Feasibility of controlling nitrification in predenitrification plants using DO, pH and ORP sensors.

Experimental studies were carried out on a bench-scale nitrogen removal system with a predenitrification configuration to gain insights into the spatial and temporal variations of DO, pH and ORP in such systems. It is demonstrated that these signals correlate strongly with the operational states of the system, and could therefore be used as system performance indicators. The DO concentration in the first aerobic zone, when receiving constant aeration, and the net pH change between the last and first aerobic zones display strong correlations with the influent ammonia concentration for the domestic wastewater used in this study. The pH profile along the aerobic zones gives good indication on the extent of nitrification. The experimental results also showed a good correlation between ORP values in the last aerobic zone and effluent ammonia and nitrate concentrations, provided that DO in this zone is controlled at a constant level. These results suggest that the DO, pH and ORP sensors could potentially be used as alternatives to the on-line nutrient sensors for the control of continuous systems. An idea of using a fuzzy inference system to make an integrated use of these signals for on-line aeration control is presented and demonstrated on the bench-scale system with promising results. The use of these sensors has to date only been demonstrated in intermittent systems, such as sequencing batch reactor systems.     

New process control strategy for wastewater chlorination and dechlorination using ORP/pH.

Due to its efficiency and relatively low capital demanding, many wastewater treatment plants have applied chlorination for disinfection of treated wastewater before discharging it. However, determination of optimal doses of chlorine for chlorination and sulfite for dechlorination, which removes residual chlorine, should made to guarantee complete destruction of microorganisms in treated wastewater and to protect aquatic life in a receiving stream. In this study, a new ORP/pH based approach to determine endpoints of breakpoint chlorination and of dechlorinating titration and to optimize doses of chlorine and sulfite. In this new method, significant points on the ORP and pH profiles occurring during the titrations for chlorination and dechlorination were utilized to determine chlorine demand and sulfite dosage.     

New anaerobic process of nitrogen removal.

This paper reports on successful laboratory testing of a new nitrogen removal process called DEAMOX (DEnitrifying AMmonium OXidation) for the treatment of strong nitrogenous wastewater such as baker's yeast effluent. The concept of this process combines the recently discovered ANAMMOX (ANaerobic AMMonium OXidation) reaction with autotrophic denitrifying conditions using sulfide as an electron donor for the production of nitrite within an anaerobic biofilm. The achieved results with a nitrogen loading rate of higher than 1,000 mg/L/d and nitrogen removal of around 90% look very promising because they exceed (by 9-18 times) the corresponding nitrogen removal rates of conventional activated sludge systems. The paper describes also some characteristics of DEAMOX sludge, as well as the preliminary results of its microbiological characterization.     

不同温度下反硝化除磷工艺ORP变化规律研究

采用SBR反应器分别研究了低温（15℃和13℃）与常温（25℃）条件下反硝化除磷工艺ORP变化规律。研究结果表明：混合液ORP在厌氧、缺氧及好氧阶段的变化与温度有关,但厌氧阶段水力停留时间在2h以上时,初始厌氧程度对DPB的厌氧释磷过程基本无影响。     

Full-cyclic control strategy of SBR for nitrogen removal in strong wastewater using common sensors.

A full-cyclic automatic control strategy for sequencing batch reactors (SBR) was proposed using only common sensors such as ORP, DO and pH. The main objective was to develop a generally applicable and robust control strategy. To accomplish this, various control schemes found in the literature or suggested by authors were examined at diverse ammonia loads and SCOD/NH4(+)-N ratios. Advantages and constraints of each scheme were discussed and compared. Ammonia load was estimated with DO lag time during the aerobic stage, and then the influent pump was manipulated to meet the desired load at the next anoxic stage. A partial denitrification scheme was chosen for the anoxic stage period control, to save anoxic time and external carbon. For external carbon dosage control, intermittent feeding at each anoxic stage was concluded to be a suitable scheme. The anoxic stage period could be successfully controlled by the combination of pH increase and DO increase. Every suggested control scheme was incorporated into a full-cyclic control strategy and tested at 0.02, 0.035, 0.08 kg NH4(+)-N/m3/sub-cycle. From the results, it is expected to perform unmanned automatic SBR operation with this strategy.     

BICT biological process for nitrogen and phosphorus removal.

