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《稀有金属》2019,(10)
黑曲霉(A.niger)在深层培养时具有复杂的生长形态,其直接影响黑曲霉的代谢产能。然而,黑曲霉浸矿过程中的形态特征及其对浸出效果的影响还未得到重视。通过黑曲霉浸铀的单因素实验,考察浸出时间、孢子接种量、碳源种类与用量、初始pH值、矿浆浓度对黑曲霉的形态特征与铀浸出的影响,分析两者之间关系。结果表明,在不同的浸出条件下,黑曲霉呈现出3种不同形态:紧实的生物矿石颗粒、松软的生物矿石颗粒和散状菌丝,当铀矿粉被黑曲霉完全包裹形成紧实的生物矿石颗粒时,铀的浸出率最高。在浸出时间4 d、孢子接种量1×10~8 spores·L~(-1)、蔗糖浓度25 g·L~(-1)、初始pH 6、矿浆浓度2%的条件下,可形成紧实的生物矿石颗粒,铀的浸出率达76.26%。 相似文献
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某红土镍矿加温搅拌浸出试验研究 总被引:3,自引:1,他引:2
某低品位红土镍矿的碱性脉石含量较高,矿石嵌布粒度细,平均镍品位0.91%,属难处理氧化镍矿,采用加温搅拌浸出方法可以有效地从中浸出镍.研究了加温搅拌浸出过程中各因素对镍浸出率的影响.结果表明,在温度85 ℃、矿石粒度-20目、酸矿质量比2∶5、液固体积质量比3∶1、搅拌浸出2 h条件下,镍浸出率可达60%以上. 相似文献
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从四川石棉矿区的酸性矿坑水和土壤中筛选到一株细菌PD-1,对其形态、理化特征及16SrDNA序列研究表明:细菌细胞呈杆状,革兰氏染色阴性,最适生长温度30℃,最适初始pH2.0,其16SrDNA序列与氧化亚铁硫杆菌的序列相似度高达99%以上,可鉴定为氧化亚铁硫杆菌菌株。利用该菌株对低品位碲矿进行摇瓶浸出实验,结果表明:菌株在接种量10%、温度30℃、初始pH2.0、转速150r/min、碲矿粒度-150μm及矿浆浓度2%的条件下浸矿,30d碲的浸出率可达67.8%。 相似文献
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从四川石棉矿区的酸性矿坑水和土壤中筛选到一株细菌PD-1,对其形态、理化特征及16SrDNA序列研究表明:细菌细胞呈杆状,革兰氏染色阴性,最适生长温度30℃,最适初始pH2.0,其16SrDNA序列与氧化亚铁硫杆菌的序列相似度高达99%以上,可鉴定为氧化亚铁硫杆菌菌株。利用该菌株对低品位碲矿进行摇瓶浸出实验,结果表明:菌株在接种量10%、温度30℃、初始pH2.0、转速150r/min、碲矿粒度-150μm及矿浆浓度2%的条件下浸矿,30d碲的浸出率可达67.8%。 相似文献
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福建紫金山含砷低品位硫化铜矿年产300tCu和1000tCu生物堆浸工业试验结果表明:铜浸出率随着矿石粒度的减小而提高,矿石粒度为-30mm,浸出周期为270d,铜的浸出率达到80.58%;铜萃取率和电积电流效率随着浸出液pH值的降低和电积液中铁的质量浓度的增加而降低,当浸出液pH值下降到1.19时,铜萃取率下降到了50%;通过增加堆高、定期中和萃余液、增加负载有机相洗涤和活性炭+沙滤+气浮塔脱除电积原液中有机物等工艺改进后,降低了萃取剂、煤油和电能的消耗量,提高了铜的浸出速率,浸出周期为200d,铜浸出率为81.31%,铜萃取--电积的耗电量为2679.98kW.h.t-1,高纯阴极铜生产成本1.05万元.t-1. 相似文献
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通过摇瓶实验,研究了活性炭在原生硫化铜矿细菌浸出中对铜与铁离子吸附的影响。研究结果表明,活性炭浓度和pH值对活性炭吸附铜和铁离子有重要影响,活性炭对铜和铁离予的吸附量随活性炭浓度增加而增加。在原生硫化铜矿石细菌浸出的初始阶段,添加活性炭可以大大加快铜的浸出速度和提高铜的浸出率,在600h内,铜的浸出率可以达到79%,比不添加活性炭时提高了68%。 相似文献
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《Hydrometallurgy》2007,89(1-4):3-18
A study of the effect of different variables (inoculation, pulp density, [Ag], nutrient medium, pH and [Fe3+]) on the silver-catalyzed bioleaching of a low-grade copper sulfide ore has been carried out in shake flasks. Chalcopyrite was the dominant copper mineral in the ore. Preliminary tests showed that addition of other ions (Sb, Bi, Co, Mn, Ni and Sn) did not enhance the copper dissolution rate. Conversely, an inoculation with mesophilic microorganisms and the addition of silver had a markedly catalytic effect on the extraction of copper. The kinetics of the silver-catalyzed chalcopyritic ore bioleaching was greatly affected by pulp density and silver concentration. Small amounts of silver (14.7 g Ag/kg Cu) dramatically accelerated the copper dissolution process while large amounts (294.12 g Ag/kg Cu) had an inhibitory effect. The copper dissolution rate was slightly affected in the range of pH between 1.2 and 2.5 but was significantly slower at pH 3.0. The effect of [Fe3+] in the presence of silver was studied both in abiotic and biotic conditions. High ferric iron concentrations in abiotic tests recovered similar copper amounts (∼ 95%) to those obtained without or with low [Fe3+] in the presence of bacteria. The leaching of copper from the low-grade copper ore can be very effectively enhanced with silver and mesophilic microorganisms. For that system, the onset of oxidizing conditions starts at an Eh value slightly higher than 650 mV. Above that critical value of potential the copper dissolution rate slows down. This also corresponds with the completion of the leaching process. As the potential rises past 650 mV, the copper extraction reaches a plateau. 相似文献
