共查询到20条相似文献,搜索用时 187 毫秒
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快冷厚带-氢破碎-磁场成型工艺制备高性能烧结钕铁硼磁体 总被引:4,自引:1,他引:3
对比分析了我国与西方国家生产烧结钕铁硼磁体工艺差距,指出了快冷厚带制备工艺是生产烧结钕铁硼磁体关键性工艺、核心技术。分别采用快冷厚带-氢破碎-磁场成型工艺和普通铸锭-氢破碎城场成型工艺制备同一成分的烧结钕铁硼磁体。结果表明:钕铁硼快冷厚带“柱状晶”穿透整个带厚、无等轴晶区、无α—Fe相、三相(主相Nd2Fel4B、富Nd相和富B相)分布均匀、耐腐蚀性能好;氢破碎后沿富Nd相均匀破碎,主相晶粒完整;气流磨后为2.8~3.2μm单晶粉末;快冷厚带可以明显提高磁体的各项性能。 相似文献
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介绍了黏结钕铁硼的发展现状及制备工艺过程。从影响黏结永磁体性能的各个因素出发,包括磁粉的制备、成型工艺、黏结剂及助剂的选择、磁体的防腐等方面介绍黏结NdFeB永磁体的发展。 相似文献
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粘结NdFeB磁体制备的研究进展 总被引:1,自引:1,他引:0
综述了制备粘结NdFeB磁体的原料、成型工艺和防腐方法;概述了近年来在磁粉和磁体制备、磁体防护等方面的最新研究进展。认为随着粘结NdFeB磁体应用的不断扩展和需求的增长,其研究也将不断深入,产量也将不断扩大。 相似文献
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利用高性能吸氢-歧化-脱氢-再复合(HDDR)NdFeB各向异性磁粉,通过两步法伴温磁场取向工艺制备高性能柔性各向异性NdFeB黏结磁体,重点研究了两步法伴温磁场取向工艺制备出不同成分配比磁体的磁性能和力学性能.结果发现:制备出磁体的取向度有大幅度提高,当成分配比(质量分数)为96.5%磁粉+1%偶联剂+2.5%黏结体系的磁体在120℃加热保温30 min磁场取向后,磁能积达到97 kJ·m-3,而磁体的矫顽力最大降幅只有1.3%,论证了两步法伴温磁场取向工艺制备柔性各向异性NdFeB黏结磁体在实际生产的可行性.环氧树脂润滑剂的加入使得制备出磁体的延伸率和柔性均大幅度下降,并且加入量越多,下降幅度越大,因此环氧树脂润滑剂最大加入量不应超过1%(质量分数). 相似文献
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采用速凝薄带加氢破碎法制备了烧结NdFeB永磁体,通过光学显微镜、扫描电镜以及AMT—4磁学特性测量仪表征了磁体的组织和性能,考察了烧结温度对磁体组织和性能的影响规律。结果表明:随着烧结温度的升高,磁体的致密度升高,剩磁、矫顽力、最大磁能积先增大后减小,其原因是随着烧结温度的升高,主晶相晶粒长大,富钕相分布更加均匀;当烧结温度超过某一值时,磁体的组织不均匀,富钕相发生团聚。 相似文献
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介绍了连续电镀锌机组的预镀镍过程,详细说明了镀镍设备的优点和预镀镍的工艺条件。采用性能优良的镀镍槽和不溶阳极时,如何保证镀液的PH值在3~4是关键的工艺条件,着重介绍了阴离子交换树脂中和SO2-4和释放OH-去维持镀液PH值的原理。 相似文献
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为制备直径为0.032mm的316L不锈钢镀镍微丝,本文对镀镍工艺和拉拔工艺进行探索。在常温时,电流3.1 A下对316L不锈钢进行酸洗活化,溶液配比为HCI:18%,HNO_3:12%,H_2O:70%;再采用浓度720g/L的Ni(NH_2SO_3)_2·4H_2O溶液为镀液,在电流0.12A进行预镀,然后在电流密度10.6A/dm~2下进行主镀,镀后采用缠绕法检测镀镍层的结合力,发现该电镀工艺可获得良好的镀镍层,镀镍层与基体结合紧密。选取镀镍层厚度10μm,直径0.22mm的镀镍细丝,采用810℃进行热处理,拉拔至直径0.12mm,采用890℃进行中间退火后,进一步拉拔至0.06mm后,拉拔至直径0.032 mm,最后采用860℃对成品进行退火。观察拉拔后的镀镍微丝微观形貌并进行拉伸性能测试。结果表明:拉拔后微丝镀镍层连续、牢固,镀镍层满足拉拔韧性需要,拉拔后微丝的抗拉强度可达到807 MPa。 相似文献
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《中国稀土学报(英文版)》2021,39(11):1409-1414
(Ho,Nd)FeB magnets with different Ho contents were prepared by Ho substitution for part of Nd during the casting process. Effects of Ho contents on the corrosion resistance and mechanical properties of (Ho,Nd)FeB magnets were analyzed by a highly accelerated aging tester, an electrochemical workstation, a microhardness tester, a bending tester, a scanning electron microscope and an X-ray diffractometer. Results show that the addition of Ho can change the main phase structure, optimize the distribution of rare-earth rich (RE-rich) phases in grain boundary, and improve the corrosion resistance and mechanical properties of NdFeB magnets. When the content of Ho increases from 0 to 21.0 wt%, the weight loss of magnets decreases from 2.672 to 0.933 mg/cm2, and the microhardness and bending strength increase from 528.74 HV and 374.92 MPa to 633.84 HV and 459.80 MPa, respectively. 相似文献
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A.Ali A.Ahmad K.M.Deen 《中国稀土学报(英文版)》2009,27(6):1003-1007