An updated biological nitrogen and phosphorus removal process--BICT (Bi-Cyclic Two-Phase) biological process--is proposed and investigated. It is aimed to provide a process configuration and operation mode that has facility and good potential for optimizing operation conditions, especially for enhancing the stability and reliability of the biological nutrient removal process. The proposed system consists of an attached-growth reactor for growing autotrophic nitrifying bacteria, a set of suspended-growth sequencing batch reactors for growing heterotrophic organisms, an anaerobic biological selector and a clarifier. In this paper, the fundamental concept and operation principles of BICT process are described, and the overall performances, major operation parameters and the factors influencing COD, nitrogen and phosphorus removal in the process are also discussed based on the results of extensive laboratory experiments. According to the experimental results with municipal sewage and synthetic wastewater, the process has strong and stable capability for COD removal. Under well controlled conditions, the removal rate of TN can reach over 80% and TP over 90% respectively, and the effluent concentrations of TN and TP can be controlled below 15 mg/L and 1.0 mg/L respectively for municipal wastewater. The improved phosphorus removal has been reached at short SRT, and the recycling flow rate of supernatant between the main reactors and attached-growth reactor is one of the key factors controlling the effect of nitrogen removal.     

Titrimetric monitoring of a completely autotrophic nitrogen removal process.

Fully autotrophic nitrogen removal processes, such as the combined SHARON-Anammox process, help to improve the sustainability of wastewater treatment. Successful operation of such a completely autotrophic system is, among others, based on the strict control of the SHARON reactor in order to produce an Anammox-suited influent with a 1:1 ammonium:nitrite ratio. The high quality and high frequency measurements provided by a titrimetric set-up measuring the total ammonium (TAN) and total nitrite (TNO2) concentrations facilitate this control considerably. In this study, the use of a titrimetric set-up for monitoring the combined SHARON-Anammox process is investigated. The technique that interprets on-line collected titration curves was applied to a lab-scale system. Comparison with classic colorimetric results gave statistically indistinguishable results for TAN and TNO2 concentrations in the SHARON reactor. In the Anammox reactor, only TAN could be determined by the investigated method due to the very low TNO2 concentrations. Phosphate, a potential inhibitor of the Anammox process, is available as an additional measurement in the effluent of the SHARON reactor. Three measurements are thus combined in one single instrument. The proposed measuring technique holds different advantages over the other TAN and TNO2 measurement techniques such as on-site availability, easy automation, the absence of the need for high dilutions and cost reduction.     

Ammonium nitrogen removal from slurry-type swine wastewater by pretreatment using struvite crystallization for nitrogen control of anaerobic digestion.

Precipitation of ammonium together with phosphate and magnesium is a possible alternative for lowering the nitrogen content of wastewater. In this study we examine the removal of ammonium nitrogen and phosphorus from slurry-type swine wastewater containing high concentrations of nutrients by the addition of phosphoric acid along with either calcium oxide or magnesium oxide, which leads to the crystallization of insoluble salts such as hydroxyapatite and struvite. The struvite crystallization method showed a high capacity for the removal of nitrogen when magnesium oxide and phosphoric acid were used as the magnesium and phosphate sources, respectively. When it was applied to swine wastewater containing a high concentration of nitrogen, the injection molar ratio of Mg2+:NH4+:PO4(3-) that gave maximum ammonium nitrogen removal was 3.0:1.0:1.5.     

Biological nitrogen removal using bio-sorbed internal organic carbon from piggery wastewater in a post-denitrification MLE process.

Nitrogen removal from a piggery wastewater was investigated in a post-denitrification modified Lüdzack Ettinger (PDMLE) process. Overall hydraulic retention time (HRT) of the PDMLE, consisting of contact/separator (C/S), nitrification, denitrification and re-aerobic bioreactor was 10 days. 60% of the influent SCOD was separated in the C/S by contacting the return sludge with the synthetic wastewater, however, only 10% of the influent SCOD was separated from the piggery wastewater. Biosorption capacities of the synthetic wastewater and piggery wastewater were 800 and 150 mg/g-MLSS, respectively. In spite of the high organic and nitrogen load, nitrification efficiency was above 95%, and nitrification rate was about 180 mg-NH4+-N/L x day. The removed delta COD/delta nitrate ratios in the denitrification tank were 4.0 and 11.5 g-SCOD/g-nitrate, while denitrification rates were 8.4 and 2.6 mg-nitrate/day for synthetic and piggery wastewater, respectively. In the proposed PDMLE process, both bio-sorbed and bypassed organic matter could be successfully used for nitrate reduction as carbon sources and the final TN removal efficiency was as high as 95%.     

