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《粘接》2008,29(5):38
黑龙江省石油化学研究院采用复合型催化剂合成了一种新型高耐热酚醛树脂,具有较高的热分解温度,且在500℃以上仍有80%的质量保留。同时,对金属的粘接性能很好,粘接钢的室温剪切强度14.7MPa,而用丁腈橡胶(NBR)和聚乙烯醇缩丁醛(PVB)增韧后性能更佳,剪切强度分别为22.4MPa和20.5MPa。当温度大于250℃时,加入增韧剂的粘接强度会有一定程度降低,但仍比一般的耐高温胶粘接强度高。纯酚醛树脂、NBR增韧和PVB增韧的300℃粘接的剪切强度分别为11.2MPa、8.4MPa、7.9MPa;400℃时分别为5.8MPa、5.1MPa、4.3MPa。由于丁腈橡胶具有较大的活性,能与酚醛树脂发生一定程度的交联,使其增韧效果好于聚乙烯醇缩丁醛。 相似文献
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选择了3种不同分子量的聚乙烯醇缩丁醛作为增韧剂对酚醛树脂进行增韧改性,通过夹层结构滚筒剥离强度,材料的60s垂直燃烧、烟密度、热释放速率等性能测试研究不同分子量和添加量的增韧剂对材料韧性和阻燃性能的影响。研究发现高分子量增韧剂对材料滚筒剥离强度的改善效果最明显,5%的添加量即能达到11%的低分子增韧剂的增韧效果;除增韧剂的添加量外,增韧剂分子量也对材料的阻燃性能有明显影响。最后通过复合材料的力学性能测试,发现经低、中、高3种分子量的增韧剂增韧的复合材料的层间剪切强度均得到了明显改善,分别提高了29%、81%和71%。 相似文献
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以苯酚、甲醛、聚乙烯醇缩甲乙醛为原料,合成了改性酚醛树脂,通过红外光谱表征了聚乙烯醇缩甲乙醛改性酚醛树脂的结构,并通过TGA分析了聚乙烯醇缩甲乙醛改性酚醛树脂的热性能。结果表明:聚乙烯醇缩甲乙醛改性的酚醛树脂初始热分解温度为271.8℃,796℃时失重76.43%,与聚乙烯醇缩丁醛改性的酚醛树脂相比,由于缩短了酚醛树脂的碳链,热稳定性增加。 相似文献
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以腰果酚、甲醛和三乙烯四胺为原料,采用一步法制备了环氧树脂(EP)用腰果酚醛三乙烯四胺新型固化剂;然后以双酚A型EP为基体树脂、腰果酚醛三乙烯四胺为固化剂和聚乙烯醇缩丁醛(PVB)为增韧改性剂,制备了室温固化EP胶粘剂。研究结果表明:当w(PVB)=10%(相对于EP质量而言)时,胶粘剂的拉伸强度(30.58 MPa)、冲击强度(6.30 kJ/m2)和剪切强度(17.71 MPa)相对最大;此时改性EP胶粘剂的热稳定性相对最好,并且其断裂方式由脆性断裂变为韧性断裂。 相似文献
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以Ba(OH)2/NaOH为复合催化剂,采用两步加入甲醛法合成了高邻位PF(酚醛树脂)胶粘剂;然后以间苯二酚为改性剂,比较了不同n(甲醛)∶n(苯酚)配比、催化剂用量和反应时间等对PF胶粘剂性能的影响。结果表明:当反应时间为2.0 h、n(甲醛)∶n(苯酚)=1.7∶1.0,w(NaOH)=2.0%、w(Ba(OH)2)=3.0%和w(间苯二酚)=10.0%(均相对于苯酚质量而言)时,所得产物的性能相对较优;催化剂Ba(OH)2的引入,能有效提高邻位羟甲基含量、降低固化温度和加快固化速率;间苯二酚的引入,可有效加快PF胶粘剂的固化反应。 相似文献
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The performance of phenol-formaldehyde (PF) resins, formulated with lignin derivatives previously synthesized as phenolic resin prepolymers, was evaluated by thermal analysis of the curing process, and by a hard maple shear block test. At 54 and 60% phenol replacement levels, respectively, kraft (KL) and steam explosion lignin (SEL)-based resoles exhibited cure behavior very similar to a standard PF resin. Acid hydrolysis lignin gelled prematurely, and was found to be incompatible with the normal synthesis procedure. Differential scanning calorimetry (DSC) was used to compare kinetic parameters for the curing process of neat and lignin derived phenolic resins. Activation energies and cure rates determined by DSC showed no difference between adhesives. High lignin contents had no inhibitory effect on resin cure. Shear strength properties were evaluated in a compression test, and results illustrate that both lignin-based resins have acceptable strength properties, both in a dry and accelerated aging test. Of the lignins