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1.
C. D. Evans Kathleen Warner G. R. List J. C. Cowan 《Journal of the American Oil Chemists' Society》1972,49(10):578-582
Panel evaluations have been made of room odors developed by edible oils and cooking fats heated to frying temperatures. Vegetable
and mixed fat shortenings, as well as oils of different iodine value and from special processing, were investigated with and
without added stabilizers. When silicones were added to frying fats, room odor scores improved markedly. Certain added autoxidative
cleavage products had little effect on odor scores at levels where they were detected easily in taste tests. To be discernible
in room odors, these additives had to be present at levels ca. 100-fold greater than their taste thresholds. Panel results
show that the undesirable frying odors contributed by unhydrogenated soybean oil in mixtures with other oils could be detected
readily at 25% levels. As the level of soybean oil was lowered further, the room odor scores of oil mixtures improved perceptibly.
One of 13 papers presented in the symposium “Flavor Research in Fats and Fat Bearing Foods,” AOCS Meeting, Atlantic City,
October 1971.
N. Market. Nutr. Res. Div., ARS, USDA. 相似文献
2.
E. Selke W. K. Rohwedder H. J. Dutton 《Journal of the American Oil Chemists' Society》1972,49(11):636-640
A small stainless steel reactor about one-millionth the volume of a home kitchen, was built to generate odors from cooking
oils heated to deep fat frying temperatures. This “microroom” was designed so that volatiles could be collected from 1–5 ml
of heated oils (193 C) directly on a gas chromatographic column, cooled to -60 C and subsequently separated by temperature
programing up to 250 C. Evaluations showed that heated oil odors from the microroom were similar to those room odors produced
by heating to 193 C 300 ml of cooking oil in an open vessel; exposure to subambient conditions did not affect the separation
efficiency of the gas chromatographic column. Provisions were made for three independent means of effluent monitoring: flame
ionization detection, odor analyses and mass spectrometry.
Presented at the AOCS Meeting, Los Angeles, April 1972.
ARS, USDA. 相似文献
3.
J. C. Cowan Helen Moser G. R. List C. D. Evans 《Journal of the American Oil Chemists' Society》1971,48(12):835-839
A table oil or a salad and cooking oil must serve both as an oil for salad dressings and for cooking potatoes in a deep-fat
fryer. Blends of peanut and unhydrogenated soybean oil that have been treated with a metal inactivating agent such as citric
acid were scored fairly high by a research taste panel after aging for 4 or 8 days at 60 C. Heating the samples to frying
temperature resulted in significantly higher room odor scores for peanut oil than for the blends. Blends of hydrogenated or
hydrogenated-winterized soybean oil with peanut oil were generally scored about equal to peanut oil in room odor tests. Potatoes
fried in these oils were generally given comparable and not significantly different scores.
Presented at AOCS Meeting, Houston, May 1971.
Northern Marketing and Nutrition Research Division, ARS, USDA. 相似文献
4.
K. Warner T. L. Mounts W. F. Kwolek 《Journal of the American Oil Chemists' Society》1985,62(10):1483-1486
Room odor characteristics produced by heated soybean oil (SBO) and soybean oils hydrogenated with copper (CuHSBO) and nickel
(NiHSBO) catalysts were evaluated by a trained panel. Oils were intermittently heated to 190 C for total heating periods of
5, 15 and 30 hr. Oil additives investigated included methyl silicone (MS), tertiary butylhydroquinone (TBHQ) and a polymeric
antioxidant in various combinations with citric acid (CA). In room odor tests directly comparing SBO, CuHSBO and NiHSBO, panelists
rated the hydrogenated oils as having significantly less odor intensity than the SBO. The combination of CA+MS had the greatest
effect in lowering odor intensity of the heated oils, followed by the mixture of CA+MS+TBHQ. The low odor intensity of the
MS-treated oils remained fairly constant throughout the tests, while the higher intensity associated with all the other additive-treated
oils decreased with increasing heating times, possibly as the result of formation of more volatile decomposition products
in the initial heating stages. Methyl silicone had the strongest effect of any additive in decreasing objectionable room odors
in the oils. Partially hydrogenated SBO treated with up to 5 ppm of MS produced cooking oils with low room odor intensity
and low color development during prolonged heating. 相似文献
5.
