The significance of many-body interactions in physical adsorption

The significance of many-body interactions in the physical adsorption of rare gas atoms on solid surfaces has been investigated. A simple model of the system was considered in which the atoms of the solid and the adsorbed atom were represented by interacting isotropic point dipoles. The fullN-body interaction energy between the adsorbed atom and the solid was calculated exactly to lowest order in the expansion parameter [₀(₀/)²]/4d ³ (, and ₀, ₀ are the solid atom's and adsorbed atom's characteristic frequency and polarizability,d is the distance from the surface of the adsorbed atom, and is the number of atoms per unit volume in the solid). The interaction was then evaluated for the adsorption of various rare gas atoms on rare gas solids. It was found that the fullN-body interaction deviated at most by only2 1/2% from the interaction obtained by considering only two-body interactions. In addition, it was found that a finite expansion in two-, three-, ... body expressions may lead to erroneous results for the interaction energy since extensive cancellations occur between successive terms of the series.     

Dielectric relaxation in polychlorotrifluoroethylene

The effect of increasing lamellar thickness in bulk polychlorotrifluoroethylene (PCTFE) by various methods (annealing and increasing time and temperature of crystallisation) on the parameters of the and relaxations has been studied.For the a relaxation consistent increase in temperature of maximum loss and activation energy with increasing lamellar thickness confirms the strong suggestion of earlier work [6] on oriented specimens and shows that the relaxation arises mainly in the interior of the lamellae with little contribution from the chain folds.No systematic changes in these parameters with increasing lamellar thickness was found for the relaxation and this is explained by the presence of _c and _a components in crystalline and amorphous regions respectively. The component _a (as well as the _c one) shows a marked anisotropy in magnitude with respect to the draw direction in oriented specimens relative to the direction of the applied electric field. This implies a lining up of the chain molecules parallel to one another in amorphous regions.The non-existence of analogous short chain compounds and experimental scatter prevented detailed checking of the consistency of the data for the relaxation with the theory for the _c-C _c model [5].     

Mutual Friction in Superfluid 4He Near the λ-Line

We present experimental results for the thermal resistivity of superfluid ⁴He along several isobars between saturated vapor pressure and the melting pressure. The measurements are for the temperature range 1–T _c(q)/T <t<2×10^–5 and the heat-flux range 3<q<70 W/cm². Here t1–T/T , T is the transition temperature in the limit of zero q, and T _c is the transition temperature at finite q. The data suggest that the resistivity has an incipient singularity at T which can be described by the power law =(t/t ₀)^–(m+) where t ₀=(q/q ₀) ^x . However, the singularity is supplanted by the transition to a more highly dissipative phase at T _c(q)<T . The results suggest a mild dependence of m+ on the pressure P, but can be described quite well by m+=2.76, x=0.89, and q ₀=q _{0, 0}–q _{0, 1} P with q _{0, 0}=401Wcm^–2 and q _{0, 1}=–5.0Wcm^–2bars^–1. The results imply that the Gorter–Mellink mutual friction exponent m has a value close to 3.46 and is distinctly larger than the classical value m=3.     

Evolution of transient thermal processes in layer counterflow apparatuses and heat exchangers

Results are given of an analytic investigation of transient processes inside counterflow apparatuses and heat exchangers with temperature disturbance in one of the heat carriers at the entry to the apparatus.Notation =(t–t₀)/(T₀–t₀),=(T–t₀)/(T₀ s-t₀) relative temperatures - t, T temperatures of material and gas respectively - t₀, T₀ same for the initial state - Z=[ _Vm₁/c(1–w/w_g)] [–(y₀–y)/w_g] dimensionless time - m₁=1/(1+Bi/) solidity coefficient - B₁=( _FR/) Biot number - _{F V} heat-exchange coefficients referred to 1 m² surface and 1 m³ layer - R depth of heat penetration in a portion - portion heat conductivity coefficient - shape coefficient (=0 for a plate,=1 for a cylinder,=2 for a sphere) - c, C_g heat capacities of material and gas respectively - , _g volumetric masses - w, W_g flow velocities of material and gas - y distance from the point of entry to the heating heat carrier - y₀ heat-exchanger length - Y= _Vm₁y/W_gC_{g g} dimensionless coordinate - m=cw/C_g– _gW_g water equivalent ratio Deceased.Translated from Inzhenerno-Fizicheskii Zhurnal, vol. 20, No. 5, pp. 832–840, May, 1971.     

