瓜尔胶和黄原胶对马铃薯淀粉及其变性淀粉糊化和流变性质的影响

研究瓜尔胶和黄原胶对马铃薯淀粉、马铃薯磷酸酯淀粉和马铃薯阳离子淀粉糊化和流变性质的影响。糊化性质实验表明瓜尔胶增加了3种淀粉的峰值黏度和成糊温度,降低了淀粉糊的热稳定性。黄原胶降低了马铃薯淀粉和马铃薯磷酸酯淀粉的峰值黏度并提高了糊的热稳定性和成糊温度,但对马铃薯阳离子淀粉起相反作用。动态流变实验表明加入黄原胶显著提高了3种淀粉的GO`、GO`O`值,降低了损耗角正切值tanδ,黄原胶对马铃薯阳离子淀粉动态流变学性质的影响最大,瓜尔胶对3种淀粉的动态流变学性质的影响不显著。静态流变实验表明加入瓜尔胶和黄原胶后的淀粉糊仍为假塑性流体,滞后环面积减少,稳定性提高,两种胶对马铃薯淀粉和马铃薯磷酸酯淀粉的作用比对马铃薯阳离子淀粉作用明显,并且黄原胶比瓜尔胶对淀粉作用更为显著。研究发现胶体与淀粉之间的电荷相互作用对复配体系的糊化性质和流变学性质起重要的作用。     

Influence of pH and hydrocolloids addition on yam (Dioscorea alata) starch pastes stability

Yam tubers (Dioscorea alata) are a non-traditional starch source that could be used as food ingredient. The stability of yam starch pastes (6/100 g suspension) submitted to different pH conditions during gelatinization and the effect of hydrocolloids addition (guar and xanthan gums) on starch syneresis under refrigeration were analyzed. Changes in pH (3, 5, 6) or the addition of gums (0.1–0.5/100 g suspension) did not affect the starch gelatinization temperature nor the gelatinization enthalpy as determined by differential scanning calorimetry. Rheological behavior was characterized by amylograph profiles and oscillatory rheometry. Amylograms showed that yam starch pastes maintained a high viscosity under heat treatment and mechanical stirring in neutral to slightly acidic conditions. Brabender viscosity increased when gums were added; the effect of guar gum on viscosity was more marked than that of xanthan gum. During refrigerated storage exudate production was observed of pastes without gums. Xanthan gum, at a concentration of 0.5/100 g suspension, showed higher effectiveness than guar gum to reduce exudate production during refrigerated storage. The addition of hydrocolloids could allow yam starch to be used in foods requiring low temperatures.     

Comparison of the effects of gums on dynamic rheological properties of acetylated sweet potato starch

Dynamic rheological properties of acetylated sweet potato starch (ASPS) pastes mixed with 3 commercial gums (guar gum, locust bean gum, and xanthan gum) were investigated at different gum concentrations. The dynamic moduli of the ASPS-gum mixtures were higher than those of the control, and they increased with an increase in gum concentration. In particular, the G′ value of xanthan and G″ value of guar gum at a 0.6% gum concentration were much higher as compared to those of other mixtures. Tan δ values of ASPS-xanthan mixtures were much lower than those of other samples, indicating that the elastic properties in the ASPS-gum mixture systems were strongly affected by the additions of xanthan. These results suggest that the presence of gums in ASPS modifies the viscoelastic properties, and that these modifications are dependent on the gum type and gum concentration.     

阿拉伯胶对马铃薯淀粉糊化及流变性质的影响

研究了阿拉伯胶对马铃薯淀粉糊化及流变性质的影响,考察了马铃薯淀粉/阿拉伯胶混合体系在盐、柠檬酸、糖等不同介质下的糊化性质.RVA结果表明在水溶液中随着阿拉伯胶含量的增加,混合体系的峰值黏度显著降低,具有更好的热稳定性,但在冷却过程中,淀粉黏度明显上升,回值略有增加.添加胶体后,马铃薯淀粉在盐溶液及柠檬酸溶液中的峰值黏度稍有降低,在糖溶液中则表现出更高的黏度.静态流变实验显示不同混合体系均表现出剪切变稀性,添加胶体后,体系假塑性增强,滞后环面积明显减小.     

