC engine. Hence, producer gas can act as a promising alternative fuel, especially for diesel engines by substituting considerable amount of diesel fuels. Downdraft moving bed gasifiers coupled with IC engine are a good choice for moderate quantities of available biomass, up to 500 kW of electric power. Hence, bioderived gas and vegetable liquids appear more attractive in view of their friendly environmental nature. Since vegetable oils produce higher smoke emissions, dual fuel operation could be adopted for improving their performance.  相似文献   

12.
In this article, the status of fat and oil derived diesel fuels with respect to fuel properties, engine performance, and emissions is reviewed. The fuels considered are primarily the methyl esters of fatty acids derived from a variety of vegetable oils and animal fats, and referred to as biodiesel. The major obstacle to widespread use of biodiesel is the high cost relative to petroleum. Economics of biodiesel production are discussed, and it is concluded that the price of the feedstock fat or oil is the major factor determining biodiesel price.Biodiesel is completely miscible with petroleum diesel fuel, and is generally tested as a blend. The use of biodiesel in neat or blended form has no effect on the energy based engine fuel economy. The lubricity of these fuels is superior to conventional diesel, and this property is imparted to blends at levels above 20 vol%. Emissions of PM can be reduced dramatically through use of biodiesel in engines that are not high lube oil emitters. Emissions of NOx increase significantly for both neat and blended fuels in both two- and four-stroke engines. The increase may be lower in newer, lower NOx emitting four-strokes, but additional data are needed to confirm this conclusion. A discussion of available data on unregulated air toxins is presented, and it is concluded that definitive studies have yet to be performed in this area. A detailed discussion of important biodiesel properties and recommendations for future research is presented. Among the most important recommendations is the need for all future studies to employ biodiesel of well-known composition and purity, and to report detailed analyses. The purity levels necessary for achieving adequate engine endurance, compatibility with coatings and elastomers, cold flow properties, stability, and emissions performance must be better defined.  相似文献   

13.
《Biomass & bioenergy》2005,28(1):77-86
Vegetable oils and their methyl/ethyl esters are alternative renewable fuels for compression ignition engines. Different kinds of vegetable oils and their methyl/ethyl esters have been tested in diesel engines. However, tobacco seed oil and tobacco seed oil methyl ester have not been tested in diesel engines, yet. Tobacco seed oil is a non-edible vegetable oil and a by-product of tobacco leaves production. To the author's best knowledge, this is the first study on tobacco seed oil methyl ester as a fuel in diesel engines.In this study, potential tobacco seed production throughout the world, the oil extraction process from tobacco seed and the transesterification process for biodiesel production were examined. The produced tobacco seed oil methyl ester was characterized by exposing its major properties. The effects of tobacco seed oil methyl ester addition to diesel No. 2 on the performance and emissions of a four cycle, four cylinder turbocharged indirect injection (IDI) diesel engine were examined at both full and partial loads. Experimental results showed that tobacco seed oil methyl ester can be partially substituted for the diesel fuel at most operating conditions in terms of performance parameters and emissions without any engine modification and preheating of the blends.  相似文献   