Temperature dependence and microwave enhancement of the critical current of superconducting microbridges

The temperature dependence of superconducting tin, thin-film, narrow bridges has been investigated. NearT _c the critical current varies with (1 – T/T_c ), with a distribution of values between 1 and 3/2. It is suggested that the values can be used to characterize the bridges. The microwave enhancement ofI _c andT _c was measured and these data were compared with a recent theory by Christiansenet al. on the microbridges. We found that their theory gives a correct prediction for the Dayem effect in the bulklike bridges (with =3/2) while their theoretical values for the junction-like bridges (with =1) are not in agreement with our data.Work supported in part by the National Science Foundation.     

Phase transformations in permanent-mould-cast aluminium bronze

The phases obtained in aluminium bronze (Cu-10Al-4Fe) cast into a permanent mould were investigated. The parameters examined were the pre-heating temperature of the mould and the graphite coating thickness. The phases and ₂ were detected as well as the metastable phases and . The intermetallics of the system Fe-Al were obtained in various stoichiometric compositions. The different cooling rates of the casting resulted in two mechanisms of transformation to grains out of the unstable phase, one being nucleation and growth producing needle-shaped grains, the other exhibiting a massive transformation to spherical grains. These two mechanisms determine the changes in the size of the a grains as result of changes in the cooling rate in its various ranges.     

A mixed finite element formulation for shells through a reduced Reissner's principle in elastodynamics

Summary The use of Mixed models based in Reissner's principle in statics has been found to lead to some desirable simplifications in Finite Element formulations, in particular in plates and shells. Reduced formulations of Reissner's principle such as the one used by Prato have proved to be even more successful. In this paper, a reduction similar to that of Prato is attempted on a mixed elastodynamic variational principle by Karnopp.

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Eine gemischte finite Elemente-Formulierung für Schalen durch ein reduziertes Reissnersches Prinzip der Elastodynamik

Zusammenfassung Die Verwendung von gemischten Modellen basiert auf Reissners Prinzip der Statik führt zu erwünschten Vereinfachungen bei der Formulierung von finiten Elementen im speziellen bei Untersuchungen von Platten und Schalen. Reduzierungen des Reissnerschen Prinzips, wie sie von Prato angewendet worden sind, haben sich sogar als noch erfolgreicher erwiesen. In dieser Untersuchung wird eine Reduktion, ähnlich der von Prato, für ein gemischtes elastodynamisches Variationsprinzip nach Karnopp, vorgenommen.

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Symbol Table A Domain of integration of the Functional. Also area of the triangle - b Second fundamental form of the shell middle surface - C ^ijkl Elastic Constants - E ₁,E ₁ ^* Strain Energy and Co-Energy density - e _ij Elastic strain tensor - f _i Body force density tensor - I _ks Karnopp's functional, specialized to shells - I _ksc Contracted Karnopp's functional, specialized to shells - i, j, k Index 1, 2, 3 - K ₁,K ₁ ^* Kinetic Energy and Co-Energy density - K ^* Kinetic co-energy density for shell - m Moment tensor defined at the mid-surface - n In-plane stress tensor defined at the middle surface - n Qualifier for the boundary normal - p ,p ³ Boundary forces - Prescribed boundary forces - p Shear force tensor defined at the mid-surface - R Position vector of a point in the volume of the shell - r Position vector of a point on the mid-surface - r _i Net impulse density tensor - S _u Portion of the boundary where displacements are preseribed - S Portion of the boundary where forces are prescribed - s Qualifier for the direction tangent to the boundary - t Time variable - t ^ij Stress tensor - u ,u ₃ Mid-surface displacements - Mid-surface velocities - V Volume - v _i Displacement tensor - , Indices. Range 1, 2 - Shear strain tensor for the middle surface - Variation operator - Mid-surface strain tensor - Mid-surface curvature strain tensor - Direction cosine tensor for boundary normal - Mid-surface rotation tensor - Mid-surface angular velocity tensor - _M Strain energy density - _M * Strain co-energy density - _B * Bending strain co-energy density - _TS ^* Transverse shear strain co-energy density - | Covariant differentiation with respect tox , etc - Partial differentiation with respect tox , etc - .(dot) Time differentiation - -(bar) Prescribed quantities     