The Relationship Between Wheat Flour and Starch Pasting Properties and Starch Hydrolysis: Effect of Non‐starch Polysaccharides in a Starch Gel System

Non‐starch polysaccharides (NSPs) and celite (used as inert filler) were incorporated into wheat flour and wheat starch paste preparations at levels of 1, 2.5, and 5% in both addition and replacement modes. Pasting properties of gums were compared using a Rapid Visco Analyser. Use of guar gum and locust bean gum elevated the peak and final viscosities of the resulting pastes (when used in either addition or replacement modes), whereas arabic gum significantly reduced the peak and final viscosity properties of the pastes. Samples which comprised wheat starch yielded higher peak and final viscosity characteristics compared to wheat flour containing samples, however higher breakdown and setback values were observed for samples using wheat flour as a base compared to wheat starch. The firmness of the gels (as determined using a texture analyser) increased with the use of wheat starch compared to wheat flour. Little significant difference was observed between NSP used and mode of application (replacement or addition). In vitro starch degradation was conducted on the wheat flour gels. Guar gum and locust bean gum reduced the amount of starch degradation in these gels, whereas arabic gum and celite increased the amount of starch hydrolysis (or were similar to the control). The rate of starch hydrolysis appears to be related to the viscosity altering behaviour of the NSPs in a starch‐rich system. The results indicate that selection of NSPs is important as gum arabic has the potential to increase starch hydrolysis compared to the control.     

Viscosity of guar gum and xanthan/guar gum mixture solutions

The viscosity of diluted guar gum solutions and the viscosity of xanthan and guar gum mixture solutions have been studied. Guar gum solutions showed pseudoplastic behaviour. Apparent viscosity increased with gum concentration and decreased with the temperature at which viscosity was measured. A maximum in the plot of viscosity versus increasing dissolution temperature was observed at 60 °C. This behaviour was related to differences in molecular structure of the polymers solved at different temperatures. Mixtures of xanthan and guar gum showed a higher combined viscosity than that occurring in each separate gum. This synergistic interaction was affected by the gum ratio in the mixture and dissolution temperature of both gums. The effect of polysaccharide concentration (1.0, 1.5 and 2.0 kg m⁻³), xanthan/guar gum ratio (1/5, 4/2, 3/3, 4/2 and 5/1) and dissolution temperature (25, 40, 60 and 80 °C for both gums) on the viscosity of solutions of mixtures were studied. The highest viscosities were observed when 2.0 kg m⁻³ gum concentration was used together with a ratio of xanthan/guar gum of 3/3 (w/w) and dissolution temperature of 40 and 80 °C for xanthan and guar gum, respectively. © 2000 Society of Chemical Industry     

直链淀粉含量对玉米淀粉/瓜尔胶复配体系糊化和流变特性的影响

为考察直链淀粉含量对淀粉/瓜尔胶复配体系性质的影响,以不同直链淀粉含量的玉米淀粉(蜡质玉米淀粉、普通玉米淀粉和高直链玉米淀粉)为原料,加入瓜尔胶,研究复配体系的糊化、流变及凝胶特性。结果表明:瓜尔胶与直链淀粉之间的相互作用是引起淀粉复配体系黏度和稠度系数增加、成糊温度和流体指数降低的主要原因。动态流变实验结果表明淀粉中直链淀粉含量不同对复配体系的动态模量的影响也不同。在糊化过程中,随着直链淀粉含量增加,直链淀粉分子与瓜尔胶间的相互作用增强,阻碍了直链淀粉分子间的聚集重排,使得复配体系硬度值减小,3种玉米淀粉形成了质地更为柔软的凝胶。     

Rheological behaviors of hydroxypropylated sweet potato starches influenced by guar,locust bean,and xanthan gums

