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为了进一步提高铁系磷化膜的耐蚀性,研究了复合成膜助剂ZY.通过正交实验确定了磷化液的组成,并讨论了磷化温度、溶液pH值以及磷化时间等参数对磷化膜耐蚀性和膜重的影响.结果表明,成膜助剂ZY明显地改善了磷化膜的表面质量,在20℃、磷化20 min时可以获得均匀致密的磷化膜,膜重为1.09/m2,耐CuSO4点滴时间超过200 s,质量分数为3%的NaCl溶液浸泡时间超过5 h. 相似文献
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研制的高耐蚀彩膜磷化添加剂 ,在铁系磷化液中加入 ( 1 0± 2 ) m L/ L,膜层耐蚀性能提高 1 0~ 2 0倍 ,Cu SO4点滴实验可达 2 0 0 s。介绍了此添加剂的配方、配制、影响效果及对含添加剂的铁系磷化液的性能、应用、优缺点。实验表明 :含添加剂的铁系磷化液具有室温、快速、少渣、无毒的特点 相似文献
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研制出一种以亚硝酸钠为促进剂的室温磷化液。介绍了其组成及配制方法,测定了磷化液及所得磷化膜的性能,分析了膜层常见缺陷并提出了解决方法。结果表明:该工艺磷化成膜速度快,在5~20℃能获得银灰色、均匀、致密、耐蚀的磷化膜。 相似文献
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常温磷化为磷化发展的主要方向,通过对添加了间-硝基苯磺酸钠等添加剂的铁系磷化液进行分析,得出该磷化液具有较好的磷化效果。 相似文献
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以磷化工艺的设计及验证过程为基础对细结晶磷化膜工艺进行研究。此工艺目的是参考大众TL 235标准得到长2~12μm、宽1~6μm,均匀、完整、致密的细结晶磷化膜层。通过优化工艺流程,调整操作参数发现:工件前处理方式、表面调整剂的浓度、磷化液的酸比对磷化膜的成形状态影响较大。经过试验确定了最终的工艺流程和细结晶操作参数,并提出了细结晶磷化膜工艺中需注意的几个问题。 相似文献
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Hot rolled steel (HRS) is used extensively in the automotive, agricultural and appliance industries. The corrosive response of HRS was investigated after it had been exposed to various surface treatments, prior to powder coating. The behaviour of three conversion coatings: zinc phosphate (ZnP), iron phosphate (FeP) and zirconium (Zr)-based nano-scaled, on HRS was studied. HRS is naturally covered with iron oxide scale and this was removed from the surface by mechanical and chemical processes, prior to the application of surface treatment and organic coatings. The following tests on differently treated panels were conducted to evaluate corrosion performance: adhesion tests such as, crosshatch, pull-off, and conical bending, SEM, XPS, salt spray and electro-chemical impedance studies were also performed. Good correlations were recorded showing that zinc phosphate conversion coating gave the best performance, and zirconium-based nano-structured conversion coating, was superior to that of iron phosphate conversion coatings on HRS. 相似文献
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复合铁钛粉改性环氧富锌重防腐涂料的研究 总被引:4,自引:1,他引:4
通过选用纳米改性复合铁钛防锈颜料对环氧富锌重防腐涂料进行改性,制得了具有优异防腐功能的新型环氧富锌涂料;研究了复合铁钛粉的种类及用量对环氧富锌防腐涂料性能的影响;确定了环氧富锌涂料的最佳PV C值。结果表明,当选用纳米改性复合铁钛防锈颜料,用量为8%,涂料的PV C值为42%时,可较大幅度地改善环氧富锌涂料的密封性、附着力、厚涂性,耐盐雾腐蚀可达1542h。 相似文献
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铝及铝合金无铬表面处理技术研究进展 总被引:2,自引:0,他引:2
综述了铝及铝合金无铬表面处理技术,包括锆钛类处理、硅烷处理,稀土转化膜、高锰酸盐转化膜、钴盐转化膜、锂盐转化膜、有机酸转化膜等.目前在实践中获得应用的有锆钛转化处理和硅烷处理,但尚无一种无铬处理工艺能够完全代替铬酸盐处理工艺. 相似文献
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In this study, a process for depositing hydrotalcite (HT) coatings on galvanized steel was developed and the resulting coatings
were characterized. Results showed that coatings formed spontaneously on galvanized surfaces upon exposure to ambient temperature
alkaline aluminate solutions. Anodic polarization and electrochemical impedance spectroscopy experiments showed clear evidence
of surface passivation. Scanning electron microscopy showed the formation of a continuous and conformal surface film comprised
on a compact mass of crystallites. X-ray diffraction confirmed that the coating contained an Al−Zn hydrotalcite compound.
