丝网印刷制备钡铁氧体永磁厚膜的研究

采用丝网印刷方法制备钡铁氧体永磁厚膜,研究了热压烧结对钡铁氧体厚膜性能的影响.XRD结果表明,在常压烧结和热压烧结的样品中均有明显的BaFe12O19衍射峰.与常压烧结相比,热压烧结的样品表面孔洞明显减少,致密性得到了很大的提高.并且热压烧结的样品磁性能也有明显的提高,其剩磁比可达0.71,矫顽力达到304.1kA/m,而常压烧结样品剩磁比和矫顽力仅为0.51和278.8kA/m.     

丝网印刷制备钡铁氧体厚膜的研究

用丝网印刷方法制备钡铁氧体(BaFe12O19)厚膜,研究烧结温度对钡铁氧体厚膜样品的微观结构和磁性能的影响。结果表明,随着烧结温度的增加,样品的晶粒尺寸逐渐增大。矫顽力随着烧结温度的升高先增加再降低,而剩磁比则随着烧结温度的增加而降低。     

空心微珠铁氧体复合粉体的改性与吸波性能

研究了柠檬酸盐溶胶-凝胶方法制备空心微珠-钡、锶、钴镍钡铁氧体复合粉体的微观形貌, 采用化学添加剂改善铁氧体的包覆性能. SEM、EDS分析表明铁氧体在空心微珠表面的包覆状态与铁氧体种类无关; 在前驱体中加入乙二醇或聚乙二醇可以使铁氧体对空心微珠的包覆更加完整、牢固致密. 用网络分析仪测试了C波段5.0～6.5GHz、X波段8.2～12.4GHz、Ku波段12.5～18.0GHz内1.8mm厚铁氧体空心微珠复合粉体制备的吸波涂层的微波损耗. 试验表明：铁氧体空心微珠复合粉体具有良好的电磁吸波性能, 吸波涂层在5～18GHz内微波反射损失总体上大于单纯铁氧体涂层; 加入乙二醇或聚乙二醇有助于提高涂层的吸波效果.     

Bi2O3对低烧Co-Ti替代钡铁氧体显微结构与高频磁性的影响

用化学共沉淀法制备了Co-Ti替代钡铁氧体磁粉,结合相结构与显微形貌分析研究了Bi2O3掺杂和Co-Ti替代量对低温烧结钡铁氧体高频磁性的影响.Bi2O3的加入明显提高了低温烧结钡铁氧体的磁导率,磁粉粒径在200nm左右时合适的Bi2O3添加量为2%(质量分数);原料磁粉的粒度越大,表面形貌越完整,烧结瓷体的磁导率就越高;替代量在1.20～1.30的范围内,添加2%(质量分数)的Bi2O3可以在900℃低温烧结出磁导率μ'＞10,截止频率不低于1GHz的Co-Ti替代钡铁氧体.     

球磨工艺对钡铁氧体浆料粒径和磁性能的影响

研究钡铁氧体永磁材料制备过程中,球磨时间和分级球磨等球磨工艺对浆料粒度的影响,以及浆料粒度对钡铁氧体磁性能的影响。结果表明:在高能球磨过程中,浆料粒径随球磨时间增加呈减小趋势,当球磨时间超过其极限值后基本保持不变。采用分级球磨后浆料粒径明显减小,且颗粒粒径分布均匀,但只有采用合适的球磨工艺才能达到最好的分散效果。钡铁氧体永磁材料的取向度、剩余磁化强度随颗粒粒径的减小呈增大趋势。     

球磨玻璃粉对低温烧结型浆料烧结膜孔洞的影响

采用机械球磨后的玻璃粉制成浆料烧结膜.讨论了不同的球磨时间对玻璃粉粒径的影响.通过SEM、X射线照相技术观察分析了浆料烧结膜的表面形貌及孔洞率,研究了不同球磨时间的玻璃粉对浆料烧结膜的表面形貌及孔洞率的影响.结果表明,球磨24h的玻璃粉平均粒径为3.5μm.这种玻璃粉制成的浆料烧结膜表面平滑致密,孔洞率最小,满足浆料的使用要求.     