tested, kraft lignin consistently demonstrated superior performance as a pre-polymer in phenolic adhesives. This was attributed to differences in the chemical structure of the two lignins, which had been found to vary in terms of their reactivity with formaldehyde and phenol. KL had been noted to be more amenable to derivatization with formaldehyde and phenol, hence its ability to crosslink with a phenol-formaldehyde fraction during resin synthesis was increased. Positive structural features in KL are a high phenolic guaiacyl (3-methoxy, 4-hydroxy phenyl) content, low carbon-to-carbon bonding between aromatic rings, high solubility in alkali, and a higher number average molecular weight than SEL. 相似文献
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以苯酚、多聚甲醛、甲醛溶液为原料,NaOH为催化剂,采用逐步共聚的聚合工艺,制备可发性甲阶酚醛树脂,采用环保型发泡剂、匀泡剂、实验室自制复合酸固化剂制备阻燃保温酚醛泡沫材料。研究了甲醛/苯酚配比(物质的量之比即F/P)进行单因素分析,对可发性甲阶酚醛树脂的物理性能、有毒物质残余量、分子结构和活性的影响以及与树脂可发性的关系。结果表明,当F/P=2.0时,可发性甲阶酚醛树脂的粘度为2 680 mPa.s,游离甲醛含量为0.75%,游离苯酚含量为2.3%,羟甲基含量为34.83%,泡沫表观密度为0.050 7 g/cm3。 相似文献
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冷压型脲醛树脂固化剂的初步应用 总被引:2,自引:0,他引:2
聚乙酸乙烯酯乳液可以作为脲醛树脂固化剂的主要组份或改性剂,为探讨聚乙酸乙烯酯乳液及甲醛捕捉剂A对脲醛树脂性能的影响。采用改性聚乙酸乙烯酯乳液、甲醛捕捉剂A、非离子型表面活性剂以及其它添加剂等配制出一种冷压型固化剂,并测定了脲醛树脂的pH值、固化时间和冷压粘接强度,结果表明该固化剂有助于提高脲醛树脂的固化特性和粘接性能,同时也指出该固化剂与脲醛树脂配比以10%-15%为宜,甲醛捕捉剂A用量以该固化剂中聚乙酸乙烯酯乳液质量的20%-40%为宜。 相似文献
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A novel phosphorus‐containing curing agent, 2‐(6‐oxid‐6H‐dibenz〈c,e〉〈1,2〉oxa‐phosphorin‐6‐yl) phenol formaldehyde novolac [OD‐PN], was prepared from phenol formaldehyde novolac resin (PN) and a reactive 2‐(6‐oxid‐6H‐dibenz〈c,e〉〈1,2〉oxa‐phosphorin‐6‐yl)chloride (ODC) while ODC was synthesized through reaction between o‐phenylphenol and phosphoryl trichloride. The compound (OD‐PN) was used as a reactive flame‐retardant in o‐cresol formaldehyde novolac epoxy resin (CNE) for electronic application. Owing to the rigid structure of ODC and pendant P group, the resulted phosphorus containing epoxy resin exhibited better flame retardancy, higher glass transition temperature, and thermal stability than the noncyclic P‐containing curing agent or the bromine containing flame‐retardant epoxy resin. UL 94‐VO rating could be achieved with a phosphorus content of as low as 1.21% (comparable to bromine content of 6%) in the cured resin, and no fumes and toxic gas emission were observed. The relationship between the structure and flammability for both phosphorus containing curing agents OD‐PN and TP‐PN (triphenyl phosphate‐phenol formaldehyde novolac reaction product) are also examined. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 1636–1644, 2000 相似文献