Breakup of an anomolously viscous liquid film in a centrifugal force field

An equation is obtained for the breakup radius with consideration of tipping moments and Laplacian pressure forces acting on the liquid ridge at the critical point.Notation K, n rhenological constants - density - surface tension - r current cup radius - R maximum cup radius - r_c critical radius for film breakup - ¯r=¯r=r/R dimensionless current radius - ¯r_c=r_c/R dimensionless critical radius - ₀, _c actual and critical film thicknesses - current thickness - R_r ridge radius - h₀ ridge height - h current ridge height - ₀ limiting wetting angle - current angle of tangent to ridge surface - angle between axis of rotation and tangent to cup surface - angular velocity of rotation - q volume liquid flow rate - v₁ and v meridional and tangential velocities - =4vv _lm/r,=4v_m/r dimensionless velocities - M moments of surface and centrifugal forces - M_v moment from velocity head - p_r pressure within ridge - P_vm pressure from velocity head - p_m, p_pm pressures from centrifugal force components tangent and normal to cup surface - deviation range of breakup radius from calculated value - ¯r_max, ¯r_min limiting deviations of breakup radius - _c angle of tangent to curve _c/°₀=f(¯r) at critical point - t random oscillation of ratio _c/_c Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 51–56, July, 1980.     

Structure of unidimensional temperature stresses

Using the structural approach, the temperature stresses are examined in a semiinfinite rod, insulated on the lateral faces and rigidly fixed at the end. A comparative analysis is made for three heat-transfer models.Notation k(t) heat flux relaxation function - (t) internal energy relaxation function - T rod temperature - ambient temperature - t time - x coordinate along the rod - _xx(x, t) stress - u(x, t) displacement - (x, t) deformation - c₀=(E/)^1/2 speed of sound in the rod under isothermal conditions - E elasticity modulus - density of the material - _t coefficient of thermal expansion - thermal-conductivity coefficient - a thermal-diffusivity coefficient - b thermal-activity coefficient - c_q=(a/_r)^1/2 velocity of heat propagation - _r heat flux relaxation time - (t) unique Heaviside function Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 33, No. 5, pp. 912–921, November, 1977.     

Vertical motion of a sphere in an electrically conducting,stratified, diffusive medium

Summary The vertical (upwards) flow of an incompressible, Newtonian, viscous, stratified, diffusive, electrically conducting fluid embedded with a uniform magnetic field that is applied in the vertical direction, past a non-conducting sphere is considered. Quasisteady approximation is made allowing for a time dependent buoyancy force. Method of matched asymptotic expansions is employed to obtain the drag exerted on the sphere, for small values of a stratification parameter such that 1,R _e ^1/3, ^–1/3,P _e ^2/3 andR _m =O(^2/3). The drag is computed for certain typical values of the magnetic interaction parameter and diffusivity parameter. The results reveal the fact that while the stratification and magnetic field have the enhancing effect over the drag, the effect of diffusivity is to decrease it.With 3 Figures     

The specific heat and critical magnetic field of superconducting PdH(D)

From the solution of the Eliashberg equations on the imaginary axis, the thermodynamic properties, specific heat, and critical magnetic field of PdH(D) have been calculated. The Eliashberg kernels ²()F() were constructed using a published value of ²(), and F() was obtained from inelastic neutron scattering data. The results for the specific heat are in good agreement with published experimental data. The critical magnetic field shows a nearly parabolic behavior as a function of temperature, in disagreement with the linear experimental behavior. The deviation function D(t) and the ratios C(T _c)/T _c and [T _c/H _c(0)]² indicate that the PdH(D) system is BCS-like. The functional derivative of T _c with respect to changes in the kernel is also calculated.On sabbatical leave from the Instituto de Investigaciones en Materiales, UNAM, Mexico.     