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Rory A. Cameron Rolando Lastra Saviz Mortazavi W. Douglas Gould Yves Thibault Pierre L. Bedard Lucie Morin Kevin J. Kennedy 《Hydrometallurgy》2009,99(1-2):77-83
This study is a continuation of previous work designed to assess the effect of elevated-pH bioleaching on a low-grade ultramafic nickel sulphide ore from Manitoba, Canada. The ore contains 21% magnesium and 0.3% nickel. Nickel is the only significant metal value, and is present primarily as pentlandite. A substantial fraction of the magnesium is present as lizardite, making processing of the ore difficult with conventional pyro- and biohydrometallurgical techniques. This work has two objectives: to maximize nickel extraction, and to minimize magnesium mobilization. Five-week stirred-tank bioleaching experiments were conducted with finely ground ore (− 147 µm) at three pH levels (3, 4 and 5) and five temperatures (5, 15, 22.5, 30, and 45 °C). The initial rate of nickel extraction from pentlandite was observed to be inversely correlated to acidity at all temperatures, while the final extraction of nickel after 5 weeks was determined to be moderately correlated to acidity at high temperatures and negatively correlated to acidity at low temperatures. The advantage of elevated-pH bioleaching was most evident at 5 °C, in which the final extraction of nickel at pH 5 was approximately 250% greater than at pH 3. Electron probe X-ray microanalysis of the post-leach residues revealed that the un-reacted lizardite was enriched with nickel during experiments conducted at pH 5, and that the extent of enrichment was a strong function of temperature. The undesirable extraction of magnesium exhibited a strong negative pH–temperature interaction and the consumption of sulphuric acid directly tracked the extraction of magnesium over all experimental conditions. Bioleaching at elevated pH substantially increased the ratio of nickel to magnesium in the leachate, and resulted in a substantial reduction in sulphuric acid consumption. 相似文献
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硫化铜矿细菌浸出试验研究 总被引:3,自引:0,他引:3
针对大红山硫化铜矿细菌浸矿的工艺参数及影响因素进行了试验研究,在pH1.5~2.5、温度20~35℃、铁离子浓度在10~20g/L的条件下,-20mm粒级矿石经24周柱浸,铜浸出率达30.62%。 相似文献
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利用紫金山低品位硫化铜矿,研究了微裂纹对铜生物浸出效果的影响。分别利用颚式破碎机、对辊破碎机和高压辊磨机对硫化铜矿进行破碎,采用体式显微镜、扫描电镜、核磁共振岩心成像系统和比表面积分析仪对矿石微裂纹及孔隙度进行观察统计与表征。结果表明,高压辊磨较颚式破碎和对辊破碎可以产生更多的微裂纹,同时高压辊磨破碎铜矿样品的孔隙度均高于颚式破碎和对辊破碎。-1.7mm粒级铜矿样品摇瓶浸出试验表明,由于高压辊磨破碎样品的比表面积和孔隙度更大,铜矿物与浸出液接触更加充分,浸出效果比颚式破碎和对辊破碎好。另外,-6.7+3.35mm粒级铜矿样品生物柱浸试验结果表明,含有更多微裂纹的高压辊磨破碎样品铜浸出率比颚式破碎提高9.10~15.43个百分点,比对辊破碎提高3.12~9.45个百分点。 相似文献
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Shijie Zhen Zhongqiang Yan Yansheng Zhang Jun Wang Maurice Campbell Wenqing Qin 《Hydrometallurgy》2009
This work investigates the bioleaching of Jinchuan low grade nickel-bearing sulfide ore containing rather high levels of olivine, chlorite and antigorite (MgO 30–35%) present in the main gangue minerals using a mixed mesophiles which are composed of Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans. It aims to test the technical feasibility to recover valuable metals from Jinchuan low-grade nickel-bearing sulfide ore by bioleaching process. The tolerance of the mixed bacteria to Mg2+ could be improved markedly from 10 g/L to 25 g/L after nearly 2 years adaptation. A nickel recovery of 91% and a cobalt recovery of 81% were achieved in 312 days column leaching process including 60 days acid pre-leaching stage and 252 days bioleaching stage. 相似文献