T. L. Mounts K. Warner G. R. List R. Kleiman W. R. Fehr E. G. Hammond J. R. Wilcox 《Journal of the American Oil Chemists' Society》1988,65(4):624-628
During the last 15 years, hybridization and induced mutation breeding of soybeans have been successful in producing an altered
fatty acid composition in the extracted oil. The objective of those investigations was to produce a low-linolenic acid soybena
oil. Crude oils extracted from the seeds of three such genotypes were processed in laboratory simulations of commercial procedures
to finished deodorized oils. Analysis of the fatty acid composition of the three oils showed the linolenic acid content to
be 3.3%, 4.2% and 4.8%. The stability of these finished oils was compared to that of oil from a soybean variety having a linolenic
acid content of 7.7% and of a commercial hydrogenated-winterized soybean oil (3.0% linolenic acid). Test and control oils
were evaluated by a trained sensory panel initially, after accelerated storage at 60 C and during use at 190 C in room tests.
Peroxide values were determined at the time of sensory evaluation. Results indicated there was no significant difference in
flavor stability during storage between test and control oils. There was no significant difference, between the oils, in peroxide
development during accelerated storage. Compared to control oils, the test oils had improved overall room odor intensity scores
and lacked the fishy odors of non-hydrogenated soybean oil and the hydrogenated odors of commercial cooking oil.
Presented at the AOCS meeting in Honolulu, HI in May 1986. 相似文献
6.
Pilot plant-processed samples of soybean and canola (lowerucic acid rapeseed) oil with fatty acid compositions modified by
mutation breeding and/or hydrogenation were evaluated for frying stability. Linolenic acid contents were 6.2% for standard
soybean oil, 3.7% for low-linolenic soybean oil and 0.4% for the hydrogenated low-linolenic soybean oil. The linolenic acid
contents were 10.1% for standard canola oil, 1.7% for canola modified by breeding and 0.8% and 0.6% for oils modified by breeding
and hydrogenation. All modified oils had significantly (P<0.05) less room odor intensity after initial heating tests at 190°C than the standard oils, as judged by a sensory panel.
Panelists also judged standard oils to have significantly higher intensities for fishy, burnt, rubbery, smoky and acrid odors
than the modified oils. Free fatty acids, polar compounds and foam heights during frying were significantly (P<0.05) less in the low-linolenic soy and canola oils than the corresponding unmodified oils after 5 h of frying. The flavor
quality of french-fried potatoes was significantly (P<0.05) better for potatoes fried in modified oils than those fried in standard oils. The potatoes fried in standard canola
oil were described by the sensory panel as fishy. 相似文献
7.
Frying quality and oxidative stability of high-oleic corn oils 总被引:1,自引:3,他引:1
To determine the frying stability of corn oils that are genetically modified to contain 65% oleic acid, high-oleic corn oil
was evaluated in room odor tests and by total polar compound analysis. Flavor characteristics of french-fried potatoes, prepared
in the oil, were also evaluated by trained analytical sensory panelists. In comparison to normal corn oil, hydrogenated corn
oil and high-oleic (80 and 90%) sunflower oils, high-oleic corn oil had significantly (P<0.05) lower total polar compound levels after 20 h of oil heating and frying at 190°C than the other oils. Fried-food flavor
intensity was significantly higher in the normal corn oil during the early portion of the frying schedule than in any of the
high-oleic or hydrogenated oils; however, after 17.5 h of frying, the potatoes fried in normal corn oil had the lowest intensity
of fried-food flavor. Corn oil also had the highest intensities of off-odors, including acrid and burnt, in room odor tests.
High-oleic corn oil also was evaluated as a salad oil for flavor characteristics and oxidative stability. Results showed that
dry-milled high-oleic corn oil had good initial flavor quality and was significantly (P<0.05) more stable than dry-milled normal corn oil after oven storage tests at 60°C, as evaluated by flavor scores and peroxide
values. Although the high-oleic corn oil had significantly (P<0.05) better flavor and oxidative stability than corn oil after aging at 60°C, even more pronounced effects were found in
high-temperature frying tests, suggesting the advantages of high-oleic corn oil compared to normal or hydrogenated corn oils. 相似文献
8.