吸附钡铁氧体的多孔陶粒吸波材料制备及其性能

以硝酸铁、硝酸钡、柠檬酸为原料,采用溶胶-凝胶法合成钡铁氧体溶胶,将其吸附于多孔陶粒表面和微孔中,经焙烧制备得到电磁吸波功能陶粒;再将该功能陶粒用作集料制备新型水泥基复合吸波材料。研究了合成的钡铁氧体的物相、形貌、复介电常数和复磁导率;结果表明合成的钡铁氧体纯度高,合成温度对其结晶度和晶体形貌有影响,经1000℃煅烧制得的钡铁氧体具有良好的吸波能力;对制得的功能陶粒进行了测试,结果表明钡铁氧体能包覆至陶粒表面和孔壁上;采用弓形法测得的功能陶粒水泥基吸波材料在8~18GHz频率范围内的电磁波反射率明显优于采用碎石和普通陶粒制备的试样。     

钡铁氧体磁粉在液相中的分散性能

为了提高分散作用效果,选用聚乙二醇-20000(PEG-20000)、十二烷基硫酸钠(SDS)及二者组成的复配分散剂,利用机械球磨与添加分散剂相结合的分散方法制备了钡铁氧体浆料,通过考察分散剂的用量、浆料的pH值、zeta电位对分散性的影响,根据红外光谱分析,研究了分散剂的分散效果及作用机理,并测定了分散前后磁场成型各向异性钡铁氧体材料的磁性能。结果表明:加入分散剂可以改善钡铁氧体的分散效果,且SDS和PEG-20000的用量为钡铁氧体质量的1%和2%时,分散效果最好。SDS和PEG-20000均为静电和空间位阻稳定作用。分散后磁场成型各向异性钡铁氧体材料的磁性能得到提高。     

钡铁氧体的表面改性与红外隐身性能的研究

以硝酸铁、硝酸钡和柠檬酸为原料，采用溶胶．凝胶自蔓延法制得钡铁氧体。为使钡铁氧体具有红外隐身性能，利用化学镀工艺对其表面进行金属化改性可以得到表面完整包覆的导电粉末。借助于XRD、SEM等测试手段，对材料的晶体结构及表面形貌进行了观察和分析表征，利用FT-IR的漫反射系统对钡铁氧体及钡铁氧体表面改性材料的红外隐身性能进行测试，结果表明：所制得的钡铁氧体为M型钡铁氧体，在8～14μm的平均红外发射率为0．8542；而经过表面改性后的钡铁氧体，在8～14μm的平均红外发射率为0．5910，具有良好的红外隐身性能。     

棒状纳米钡铁氧体的制备及镧掺杂对其性能的影响

为了研究制备工艺和掺杂对纳米钡铁氧体形貌及性能的影响规律,采用柠檬酸溶胶-凝胶法与燃烧相结合的方法制备出了BaFe12O19及掺镧钡铁氧体棒状纳米粒子.采用X射线衍射仪（XRD）,透射电镜（TEM）和磁强样品振荡计（VSM）对BaFe12O19及掺镧钡铁氧体的结构、形貌及磁性能进行了表征.通过对几个主要参数的摸索,得出制备棒状钡铁氧体的最佳工艺条件：pH值为4,煅烧温度为850℃,煅烧时间2h.该条件下制得的BaFe12O19样品分散均匀,呈棒状,直径约为50nm,长径比为6：1,矫顽力高达43460e;采用同样的方法,对钡铁氧体进行了稀土镧元素掺杂,所得掺镧钡铁氧体粒度在纳米范围,也呈现明显的棒状.另外,通过掺杂稀土元素镧使钡铁氧体的成相得到改善,对钡铁氧体的磁性能有一定程度的影响.     

Synthesis of <Emphasis Type="Italic">c</Emphasis>-Axis Barium Hexaferrite Puck for Communication Application

Recent progress and needs by telecommunication industries require thick barium ferrite film with excellent magnetic properties for microwave monolithic integrated circuit applications. In the present work we show a novel barium hexaferrite (BaFe₁₂O₁₉, or BaM) composite material, BaFe₁₂O₁₉ nanopowder mixture with epoxy, as a low-cost solution to fabricate thick BaM films. The mix is used to fabricate thick puck of BaM within an alumina substrate. The resulting barium hexaferrite thick pucks have good magnetic properties with a magnetization saturation 4πMs between 2000 and 2500 Gauss, a perpendicular coercivity of 3800 to 4000 Oe and a close to 0.9 squareness. In addition, we have successfully fabricated and tested a self-biased microwave circulator by depositing and patterning copper contact lines on the alumina substrate and the BaM thick puck.     

