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1.
Sorghum wax, sorbitol, glycerin, and soy protein isolate (SPI) composite films were prepared. Effects of sorghum wax, sorbitol,
and glycerin concentrations on various films were evaluated using response surface methodology. All independent variables
significantly (P<0.05) affected film water vapor permeability (WVP), tensile strength (TS), elongation at break (E), total color difference,
and total soluble matter (TSM). Increasing the sorghum wax concentration decreased WVP and E. As sorbitol content increased
in the composite films, WVP and TS increased. Sorbitol had a critical point of 2–5 g/5 g SPI for low values of TSM. The addition
of sorbitol contributed more to the properties of the film than did glycerin. 相似文献
2.
The water vapor permeability (WVP) of whey protein emulsion films was investigated. The exponential effect of relative humidity
on the WVP of whey protein films was reduced through lipid incorporation. Film orientation had a significant effect on WVP
due to emulsion separation during film formation. Heat denaturation of whey proteins lowered emulsion film WVP. Increasing
fatty acid and fatty alcohol chainlengths significantly reduced WVP, as did increasing lipid concentration. The WVPs of fatty
acids, fatty alcohols and beeswax were compared in whey protein-lipid emulsion films. Scanning and transmission electron microscopy
revealed the crystalline microstructure of lipid particles in emulsion films. 相似文献
3.
Jie Shen Yang Hu Ling-Xiao Li Jian-wu Sun Cheng-you Kan 《Journal of Coatings Technology and Research》2018,15(1):165-173
In order to improve the water vapor permeability and mechanical properties of latex films, polysiloxane/polyacrylate (PSi/PA) composite latexes were fabricated via seeded emulsion polymerization of methyl methacrylate and butyl acrylate onto PSi latex particles, and the effects of the silane coupling agent 3-methacryloyloxypropyl trimethoxysilane (MATS) on the morphologies of the latex particles and films, as well as the microphase separation degree, the water vapor permeability and the mechanical properties of the latex films were investigated. Results indicated that MATS was essential for obtaining the PSi/PA composite latex particles with PSi as core and PA as shell and made a great contribution to restrict the phase separation. The PSi/PA core/shell latex films showed similar tensile strength and elongation with pure PA film, while exhibiting promising water vapor permeability. It was found that the influences of MATS content on the water vapor permeability and mechanical properties were opposite, and on the premise of the requirements for mechanical properties, lower MATS content could provide the PSi/PA core/shell latex films with better water vapor permeability. 相似文献
4.
Nedim Gürler 《Polymer Engineering and Science》2023,63(2):426-440
In this study, chitosan (C)/gelatin(G)/starch(S) composites incorporated pineapple peel extract (PPE) and aloe vera gel (AVG) were prepared by the casting method as antioxidant agents. Mechanical, water vapor permeability (WVP), moisture content, solubility, opacity, and color properties of the effects of PPE and AVG at different concentrations (0%, 10%, and 30%) were investigated. The prepared films were characterized by Fourier transform infrared spectroscopy in attenuated total reflection (ATR-FTIR), X-ray diffraction (XRD), Thermal gravimetric analysis (TGA), Scanning electron microscope (SEM), mechanical, water barrier, opacity, and color. PPE and AVG extract incorporated edible films improved thermal stability of edible films. Tensile strength decreased with the addition of extracts; the maximum tensile strength was 8.15 MPa for CGS film. The WVP of the films increased with the increasing PPE and AVG concentration. As a biological activity, the films inhibited the growth of gram-positive (Staphylococcus aureus) and gram-negative bacteria (Escherichia coli). With the addition of PPE and AVG to the CGS film, its antioxidant properties were enhanced. In addition, the prepared films were applied for strawberry coating both in the refrigerator and at room temperature. Consequently, these edible-coated films can be used for active food packaging/coating to extend the shelf life of fruits. 相似文献
5.
The aim of this research was to investigate the effect of rapeseed oil concentration (1–3% w/w) on the water vapor, oxygen and carbon dioxide permeability, water vapor sorption and surface properties of whey protein isolate emulsion‐based films. The water contact angle as affected by oil content, film side and time was analyzed. The effect of temperature (5 and 25°C) on the water vapor permeability (WVP), water vapor sorption kinetics and diffusion coefficient was also studied. The results showed that the incorporation of a lipid phase to whey protein film‐forming solutions was able to decrease the WVP, water hydrophilicity (increasing water contact angle) and water transfer of whey protein films. However, the films containing oil were more permeable to oxygen and carbon dioxide. Significantly higher values of WVP and diffusion coefficient were obtained at 5°C than at 25°C, indicating that storage temperature should be taken into account when designing the composition of edible films and coatings for food applications. POLYM. ENG. SCI., 59:E375–E383, 2019. © 2018 Society of Plastics Engineers 相似文献
6.