Sintered NdFeB magnets have complex microstructure that makes them susceptible to corrosion in active environments.The current paper evaluated the anticorrosion characteristics of multilayer titanium nitride ceramic coating applied through cathodic arc physical vapour deposition(CAPVD) for protection of sintered NdFeB permanent magnets.The performance of ceramic coating was compared to the electrodeposited nickel coating having a copper interlayer.Electrochemical impedance spectroscopy(EIS) and cyclic polar... 相似文献
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设计了新型耐蚀镍铸铁的组织及其化学成分。试验结果表明,除了石墨和奥氏体基体外,还有合金渗碳体存在。该镍铸铁具有良好的耐蚀性能、较好的机械性能与满意的铸造性能。 相似文献
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Weiqiang Liu Wang Xi Ruijin Hu Ming Yue Yuxia Yin Jingang Guo Dongtao Zhang Hongguo Zhang 《中国稀土学报(英文版)》2019,37(10):1083-1087
As an organic binder for bonded Nd-Fe-B magnets, epoxy resin(EP) has poor heat resistance but good moisture resistance, while sodium silicate(SS) has poor moisture absorption but better heat resistance and corrosion resistance. In order to improve high temperature stability and decrease moisture absorption of bonded Nd-Fe-B magnets, EP/SS composites were applied as the binder to prepare bonded Nd-Fe-B magnets. The magnetic properties, moisture absorption, corrosion resistance, compressive strength and microstructure of composite bonded magnets were investigated. The results show that EP/SS bonded magnets can obtain excellent magnetic properties at room temperature, and even useable magnetic properties a thigh temperature environments at 200°C. EP/SS composite binder effectively improves heat resistance and corrosion resistance of bonded Nd-Fe-B magnets, and reduces the hygroscopic properties. The molecule of sodium silicateis rigid and keeps it original shape at high temperature environments. In addition, SS in composite binder improves the mobility of the magnetic powders during the pre-pressing process, which makes the magnetic powders attain a more regular structure. These two factors will increase the mechanical properties. Moreover, sodium silicate in the composite binder can also cover the surfaces protecting the magnetic powders from oxidation and corrosion. EP in composite binder can cover SS surface to reduce the water absorption of SS as epoxy is a hydrophobic material. The EDX analysis shows that the composite binder has accumulated in the gaps of the magnet powders, which not only improves heat resistance and corrosion resistance, but also increases the mechanical properties. Therefore, EP/SS composite binder endows bonded Nd-Fe-B magnets excellent comprehensive properties. 相似文献
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Nd-Fe-B permanent magnets with a small amount of Al nano-particles doping were prepared by conventional sintered method. Effect of Al content on magnetic property, corrosion resistance and oxidation properties of the magnets were studied. Investigation showed that the coercivity rose gradually, while the remanence decreased simultaneously with increase of Al doping amount. Further investigation revealed that most Al element diffused into the main phase and some Al element diffused into the Nd-rich phase. The autoclave test results showed that the corrosion rate of the magnets decreased with Al content increasing. After oxidation, the maximum energy product losses of the magnets with 0.0 wt.% and 0.2 wt.% Al nano-particles doping were 6.13% and 3.99%, respectively. Therefore, Al nano-particles doping was a promising way to enhance the coercivity and corrosion resistance of sintered Nd-Fe-B magnet. 相似文献
