Periodicities in the properties associated with the friction of model self-assembled monolayers

The classical molecular dynamics simulations presented here examine the periodicities associated with the sliding of a diamond counterface across a monolayer of hydrocarbon chains that are covalently bound to a diamond substrate. Periodicities observed in a number of system quantities are a result of the tight packing of the monolayer and the commensurate structure of the diamond counterface. The packing and commensurability of the system force synchronized motion of the chains during sliding contact. This implies that the size of the simulations for this special case can be reduced so that the simulations can be conducted with sliding speeds and time durations that may bridge the gap between theory and experiment.     

Simulations on atomic-scale friction between self-assembled monolayers: Phononic energy dissipation

Atomic-scale friction between self-assembled monolayers (SAMs) on Au (1 1 1) has been studied through molecular dynamics simulations, with emphasis on the mechanism of energy dissipation. Results show that the shear stress and chain angle on commensurate SAMs exhibit a clean periodic pattern and atomic stick–slip friction, which manifests a gradual storage and sudden release of energy. Using a simple model of two atoms, analysis shows that the atomic stick–slip originates from the dynamic instability of molecule motion. Energy has been built up during the stick, followed by a sudden separation as the equilibrium becomes unstable, and most energy dissipates at the time of slip. Moreover, the simulations reveal that more energy is stored and released in commensurate sliding, resulting in much higher friction than that in incommensurate cases. The contradictory frictional behavior can be traced to the difference in the number and strength of the Van der Waals bonds, formed in the two types of contacts.     

Mechanism of energy dissipation in mechanical system with dry friction

Determination of the energy dissipative mechanism in a mechanical system composed of two elastic structures in dry contact is presented. The analysis is based on the measurement of displacement ratio of the contacting elastic structures as a function of frequency due to light impulse excitation at a single point on any of the two elastic structures. The theoretical analysis depends on a very simple model of a two-degree-of-freedom system where two solid friction models are adopted in the analysis of the mathematical model. Several experiments are presented to illustrate the dominant friction mechanism of contacting surfaces within the micro slip regime in a frequency range of oscillation up to 400 Hz. It was shown experimentally that the solid friction model behaves in a way that is described as structural (hysteretic) damping. In other words, the energy dissipated due to dry friction during micro slip regime does not depend on the relative velocity between the two contacting surfaces but it is proportional to their relative displacements. The determination of the contact stiffness and damping loss factor in addition to their variation with the applied normal load was also shown.     

A friction energy approach to quantifying lubrication under fretting sliding

The problem of a proper lubrication under low‐speed small oscillatory movement can be a decisive factor for the reliability of various components. There is a need to characterise the lubricious behaviour of the interface under oil‐bath fretting wear conditions for ball bearing applications. Fast and reliable methods to quantify this behaviour for broad range of mechanical conditions are proposed and validated. Pure sliding reciprocation induces mixed lubrication mode. It was found that transient film profiles depend on the non‐Newtonian response of the oils and the type of motion. Running‐in period has a crucial importance for the tribofilm formation, and is a result of the interplay of the oil‐sliding surfaces interface and is directly connected with the total energy dissipated from the contact region. The stability of structured tribofilm in steady‐state period relies on the balance between the competitive processes: replenishment of the oil to the contact and ejection of the oil pending the oscillatory movement. The phenomenon of starvation was observed when the system was moved away from dynamical equilibrium and the growth of the dissipated energy was spotted. A proposed methodology provides the evaluation of the lubrication properties of the oil in a quantitative way. Copyright © 2010 John Wiley & Sons, Ltd.     

