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1.
二次氮化法制备γ‘—Fe4N超细粉末 总被引:2,自引:0,他引:2
以FeCl2.nH2O和NH3为原料,采用一步气相合成法制备了Fe/N超细粉末,并研究了二次氮化法制备化铁超细粉末的工艺技术,通过比较实验,证实二次氮化法能够制备单相的γ-Fe4N粉末。利用XRD、TEM、XPS和VSM实验手段对Fe/N和γ’-Fe4N粉末的晶态、物相、形貌、成分、粒度和磁性进行了初步表征。 相似文献
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研究了热处理对AlN/SiCw(Y2O3+SiO2)复合材料机械性能的影响。结果表明,该材料经热处理后的强度提高,当添加剂Y2O3/SiO2=1/2.5摩尔比时,提高幅度最大。经XRD,SEM,TEM/EDAX和HREM分析,热处理增强的机理主要是粒界玻璃相在高温氧化气氛中和AlN颗粒表层作用,生成的纤维2H^δSialon相和SiCw形成空间交错结构。 相似文献
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CALIXE[4]ARENE AS A TEMPLATE FOR CONTROLLING REGIOCHEMISTRY OF PHOTODIMERIZATION OF 9-SUBSTITUTED AN
《感光科学与光化学》1995,(2)
CALIXE[4]ARENEASATEMPLATEFORCONTROLLINGREGIOCHEMISTRYOFPHOTODIMERIZATIONOF9-SUBSTITUTEDANTHRACENELIYI;TONGZHEN-HE(CHEN-HOTUNG... 相似文献
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1—2折流换热器流体温度沿程变化及其LMTD的计算 总被引:1,自引:0,他引:1
1-2折流换热器流体温度沿程变化及其LMTD的计算梁日忠THEVARIATIONOFFLUIDTEMPERATUREALONGSIDPASSANDTHECALUATIONOFLMTDIN1-2BAFFLEHEATEXCHANGER1前言换热器设计中,... 相似文献
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以Ba(OH)2.8H2O,Al(NO3)3.9H2O,TEOS为原料,采用溶胶-凝胶法制备BaO-Al2O3-SiO2三元系粉末,研究了不同因素对生成稳定溶胶和胶化时间的影响,用TG-DTA,XRD研究了溶胶-凝胶的热处理过程,用TEM观察了粉体的粒径。 相似文献
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EXPERIMENTALINVESTIGATIONOFKINETICANDTRANSPORTPARAMETERSINAWALL-COOLEDFIXED-BEDREACTORZhen-MinCHENGandWei-KangYUAN(UNILABRese... 相似文献
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激光诱导二甲基二乙氧基硅烷气相合成碳化硅超细粉 总被引:1,自引:0,他引:1
本工作首次采用有机硅试剂二甲基二乙氧基硅烷为反应物,进行了激光导气相反应,制备出平均粒径为40nm的非晶SiC粉末,粉末中C/Si比随反应气流量的变化而变化。非晶SiC粉末在1873K,氮气中退火1h后转变为β-SiC及α-SiC,同时,粉末中部分氧杂质及自由碳脱出粉末。 相似文献
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晶须表面涂层对SiCw/TZP陶瓷复合材料力学性能和界面结构的影响 总被引:3,自引:3,他引:3
研究了在SiC晶须表面涂覆10~100nm厚的氧化铝或莫来石对15%(vol)SiCw/2.5Y-TZP陶瓷复合材料力学性能的影响。结果表明:涂层可显改善复合材料的力学性能,其中涂覆莫来石效果最佳,室温σ1=1450MPa,K1c=17MPa·m^1/2,1000℃下σf=520MPa,比无涂层的复合材料力学性能分别提高了80%,100%和45%。SEM,TEM和HREM观察表明:SiCw表面涂 相似文献
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Laser-driven pyrolysis of the organosilicon compound 1,1,1,3,3,3-hexamethyldisilazane ((Me3 Si)2 NH) yields amorphous fine powders (0.1 μm) containing Si, C, and N. Reactant Si and N retentions are 100% and 90%, respectively. The C content of the powder can be varied by changing the pyrolysis temperature, and the N content can be varied by adding NH3 to the reactant gas. Upon firing, SiC is produced, with unusually facile loss of nitrogen from the powder. 相似文献
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《Journal of the European Ceramic Society》2003,23(1):37-46
This paper reports a comparison between two different methods used for the synthesis of amorphous Si/C/N pre-ceramics: the laser pyrolysis method, coupled with an aerosol generator, and thermolysis in a furnace in an inert gas atmosphere. The same precursor, liquid oligomethylvinylsilazane (OMVS, [−(CH3)Si(HCCH2)NH−]n) has been chosen to establish this comparison. Laser spray pyrolysis of OMVS produces nano-sized powder particles with a specific surface area of about 120 m2/g. The characteristics of the as-formed Si/C/N nanopowders (chemical composition, local order, structural evolution...) are compared to those of pre-ceramic samples obtained by thermolysis in a furnace (at 800 and 1050 °C). The amorphous network of the as-pyrolysed materials mainly consists of SiCxN4−x (x=0,1,2) units and amorphous or sp2-hybridized carbon. The carbon and hydrogen contents are higher in samples obtained by laser spray pyrolysis. Heat-treatment experiments at temperatures up to 1550 °C were performed to investigate the high temperature behaviour of the various samples. Decomposition was observed at about 1500 °C. 相似文献
