矿渣基胶凝材料固化垃圾焚烧飞灰中重金属的研究

以矿渣部分或全部替代水泥，与垃圾焚烧飞灰和脱硫石膏组成胶凝材料，研究随矿渣掺量变化，胶凝材料对垃圾焚烧飞灰重金属的固化效果。结果表明：随着矿渣替代水泥量的增大，净浆试块抗压强度呈现先增大后减小的趋势；当飞灰掺量为20%、矿渣掺量为70%、脱硫石膏掺量为10%时制成的净浆试块，在温度为35 ℃、湿度为95%下养护28 d，试块的抗压强度达到47 MPa，重金属元素Cr、Cd、Cu、Hg、Pb、Zn的浸出浓度均低于饮用水标准；对Pb、Cr的固化效果明显优于纯水泥胶凝体系。XRD和FT-IR检测表明：该矿渣基胶凝材料水化生成的主要产物有钙矾石、C-S-H凝胶和水铝钙石，水化产物对重金属离子有良好的包裹作用。矿渣基胶凝体系比水泥基胶凝材料体系在固化垃圾焚烧飞灰重金属方面优越性明显。     

矿渣基胶凝材料固化垃圾焚烧飞灰中重金属的研究

以矿渣部分或全部替代水泥，与垃圾焚烧飞灰和脱硫石膏组成胶凝材料，研究随矿渣掺量变化，胶凝材料对垃圾焚烧飞灰重金属的固化效果。结果表明：随着矿渣替代水泥量的增大，净浆试块抗压强度呈现先增大后减小的趋势；当飞灰掺量为20%、矿渣掺量为70%、脱硫石膏掺量为10%时制成的净浆试块，在温度为35 ℃、湿度为95%下养护28 d，试块的抗压强度达到47 MPa，重金属元素Cr、Cd、Cu、Hg、Pb、Zn的浸出浓度均低于饮用水标准；对Pb、Cr的固化效果明显优于纯水泥胶凝体系。XRD和FT-IR检测表明：该矿渣基胶凝材料水化生成的主要产物有钙矾石、C—S—H凝胶和水铝钙石，水化产物对重金属离子有良好的包裹作用。矿渣基胶凝体系比水泥基胶凝材料体系在固化垃圾焚烧飞灰重金属方面优越性明显。     

金山店铁尾矿用作路基材料的研究

为了使金山店铁选厂大量堆存的铁尾矿得到有效的应用,进行了铁尾矿用作路面基层材料的试验、研究。经过无机结合料稳定土配比研究、击实试验、无侧限抗压强度试验后发现,当水泥剂量为5%、聚丙烯纤维掺量为1.4kg/m3、碎石掺量为30%、铁尾矿用量70%时,混合料7d无侧限抗压强度可达4.24MPa,达到了高速公路及一级公路路面基层材料无侧限抗压强度的要求。试验结果为下一步将金山店铁尾矿应用于公路工程奠定了良好的基础。     

煤矸石质固土材料的制备

利用大量排放的工矿业固体废弃物煤矸石,按一定比例掺加矿渣、水泥熟料、消石灰以及石膏,可制备出性能优良、成本低廉的煤矸石质固土材料.试验结果表明,煤矸石质固土材料的各组分含量对固化土的无侧限抗压强度都有较大影响,固化土的强度随着煤矸石与矿渣比的上升而下降;随着消石灰外掺量的增加而上升,并在消石灰掺量为20%时达到最大;石膏外掺量的增加也能有效提高固化土强度,测得其固化土7 d无侧限抗压强度为4.3 MPa,28 d和90 d分别可达5.3MPa和6.55 MPa.     

无碱液体速凝剂对掺不同石膏的水泥性能影响

研究无碱液体速凝剂对不同石膏种类及掺量水泥性能的影响.凝结时间、抗压强度试验结果表明,随着水泥中石膏含量增加,水泥净浆凝结时间减少,砂浆1 d抗压强度略有增加;相同掺量下,掺二水石膏的水泥净浆凝结时间最短,掺半水石膏凝结时间最长,掺无水石膏的水泥胶砂1 d抗压强度最高,掺半水石膏抗压强度最低.水化温度、X射线衍射(XR...     