C. D. Evans Helen A. Moser G. R. List H. J. Dutton J. C. Cowan 《Journal of the American Oil Chemists' Society》1971,48(11):711-714
Room odors developed on heating edible fats in open vessels were evaluated and characterized by a 20 member odor panel. Edible
fats tested were: special soybean salad and cooking oils, hydrogenated soybean oil and some commercial salad and cooking oils.
Factors were investigated that affect reliability and reproducibility of the test and the acuity of the panel members. The
effects of fry temperature and size of sample were investigated. The method has been applied to a study of hydrogenated and
unhydrogenated soybean oil samples.
Presented at the AOCS Meeting, Chicago, September 1970.
No. Market. Nutr. Res. Div., ARS, USDA. 相似文献
9.
K. Warner W. E. Neff G. R. List Peter Pintauro 《Journal of the American Oil Chemists' Society》2000,77(10):1113-1118
Soybean oils were hydrogenated either electrochemically with Pd at 50 or 60°C to iodine values (IV) of 104 and 90 or commercially
with Ni to iodine values of 94 and 68. To determine the composition and sensory characteristics, oils were evaluated for triacylglycerol
(TAG) structure, stereospecific analysis, fatty acids, solid fat index, and odor attributes in room odor tests. Trans fatty acid contents were 17 and 43.5% for the commercially hydrogenated oils and 9.8% for both electrochemically hydrogenated
products. Compositional analysis of the oils showed higher levels of stearic and linoleic acids in the electrochemically hydrogenated
oils and higher oleic acid levels in the chemically hydrogenated products. TAG analysis confirmed these findings. Monoenes
were the predominant species in the commercial oils, whereas dienes and saturates were predominant components of the electrochemically
processed samples. Free fatty acid values and peroxide values were low in electrochemically hydrogenated oils, indicating
no problems from hydrolysis or oxidation during hydrogenation. The solid fat index profile of a 15∶85 blend of electrochemically
hydrogenated soybean oil (IV=90) with a liquid soybean oil was equivalent to that of a commercial stick margarine. In room
odor evaluations of oils heated at frying temperature (190°C), chemically hydrogenated soybean oils showed strong intensities
of an undesirable characteristic hydrogenation aroma (waxy, sweet, flowery, fruity, and/or crayon-like odors). However, the
electrochemically hydrogenated samples showed only weak intensities of this odor, indicating that the hydrogenation aroma/flavor
would be much less detectable in foods fried in the electrochemically hydrogenated soybean oils than in chemically hydrogenated
soybean oils. Electrochemical hydrogenation produced deodorized oils with lower levels of trans fatty acids, compositions suitable for margarines, and lower intensity levels of off-odors, including hydrogenation aroma,
when heated to 190°C than did commercially hydrogenated oil. 相似文献
10.
Soybeans produced by induced mutation breeding and hybridization were cracked, flaked and hexane-extracted, and the recovered
crude oils were processed to finished edible oils by laboratory simulations of commercial oil-processing procedures. Three
lines yielded oils containing 1.7, 1.9 and 2.5% linolenic acid. These low-linolenic acid oils were evaluated along with oil
extracted from the cultivar Hardin, grown at the same time and location, and they were processed at the same time. The oil
from Hardin contained 6.5% linolenic acid. Low-linolenic acid oils showed improved flavor stability in accelerated storage
tests after 8 d in the dark at 60°C and after 8h at 7500 lux at 30°C, conditions generally considered in stress testing. Room
odor testing indicated that the low-linolenic oils showed significantly lower fishy odor after 1 h at 190°C and lower acrid/pungent
odor after 5 h. Potatoes were fried in the oils at 190°C after 5, 10 and 15 h of use. Overall flavor quality of the potatoes
fried in the low-linolenic oils was good and significantly better after all time periods than that of potatoes fried in the
standard oil. No fishy flavors were perceived with potatoes fried in the low-linolenic oils. Total volatile and polar compound
content of all heated oils increased with frying hours, with no significant differences observed. After 15 h of frying, the
free fatty acid content in all oils remained below 0.3%. Lowering the linolenic acid content of soybean oil by breeding was
particularly beneficial for improved oil quality during cooking and frying. Flavor quality of fried foods was enhanced with
these low-linolenic acid oils. 相似文献
11.