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原位燃烧合成Si3N4/Ti(C,N)/SiC复相陶瓷热力学分析 总被引:3,自引:0,他引:3
研究了用TiC作添加剂时Si粉坯在高压氮气中的燃烧行为,结果表明:TiC加入量对燃烧合成产物的相组成有重要影响,原因在于TiC加入量直接影响燃烧过程中氮气向反应前沿的渗透性,从而影响试样中不同部位氮气分压的变化,适当调整工艺参数,可以合成Si3N4/Ti(C,N)/SiC复相陶瓷,并从热力学角度对实验结果进行了合理的解释。 相似文献
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Masaaki Suzuki Yoshihisa Hasegawa Masayuki Aizawa Yoshinori Nakata Takeshi Okutani Kohei Uosaki 《Journal of the American Ceramic Society》1995,78(1):83-89
The structure of silicon carbide–silicon nitride (SiC–Si3 N4 ) composite particles synthesized using a CO2 laser was studied by magic angle spinning nuclear magnetic resonance (MAS-NMR) and electron spin resonance (ESR). The structure around Si atoms changed by introducing N. C atoms around Si were substituted by N atoms, and N-rich configurations around Si atoms increased stepwise as the N content increased. The low N content composite particles consisted of mainly SiC phase containing dissolved N. N atoms were partly present in β-SiC microcrystal and partly in the grain boundary layer in the particle. N atoms were tetrahedrally surrounded by four Si atoms in β-SiC microcrystal and were trivalent state bonded to three Si atoms in the grain boundary layer. The high N content particles consisted of SiC, Si3 N4 , and amorphous phases, whose amount depended on N content. 相似文献
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Fengxia Li Li Fu Xiaojian Ma Changhui Sun LianCheng Wang Chunli Guo Yitai Qian Yitai Qian 《Journal of the American Ceramic Society》2009,92(2):517-519
Starting from Si powder, NaN3 and different additives such as N -aminothiourea, iodine, or both, Si3 N4 nanomaterials were synthesized through the nitridation of silicon powder in autoclaves at 60°–190°C. As the additive was only N -aminothiourea, β-Si3 N4 nanorods and α-Si3 N4 nanoparticles were prepared at 170°C. If the additive was only iodine, α-Si3 N4 dendrites with β-Si3 N4 nanorods were obtained at 190°C. However, when both N -aminothiourea and iodine were added to the system of Si and NaN3 , the products composed of β-Si3 N4 nanorods and α, β-Si3 N4 nanoparticles could be prepared at 60°C. 相似文献
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将天然石墨、酚醛树脂和微米级硅粉进行球磨处理制备复合材料前驱物,再于N2气氛下700℃炭化得到硅/石墨/炭(Si/G/C)复合电极材料,采用X射线衍射仪、扫描电镜和透射电镜及电化学循环充放电对其形貌、结构及其电化学性能进行表征.结果表明,Si/G/C作为锂离子电池负极材料具有高于900 mA·h/g的可逆比容量,40次循环后保持在550 mA·h/g.对电极进行热处理后,其循环性能显著提高,40次循环后比容量保持在700 mA· h/g.扫描电镜分析结果显示,热处理后集流体上电极材料分布更均匀,因涂抹不均形成的空隙不复存在.热处理后电极结构更致密、内部黏结强度增大使其结构稳定性明显提升,是电极循环性能提高的主要原因. 相似文献
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研究了采用Si,N4与Al的混合粉,经压制、烧结制备AIN/Al-Si复合材料的技术方法。试验结果表明:AIN的反应生成机制属于一种连续渐进式反应形成过程,即于高温下液相Al中的Al原予渗入Si3N4的晶体点阵取代Si原予而逐渐使之向AIN晶体点阵转化的过程。被取代的Si原予从固相Si3N4中析出,扩散溶入液相Al中,冷却后形成Al-Si舍金固溶体,一般呈网状分布于AIN晶体相的周围。新生成的AIN与Al-Si合金相之间表现出很好的界面亲和性。 相似文献
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用50W连续波CO_2激光器为热源,诱发SiH_4和C_2H_4反应,合成SiC超细粉末。实验确定了反应腔体内压力p、气源中的C/Si原子比、喷嘴内径2r以及激光功率密度与粉末特性之间的关系,并对合成的产物进行物理、化学表征。 相似文献
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表面改性处理的纳米Si3N4粉体与聚苯硫醚(PPS)熔融共混挤出制成PPS/纳米Si3N4复合材料,通过拉伸、冲击实验及动态力学性能测试考察了纳米粉体加入量对复合体系各项性能的影响。结果表明,纳米Si3N4填充PPS基复合材料的力学性能明显优于纯PPS。随粉体添加量的增加,复合材料的拉伸强度增大,当添加量为0.8 %时,拉伸强度提高了22 %。随粉体添加量的增加,复合体系冲击强度增大,当粉体添加量为1.2 %时,冲击强度和缺口冲击强度出现最大值,分别比纯PPS增加了33 %和41 %。动态力学性能测试表明,随粉体添加量的增加,PPS分子链段松弛所需能量增加,松弛过程增长,体系储能模量降低,损耗模量增加。 相似文献