Chitosan‐methyl cellulose based films which incorporatate vanillin as an antimicrobial agent and polyethylene glycol 400 (PEG) as a plasticizer were developed in this study. The effects of vanillin and plasticizer concentration on mechanical, barrier, optical, and thermal properties of chitosan‐methyl cellulose film were evaluated. When the vanillin concentration was increased at a given PEG level, film flexibility decreased while tensile strength increased slightly. Vanillin increased the barrier to oxygen but not water vapor. Increasing vanillin content resulted in less transparency and a more yellowish tint. The bulky nature of vanillin reduced film crystallization. When PEG concentration was increased at a given vanillin level, it resulted in greater film flexibility but reduced film strength. Water vapor permeability (WVP) and oxygen permeability (OP) increased with increase in PEG content. PEG contributed less to the opacity, yellowness, and crystallization of the film than did vanillin. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
7.
Summary
Bilayer films composed of a wheat gluten layer and a functionalized polyolefin film were performed by hot press process with
the aim to improve the moisture barrier property of hydrophilic gluten films. An ethylene/acrylic ester/maleic anhydride terpolymer
(Lotader 3410) and an ethylene/glycidyl methacrylate copolymer (Lotader GMA) were used. The use of both Lotader products had
no incidence on film opacity, and was effective to reduce dispersion in water and water vapor permeability. In the presence
of the terpolymer, the mechanical properties were enhanced and the wide range selectivity of gluten films was preserved.
Received: 23 June 1999/Revised version: 30 September 1999/Accepted: 30 September 1999 相似文献
8.
Jaroslaw M. Wasikiewicz Deepen Paul Nima Roohpour Jaina Vaghela Michael F. Grahn Pankaj Vadgama 《应用聚合物科学杂志》2011,119(5):2917-2924
A new modified silicone was obtained by the physical entrapment of a hydrophobic lipid, isopropyl myristate (IPM), to improve the encapsulation properties and corrosion resistance of medical electronic implants. Differences between the water transport for films in contact with water vapor versus those in contact with liquid water were identified; they showed increased permeability to water vapor, which was possibly the result of differences in the water organization at the hydrophobic film interface. Improvements, including enhanced scratch resistance and adhesion, in the mechanical properties of the modified material was also achieved. The incorporation of IPM further resulted in a significant improvement in the cell biocompatibility compared with the unmodified polymer; this suggested that the IPM combination could be a viable basis for implant device packaging. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
9.
Preparation and characterization of soy protein isolate films modified with sorghum wax 总被引:2,自引:0,他引:2
Ki Myong Kim Keum Taek Hwang Curtis L. Weller Milford A. Hanna 《Journal of the American Oil Chemists' Society》2002,79(6):615-619
The effect of increasing the concentration of sorghum wax paste on the characteristics of soy protein isolate (SPI) films
was investigated. Water vapor permeability (WVP), tensile strength (TS), elongation at break (E), and total soluble matter
(TSM) of cast SPI films were determined. Sorghum wax paste extracted with ethanol was added to film-forming solutions of SPI
at 5, 10, 15, or 20% w/w of protein. As the concentration of wax paste increased, mean WVP, E, and TSM values of SPI-sorghum-wax-paste
composite films decreased and were lower than those of control SPI films. Mean TS values were lower than the control upon
addition of 5 and 10% wax paste; however, TS values increased at 15 and 20% was concentrations. Although no differences in
components of sorghum wax were observed between paste extracted with ethanol and wax extracted with hexane, paste extracted
with ethanol was miscible with the filmforming solution. SPI-sorghum wax paste films had better water barrier and physical
properties compared to control films. 相似文献
10.
11.
Semi-refined carrageenan (SRC) films are sensitive to moisture and generally have poor mechanical properties. These factors limit their use in applications where moisture levels are high and good mechanical strength is required. This work investigated the incorporation of nanoclay (NC) into SRC film in combination with surface lamination using a thin layer of poly(caprolactone) (PCL) to enhance the barrier properties and hydrophobicity of the SRC film and concurrently improved the mechanical properties. The water vapor permeability, moisture uptake, and water solubility decreased by 92, 24, and 11%, respectively, and the water contact angle increased from 72° to 95°. The tensile strength and elongation at break increased by 17.9 and 2.8%, respectively, and the thermal stability also increased slightly. The PCL lamination was the main contributor to the enhanced barrier and mechanical properties of the films, whereas the NC inclusion contributed more to the enhanced thermal properties. 相似文献
12.