氨基表面自组装膜成膜及摩擦性能研究

运用原子力显微镜与接触角测量仪研究了3-氨丙基三乙氧基硅烷(APTES)自组装膜不同成膜时间的表面形貌平均粗糙度、接触角,并进行了XPS(X射线光电子能谱)元素分析,表明APTES自组装膜以“岛”状生长,随着反应的时间的延长,岛的数量急剧增加,形成平整光滑的膜,进一步延长成膜时间,可能形成多层膜,从而平均粗糙度先增大再减小然后再增大,表面性质一直变化不大。微摩擦磨损实验研究表明,APTES自组装膜大大降低镀Cr钢球与硅片之间的摩擦因数,摩擦因数从0.71左右降低到0.16左右,在分子级润滑中有广阔的应用前景。     

A predictive analytical friction model from basic theories of interfaces, contacts and dislocations

Friction between crystalline bodies is described in a model that unifies elements of dislocation drag, contact mechanics, and interface theory. An analytic expression for the friction force between solids suggests that dislocation drag accounts for many of the observed phenomena related to solid–solid sliding. Included in this approach are strong arguments for agreement with friction dependence on temperature, velocity, orientation, and more general materials selection effects. It is shown that calculations of friction coefficients for sliding contacts are in good agreement with available experimental values reported from ultrahigh vacuum experiments. Extensions of this model include solutions for common types of dislocation barriers or defects. The effects of third-body solid lubricants, superplasticity, superconductivity, the Aubry transition, and supersonic dislocation motion are all discussed in the framework of dislocation-mediated friction.     

Analysis of frictional energy dissipation on an annular surface with harmonic loading

Metallic mating surfaces in structural joints offer a good source of frictional energy dissipation resulting in a damped dynamic structural response. This paper reports the results of experiments where the energy dissipation per cycle occurring at a preloaded flat metallic annular interface subjected to cyclic tangential forces is measured. The effects of certain pertinent joint variables on this frictional energy dissipation are investigated by the application of Response Surface Methodology. A central composite rotatable design was utilized for developing empirical expressions for energy loss. The methodology presented suggests a useful technique for tribological research.     

Atomic-scale study of friction and energy dissipation

This paper presents an analysis of the interaction energy and various forces between two surfaces, and the microscopic study of friction. Atomic-scale simulations of dry sliding friction and boundary lubrication are based on the classical molecular dynamics (CMD) calculations using realistic empirical potentials. The dry sliding of a single metal asperity on an incommensurate substrate surface exhibits a quasi-periodic variation of the lateral force with two different stick-slip stage involving two structural transformation followed by a wear. The contact area of the asperity increases discontinuously with increasing normal force. Xe atoms placed between two atomically flat Ni surfaces screen the Ni-Ni interaction, decrease the corrugation of the potential energy as well as the friction force at submonolayer coverage. We present a phononic model of energy dissipation from an asperity to the substrates.     

Determination of energy dissipation of a spider silk structure under impulsive loading

Various researches and studies have demonstrated that spider silk is much stronger and more deformable than a steel string of the same diameter from a mechanical approach. These excellent properties have caused many scientific disciplines to get involved, such as bio-mechanics, bio-materials and bio-mimetics, in order to create a material of similar properties and characteristics. It should be noted that the researches and studies have been oriented mainly as a quasi-static model. For this research, the analysis has taken a dynamic approach and determined the dissipation energy of a structure which is made of spider silk “Dragline” and produced by the Argiope-Argentata spider, through an analytical-experimental way, when being subjected to impulsive loading. Both experimental and analytical results, the latter obtained by using adjusted models, have given high levels of dissipation energy during the first cycle of vibration, which are consistent with the values suggested by other authors.     

An energy-based model for the wear of UHMWPE

An energetic approach to model the wear of tribological systems in which one of the components of the pair is polymeric is presented in this work. Experimental data, obtained in ultra-high molecular weight polyethylene (UHMWPE) pin-on-disk tribological tests, showed that a linear correlation between the wear rate of the polymer and the dissipated energy exists, independently of the lubricant, of the material used as counterbody and of the surface finishing of both polymer and counterbody. This fact strongly suggests that, in UHMWPE-based tribological systems, energy dissipation is mainly caused by the elasto-plastic deformation and wear of the polymer. Based on this assumption, it is developed a mathematical model that yields for a physical interpretation of the parameters of the experimental wear vs. energy correlation. These parameters are intrinsic wear properties of the polymer and can be used for the optimization of polymer-based tribological systems.     