A superconducting vibrating reed applied to flux-line pinning. I. Theory

A theoretical treatment is given of a superconducting reed clamped at one end and performing flexural vibrations in a homogeneous longitudinal magnetic fieldB _a. When the flux lines are rigidly pinned the reed behaves like an ideal diamagnet whose bending distorts the external field. This generates a magnetic restoring force (line tension) B _a ² which is independent of the reed thicknessd, whereas the mechanical restoring force (stiffness) is d ³. Therefore, the resonance frequency /2 of a thin superconducting reed increases drastically when a fieldB _a is applied, or for a givenB _a, when the reed is cooled below its critical temperatureT _c. With decreasing pinning strength (characterized by Labusch's parameter ) the resonance frequency decreases, ²²– _pin ² where _pin ^{2 –1}, and an attenuation _v ^–2 occurs due to the viscous motion of flux lines. For larger vibration amplitudes an additional, amplitude-dependent damping _h ^–3 occurs due to the hysteretic losses caused by elastic instabilities during flux motion.On leave from Centro Atómico, Bariloche, Argentina.     

Influence lines for bending under a ring load of a free shell,a shell embedded in a soft medium and a shell containing a soft core

Summary Theoretical expressions for stresses and displacements have been derived for bending under a ring load of a free shell, a shell embedded in a soft medium, and a shell containing a soft core. Numerical work has been done for typical cases with anElliot 803 Digital Computer and influence lines are drawn therefrom.

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Einflußlinien für die Biegung einer freien Schale, einer Schale in einer weichen Bettung und einer Schale mit weichem Kern

Zusammenfassung Für die Biegung einer freien Schale, einer weich gebetteten Schale und einer Schale mit weichem Kern unter einer Ringlast werden Ausdrücke für die Spannungen und Verschiebungen hergeleitet. Die Ergebnisse wurden für einige typische Fälle mit einem DigitalrechnerElliot 803 numerisch ausgewertet. Die sich ergebenden Einflußlinien wurden graphisch dargestellt.

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Nomenclature A (),B () Functions of - a, t Mean radius and thickness of the shell - E _S , _S Young's modulus andPoisson's ratio of the shell - G _c , _c Shear modulus andPoisson's ratio of the casting or core - I ₀ (r),I ₁ (r) ModifiedBessel functions of the first kind and order zero and one respectively - K ₀ (r),K ₁ (r) ModifiedBessel functions of the second kind and order zero and one respectively - p Ring load, lb/in - U, W Displacement components in the casing or core in thez andr direction - u, w Displacement components of a middle surface point in the shell - _r , _rz Radial and shearing stress components - Independent variable of infinite integrals - k [3(1–S ²)a ²/t ²]^1/4 With 13 Figures     

Heat conduction in a multilayer composite wedge

A new method for analytically solving a problem of steady-state heat conduction for multilayer composite wedge-shaped bodies is suggested based on a generalization of the integral Mellin transform.Notation T temperature - _rr, thermal conductivity coefficients - thickness of composite material layers (1) - N₁(), N ₂ ⁽¹⁾ (), N ₂ ⁽²⁾ () auxiliary local functions from the rapid variable =r/ - m(r, p) auxiliary function entering the core of the generalized integral Mellin transform - ₀ half of the wedge aperture angle Moscow Institute of Chemical Engineering. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 64, No. 4, pp. 487–491, April, 1993.     