I. Petukhov L. J. Malcolmson R. Przybylski L. Armstrong 《Journal of the American Oil Chemists' Society》1999,76(8):889-896
The storage stability of potato chips fried in regular (RCO), hydrogenated (HYCO), low-linolenic (LLCO), and high-oleic (HOCO)
canola oils was compared. Potato chips were fried in each oil over a 5-d period for a total of 40 h of frying. Chips from
frying day 1 and 5 were packaged and stored at 60°C for 0, 1, 2, 4, 8, and 16 d. Lipids were extracted from the stored chips
and analyzed for peroxide values, free fatty acids (FFA), conjugated dienoic acids (CDA), and polar components. A trained
sensory panel evaluated the stored chips for odors characteristic of oxidation. Chips were also analyzed for volatile components.
Potato chips fried in RCO, LLCO and HOCO developed an intense painty odor, whereas chips fried in HYCO developed an intense
stale/musty odor by the end of the 16 d of storage. Chips fried in RCO had greater rates of accumulation of peroxides, FFA,
CDA, and polar components and developed higher levels of total volatiles over the 16 d of storage than chips fried in the
other three oils. Chips fried in HYCO had lower rates of accumulation of peroxides and CDA than chips fried in LLCO and HOCO,
and lower rates of FFA accumulation than chips fried in LLCO. Chips fried in HYCO and HOCO had the lowest amounts of total
volatiles during storage. The effect of oil degradation products on potato chip storage stability was not shown in this study
since only the chips fried in HYCO from frying day 5 exhibited a significantly greater rate of off-odor development than chips
from frying day 1, and only the chips fried in LLCO from frying day 5 had a greater rate of accumulation of volatiles than
chips from frying day 1. 相似文献
12.
T. L. Mounts K. Warner G. R. List W. E. Neff R. F. Wilson 《Journal of the American Oil Chemists' Society》1994,71(5):495-499
Oil was hexane-extracted from soybeans that had been modified by hybridization breeding for low-linolenic acid (18∶3) content.
Extracted crude oils were processed to finished edible oils by laboratory simulations of commercial oil processing procedures.
Oils from three germplasm lines N83-375 (5.5% 18∶3), N89-2009 (2.9% 18∶3) and N85-2176 (1.9% 18∶3) were compared to commercial
unhydrogenated soybean salad oil with 6.2% 18∶3 and two hydrogenated soybean frying oils, HSBOI (4.1% 18∶3) and HSBOII (<0.2%
18∶3). Low-18∶3 oils produced by hybridization showed significantly lower room odor intensity scores than the commercial soybean
salad oil and the commercial frying oils. The N85-2176 oil with an 18∶3 content below 2.0% showed no fishy odor after 10 h
at 190°C and lower burnt and acrid odors after 20 h of use when compared to the commercial oils. Flavor quality of potatoes
fried with the N85-2176 oil at 190°C after 10 and 20 h was good, and significantly better at both time periods than that of
potatoes fried in the unhydrogenated oil or in the hydrogenated oils. Flavor quality scores of potatoes fried in the N89-2009
oil (2.9% 18∶3) after 10 and 20 h was good and equal to that of potatoes fried in the HSBOI oil (4.1% 18∶3). Fishy flavors,
perceived with potatoes fried in the low-18∶3 oils, were significantly lower than those reported for potatoes fried in the
unhydrogenated control oil, and the potatoes lacked the hydrogenated flavors of potatoes fried in hydrogenated oils. These
results indicate that oils with lowered linolenic acid content produced by hybridization breeding of soybeans are potential
alternatives to hydrogenated frying oils. 相似文献
13.
Alkaline contaminant materials are formed in frying oils during cooking. The ACM can be eluted from the same International
Union of Pure and Applied Chemists-Association of Official Analytical Chemists (IUPACAOAC) silica gel column used to determine
polar materials in frying oils. The ACM are eluted with methanol after “non-polar” and “polar” fractions already have been
eluted from the column. A residue of silica gel in the methanol eluate must be insolubilized before the ACM can be identified
and quantitated. IR was used to identify sodium oleate as the major constituent of ACM from a set of restaurant generated
frying oil samples. 相似文献
14.