Coating formation was enhanced by oxidizer and ammonium salt additions. Coatings formed by using best practices were deposited
in less than 10 minutes and demonstrated good surface coverage and good organic coating adhesion. HT coatings formed by using
best practices showed excellent organic coating adhesion compared to zinc phosphate control coatings. In salt spray testing,
the presence of a hydrotalcite conversion coating under an epoxy neat resin was found to delay the onset of red rusting compared
to control samples that were epoxy coated, but not conversion coated. 相似文献
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A method to facilitate electrochemical coatings from a non-aqueous, poorly conductive (and therefore normally difficult to work with) electrolyte is presented. The process involves loading the electrolyte with pretreated ion-exchange beads to provide multiple low-resistivity paths for ionic but not electronic conduction between a counter-electrode and workpiece. Using the formation of iron phosphate conversion coatings from an oil-based lubricant as a test case, the effects of bead moisture content and oil additive concentration on the coating process are described. With this new approach electrochemical coating is possible, even in poorly conductive fluids, over a far larger range of electrode separations than could otherwise be accomplished. 相似文献
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Corrosion stability of polyester coatings on steel pretreated with different iron–phosphate coatings
B.V. Jegdić J.B. Bajat J.P. Popić V.B. Mišković-Stanković 《Progress in Organic Coatings》2011,70(2-3):127-133
The influence of steel surface pretreatment with different types of iron–phosphate coatings on the corrosion stability and adhesion characteristics of polyester coatings on steel was investigated. The phosphate coating was chemically deposited either from the simple novel plating bath, or with the addition of NaNO2, as an accelerator in the plating bath. The morphology of phosphate coatings was investigated using atomic force microscopy (AFM). The corrosion stability of polyester coatings on steel pretreated by iron–phosphate coatings was investigated by electrochemical impedance spectroscopy (EIS) in 3% NaCl solution, while “dry” and “wet” adhesion were measured by a direct pull-off standardized procedure. It was shown that greater values of pore resistance, Rp, and smaller values of coating capacitance of polyester coating, Cc, on steel pretreated with iron–phosphate coating were obtained, as compared to polyester coating on steel phosphated with accelerator, and on the bare steel. The surface roughness of phosphate coating deposited on steel from the bath without accelerator is favorable in forming stronger bonds with polyester coating. Namely, the dry and wet adhesion measurements are in accordance with EIS measurements in 3% NaCl solution, i.e. lower adhesion values were obtained for polyester coating on steel phosphated with accelerator and on the bare steel, while the iron–phosphate pretreatment from the novel bath enhanced the adhesion of polyester coating on steel. 相似文献
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磷酸锌/云铁灰环氧涂层防腐性能的研究 总被引:1,自引:0,他引:1
选用磷酸锌为主要防锈颜料,协同云母氧化铁灰,制备无溶剂型环氧防腐涂料.考察涂层的基本性能,并采用交流阻抗(EIS)测试技术,分析了颜料体积浓度(PVC)、活性稀释剂和防锈颜料质量比对涂层防腐性能的影响.实验结果表明:该涂料固含量高达98%以上,是环境友好型涂料;PVC小于12%时,涂层具有较好的防腐性能;PVC为8%,活性稀释剂添加量为2%,云铁灰与磷酸锌质量比为1:4时涂层的防腐性能最佳.在涂层浸泡一定时间后,磷酸锌能防止腐蚀的进一步发生,起到有效抑制腐蚀的作用. 相似文献