45钢的摩擦磨损特性实验研究

采用自制的销盘式干滑动摩擦磨损试验机,研究了45钢配副的摩擦磨损特性.结果表明:材料的磨损率随着速度、载荷的增加而增大;摩擦系数随着速度、载荷的增加而减小.磨损机理主要为磨粒磨损和粘着磨损.     

Static energy calculations of stress‐strain behavior of self‐assembled monolayers

The mechanical response of alkanethiol/Au(111) self‐assembled monolayers to normal stress is simulated using the static energy minimization technique. The calculation results are discussed in terms of stress‐induced structural changes, stress‐strain relationships and Young's moduli. The dependence of the calculated elastic properties on the monolayer configuration, force field, and chain length is examined. This revised version was published online in July 2006 with corrections to the Cover Date.     

Investigation of the effect of additives to lubricant Litol-24 on abrasive wearing of steel under sliding friction

The structure of a three-ball friction machine developed for testing lubricants is described and its advantages over the four-ball one in tests with sliding friction are shown. Using the developed machine and the testing procedure, a lubricant grease Litol-24 was subjected to testing with additions of solid lubricants (graphite powder and MoS₂) and organic dopes containing P, Cl, S, and O. According to results of investigation of their lubricity in conditions of boundary friction with abrasives, the optimal formulations of lubricants have been determined.     

A contribution to determining the friction coefficient in hydroforming of tubes

Hydroforming is a relatively new technology, which enables complex shaped hollow parts to be produced efficiently. Compared to alternative methods, this technology is characterised by significant potential advantages, such as complex shape production, lightweight design, high accuracy, and process integration. The tribological aspects of hydroforming are very significant, as friction influences all the main process parameters practically in a direct or indirect way. However, there is a paucity of information relating to hydroforming tribology. In most reports on this subject only qualitative data regarding the friction coefficient are given. However, for finite‐element method simulation and optimal process and tool design, quantitative data are indispensable. This paper describes an attempt to determine the coefficient of friction in both the elastic and plastic states of a workpiece during tube hydroforming processes. Push‐through tests were carried out in order to determine the coefficient of friction in the elastic state, and tube upsetting tests were conducted for the plastic state. Various commercial lubricants were used in the experiments.     

基于DEM算法的多颗粒碰撞耗能机理分析与振动抑制研究

针对机械构件主系的封闭空间中填充微小颗粒,进行振动抑制问题,对填充颗粒的尺寸、数量以及材料特性因素对振动抑制效果的影响开展了研究。通过采用离散单元法(discrete element method,DEM),分析了颗粒与颗粒以及颗粒与主系统之间的运动学特性,建立了能够充分表达颗粒在相互碰撞摩擦过程中的受力、变形关系以及耗能计算模型,分析了多个颗粒之间的碰撞与耗能机理,确定了碰撞过程中颗粒的状态、受力及耗能大小的计算求解算法。在Matlab环境下,针对不同颗粒材质、数量及大小对系统振动抑制性能进行了仿真分析,得出了颗粒材质大小以及数量对减振性能的影响规律,并通过搭建的试验台,进行了试验数据采集和分析。试验结果与仿真结果相吻合,验证了算法的有效性,该算法为提高机械构件的减振性能设计提供了重要参考。     

Dissipated energy and boundary condition effects associated to dry friction on the dynamics of vibrating structures