E. N. Frankel K. Warner K. J. Moulton Sr. 《Journal of the American Oil Chemists' Society》1985,62(9):1354-1358
Soybean oil was continuously hydrogenated in a slurry system to investigate the effects of linolenate content and additives
on cooking oil performance. Room odor evaluations carried out on oils heated to 190 C after frying bread cubes showed that
the oils hydrogenated with Cu catalyst to 2.4% linolenate (Cu-2.4) and with Ni catalyst to 4.6 linolenate (Ni-4.6) had a significantly
lower odor intensity score than the unhydrogenated soybean oil (SBO). Other hydrogenated oils (Cu-0.5 and Ni-2.7) were not
significantly better than SBO. Oil hydrogenated with Ni (Ni-0.4) scored poorly because of its strong “hydrogenated-paraffin”
odor. The performance of all partially hydrogenated oils (2.4, 2.7 and 4.6% linolenate) was improved by adding methyl silicone
(MS), but the most hydrogenated oils (0.5 and 0.4% linolenate) were not improved. Although with tertiary butyl hydroquinone
(TBHQ) no improvement was obtained, with the combination of TBHQ + MS all odor scores were lower, indicating a synergistic
effect. Evaluations of bread cubes after intermittent heating and frying showed that the breads fried in most hydrogenated
oils (Ni-0.4, Cu-2.4 and Ni-2.7) were rated significantly better in flavor quality than breads fried in SBO. The bread cubes
fried in MS-treated oils had significantly higher flavor quality scores than breads fried in SBO or SBO containing TBHQ. Dimer
analyses by gel permeation chromatography and color development after heat treatments also did not correlate with sensory
analyses. 相似文献
15.
At the present time, vegetable oils are the source of most of the visible fat in the U.S. diet. They are used as salad and
cooking oils, in salad dressing, margarine and shortening. Processing methods include extraction, refining, hydrogenation
and interesterification. During storage and use, the products are exposed to oxygen and/or heat, particularly during frying.
Processing, storage and use are related to changes in composition, nutritive value and physical characteristics of vegetable
oils. Refining removes undesirable minor components present in crude oils. Refined polyunsaturated vegetable oils are the
primary dietary source of tocopherols. Hydrogenation modifies physical characteristics and improves sensory and oxidative
stability. This process converts some of the polyunsaturated fatty acids to new fatty acid isomers. Although the biochemical
effects of these isomers are still being studied, long-term animal feeding trials and human experience have demonstrated that
the partially hydrogenated oils in margarines and shortenings are wholesome foodstuffs. Abusive overheating of fat in air
sharply decreases its palatability and nutritive value and may create minor amounts of carcinogenic materials. However, long-term
animal feeding studies with properly used frying fats have revealed little, if any, effect on life span and incidence of pathological
conditions. 相似文献
16.
Nikolaos K. Andrikopoulos George V. Z. Dedoussis Vassilios Tzamtzis Antonia Chiou George Boskou 《European Journal of Lipid Science and Technology》2002,104(2):110-115
Some frying by‐products of medium polarity called medium polarity materials (MPMs) were isolated by reversed‐phase high‐performance liquid chromatography (RP‐HPLC) from three different cooking oils used for frying during the domestic successive deep‐frying of potatoes. The cooking oils investigated were virgin olive oil, sunflower oil and a vegetable shortening oil. The relative RP‐HPLC increments of the MPM fractions showed a significant correlation to the total polar material and to the polymerised triacylglycerol increment. They could be used as a new method for the assessment of fried oil deterioration. The capillary gas chromatography/mass spectrometry analysis revealed two main groups of peaks for the MPM fractions, which are almost identical in the three examined oils. This indicates that the MPM constituents rather result from the triglycerides than from minor constituents of the oils. 相似文献
17.