14.
This paper reviews the production and characterization of biodiesel (BD or B) as well as the experimental work carried out by many researchers in this field. BD fuel is a renewable substitute fuel for petroleum diesel or petrodiesel (PD) fuel made from vegetable or animal fats. BD fuel can be used in any mixture with PD fuel as it has very similar characteristics but it has lower exhaust emissions. BD fuel has better properties than that of PD fuel such as renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. There are more than 350 oil bearing crops identified, among which only sunflower, safflower, soybean, cottonseed, rapeseed and peanut oils are considered as potential alternative fuels for diesel engines. The major problem associated with the use of pure vegetable oils as fuels, for Diesel engines are caused by high fuel viscosity in compression ignition. Dilution, micro-emulsification, pyrolysis and transesterification are the four techniques applied to solve the problems encountered with the high fuel viscosity. Dilution of oils with solvents and microemulsions of vegetable oils lowers the viscosity, some engine performance problems still exist. The viscosity values of vegetable oils vary between 27.2 and 53.6 mm2/s whereas those of vegetable oil methyl esters between 3.59 and 4.63 mm2/s. The viscosity values of vegetable oil methyl esters highly decreases after transesterification process. Compared to no. 2 diesel fuel, all of the vegetable oil methyl esters were slightly viscous. The flash point values of vegetable oil methyl esters are highly lower than those of vegetable oils. An increase in density from 860 to 885 kg/m3 for vegetable oil methyl esters or biodiesels increases the viscosity from 3.59 to 4.63 mm2/s and the increases are highly regular. The purpose of the transesterification process is to lower the viscosity of the oil. The transesterfication of triglycerides by methanol, ethanol, propanol and butanol, has proved to be the most promising process. Methanol is the commonly used alcohol in this process, due in part to its low cost. Methyl esters of vegetable oils have several outstanding advantages among other new-renewable and clean engine fuel alternatives. The most important variables affecting the methyl ester yield during the transesterification reaction are molar ratio of alcohol to vegetable oil and reaction temperature. Biodiesel has become more attractive recently because of its environmental benefits. Biodiesel is an environmentally friendly fuel that can be used in any diesel engine without modification.  相似文献   

15.
In this investigation, castor methyl ester (CME) was prepared by transesterification using potassium hydroxide (KOH) as catalyst and was used in four stroke, single cylinder variable compression ratio type diesel engine. Tests were carried out at a rated speed of 1500 rpm at different loads. Straight vegetable oils pose operational and durability problems when subjected to long term usages in diesel engines. These problems are attributed to high viscosity, low volatility and polyunsaturated character of vegetable oils. The process of transesterification is found to be an effective method of reducing vegetable oil viscosity and eliminating operational and durability problems. The important properties of methyl ester of castor seed oil are compared with diesel fuel. The engine performance was analysed with different blends of biodiesel and was compared with mineral diesel. It was concluded that the lower blends of biodiesel increased the break thermal efficiency and reduced the fuel consumption. The exhaust gas temperature increased with increasing biodiesel concentration. The results proved that the use of biodiesel (produced from castor seed oil) in compression ignition engine is a viable alternative to diesel.  相似文献   

16.
Performance of rapeseed oil blends in a diesel engine   总被引:5,自引:0,他引:5  
The concept that 100% vegetable oil cannot be used safely in a direct-injection diesel engine for long periods of time has been stressed by many researchers. Short-term engine tests indicate good potential for vegetable oil fuels. Long-term endurance tests may show serious problems in injector coking, ring sticking, gum formation, and thickening of lubricating oil. These problems are related to the high viscosity and nonvolatility of vegetable oils, which cause inadequate fuel atomization and incomplete combustion. Fuel blending is one method of reducing viscosity. This paper presents the results of an engine test on three fuel blends. Test runs were also made on neat rapeseed oil and diesel fuel as bases for comparison. There were no significant problems with engine operation using these alternative fuels. The test results showed increases in brake thermal efficiency as the amount of rapeseed oil in the blends increases. Reduction of power-output was also noted with increased amount of rapeseed oil in the blends. Test results include data on performance and gaseous emissions. Crankcase oil analyses showed a reduction in viscosity. Friction power was noted to increase as the amount of diesel fuel in the blend increases.  相似文献   