无熟料垃圾底灰胶凝材料固化海洋土工程特性研究

以垃圾底灰、粉煤灰、矿渣和脱硫石膏为主要原材料,外掺少量复合激发剂,配制出无熟料固化剂,该无熟料固化剂的物理力学性能满足32.5复合水泥的技术要求。分别对无熟料垃圾底灰固化剂和32.5复合水泥固化海洋土进行不同掺量和不同龄期的无侧限抗压强度、劈裂抗拉强度、压缩和抗剪性能等工程特性研究。结果表明,无熟料垃圾底灰胶凝材料固化海洋土可行,且固化剂掺入比为24%的固化海洋土的工程特性相当于水泥固化海洋土中32.5复合水泥掺入比为12%。     

煤矸石作井下充填材料的研究

介绍了用硫铝酸盐-铝酸盐水泥体系制备高水充填材料的方法,进行了单浆凝结时间、胶凝时间和抗压强度测试。结果表明,用铝酸盐水泥熟料替代5%～30%的硫铝酸盐水泥熟料来制备高水充填材料,能大幅度提高材料后期强度,28d抗压强度最大可提高44.9%,而对材料胶凝时间及早期强度影响不大。用自燃后的煤矸石（红矸）作骨料,采用不同的水灰比、灰砂比,可制备出28d抗压强度达6.7MPa的充填体。     

FZ-H800巷道注浆堵水加固水泥基外加剂试验研究

针对目前注浆材料常出现回弹率大、早期强度不够、抗渗抗裂性能不佳等问题,研制了FZ-H800注浆专用水泥基外加剂。对该外加剂不同掺量的浆液进行试验,通过"BGF-7型指针式压浆剂凝结时间测定仪"、无侧限抗压仪、抗渗性测试和自主研发的膨胀率测试装置分别测出配方浆液的凝结时间、抗压强度、抗渗性和膨胀率。通过分析可知,最佳外加剂掺量为10%,常温下10%外加剂掺量的配方浆液初凝时间184 s、终凝时间339 s,凝结时间快;7 d可达45 MPa,28 d强度可接近或达到70 MPa;抗渗等级可达P8以上;膨胀率可达到0.31。FZ-H800注浆专用水泥基外加剂具有凝结快、早强、抗渗性高、微膨胀等特点。     

硅酸钠对水泥-粉煤灰基煤矿膏体充填材料的影响研究

山东省某煤矿膏体凝结时间缓慢,影响矿山正常开采,为此,提出了掺入硅酸钠缩短膏体凝结时间的构想,并在室内进行了相关的试验。试验结果表明:随着硅酸钠掺量的增加,水泥-粉煤灰基胶凝体系的初终凝时间逐渐缩短,在掺量为3%时,促凝效果较为明显,当掺量继续增加时,促凝效果不显著。且加有硅酸钠的水泥-粉煤灰基建筑垃圾膏体材料的凝结规律与胶凝体系的凝结时间规律保持一致,当硅酸钠掺量为3%时,其早期强度提高明显,8h和1d的抗压强度分别达到了0.21 MPa和0.52 MPa,从而保证了矿山的正常高效开采。     

夯实水泥土强度影响因素的试验研究

通过水泥土试块无侧限抗压强度的试验研究,定量分析了含水量、水泥掺量和养护龄期对黄土性粉质粘土水泥土桩无侧限抗压强度的影响.同时建立了水泥土试块无侧限抗压强度与水泥掺量、水泥土试块无侧限抗压强度与养护龄期、水泥土试块无侧限抗压强度与养护龄期和水泥掺量的关系式.为寻求更加经济、合理的施工配合比和参数提供了依据.     

Current situation and future trend of China rare earth luminescent material industry

<正>Rare earth luminescent material is one of the most important application sectors of rare earths.China enjoys the exceptional advantage to develop rare earth luminescent material for its abundant rare earth resources.After several decades'endeavor,China's rare earth luminescent material industry,headed by rare earth phosphor for lamp and LED and high efficient rare earth energy-saving light source,has been gradually developed into a scale industry.China has become a major production base of rare earth phosphor for lamps and rare earth     

China rare earth market review

正June 1~10,2014Rare earth market remained weak.Quoted price of rare earth products was similar to that in May.There was no sign of recovery in downstream market.The market of NdFeB magnetic materials and phosphor was depressed.Catalyst,polishing powder and ceramic industries remained inactive.Demand from downstream industry was soft.Consumers purchased on their needs.Suppliers had strong intention to sell.Prices of rare earth products     