This study examined the steady flow and dynamic rheological behaviors of hydroxypropylated sweet potato starch (HPSPS) pastes mixed with guar gum (GG), locust bean gum (LBG), and xanthan gum (XG) at different concentrations (0, 0.3, and 0.6%). The HPSPS–gum mixtures had higher shear‐thinning fluid characteristics than the control (0% gum) at 25°C. The addition of the gums resulted in an increase in the consistency index (K) and apparent viscosity (η_a,100). The dynamic moduli (G′, G″) and complex viscosity (η*) values of the HPSPS–gum mixtures were higher than those of the control, and they increased with an increase in gum concentration. In particular, the presence of XG at 0.6% in the HPSPS–gum mixture systems gave rise to the greatest viscoelastic properties among the gums examined at different concentrations. The tan δ (ratio of G″/G′) values (0.35–0.57) of the HPSPS–GG and HPSPS–XG mixtures were much lower than those of the control (0.82) and HPSPS–LBG (0.88–1.06), indicating that the elastic properties in the HPSPS–gum mixture systems were strongly affected by the additions of GG and XG. These steady flow and dynamic rheological parameters indicated there were synergistic interactions between the HPSPS and gums. The synergistic effects of the gums and modified starch were hypothesized by considering the molecular incompatibility and molecular interactions between the gums and HPSPS.     

Effects of guar gum and arabic gum on the physicochemical,sensory and flow behaviour characteristics of frozen yoghurt

This study investigated the effect of guar gum and arabic gum on physicochemical, sensory and flow behaviour properties of frozen yoghurt. The results indicated that gums significantly affected the viscosity, overrun and melting rate of frozen yoghurt. The highest overrun value was observed in sample containing 0.5% arabic gum. Frozen yoghurt containing 0.3% guar gum had the highest viscosity. The longest first dripping time was observed in sample containing 0.5% arabic gum. Flow behaviour of samples showed that all frozen yoghurts exhibited shear thinning behaviour. Guar gum at a concentration of 0.2% and arabic gum at a concentration of 0.5% presented the best total acceptability. The results of this study revealed that the frozen yoghurt produced with arabic gum had the better overall sensory and physicochemical characteristics.     

四种常见亲水胶体对面团特性的影响研究

采用粉质仪、快速黏度分析仪和流变仪研究添加黄原胶、κ-卡拉胶、魔芋胶和瓜儿豆胶对小麦粉粉质特性、糊化特性及面团流变特性的影响.研究结果表明,亲水胶体可以提高小麦粉的黏度,改善面团的黏弹特性,不同亲水胶体的作用效果存在差异,添加质量分数1%的黄原胶和魔芋胶后小麦粉吸水率分别增大了4.9%和7.9%,添加质量分数1%黄原胶、κ-卡拉胶和瓜儿豆胶后小麦粉糊的糊化温度分别降低了21.35℃、18℃、14.7 ℃,添加黄原胶和瓜儿豆胶能够显著地提高面团的稳定性,而添加魔芋胶能够延缓淀粉的重结晶特性.     

亲水胶体对石蒜淀粉糊特性的影响

为改善石蒜淀粉的加工品质特性,系统研究亲水胶体对石蒜淀粉溶胀能力、糊化特性、冻融稳定性及流变特性的影响。添加亲水胶体后,石蒜淀粉膨胀力均有所下降,除魔芋胶外,混合体系的溶解度均有所提高;亲水胶体有效抑制了淀粉的回生,使冻融稳定性增强,其中黄原胶效果较明显。糊化性质表明亲水胶体的加入使峰值时间和成糊温度升高,峰值黏度、崩解值和回生值降低,提高了石蒜淀粉的热稳定性和冷稳定性。静态流变实验结果表明：Herschel-Bulkley方程能很好拟合稳态流变曲线,加入亲水性胶体后体系仍为典型的假塑性流体,除阿拉伯胶外,其他胶体的添加均不同程度地降低了淀粉凝胶的触变性。动态流变实验结果表明所有样品体系G’均大于G”,且呈现出频率依赖性,说明具有典型的弱凝胶特性。加入亲水胶体能保持淀粉体系内部结构稳定,增强其抗剪切性。因此,亲水胶体可以一定程度改善石蒜淀粉糊的性质,且与亲水胶体的种类、结构有关。     