Complex Permittivity and Permeability of Co$_2$U (Ba$_4$Co$_2$Fe$_36$O$_60$) Hexaferrite Bulk and Composite Thick Films at Radio and Microwave Frequencies

We measured dielectric, magnetic, and microwave properties of Co ₂U hexaferrite (Ba₄Co₂Fe₃₆O ₆₀) polycrystalline bulk and composite thick film samples, and studied the effect of annealing temperature on phase formation and microstructure. We synthesized the bulk samples from a precursor prepared by the citrate method. The values of dielectric constant at radio frequencies (50 Hz-1 MHz) of the bulk Co₂U12 sample sintered at 1200degC are much higher, and the resistivities are lower, compared to M-type barium hexaferrites. Coercivity is also low, having a value of 5 G for the Co₂U12 sample, whereas the saturation magnetization value is 59 emu/g, which is comparable to that of M-type hexaferrites. We also measured the complex permittivity and permeability for Co₂U12 samples at microwave frequencies and found the values high compared to M-type barium hexaferrite at these frequencies. Thick composite films were prepared from a ferrite-polymer mix, and all the above properties were studied for these films. We observed that these thick films have lower values of dielectric and magnetic parameters both at low and microwave frequencies. We measured microwave-absorbing properties for the ferrite-polymer sample (ferrite to polymer ratio 70/30) which showed a maximum reflection loss of -37.5 dB at 11.5 GHz for the 3.5-mm-thick sample     

热处理温度对M-Ba铁氧体微米纤维结构和磁性能的影响

以柠檬酸和金属盐为原料,采用有机凝胶先驱体转化法成功制备了直径为500～600nm的钡铁氧体(BaFe12O19)微米纤维。通过XRD、SEM和VSM等技术对所制备的目标纤维进行了表征。结果表明,经750℃焙烧2h后,可获得M-Ba铁氧体纯相。随着焙烧温度的升高,晶粒逐渐长大,经850℃焙烧2h后,纤维主要由比较规则的片状晶粒组成。钡铁氧体纤维的磁性能主要受晶粒尺寸和测试温度的影响。经950℃焙烧2h后,组成纤维的晶粒尺寸约为62nm,室温下测得的饱和磁化强度和矫顽力均取得最大值,分别约为67A.m2/kg和328kA/m。在液氮(77K)条件下,纤维的饱和磁化强度有显著提高,最大值约为87A.m2/kg,这主要是由于纳米晶的表面自旋有序程度提高造成的。     

Binder chemistry,adhesion and structure of interfaces in thick-film metallized aluminium nitride substrates

Aluminium nitride substrates from three different sources were metallized by standard thick film processing using gold conductor pastes, Pd-Ag paste, and a ruthenium oxide resistor paste. Screen printed pastes were fired in a typical three-zone furnace to obtain metallized AIN substrates. Interfacial reaction zones were studied by microscopic (optical and scanning electron microscopy) and electron beam microprobe analysis techniques. The elements in the binder materials in thick film pastes form amorphous phases at the interface which influence the adhesion of thick films to the AIN substrate. The lack of certain elements (Cd, Zn, Ca) in the binder of the gold thick-film paste led to weaker adhesion and severe degradation of the thick-film adhesion during thermal cycling.     

An investigation of co-fired varistor-NiZn ferrite multilayers

The co-firing characteristics of ZnO varistor and NiZn ferrite thick films were investigated, the objective being to create an integrated passive device. Bismuth oxide additions were used to increase the shrinkage of the ferrite during sintering. Dilatometry analysis proved that well-matched shrinkage characteristics could be obtained for bismuth oxide-modified ferrite compositions and the starting varistor material. Cross-boundary diffusion across the co-fired varistor-ferrite interface occurred during sintering, but application of a barrier layer of pure zinc oxide reduced this phenomenon considerably. By tailoring the shrinkage, strong, crack-free co-fired layers with no evidence of cracking or delamination were obtained. No deleterious effects were observed due to electroding of the varistor and ferrite materials.     

Electrical properties of silver paste prepared from nanoparticles and lead-free frit

Recently, PbO containing glass systems in commercial silver paste have been used due to their low glass transition temperature, good thermal and electrical properties. However, PbO is a hazardous material to both health and the environment. In this study, Pb-free silver paste was prepared by mixing commercial silver powder and silver nanoparticles. The commercial powder has an average particle size of 1.6 microm. The silver nanoparticles with particles size of 20-50 nm were synthesized by a chemical reduction method using surfactant. Pb-free frit was added into the mixed silver powder as the amounts of 3, 6 and 9 wt%. Using the obtained paste, thick films were fabricated by a screen printing on alumina substrate and the films were fired at temperature from 400 to 550 degrees C. The films had thickness of 6-11 microm and sheet resistivity of about 4-11 microomega cm.     

The effect of the molar ratio of cations and citric acid on the synthesis of barium ferrite using a citrate process

A model is presented to evaluate the concentration of species in a citric solution for preparing barium ferrite powder. The evaluated concentration of species provides valuable information and help in selecting the optimal condition for preparation of the barium ferrite powder using the citrate process. The influence of the molar ratio of cations and citric acid on the formation of barium ferrite is studied. The formation temperature of barium ferrite decreases as the ratio increases. When the molar ratio of cations and citric acid is 13∶20, the barium ferrite can completely form at 700 °C.