多级生物滤池工艺脱氮效能研究

为实现BAF工艺的高效稳定脱氮,采用了外加碳源的后置反硝化三级BAF工艺(C+N+DN).研究了水温、污染物负荷、硝化液回流等条件下低碳氮比生活污水的脱氮效果.结果表明,在无硝化液回流的条件下,水温高于23℃时,系统具有高效稳定的脱氮效果,出水NH3-N稳定低于5 mg/L;水温低于23℃时,系统出水NH3-N明显升高.当水温为12～23℃时,采取50%硝化液回流并降低负荷后,硝化和反硝化效果明显提高,C柱和N柱对NH3-N和TN的去除率分别提高了19%和22%,最终出水中NH3-N与TN稳定达到<城镇污水处理厂污染物排放标准>(GB18918-2002)一级A标准.     

高效脱氮除磷工艺(NPR)中试研究

NPR工艺是将A2/O和BAF工艺经改进后有机结合形成的一种新型的更为高效的生物脱氮除磷技术.通过中试规模的试验,研究了该工艺处理生活污水时的脱氮除磷效果.结果表明,该工艺成功地解决了好氧段硝化菌与聚磷菌对泥龄的不同需求、厌氧段反硝化释氧与聚磷菌释磷之间矛盾的难题;NH3-N、TN和TP的去除率分别达到92.6%、68.3%和82.4%,同时CODCr和SS去除率分别达到93.4%、95.8%,且运行效果稳定.     

Influence of ORP variation, carbon source and nitrate concentration on denitrifying phosphorus removal by DPB sludge from dephanox process.

The effect of added carbon source and nitrate concentration on the denitrifying phosphorus removal by denitrifying phosphorus removal bacteria sludge was systematically studied using batch experiments, at the same time the variation of ORP was investigated. Results showed that the denitrifying and phosphorus uptake rate in the anoxic phase increased with the high initial anaerobic carbon source addition. However, once the initial COD concentration reached a certain level, which was in excess of the PHB saturation of Poly-p bacteria, residual COD carried over to the anoxic phase inhibited the subsequent denitrifying phosphorus uptake. This was equal to supplementing the external carbon source to the anoxic phase, furthermore the higher the external carbon source concentration the more powerful the inhibition caused. High nitrate concentration in the anoxic phase increased the initial denitrifying phosphorus rate. Oncethe nitrate was exhausted, phosphate uptake changed to phosphate release. Moreover, the time of this turning point occurred later with the higher nitrate addition. On the other hand, through on-line monitoring the variation of the ORP with different initial COD concentration, it was found that ORP could be used as a control parameter for phosphorus release, but it is impossible to utilize ORP for controlling the dinitrification and anoxic phosphorus uptake operations.     

Optimizing and modelling nitrogen removal in a new configuration of the moving-bed biofilm reactor process.

A new configuration of the moving-bed biofilm reactor process with pre-denitrification and nitrification was investigated in a pilot plant, which is fed with urban raw wastewater, the primary settler is located between the anoxic and the aerobic reactors, and primary sludge is recycled to the anoxic reactor as a hybrid pre-denitrification. The carriers used in the experiments are made of high-density polyethylene, with a diameter of 10 mm and a specific surface area of 400 m(2)/m(3). The new process was compared with conventional pre-denitrification-nitrification using in-series reactors fed with settled wastewater. The new configuration achieved an increase of 45% for the denitrification rate and of 30% for the nitrification rate when compared with conventional configuration. These results were analysed in light of the calibration study of the mixed-culture biofilm (MCB) model and simulations in AQUASIM 2.1 platform. Regarding denitrification, the high values obtained in the new configuration were attributed to a higher removal of the slowly biodegradable substrate (Xs) in the anoxic reactor due to the use of raw wastewater and sludge recycle. Accordingly, the amounts of heterotrophic biomass (XH) and Xs obtained in simulations were higher in both the biofilm and the bulk liquid. Regarding nitrification, the higher values were attributed to a lower removal of Xs in the aerobic reactors and accordingly, a lower accumulation of heterotrophic biomass in the biofilm was found in the simulations.     

CASS工艺生物脱氮除磷效果分析

对CASS工艺脱氮除磷效果进行了试验研究,重点研究了温度和回流比对脱氮效果的影响,曝气量对除磷效果的影响。研究结果表明,水温在30℃时系统脱氮效果最好,此时NH3-N去除率在80%左右,TN去除率在70%左右;污泥回流比为25%、50%、100%和200%时,TN去除率分别为50%、58%、62%和70%,增加回流比可以提高脱氮效率;好氧区DO维持在2mg/L和4 mg/L时,TP去除率分别为82%和37%。     

Use of industrial wastewaters for the optimization and control of nitrogen removal processes.