During cooking oils and fats are exposed to high temperatures that may affect the nutritional quality of foods that are prepared in this way. Concerns have been raised about the degradation of polyunsaturated fatty acids and the formation of potentially harmful compounds during deep frying, but relatively little is known about these changes in other cooking processes. In the present study sponge cakes and fried potatoes were prepared via standardised baking and shallow frying procedures by using different oils and fats (sunflower oil, rapeseed oil, various margarines or butter). The effect of cooking on the retention of two essential fatty acids (linoleic acid and α-linolenic acid) and the formation of trans fatty acids (TFA) and polymerised triacylglycerols (PTG) was evaluated by analyzing fat extracted from the cooked food. It was found that over 95 % of essential fatty acids were retained upon completion of both cooking techniques. The formation of TFA was not significant. Polymerisation was noticeable only in shallow frying, although the final levels of PTG were negligible (<1.3 %). Overall, in contrast to deep frying, oil-based media high in polyunsaturated fatty acids seem to be a good alternative for domestic cooking techniques as they increase the nutritional value of the prepared food. 相似文献
18.
N. A. M. Eskin M. Vaisey-Genser S. Durance-Todd R. Przybylski 《Journal of the American Oil Chemists' Society》1989,66(8):1081-1084
The effect of heating on the oxidation of low (1.6%) linolenic acid canola oil (C18∶3) at frying temperature (185 ±5°C) under
nitrogen and air was examined and then compared to a laboratory deodorized (9.0%, C18∶3) and a commercially deodorized (8.5%,
C18∶3) canola oil sample. A significantly lower development of oxidation was evident for the low C18:3 canola oil, based on
the measurement of peroxide value (PV), thiobarbituric acid (TBA), free fatty acids (FFA), dienals and carbonyls. The greater
stability of the low C18:3 canola oil was also reflected by a corresponding improvement in heated room odor intensity scores.
Heating under nitrogen (rather than air) not only improved the odors but limited the oxidation in all oils. While the low
C18:3 canola oil heated under nitrogen was acceptable in 94% of odor judgments the same oil heated in air was acceptable in
only 44%. This suggests that even low levels of C18:3 may contribute to the development of the heated room odor phenomenon. 相似文献
19.
Chang Mo Li Fumiko Kimura Yasushi Endo Chizuko Maruyama Kenshiro Fujimoto 《European Journal of Lipid Science and Technology》2005,107(3):173-179
The stabilities of a commercial diacylglycerol‐rich oil (DAG) and a salad oil (TAG) that had been prepared from a mixture of rapeseed and soybean oils were compared while frying potatoes at 180 °C for 3 h. The representative chemical and physical characteristics of the oils were assessed before and after frying, together with the amount of volatile aldehydes in the exhaust of frying. Among the deterioration indications, the carbonyl value, polymer content, and residual polyunsaturated fatty acid content were similar and not significantly different between the TAG and DAG. On the other hand, the characteristics relating to free fatty acids, i.e. the acid value and emission of chemiluminescence at 100 °C, were greater and the smoke and flash points were lower in the DAG than in the TAG. An irritating odor was generated from the DAG after 1 h of frying and got stronger as frying continued. These results suggested that DAG more easily forms free fatty acids under frying conditions than TAG. 相似文献
20.
M. J. H. Keijbets G. Ebbenhorst-Seller J. Ruisch 《Journal of the American Oil Chemists' Society》1985,62(4):720-724
The suitability of hydrogenated soybean oils (fats) for prefrying of deep-frozen french fries has been investigated in a frying and storage experiment with five hydrogenated oils, of which four were commercially available and one was experimentally prepared. Three frying oils were hydrogenated soybean fats (0% C18:2 and C18:3), one was a partly hydrogenated soybean oil (25% C18:2; 0% C18:3) and one a hydrogenated palm fat (0% C18:2). An intermittent frying and heating procedure was used. Prefried french fries were stored deep-frozen at ?18 to ?20 C for a period of one year. Although differences in hydrolysis and oxidation during frying were observed, the five hydrogenated frying oils were quite stable. During the storage period, hydrolytic and oxidative changes in the oil phase of prefried french fries were not detected, regardless of the frying oil used. Only slight changes in sensory quality could be detected in all french fry samples stored for one year at ?18 to ?20 C. Some differences in odor and taste of finish-fried french fries observed initially were not observed after prolonged storage. Thus, it has been concluded that hydrogenated soybean oils, including a partly hydrogenated one, are suitable for prefrying french fries and for long-term storage of deep-frozen products. 相似文献