Motion of a thermal wave front in a nonlinear medium with absorption

We study the evolution of a thermal perturbation in a nonlinear medium whose thermal conductivity depends on the temperature and the temperature gradient according to a power law.Notation u temperature - k coefficient of thermal conductivity - t time - x spatial variable - x₊ a point on the thermal wave front - a ² generalized coefficient of thermal diffusivity - , , , and s parameters of the process - (x^s) Dirac delta-function - B[, ] a beta function - v(, x), (t) auxiliary functions - A, C, T_o, T_m, T*, R, r, p, and _m constants and parameters Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 4, pp. 728–731, October, 1980.     

Density Response and Equilibration in a Pure Fluid Near the Liquid-Vapor Critical Point: 3He

We report measurements of the local density response inside a quasi 1-D horizontal ³ He fluid layer to a step-like change T of the boundary temperature, where |T| 80 K and much smaller than |T – T_c| where T_c is the critical temperature. These experiments used a new cell design, described in the text, and were carried out along the critical isochore both above and below T_c. The observed temporal and spatial density response (t, z) and its equilibration time are described adequately by the relations developed from the thermodynamic theory of Onuki and Ferrell. We verify that over the temperature range of low stratification, where computer simulations and closed-form calculations can be compared, they are in exact agreement. The systematic differences of experimental results from predictions can be accounted for by the departure of the cell from the ideal 1-D geometry. The much larger disagreement between the experimental and predicted equilibration time scale in earlier experiments is also explained. Finally, deviations from linearity observed in the density response for steps |T| larger than 90 K are reported and the implications of such nonlinearity for the (t, z) profile and especially the effective relaxation time _eff are analyzed. We also discuss the predicted onset of convection near T_c for the conditions in our experiment. In the Appendix, the likely sources for systematic deviations in the density response function for the experimental cell from calculations in the ideal 1-D geometry are presented and their effects calculated. The so-obtained response function Z_F(, z) is compared with previously published data.     

A scaled equation of state for real fluids in the critical region

A scaled equation of state is proposed for real fluids in the critical region which incorporates asymmetry with respect to the critical isochore. In the range of reduced densities 0.65(/ _c)1.4 and for reduced temperatures (T/T _c)1.2, the equation represents P-V-T data for steam within the experimental accuracy.     

Transport properties of helium near the liquid-vapor critical point. II. Thermal conductivity of a3He-4He mixture

Measurements of the thermal conductivity are reported for an 80%³He-20%⁴He mixture above the critical point along several isotherms and near-critical isochores, using the same techniques and apparatus described for a study of³He. Using again the assumption that the observed conductivity can be decomposed into a sum of a regular and a singular contribution _reg and _sing, it is shown that along two near-critical isochores, _sing diverges. In particular, along the isochore showing the largest at the phase transition, the divergence is nearly the same as for³He and can be roughly characterized by a simple power law (T-T_c)^– with 0.58. This observation is contrary to predictions that foresee _sing0 asT _c is approached. The relaxation times characterizing the attainment of steady state conditions after switching the heat flux on and off show a similar behaviour as a function of reduced temperature as do those for pure³He. This result might indicate a substantial coupling between concentration and entropy diffusion. In the Appendix, the correlation length for³He nearT _c is calculated from heat conductivity, viscosity, and specific heat data.Work supported by Grant DMR 8024056 of the National Science Foundation.     

Thermodynamic properties of the superconductorsBaPb 0.7 Bi 0.3 O 3 andBa 0.7 K 0.3 BiO 3 using Eliashberg theory

We present results of a thermodynamic analysis for the superconductors compounds BaPb_0.7Bi_0.3O₃ and Ba_0.7K_0.3BiO₃. The physical quantities are calculated making use of the Eliashberg theory and the electron-phonon spectra ²()F() as calculated by Shirai et al. For the superconductor BaPb_0.7Bi_0.3O₃, several models of the ²()F() were studied looking for a better agreement with experimental data. The best fit is achieved with a simple constant scaling (C = 1.25) of the Shirai's spectra. The functional derivative of the deviation function D(t) with respect to changes in ²()F() is also calculated.