瓜尔豆胶对锥栗淀粉糊化和流变学特性的影响

以新鲜锥栗为原料,考察了瓜尔豆胶对锥栗淀粉的糊化特性和流变学特性的影响。结果表明,向锥栗淀粉中添加瓜尔豆胶后,锥栗淀粉糊化溶液的峰值黏度和终值黏度增大,且随瓜尔豆胶添加比例的增加而增大;添加瓜尔豆胶增大了锥栗淀粉的起始糊化温度和峰值糊化温度,提高了锥栗淀粉的吸热焓,使得糊化过程更长,吸热更多。添加瓜尔豆胶后的锥栗淀粉溶液显示为假塑性流体,剪切变稀现象更为明显,具有更大的黏弹性。添加瓜尔豆胶后,混合物形成的凝胶表面空隙中填充物增多,空隙数量减少,且空隙分布更加均匀。     

食品胶协同干热处理对马铃薯淀粉理化特性的影响

为了改善马铃薯淀粉加工特性,选用瓜尔胶、羧甲基纤维素钠和黄原胶3种食品胶分别与马铃薯淀粉复配后进行干热处理,研究食品胶协同干热处理对马铃薯淀粉糊化、老化和流变特性的影响。研究发现,中3种食品胶协同干热处理均能够降低糊化温度与糊化焓,并且均能增强淀粉体系稳定性,使其呈现出弹性流体性质,不仅如此还均能提高淀粉糊热稳定性以及耐剪切能力,此外均能增强淀粉凝胶的冻融稳定性。结果表明,3种食品胶协同干热处理均能起到改善马铃薯淀粉加工特性的作用,对其改善程度对比分析发现,黄原胶协同干热处理改善马铃薯淀粉特性效果最好。     

Viscosity of solutions of xanthan/locust bean gum mixtures

Xanthan and locust bean gums are polysaccharides able to produce aqueous solutions with high viscosity and non‐Newtonian behaviour. When these solutions are mixed a dramatic increase on viscosity is observed, much greater than the combined viscosity of the separated polysaccharide solutions. In this work the influences of different variables on the viscosity of solutions of mixtures of xanthan/locust bean gum have been studied. Total polysaccharide concentration, xanthan and locust bean ratio on mixture and temperature at which the gum was dissolved (dissolution temperature) for both xanthan and locust bean gums have been considered. Under these different operational mixture conditions shear rate and time have also been considered to describe the rheological behaviour of the solutions studied. The high viscosity increase observed in these mixtures is due to the interaction between xanthan gum and locust bean gum molecules. This interaction takes place between the side chains of xanthan and the backbone of the locust bean gum. Both xanthan molecule conformation in solution – tertiary structure – and locust bean gum structure show great influence on the final viscosity of the solution mixtures. Xanthan conformation changes with temperature, going from ordered structures to disordered or chaotic ones. Locust bean gum composition changes with dissolution temperature, showing a dissolved galactose/mannose ratio reduction when temperature increases, ie the smooth regions – zones without galactose radicals – are predominantly dissolved. The highest viscosity was obtained for the solution mixture with a total polysaccharide concentration of 1.5 kg m⁻³ and a xanthan/locust ratio of 2:4 (w/w) and when xanthan gum and locust bean gum were dissolved at 40°C and 80°C, respectively. © 1999 Society of Chemical Industry     

盐及非盐物质对常用低浓度食品胶溶液粘度影响的研究

对饮料生产中常用的食品胶－黄原胶、海藻酸钠、瓜尔胶和琼脂在低浓度水相体系中外加盐（阴、阳离子）、乙醇、蔗糖及柠檬酸对溶液粘度的影响作了探讨性研究,结果表明四种胶溶液（０．１０％黄原胶、０．３０％海藻酸钠、０．２５％瓜尔胶、０．１０％琼脂）中、瓜尔胶溶液对盐的耐受性最好,即大多数阴阳离子都不会对其粘度产生影响,而常用金属盐阳离子及Ｃｌ＾－、ＳＯ３＾２－对黄原胶溶液粘度的影响与阴阳离子对海藻酸钠和琼脂     

