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不饱和聚酯树脂涂料的研究进展 总被引:2,自引:0,他引:2
不饱和聚酯树脂(UPR)涂料是发展最早的涂料品种之一,将UPR作为涂料的成膜树脂不但涂膜性能优良而且成本低廉,因此UPR涂料在涂料工业中应用广泛。文章就现有各种UPR涂料的研究进展进行回顾。将UPR涂料分为气干性UPR涂料、防污UPR涂料、防火UPR涂料、防腐UPR涂料、绝缘UPR涂料以及低(零)挥发性有机化合物(VOC)排放UPR涂料。分别阐述了各种涂料的特点及其发展现状,简要叙述了涂料的作用机理,并对UPR涂料的未来发展趋势和研究方向作出了展望。 相似文献
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国内外涂料工业现状及发展趋势(一)--世界涂料工业现状及发展趋势 总被引:5,自引:0,他引:5
概述了国外涂料工业现状。对世界范围内的水性涂料、粉末涂料、无溶剂型涂料和高固体份涂料等低污染、无公害涂料和环境贡献型涂料、功能型涂料(包括氟碳树脂涂料、喷涂聚脲弹性体、有机-无机复合涂料、高装饰涂料、隐身涂料和智能型涂料)等方面的应用与研究概况以及纳米材料在涂料中的应用进行了总结,指出了今后的发展趋势。 相似文献
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少烟三元乙丙橡胶材料研制 总被引:1,自引:0,他引:1
以三元乙丙橡胶(EPDM)为基体材料,三氧化二锑、十溴苯醚为阻燃剂制备了材料配方,试验了三氧化二锑(Sb22O3)、十溴苯醚(DBDPO))配比对材料烟雾和力学性能的影响,测试了材料的氧指数,可见光的透过率,自熄性等。结果表明,DBDPO与EPDM的相容性比较好,Sb2O3的相容性则相对比较差,两者都可以提高材料的阻燃性能。以4045EPDM橡胶为基体材料,当EPDM100g,白炭黑10g,二硫化四甲基秋兰姆(TMTD)2g,ZnO5g,促进剂M1g,硬脂酸2g,硫磺3g,Sb2O3和DBDPO质量比为20.0/40.0,可以获得具有较好力学性能的少烟EPDM橡胶材料。 相似文献
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国内甲醇消费市场状况 总被引:1,自引:0,他引:1
黄克勇 《精细与专用化学品》2005,13(5):23-27
我国甲醇主要用于甲醛、对苯二甲酸二甲酯、农药、甲基叔丁基醚、醋酸的生产,我国甲醇消费量增长最快的领域将是燃料甲醇、醋酸和甲醛。预计 2005年甲醛对甲醇的需求量为 175万t左右,聚甲醛对甲醇的需求量为 40万t,醋酸需求甲醇为 62万t,甲基叔丁基醚为 46万t左右,甲胺为 30万t,碳酸二甲酯为 11万t,甲烷氯化物为 10万t,甲醇燃料为 80万t,农药为 22万t,对苯二甲酸二甲酯 3 0万t,其他衍生物 27万t。 相似文献
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Hamed Abbasfard Sattar Ghader Hasan Hashemipour Rafsanjani Mehdi Ghanbari 《Drying Technology》2013,31(11):1297-1306
Drying of ammonium nitrate (AN) is accomplished in the Shiraz Petrochemical Complex (SPC) using a concurrent rotary dryer following a countercurrent rotary dryer. A mathematical model for these rotary dryers including heat and mass transfer was developed. The model was checked against industrial-scale data, which showed a good agreement. The average absolute deviation of the simulation results compared to the industrial data for the concurrent dryer was 4.0% for solids moisture, 1.3% for solids temperature, and 1.8% for air temperature and for the countercurrent dryer it was 9.0% for the solids moisture, 2.0% for solids temperature, and 4.6% for air temperature. These simulation results reveal that for outlet solid moisture, inlet AN moisture, and air temperature as well as the outlet temperature of product, the inlet solid and air temperature have major effects for both concurrent and countercurrent flow. 相似文献
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汽车工业用粘接材料的现状与展望 总被引:3,自引:0,他引:3
本文按照汽车制造工序介绍国外汽车工业折边用胶粘剂、点焊胶接用胶粘剂、车身密封胶、车身底涂料、窗玻璃用单组份湿气固化型聚氨酯胶粘剂以及纤维增强树脂用结构胶粘剂等主要胶种的最新技术发展动向。讨论了我国汽车工业用胶粘剂的现状和差距,提出几点建议。 相似文献
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The article presents the results of studies concerning the hydraulic permeability of integrated membrane systems during the treatment of municipal landfill leachate. The laboratory-scale experiments were conducted to determine the effectiveness of coagulation as a pretreatment option for treating stabilized landfill leachate and effectiveness of nanofiltration (NF) and reverse osmosis (RO) processes. The municipal landfill leachates were analyzed for the concentration of the following: polycyclic aromatic hydrocarbons (PAHs), nitrate nitrogen, ammonium nitrogen, chemical oxygen demand (COD), total organic carbon (TOC), total carbon (TC), suspended soils (SS), turbidity, pH. The commercially available coagulant – aluminum sulfate Al2(SO4)3·18H2O (alum) was used as a coagulant. The NF process was carried out at the transmembrane pressure of 1.5 MPa. The membrane separation process was based on a thin film membrane (DK). The transmembrane pressure of the RO stood at 2 MPa and for this process one polyamide membrane (AG) was used. The level of leachate treatment was defined for raw and cleaned wastewater indicators. Both NF and RO membranes allowed obtaining the high level of pollutants removal. In the coagulation–NF system, the removal efficiency was equal to 77% for PAHs, 88% for COD, 72% for ammonium nitrogen, 80% for nitrate nitrogen, 67% for TOC, 80% for TC, 96% for SS and during the RO – 86% for PAHs, 98% for COD, 93% for ammonium nitrogen, 87% for nitrate nitrogen, 89% for TOC, 100% for TC, 98% for SS. The calculations based on the assumptions of the mathematical filtration model (relaxation) made it possible to predict the efficiency of commercial filtration membranes used for leachate treatment. 相似文献
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采用DUO-ICP-AES同时测定精对苯二甲酸中钴、铬、铁、锰、钼、镍、钛,并对仪器的分析线选择、背景校正、入射功率、雾化器压力、辅助气流量、冷却气流量、蠕动泵转速的影响及共存元素的干扰、硝酸铯灰化助剂等因素进行了详细的研究。方法的检测限:钴0.0097 mg/L;铬0.0021 mg/L;铁0.0078 mg/L;锰0.0012 mg/L;钼0.0027 mg/L;镍0.016 mg/L;钛0.0027 mg/L,回收率和精密度分别为93.0%~99.5%和0.37%~3.2%。该方法快速简便,具有良好的精密度和准确度,适用于进出口精对苯二甲酸的日常检验。 相似文献
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Satoshi KANECO Hiroaki KITANAGA Hideyuki KATSUMATA Tohru SUZUKI 《Frontiers of Chemical Science and Engineering》2012,6(4):432
In the present work, a new preconcentration method of trace elements by adsorption onto a niobium wire has been developed for electrothermal atomization atomic absorption spectrometry (ETAAS) with a tungsten tube atomizer. Detection limits (pg·mL–1) by this method combined with ETAAS were 45 for bismuth, 7.0 for cadmium, 20 for copper, 1.3 for gold, 36 for lead, 65 for manganese, 9.5 for rhodium and 19 for silver. 相似文献
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Sang Hoon Ahn Seung Nam Joung Ki-Pung Yoo Min Jeong Noh Joo Hee Han Seung Ho Han 《Korean Journal of Chemical Engineering》1998,15(4):390-395
Supercritical water oxidation (SCWO) was carried out in a flow-type reactor for modeling of waste-water containing phthalic
or adipic acid. For each acid, the reaction order and rate constant, k, were determined over a wide range of experimental
conditions : temperatures from 633.15 to 713.15 K, pressures from 18 to 29 MPa, excess amounts of hydrogen peroxide from zero
to 800 percent, and the mean residence time in the reactor from 1.1 to 49.1 seconds. The concentration of both acids in model
wastewater was set by 500 ppm. For phthalic acid, we found that the orders of decomposition reaction with respect to the reactant
concentrations were 0.56 for phthalic acid, 0.31 for hydrogen peroxide, and 0.53 for water. For adipic acid, the orders of
oxidation were 0.78 for adipic acid, 0.53 for hydrogen peroxide, and 0.74 for water. Then measured activation energy for phthalic
acid was 33.08 kcal/mol and that for adipic acid was 19.51 kcal/mol, respectively. 相似文献