In this experimental study the characterization of 2 industrial wastewaters, coming from an ice cream production industry (IW1) and a beet-sugar factory (IW2), with respect to their readily biodegradable fraction and denitrification potential, has been performed. To this end physical-chemical and biological characterization methods, both anoxic and aerobic, were used. Moreover a pilot scale SBR fed with municipal wastewater was started to verify the effect of the gradual addition of the concentrated organic wastewaters during the anoxic phase. The SBR was initially fed only with a primary municipal wastewater, then the organic load was increased by adding to the feed, during the anoxic phase, a small amount of the IW1 (second period). Once the initial conditions were restored the load was again raised using the second industrial wastewater (IW2) (third period). With those additions the nitrogen removal efficiency increased from 26% to 50%, in the case of the IW1 and from 23% to 53% in the case of the wastewater IW2, without any negative effect on the global performance of the system. In addition, periodical kinetic studies of denitrification and nitrification in the SBR, were performed.     

Upgrading of wastewater treatment plants for nitrogen removal: Industrial application of an automated aeration management based on ORP evolution analysis

Upgrading conventional wastewater treatment plants for nitrogen removal involves total control of nitrification, denitrification and carbon removal. On low-load activated sludge processes, a comprehensive survey on fast and low kinetic biological reactions has been carried out, which describes the short-term and long-term requirements on the aeration sequences in a single tank. Although soluble and adsorbed pollution have to be treated in routine conditions, soluble pollution treatment becomes a priority during limited overloads, indicated by a slow ORP evolution. The treatment of adsorbed material is hence delayed. In order to implement the appropriate strategy, an automated aeration management system has been developed. This system is based on the analysis of both the real time signal and time evolution of the Redox potential signal. This information is used for command and control purposes. The application of this logic-based approach at full scale has been fruitful in evaluating its adaptability to the industrial environment and its potential results. The operation of seven plants under the control of the automated management system has enabled the nitrogen removal performance to be increased. Most of the nitrification and denitrification yields reach 90%, whereas previous results were far lower and more erratic. In addition, the present work determines limiting conditions for a guaranteed long-term result and a successful upgrading.     

改良型A/O工艺强化脱氮的试验研究

针对城郊住宅小区生活污水氨氮含量偏高的特点,对传统A/O工艺进行改良,提出了缺氧—好氧—硝化(A/O/N)处理工艺。试验结果表明,该工艺处理生活污水时脱氮效果明显优于传统A/O工艺,总氮去除率高于85%。对A/O/N工艺系统中氮的迁移转化进行了分析,并探讨了其脱氮机理。     

SH-A节能型生物脱氮工艺处理焦化废水工程实例

采用SH-A节能型生物脱氮工艺处理氨氮含量高、有机物可生化性差的焦化废水。工程处理水量为1600m3/d。进水CODCr约2500mg/L,NH3—N约260mg/L。处理后出水各项指标均达到了《污水综合排放标准》(GB8978—1996)一级标准,其中CODCr≤100mg/L,NH3—N≤15mg/L。     

Enhanced nitrogen removal using C/N load adjustment and real-time control strategy in sequencing batch reactors for swine wastewater treatment.

The laboratory-scale sequencing batch reactor (SBR) was used to study the effectiveness of an integrated strategy of real time control with C/N ratio adjustment for practical swine wastewater treatment. Swine waste was used as the external carbon source for continuous treatment in the SBR reactors. Oxidation-reduction potential and pH were used as parameters to control the continuous denitrification and nitrification process, respectively. A constant effluent quality could be obtained, despite drastic variations in the characteristics of influent wastewater. Also, a relatively complete removal of nutrients was always ensured, since the optimum quantity of the external carbon source could be provided for complete denitrification, and a flexible hydraulic retention time was achieved by the successful real-time control strategy. The average removal efficiencies of total organic carbon and nitrogen were over 94% and 95%, respectively.     

High rate nitrogen removal by the CANON process at ambient temperature

Completely autotrophic nitrogen removal over nitrite (CANON) is a cost-effective nitrogen removal process. Implementation of the CANON process relies on the cooperation of ammonium-oxidizing and Anammox bacteria, as well as the inhibition of nitrite-oxidizing bacteria. Strict limitations on dissolved oxygen (DO) concentration in the reactor, and the addition of sufficient inorganic carbon in the influent, were adopted as the main operational strategies. The reactor was fed with synthetic inorganic wastewater composed mainly of NH(4)(+)-N, and operated for 106 days. Stable nitrogen removal rates (NRR) of around 1.4 kg N m(-3) d(-1) were obtained at ambient temperature. Morphological characteristics and analysis of bacterial community confirmed the formation of functional outer aerobic and inner anaerobic granular sludge, providing evidence of stable nitrogen removal.