不同添加物对羟丙基木薯淀粉流变特性的影响

淀粉糊流变特性是影响淀粉类食品加工品质的主要因素。利用流变仪测定了不同添加物质对羟丙基木薯淀粉流变特性的影响,结果表明:添加不同的物质均未改变羟丙基木薯淀粉糊的流体类型,各流变参数经Herschel-Bulkley模型进行拟合,拟合系数接近1。单甘酯、食盐、柠檬酸使羟丙基木薯淀粉糊的剪切应力不同程度降低,黏稠系数减小,流变特性指数增加;蔗糖酯、酪朊酸钠、黄原胶、CMC、瓜尔豆胶、蔗糖使羟丙基木薯淀粉糊的剪切应力明显提高,黏稠系数增加,流变特性指数减小。     

Influence of Gluten and Gum Additives and Cryogenic Treatment on Some Properties and Morphology of Wheat Starch Complex Gels

The influence of gums (guar and xanthan) and gluten additives on the physicochemical properties and structural features of wheat starch gels (8%, w/w) subjected to cryogenic treatment at various temperatures (−9°C, −20°C, −40°C) was studied. Shear modulus and breaking stress of the gels were measured, the gels' morphology was studied with optical microscopy and the local mobility of water in the gels was determined with ESR. The total concentration of polysaccharide additives did not exceed 1% (w/w), and a 65:35 (w/w) mixture of guar and xanthan gums proved to be the optimal additive, which caused a noticeable increase in rigidity and strength of the resulting complex gels. Shear modulus and breaking stress of the gels decreased with lowering the temperature of the cryogenic treatment. The heterogeneous morphology of thin sections of the gel samples was revealed via optical microscopy. ESR studies showed that the local mobility of water was much lower in the gels than in pure water.     

Influence of non-starch polysaccharides on the in vitro digestibility and viscosity of starch suspensions

The effects of adding non-starch polysaccharides (xanthan gum, guar gum, konjac glucomannan, and pectin) on the starch digestibility and viscosity of raw starch suspensions in a mixed system were determined. Each type of polysaccharide was added to high-amylose corn starch suspensions at defined concentrations. High-amylose rice starch suspensions mixed with xanthan and guar gum were prepared for comparison. The extent of starch digestibility was determined by an in vitro method, and the glucose diffusibility from the dialysis tube in the presence of polysaccharides was measured. The added polysaccharides were observed to decrease the starch digestibility in a mixed system. When compared at the same concentration, xanthan gum showed the most pronounced suppressive effect on starch digestibility and glucose diffusibility from the dialysis tube. The addition of polysaccharides increased the viscosity of the starch suspension. Significant relations were found between the extent of starch digestibility and the apparent viscosity at low shear rate.     

Stabilization of olive oil – lemon juice emulsion with polysaccharides

An olive oil – lemon juice Greek salad dressing was developed employing xanthan gum as stabilizer and gum arabic or propylene glycol alginate as emulsifier in various combinations. In general, samples containing xanthan gum arabic were more stable against oil droplet coalescence and less stable against creaming. The use of propylene glycol alginate in the place of gum arabic, on the other hand, resulted in emulsions of higher creaming stability. Application of steady shear rheology and determination of rheological parameter values from the shearing stress-rate of shear curves, indicated that the rheological properties of the dressings were decreased with storage. Dressing texture assessment preference tests indicated that potential consumers of the product may opt for a medium viscosity product and this has to be taken into consideration when designing polysaccharide – stabilized dressings exhibiting a decrease in their textural characteristics with storage time.     

Effect of non-starch polysaccharides on the in vitro digestibility and rheological properties of rice starch gel

The starch digestibility and rheological properties of gels were evaluated in the presence of three non-starch polysaccharides (agar, xanthan gum and konjac glucomannan) with rice starch. Each polysaccharide was added to 30% (w/w) rice starch suspension at defined concentrations and starch gels were prepared. The extent of starch gel digestibility was determined by an in vitro method and rheological properties by a dynamic oscillatory test and a compression test. The added polysaccharides suppressed starch hydrolysis in the gels compared with the control, and a concentration dependency of this suppressive effect was observed. Adding agar and xanthan gum increased the storage shear modulus (G′) of starch gels, while adding konjac glucomannan decreased G′ values. The results indicate that the suppressive effect of non-starch polysaccharides on starch digestibility appears to be not only due to the rigidity of the gel, but also the interaction between starch and non-starch polysaccharides.