17.
Methyl and ethyl esters as biodiesel fuels were prepared from linseed oil with transesterification reaction in non-catalytic supercritical fluids conditions. Biodiesel fuel is a renewable substitute fuel for petroleum diesel fuel made from vegetable or animal fats. Biodiesel fuel has better properties than that of petroleum diesel fuel such as renewable, biodegradable, non-toxic, and essentially free of sulfur and aromatics. The purpose of the transesterification process is to lower the viscosity of the oil. The viscosity values of linseed oil methyl and ethyl esters highly decreases after transesterification process. The viscosity values of vegetable oils vary between 27.2 and 53.6 mm2 s?1, whereas those of vegetable oil methyl esters between 3.59 and 4.63 mm2 s?1. Compared with no. 2 diesel fuel, all of the vegetable oil methyl esters were slightly viscous. The flash point values of vegetable oil methyl esters are highly lower than those of vegetable oils. The transesterification of linseed oil in supercritical fluids such as methanol and ethanol has proved to be the most promising process. Methanol is the commonly used alcohol in this process, due in part to its low cost. Methyl esters of vegetable oils have several outstanding advantages among other new-renewable and clean engine fuel alternatives. The most important variables affecting the methyl ester yield during the transesterification reaction are molar ratio of alcohol to vegetable oil and reaction temperature. Biodiesel has become more attractive recently because of its environmental benefits. Biodiesel is an environmentally friendly fuel that can be used in any diesel engine without modification.  相似文献   

18.
Progress in biodiesel processing   总被引:3,自引:0,他引:3  
Biodiesel is a notable alternative to the widely used petroleum-derived diesel fuel since it can be generated by domestic natural sources such as soybeans, rapeseeds, coconuts, and even recycled cooking oil, and thus reduces dependence on diminishing petroleum fuel from foreign sources. The injection and atomization characteristics of the vegetable oils are significantly different than those of petroleum-derived diesel fuels, mainly as the result of their high viscosities. Modern diesel engines have fuel-injection system that is sensitive to viscosity change. One way to avoid these problems is to reduce fuel viscosity of vegetable oil in order to improve its performance. The conversion of vegetable oils into biodiesel is an effective way to overcome all the problems associated with the vegetable oils. Dilution, micro-emulsification, pyrolysis, and transesterification are the four techniques applied to solve the problems encountered with the high fuel viscosity. Transesterification is the most common method and leads to monoalkyl esters of vegetable oils and fats, now called biodiesel when used for fuel purposes. The methyl ester produced by transesterification of vegetable oil has a high cetane number, low viscosity and improved heating value compared to those of pure vegetable oil which results in shorter ignition delay and longer combustion duration and hence low particulate emissions.  相似文献   

19.
The present review aims to study the prospects and opportunities of introducing vegetable oils and their derivatives as fuel in diesel engines. In our country the ratio of diesel to gasoline fuel is 7:1, depicting a highly skewed situation. Thus, it is necessary to replace fossil diesel fuel by alternative fuels. Vegetable oils present a very promising scenario of functioning as alternative fuels to fossil diesel fuel. The properties of these oils can be compared favorably with the characteristics required for internal combustion engine fuels. Fuel-related properties are reviewed and compared with those of conventional diesel fuel. Peak pressure development, heat release rate analysis, and vibration analysis of the engine are discussed in relation with the use of bio-diesel and conventional diesel fuel. Optimization of alkali-catalyzed transesterification of Pungamia pinnata oil for the production of bio-diesel is discussed. Use of bio-diesel in a conventional diesel engine results in substantial reduction in unburned hydrocarbon (UBHC), carbon monoxide (CO), particulate matters (PM) emission and oxide of nitrogen. The suitability of injection timing for diesel engine operation with vegetable oils and its blends, environmental considerations are discussed. Teardown analysis of bio-diesel B20-operated vehicle are also discussed.  相似文献   

20.
《能源学会志》2020,93(3):953-961
There is a high potential for plant oils as alternative fuel for low and medium speed diesel engines, making petroleum-derived fuels likely to be replaced in these types of engines. Vegetable oils have important advantages over both heavy fuel oil (HFO) and marine gas oil (MGO), the fuels currently used in diesel power plants by large two stroke low-speed diesel engines and by medium speed diesel engines, respectively. The emission of certain pollutants and greenhouse gases like SOx, soot and, mainly, CO2 can be reduced by using vegetable oils in these types of engines. This work discusses the potential of vegetable oils as fuel for power plant diesel engines and the problems that can be derived from their use. Current experiences with medium speed diesel engines together with the analysis carried out in this paper indicate that vegetable oils can substitute HFO and MGO, without almost any engine modification.  相似文献   

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