In turbomachines, dry friction devices (under platform dampers, shrouds, and tie-wire) are usually introduced to reduce resonant responses of bladed disks. Dry friction between rubbing elements induces a highly nonlinear dynamic behaviour which flattens the frequency response functions. It is clear that such behaviour requires an optimisation process to find the optimum parameters that lead to the minimum forced response amplitudes. However, different interpretations still remain concerning the explanation of the physical origin of this type of flattening. The most common one is based on dissipated energy. In this case, heat resulting from the relative frictional motion between contacting surfaces is supposed to bring sufficient dissipation to flatten response functions. On the other hand, a different approach considers that a decrease in vibrational amplitudes is explained by changes in boundary conditions induced by a stick/slip behaviour. In this study, a single degree-of-freedom system is used and analysed both in time and in frequency domains (Harmonic Balance Method) in order to show the contribution of respectively energy dissipation and change of contact state on peak levels.     

On the friction and wear performance of boric acid lubricant combinations in extended duration operations

Lubrication is critical for minimizing wear in mechanical systems that operate for extended time periods. Developing lubricants that can be used in engineering systems without replenishment – particularly those that are environmentally friendly – is very important for increasing the functional lifetime of mechanical components. In the present investigation, extended duration pin-on-disk experiments were carried out to determine the relative performance of a wide range of lubricant combinations in a commercial brake valve assembly. In the experiments, the lubricants were initially applied to the disk surface but were not replenished over a sliding distance of more than 6000 m. The experimental results revealed that the environmentally friendly lubricant boric acid was highly ineffective for reducing the wear in the surfaces tested. When combined with a commercial transmission fluid, however, the boric acid mixture proved to be highly effective in terms of both friction and wear performance. Based on the success of the combined lubricant experiments, the boric acid was then mixed with canola oil to form a completely natural lubricant combination. Based on further pin-on-disk experiments, this lubricant combination yielded the best wear performance of all the lubricants tested. The importance of these results, as related to the use of the natural lubricant combination in other engineering systems such as sheet metal stamping, was subsequently ascertained and discussed.     

The effect of lubricant additives on friction and wear studies of polyphenylene sulphide

Polyphenylene sulphide is a polymer with good thermal stability and high crystallinity. This paper summarizes the results of friction and wear studies of polyphenylene sulphide and its composites made with conventional solid lubricants to ascertain the suitability of the material as a matrix for solid lubricant additives. The polymer itself has a high coefficient of friction. Wear rate increases with load and speed. Addition of solid lubricant additives helps in improving the friction and wear of the polymer. Composites with MoS₂-Sb₂O₃ and PTFE gave better results than composites made by the addition of graphite and MoS₂ graphite. Wear rate of these composites increased with load and speed; but load and speed had little effect on friction.     

The relationships between interfacial friction and the conformational order of organic thin films

This report describes studies of the relationships between the structures of organic monolayers and their molecular-scale frictional properties. Several distinct self-assembled monolayers (SAMs) were formed by the adsorption of a series of spiroalkanedithiols and a single structurally related normal alkanethiol. Measurements of hexadecane wettability, infrared vibrational spectroscopy, and X-ray photoelectron spectroscopy revealed that the films possessed a wide range of interfacial structures and conformational orders. Atomic force microscopy was used to measure the frictional properties of the well-characterized SAMs on the molecular scale. Comparison of the frictional data with structural information derived from complementary analytical techniques revealed a high correlation between the conformational order of the films and the observed frictional response.     

Rolling and sliding: Separation of adhesion and deformation friction and their relative contribution to total friction

This study is concerned with determining the relative contribution of adhesion and deformation friction using rolling and sliding method. The challenges associated with in-vivo friction testing were overcome by utilising a novel substrate that mimics the viscoelastic behaviour and surface texture of human skin combined with a repeatable and reproducible test setup. The results show that in the dry state, deformation friction contributes 20% of the total friction while the remaining proportion is due to adhesion. These proportions are affected by probe material where for PTFE, deformation friction contributes 30% of the total friction. For the lubricated state, the contribution of deformation friction to total friction increases approaching 50–50% at the higher sliding speeds and normal loads investigated.