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由于受资源条件的限制,酒钢高炉入炉原燃料中K、Na、Zn、Pb等有害元素含量较高,给高炉生产带来极大的危害。本文重点介绍了近年来对1号高炉有害元素的调查及采取的抑制措施,为进一步优化高炉操作提供有益借鉴。 相似文献
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因原料中的Zn、K和Na等有害元素在高炉富集,造成炉墙结厚、炉凉等事故发生。通过对有害元素影响过程的分析,总结出炉况变化的征兆和处理措施。 相似文献
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为了研究首钢高炉入炉碱负荷与炉内焦炭劣化的关系,利用碱金属循环富集模型计算碱金属在高炉内的最大富集量及在高炉内部不同部位的分布,然后进行焦炭在不同浓度碱蒸气下的熔损试验,通过反推计算最终得到了在不同入炉碱负荷情况下焦炭劣化的程度。结果表面,钾和钠在首钢高炉内最大的富集量分别为34.89和7.44kg/t,炉内焦炭已经发生严重劣化,反应性CRI为53.14%,反应后强度CSR为61.69%。要想控制住碱金属对首钢高炉的危害,入炉K2O和Na2O质量必须分别限制在0.48和3.11kg/t以内。 相似文献
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The circulation and accumulation of harmful elements in the blast furnace leads to a decrease in gas utilisation and an increase in heat consumption, which can cause the increase of coke ratio. In this paper, the effect of harmful elements on the coke ratio was quantitatively studied using the Rist diagram. The results show that the effect degree of each harmful element on the coke ratio varies. The influence orders of accumulation times and loads of harmful elements on the coke ratio are Na?>?K>Zn and Zn?>?Na?>?K, respectively. The increase of heat consumption has more effect on the coke ratio than the decrease of gas utilisation. The total increase of coke ratio by the effect of K, Na and Zn is 14.2, 35.8 and 9.3?kg/tHM, respectively, of which the effect of heat consumption accounts for 55.9, 60.9, 60.9%, respectively. 相似文献
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The circulation and accumulation of harmful elements in blast furnace were investigated. The results show that the maximum concentration of K and Na in the belly is about 50 times of that in the charge. The zinc increased by 80 times and the Pb is insignificant. The impact of the circulation and accumulation of K, Na, Pb and Zn on the fuel consumption was quantitatively analyzed using Rist diagram. The results show that the gas utilization decreased and the coke rate increased linearly with the increase of load and accumulation times of each harmful element. Given the accumulation times of each element, the loading of Na, K, Zn and Pb into BF leads to the increase of coke rate by 13.99 kg/tHM, 6.25 kg/tHM, 3.63 kg/tHM and 0.02 kg/tHM, respectively. The increased coke rate and the decreased gas utilization under various loads and accumulation times of each element was estimated. 相似文献
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Alkali metals are one of the important factors promoting the degradation of coke in blast furnace. Previous studies usually focused on the properties of coke affected, respectively, by K and Na separately, while K and Na will simultaneously affect coke performance in the actual production of blast furnace. Through simulating the actual situation where coke is affected by K and Na vapours simultaneously in blast furnace, the evolution of coke structure and thermal properties (CRI, CSR) after alkalisation with different proportions of K and Na vapours are revealed in this study. Results showed that coke structure was broken when the proportion of alkali vapours reached 3%, and coke fine formation rate increased with the increase of K vapour, indicating that K vapour caused a great damage to coke structure; CRI of coke reached the highest and CSR the lowest when K/Na ratio was 3/7. It was observed with SEM/energy dispersive spectrometer that K and Na existed in both mineral matters and carbon matrix; nepheline, generated when coke reacted with alkaline (K, Na) vapours, was determined by XRD. The content of K and Na in nepheline is dependent on the ratio of alkaline (K, Na). 相似文献
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红钢炼铁工序有害元素平衡研究 总被引:1,自引:0,他引:1
对红钢炼铁工序中的有害元素来源、平衡及生产进行总结,并就各有害元素在高炉不同生产条件下的分配比率进行统计分析。表明在红钢条件下S、KNa、PbZn等有害元素负荷分别达到5.0kg/t、5.5kg/t、2.0kg/t,对产品质量、炉型、生产技术指标均产生了不良影响;采取了若干有针对性的治理措施后,各有害元素脱除率分别达到了85%、95%、85%以上,不但使高炉继续保持了一定水平的稳定生产,也做到了因地制宜合理利用本地化资源。 相似文献
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涟钢高炉有害元素的分布与控制 总被引:1,自引:0,他引:1
研究分析了K,Na,Pb,Zn,Cu,As,Sn等有害元素在涟钢高炉炉料及产品中的分布情况。以光学显微镜、荧光分析仪、扫描电镜等仪器研究了有害元素在烧结矿、球团矿、块矿、焦炭、生铁、炉渣中的分布形态及其在富集载体渣皮、耐火材料、死铁层中的分布情况。同时,对高炉主要原燃料及产品中有害元素与其他元素的相关性进行了分析,并提出了一些控制高炉有害元素危害的方法与原则。 相似文献
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为了进一步研究焦炭在高炉内的劣化行为,探索更加适合高炉的的焦炭评价指标,利用武钢6号高炉中修挖炉缸的机会,从炉内自上而下分层取出焦炭试样,测定分析经高温反应后的焦炭试样的各项理化性能。采用开元5E-MAG6700全自动工分仪测定其水分、灰分和挥发分,采用科翔XQK-2000型显气孔率测定仪测定其显气孔率和灰分。研究结果表明,炉内残留焦炭相对于入炉焦灰分质量分数较高,固定碳质量分数下降明显,焦炭孔隙内滞留大量炉渣。高炉内初渣中SiO2、Al2O3、CaO和MgO质量分数并不高,MnO和P2O5质量分数是终渣中几倍甚至10倍,有相当部分的造渣是在炉缸下部进行的。高炉内碱金属在炉腹下部至炉缸上部富集量最大,锌在炉缸上部富集量最大。通过对高炉中修残留焦炭的研究分析,对焦炭在高炉各部位的劣化行为规律认识更加深刻,并对高炉的特性把握更加准确,可用于指导高炉生产。 相似文献
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通过模拟高炉内焦炭同时受钾和钠蒸汽影响的实际情况,得到在钾和钠不同比例条件下焦炭结构和热性能(CRI、CSR)的变化。结果表明,碱金属的比例达到3%时,就会破坏焦炭结构,而且随着钾蒸汽比例的提高,焦炭粉末也会增多,这表明钾蒸汽对焦炭结构造成了巨大破坏。当钾和钠的质量比为3︰7时,焦炭的反应性(CRI)达到最高,反应后强度(CSR)达到最低。通过扫描电镜和能量光谱仪观察发现,焦炭基体和矿物质中均存在钾和钠;通过X射线衍射检测发现,焦炭和碱金属蒸汽发生反应生成了霞石,霞石中钾和钠的含量取决于碱金属蒸汽中两者的比例。 相似文献