Antioxidant,antifungal, water binding,and mechanical properties of poly(vinyl alcohol) film incorporated with essential oil as a potential wound dressing material
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Gholamreza Kavoosi Behroz Nateghpoor Seyed Mohammad Mahdi Dadfar Seyed Mohammad Ali Dadfar 《应用聚合物科学杂志》2014,131(20)
In this study, the properties of poly (vinyl alcohol) (PVA) films incorporated with Zataria multiflora essential oil (ZMO) as a potential antioxidant/antibacterial material was investigated. PVA films were prepared from PVA solutions (2% w/v) containing different concentrations of ZMO. Water solubility, moisture absorption, water swelling, and water vapor permeability for pure PVA films were 57 ± 1.1, 99 ± 3.2%, 337 ± 8%, and 0.453 ± 0.015 g mm/m2 h, respectively. Incorporation of ZMO into PVA films caused a significant decrease in water swelling and moisture absorption and increase in solubility and water vapor permeability. Tensile strength, elastic modulus, and elongation at break for pure PVA films were 13.5 ± 0.61 MPa, 15.2 ± 0.8 MPa, and 216 ± 4%, respectively. Incorporation of ZMO into the PVA films caused a significant decrease in tensile strength and elastic modulus and increase in elongation at break of the films. Pure PVA film showed UV‐visible light absorbance ranging from 280 to 440 nm with maximum absorbance at 320 nm. Addition of ZMO caused a significant increase in light absorbance and opacity. PVA films exhibited no antioxidant and antifungal activities, whereas PVA/ZMO films exhibited excellent antioxidant and antifungal properties. Although the bioactivity PVA films were improved by the addition of ZMO, however, the mechanical properties and water binding capacity of the films were weaken slightly. Thus, ZMO emulsified in the ethanol not compatible with PVA matrix and more suitable emulsifier was needed in order to obtain strong film with higher mechanical properties. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40937. 相似文献
13.
The water vapor (WVP) and oxygen (O2P) permeabilities of beeswax (BW), candelilla wax (CnW), carnauba wax (CrW) and microcrystalline wax (MW), formed as freestanding
films, were determined. CnW and CrW both had small values for O2P (0.29 and 0.26 g·m−1·sec−1·Pa−1 × 10−14, respectively), which are less than half the value for high-density polyethylene and about a decade greater than the value
for polyethylene terephthalate. O2P values for BW and MW were about 6−9× greater than those of CnW and CrW. WVP of CnW was 0.18 g·m−1·sec−1·Pa−1 × 10−12, which is about one-half the value for CrW and MW and about one-third the value for BW. The WVP of CnW was somewhat less
than that of polypropylene and somewhat greater than that of high-density polyethylene. Differences in permeabilities among
the wax films are attributed mainly to differences in chemical composition and crystal type as determined by X-ray diffraction. 相似文献
14.
The objectives of this study were to prepare starch nanocomposite films incorporating grape pomace extract (GPE) and cellulose nanocrystal (CNC) using a solvent‐casting method, and to characterize the mechanical properties, color, water vapor transmission rate (WVTR), crystalline structure, morphology, thermal stability, phenolic compound release profile and antibacterial activity of the films. Incorporating CNC and GPE significantly (P < 0.05) increased the films’ thickness, mechanical properties, and opacity. Brightness and color were mainly influenced by GPE level, while CNC had a great impact on the reduction of WVTR values of the film. Three characteristic cellulose I crystalline peaks were observed using X‐ray diffraction in CNC‐containing nanocomposite films. However, the effect of CNC levels on thermal stability was not significant. Phenolic compound releases were time and film dependent, and the nanocomposite films incorporating with GPE and CNC exhibited stronger inhibitory effect against Staphylococcus aureus ATCC 29213 compared to Listeria monocytogenes ATCC 7644. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44438. 相似文献
15.
