共查询到20条相似文献,搜索用时 78 毫秒
1.
2.
氮化铝(AlN)粉体中的金属杂质与氧化是影响其纯度和性能发挥的主要因素,而酸洗是提纯AlN粉体的有效手段.实验采用磷酸(H3 PO4)、硝酸(HNO3)、氢氟酸(HF)和盐酸(HCl)对AlN粉体进行酸洗提纯,主要研究了酸洗过程中酸液的选择与配比对提纯效果的影响.实验结果表明:这四种酸均显著降低了AlN粉体表面的金属杂质含量,而HF和HNO3的混合酸具有更好的提纯效果,特别能降低其中的Na、W、Fe等金属杂质,而且还可通过HF与Al2O3的反应有效去除氧杂质.HF/HNO3酸液的适宜配比为HF:HNO3=2:1,在该条件下酸洗后的AlN粉体中,金属杂质含量均下降到100 ppm以下,氧含量仅为1.2wt%. 相似文献
3.
4.
对5种不同钢铁基体的光亮镀镍、镍铁合金镀层进行退镀。分析了退镀液配方中ST-1添加剂含量、pH值、温度、电流密度对退镀速度和基体腐蚀的影响。退镀液的pH值为3.5~5.5。 相似文献
5.
微波消解-火焰原子吸收法测定硅橡胶催化剂中铂的含量 总被引:5,自引:1,他引:4
采用微波消解系统消解硅橡胶催化剂,再用火焰原子吸收法测定了其中铂的含量。考察了消解试剂种类、无机酸、共存离子对测定结果的影响及抑制方法。结果表明,采用HNO3+HF或HCl+HF或王水+HF为消解试剂对硅橡胶催化剂进行微波消解时效果好,消解时避免使用H2SO4;为防止消解液爆沸,需进行预消解。常见共存离子K+、Na+、Fe2+、Cu2+、Pb2+、Zn2+、Ca2+、Mg2+、Si对铂含量测定结果的影响很大,无机酸HCl、HNO3及HF对铂含量的测定结果也有一定的影响;采用CuSO4作干扰抑制剂不仅能有效抑制无机酸和共存离子的影响,而且具有明显的增敏作用。此方法的相对标准偏差小于2%,回收率为92.43%~109.05%。 相似文献
6.
铜—镍—铬(镍铁—铬)镀层酸性电解退镀液 总被引:2,自引:0,他引:2
对5种不同钢铁基体的光亮镀镍,镍铁合金镀层进行退镀。分析了退镀液想方中ST-1添加剂含量,pH值,温度,电流密度对退镀速度和基体腐蚀的影响。退镀液的pH值为3.5-5.5。 相似文献
7.
太阳能硅制备过程湿法提纯SiO2的工艺优化 总被引:1,自引:0,他引:1
考察了HF质量分数、H2C2O4质量分数、HNO3质量分数、酸浸时间、粒径、液体质量与固体质量的比值(简称液固比,下同)等因素对混酸法提纯SiO2工艺过程的影响,利用电感耦合等离子体发射光谱仪(ICP-OES)、场发射扫描电子显微镜(SEM)进行表征。结果表明,最佳工艺条件为:w(HF)=2%、w(H2C2O4)=3%、w(HNO3)=30%、酸浸时间4 h、粒径100~120目、液固比4∶1、酸浸温度30℃。Fe、Al、Ca、P杂质的去除率分别达到99.99%、14.02%、73.27%、60.00%,经混酸法处理后SiO2中杂质总量的质量分数降至1.465×10-4。 相似文献
8.
9.
采用化学镀法在硅基底上直接施镀了Ni-Co-P磁性薄膜,通过调整镀液中金属盐浓度比控制镀层中镍、钴含量,优化薄膜软磁性能。采用SEM、EDAX、XRD和VSM研究了镀液中不同的镍、钴浓度比对薄膜形貌、成分、厚度、镀速、结构和磁性能的影响。结果表明:化学镀Ni-Co-P薄膜由瘤状Ni-Co颗粒组成,镀态的Ni-Co-P镀层由非晶相构成。随着镀液中Co2+浓度的增加,镀层中Co元素的含量增多,Ni元素的含量降低,但镀层的镀速减缓,当镀液中Co2+含量过高时,施镀非常困难,而镀液中金属盐浓度比对镀层中非金属元素P的沉积量影响不大。Ni-Co-P合金薄膜的饱和磁化强度随着镀层中Co元素含量的增加有上升趋势,矫顽力同时呈现下降趋势。当镀液中c(Ni2+)∶c(Co2+)=2∶3时,制备的Ni-Co-P镀层软磁性能最好,其饱和磁化强度达到820 emu/cc,矫顽力仅为4 Oe。 相似文献
10.
11.
12.
M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
13.
14.
Cheng-Le Zhao Shane Porzio Alan Smith Haiyan Ge H. T. Davis L. E. Scriven 《Journal of Coatings Technology and Research》2006,3(2):109-115
Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively.
There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized.
High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without
the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of
fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to
achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic
SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve
F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender
particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing,
and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing
or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually
preserves suspension stability during freezing.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago,
IL. Tied for first place in The John A. Gordon Best Paper Competition. 相似文献
15.
Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae
and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted
in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures
(release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species
(Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species
to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were
exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of
separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles
from the southeastern region of the US. 相似文献
16.
17.
18.
Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed. 相似文献
19.
中蓝晨光化工研究院有限公司《塑料工业》编辑部 《塑料工业》2009,37(3)
收集了2007年7月~2008年6月世界塑料工业的相关资料,介绍了2007~2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍. 相似文献
20.
中蓝晨光化工研究院《塑料工业》编辑部 《塑料工业》2007,35(3):1-25,67
收集了2005年7月~2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、通用热固性树脂(酚醛、聚氨酯、不饱和树脂、环氧树脂)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。 相似文献