Annual Report analysis of Chinese rare earth-related listed companies in 2013

<正>Chinese rare earth-related listed companies have published their 2013 annual reports.It can be understood from their reports that production and operation activities of Chinese rare earth-related companies were still heavily affected by macro economy and industrial policies.They basically followed the steps of national economy.In 2013,world economy recovered slowly but the economy     

Market opportunities and challenges for rare earth polishing powder

正1.Status of rare earth polishing powder Rare earth polishing powder with high content of cerium oxide began to replace iron oxide for glass polishing and became one of the key materials in glass polishing process since 1940.Compared with traditional iron oxide,rare earth polishing powder has many advantages,such as fast polishing rate,high polishing quality and long service life.It can achieve good surface quality and improve operation conditions.For example,in lens polishing,the polishing work that cerium     

Baotou Research Institute of Rare Earths developed a new RE alloy preparation technology

正Pyrometallurgy Laboratory of Baotou Research Institute of Rare Earths had independently developed a new preparation technology of rare earth alloy for NdFeB.The alloy can remarkably enhance the coercivity of NdFeB magnet but also evidently reduce the production cost of the magnet.The new master alloy was prepared in the kA pilot-scale electrolytic cell by the independent technology.The rare earth master alloy can be used as the raw material for NdFeB.Compared     

矿用防爆轴流对旋主要通风机叶片ANSYS模态分析及应用

高效节能矿用防爆对旋主要通风机的叶片是主要通风机运行的关键部件,叶片在运行时不断受到气流的作用力,从而使叶片产生振动,当叶片振动的频率与叶片的固有频率接近时,容易产生共振从而导致叶片的断裂。一旦叶片断裂时,对主要通风机的安全运行产生致命的影响,从而导致矿山、化工等企业发生重大事故,将会产生不可估量的损失。基于有限元分析软件ANSYS,对高效节能矿用防爆轴流对旋主要通风机叶片进行模态分析及产生对应的六阶模态频率,对主要通风机叶片的运行频率、固有频率及产生的共振问题进行了原理分析,并且解决了叶片频率共振的问题,从而为主要通风机叶片结构设计提供理论依据,并对主要通风机叶片的安全运行提供保障。     

2013 NdFeB export analysis

<正>China totally exported nearly 24,000 tonsof NdFeB products during 201 3,including 18,825 tons of permanent magnet,valued USD 1.34 billion at an average price of 71.4 USD/kg;3,277 tons of NdFeB magnetic powder,valued USD 1 01 million at an average price of 30.9 USD/kg;1,334 tons of strip casting ribbon,with total export value of USD 74million at an average price of 55.3 USD/kg;and 586     

Market and recycling of NiMH battery

<正>Market status and future trend of NiMH battery1.Global market of small NiMH battery Global market size of small NiMH batteries declined year on year since 2011.The trend will continue to 2018,at the rate of 5%to 10%annually.Demand for small NiMH batteries will be stable gradually.Many electrical apparatuses are powered by the built-in lithium battery today,which is the main reason for the shrunk market of small NiMH batteries.But,for some products,small NiMH     

China rare earth market review

正September 1-10,2014 Affected by the National Day holiday,rare earth transaction was stagnant and the market showed a weak steady state.As there was no good news for downstream market,some products with flat demand would likely rally slightly for some time to     

唐口煤矿深部复杂开采工作面瓦斯分源涌出规律研究

研究工作面瓦斯涌出规律对工作面瓦斯治理有重要意义。为了得到唐口煤矿深部3号煤层复杂开采条件下工作面回采时期瓦斯涌出时空演化规律,选取6304工作面作为对象,采用实测方法研究6304工作面瓦斯涌出规律。结果表明:6304工作面瓦斯涌出量为6.534 m³/min,其中煤壁占34.27%,落煤占29.62%,采空区占36.11%;沿工作面倾向由低到高,瓦斯浓度整体为上升趋势,其中1—76号架工作面瓦斯浓度小于0.20%,76—102号架瓦斯浓度上升明显,最大为0.387%;上隅角的后部采空区是工作面的瓦斯主要涌出源,上隅角1号测点瓦斯浓度0.78%,上隅角周边3号、5号、7号、8号、9号测点瓦斯浓度平均为0.643%;周期来压时,上隅角瓦斯相对平时较高。研究为针对性的瓦斯分源监控与灾害防治提供基础。