Silk fibroin/chitosan blend films were examined through IR spectroscopy to determine the conformational changes of silk fibroin. The effects of the fibroin/chitosan blend ratios (chitosan content) on the physical and mechanical properties were investigated to discover the feasibility of using these films as biomedical materials such as artificial skin and wound dressing. The mechanical properties of the blend films containing 10–40% chitosan were found to be excellent. The tensile strength, breaking elongation, and Young's modulus were affected by the chitosan contents of the blend films, which were also related to the density and degree of swelling. The coefficient of water vapor permeability of the blend films increased linearly with the chitosan content, and the values of 1000–2000 g m?2 day?1 were comparable to those of commercial wound dressings. Silk fibroin/chitosan blend films had good oxygen and water vapor permeabilities, making them useful as biomaterials. In particular, the blend film containing 40–50% chitosan showed very high oxygen permeability. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 928–934, 2001 相似文献
16.
高固含量石蜡乳液乳化剂的研制 总被引:1,自引:0,他引:1
解决了目前石蜡乳液在固含量高时制备困难和产品流动性差的问题。采用均匀设计与调优软件进行乳化剂配方的设计和实验结果的优化,考察了表面活性剂间的协同作用。结果表明,最佳配方为:Span-80 22.2%,Tween-80 20.7%,OP-10 31.4%,稳定剂19.8%,十二烷基硫酸钠5.9%(共占乳液总质量的6%),可使固含量为50%的石蜡乳液在3000 r/min的转速下离心30 min不分层。常温下,乳液的表观粘度为370~630 mPa.s。 相似文献
17.
Poly(propylene carbonate)/aluminum flake composite films with enhanced gas barrier properties
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A series of poly(propylene carbonate) (PPC)/aluminum flake (ALF) composite films with different ALF contents were prepared via a melt‐blending method. Their cross‐section morphologies, thermal properties, tensile strength (TS), and gas barrier properties were investigated as a function of ALF contents. SEM images reveal the good dispersion and orientation of ALF along with melt flow direction within PPC matrix. The oxygen permeability coefficient (OP) and water vapor permeability coefficient (WVP) of the composite films decrease continuously with ALF contents increasing up to 5 wt %, which are 32.4% and 75.2% that of pure PPC, respectively. Furthermore, the TS and thermal properties of PPC/ALF composite film are also improved by the incorporation of ALF particles. The PPC/ALF composite films have potential applications in packaging area due to its environmental‐friendly properties, superior water vapor, and oxygen barrier characteristics. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41663. 相似文献
18.
Rasoul Niknam Mohammad Reza Soudi Mohammad Mousavi 《Journal of the American Oil Chemists' Society》2023,100(2):163-174
Nowadays, preparing biodegradable films based on hydrocolloids has become thoroughly crucial in food packaging. Also, to enhance some of the aspects of these films, adding oil to the formulation of the films has been considered as a valid method. In this study, a variety of films based on two biopolymers (fenugreek galactomannan and xanthan gum) in the presence or absence of grape seed oil were produced and the various aspects of the obtained films were comprehensively investigated. The obtained data demonstrated that preparing composite films based on two hydrocolloids improved the aspects including film thickness, water vapor permeability (WVP), oxygen permeability (OP), mechanical and thermal properties more than films based on only one hydrocolloid. This improvement was mostly related to the good and acceptable interaction between two biopolymers. The X-ray diffraction (XRD) patterns indicated that all films had an amorphous or non-crystalline structure. Also, the scanning electron microscope images demonstrated that films based on fenugreek galactomannan and composite films based on two hydrocolloids. The value of film thickness and strain at break (SAB) increased by adding oil to the formulation. Contrarily, the moisture content and absorption, WVP, OP, opacity, and ultimate tensile strength (UTS) values of the films decreased by adding oil. 相似文献
19.
Tomoyuki Yoshino Seiichiro Isobe Takaaki Maekawa 《Journal of the American Oil Chemists' Society》2002,79(4):345-349
Zein is a hydrophobic protein produced from maize. Biodegradable zein films without additional reagents were prepared using
various controlled drying conditions. The zein films were transparent. Mechanical properties (tensile strength and puncture
strength), gas permeability, and water vapor permeability (WVP) of the zein films were measured. The tensile strengths of
the zein films were between 7 and 30 MPa and the puncture strengths between 37 and 191 MPa. The zein films had higher oxygen
permeability than carbon dioxide permeability. The lowest WVP of the zein film was 0.012×10−9 g·m/m2·s·Pa. We found differences in the WVP between the sides of the zein films; i.e., the air side of the zein film had a higher
WVP than the basal side of the zein film when the films were exposed to high humidity during testing. This indicates a relationship
between the WVP of the zein film and the contact angle of the zein film. The mechanical properties of the zein film depended
on the drying conditions during preparation. Zein films with various useful physical mechanical properties were produced. 相似文献
20.