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Jia Li Qingrong Yao Weichao Huang Jue Xie Zhilin Mo Jianqiu Deng Jiang Wang Guanghui Rao Huaiying Zhou 《中国稀土学报(英文版)》2022,40(5):784-791
New energy vehicles and offshore wind power industries have a high demand for sintered Nd–Fe–B magnets with high intrinsic coercivity and high corrosion resistance. In this study, the magnetic properties, anticorrosion properties, and microstructure of Nd–Fe–B sintered magnets with the intergranular addition of low-melting-point eutectic Tb68Ni32 alloy powders were investigated. The aim is to determine if the addition of Tb68Ni32 can improve these properties. A low melting-point eutectic alloy Tb68Ni32 powders was prepared as a grain boundary additive and blended with the master alloy powders prior to sintering. The coercivity of the resultant magnets gradually increases from 1468 to 2151 kA/m by adding increasing amounts of Tb68Ni32. At the same time, the remanence first increases and then slightly decreases. After studying the microstructure and elemental composition of the Tb68Ni32 added magnets, it is found that the significant increase in coercivity and the negligible reduction in remanence is due to densification, improved grain orientation, a uniform and continuous boundary phase distribution, as well as the generation of a (Nd,Pr,Tb)2Fe14B “core–shell” structure surrounding the main-phase grain. Moreover, the corrosion resistance of the magnet is greatly improved owing to the enhancement of electrochemical stability, as well as the optimization of the distribution and morphology of the intergranular phase. 相似文献
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低压冷喷涂(LPCS)是一种拥有便携式冷喷涂系统的涂层技术。例如DYMET304K系统就应用于这项涂层技术中。通常情况下,压缩空气作为冷喷涂工艺中的运载气体。低压冷喷涂适用于喷涂金属基陶瓷复合粉末,如Cu基、Ni基、Zn基、Al基添加Al2O3粉的复合粉。硬质陶瓷相主要起到清洁喷嘴、增加表面活性和喷丸强化的作用,该方法在尺寸修复领域中具有优势。在这个领域里,修复铸造加工中的缺陷和气孔是一个很热门的应用。例如,Zn基复合材料就适用于防止电化学腐蚀和修复机械损伤造成的尺寸差异。本文对Zn+Al+Al2O3,Zn+Cu+Al2O3和Zn+Ni+Al2O3等复合材料做了实验研究。Zn和Al在腐蚀环境中起到阴极保护的作用,而Cu和Ni也有助于提高材料的机械性能。经过对微观孔蚀电位反应和力学性能(硬度和结合强度)的研究发现,涂层具有相对致密的结构和耐蚀性能。Zn在复合涂层中对其它金属起到阴极保护的作用。此外,在Fe52型铁基材料上的涂层有着足够的力学性能,硬度和结合强度较高。这一类涂层在修复宏观的铸造缺陷上具有很高的潜在应用价值。 相似文献
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《中国稀土学报(英文版)》2020,38(7):735-741
Sintered(Ce,Nd)-Fe-B magnets with high cost performance were prepared by substituting of Ce for Nd with the dual-main phase method.The corrosion behaviors of dual-main phase sintered(Ce_xNd_(1-x))_(30)Fe_(69)B_1(x=0.15 wt%,0.3 wt%) magnets,which were named as Ce15 and Ce30,were studied in 3.5 wt% NaCl,6.6 wt% Na_2 SO_4 and 3.0 wt% NaOH aqueous solutions,respectively.The galvanic corrosion of Ce30 is stronger than that of Ce15.However,the mass loss value of Ce30 is smaller than Ce15 after free corrosion for 33 d in NaCl solution.In the other two solutions,all the results show that the corrosion resistance of Ce30 is better than that of Ce15.The scanning electron microscope results show that the crack and shedding of the magnetic phase of Ce30 is less than that of Ce15.Combined above,the abnormal corrosion behavior shows that Ce30 magnets perform better corrosion resistance than Ce15,and the degradation degree of magnetic phase mainly affects the corrosion resistance of magnets. 相似文献