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电沉积Fe-36%Ni磁性合金工艺的研究 总被引:3,自引:0,他引:3
采用电沉积法制备Fe-36%Ni磁性合金。通过正交实验研究了nFe2 /nNi2 、电流密度、镀液pH值、镀液温度与合金中铁含量的关系,用极差法分析了各工艺参数对Fe—Ni合金镀层成分的影响,并确定了最佳工艺条件为nFe2 /nNi2 0.6,镀液pH值3.5,施镀温度65℃,阴极电流密度6A/dm2。实验结果表明,合金镀液中nnFe2 /nNi2 较大,电流密度增加,pH值升高,均有利于镀层Fe含量的提高:实验所得合金镀层光亮、致密、外观平整,显微结构是层状,镀层中wFe为64.1%,wNi为35.9%,符合Fe-36%Ni合金成分设计要求。 相似文献
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工艺参数对电镀镍铜合金镀层成分及相结构的影响 总被引:1,自引:0,他引:1
采用由200 g/L NiSO4·6H2O、10 g/L CuSO4·5H2O、80 g/L Na3C6H5O7·2H2O、0.2 g/L C12H25SO4Na和0.5 g/L糖精钠组成的镀液,在10~60 mA/cm2、pH=2.5~5.0和25~50°C条件下电沉积制备了NiCu合金镀层。探讨了镀液pH、电流密度、温度等工艺参数对镍铜合金镀层相结构和组成的影响。结果表明,NiCu合金镀层的铜含量随电流密度或温度升高而增大。但随pH增大,镀层铜含量降低,pH小于4.0时,NiCu合金镀层中含有单质铜。 相似文献
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在铜板表面电沉积Fe-Ni合金。采用单一变量法研究了镀液配方、电流密度、镀液温度、镀液pH值和搅拌速率对Fe-Ni合金中Fe的质量分数的影响。结果表明:Fe的质量分数随电流密度的增加和镀液温度的升高而降低,随镀液pH值的升高和搅拌速率的增大而升高;向镀液中加入适量的稳定剂和配位剂,对提高Fe-Ni合金中Fe的质量分数有利。采用配方B,在电流密度1.0A/dm~2、镀液温度40℃、镀液pH值3.0、搅拌速率150r/min的条件下,电沉积得到的Fe-Ni合金的形貌良好,Fe的质量分数为52.83%。 相似文献
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在乙酸盐-铵盐体系电镀锌–镍合金镀液配方中添加次磷酸钠,以45钢为基体电沉积锌–镍–磷合金。通过循环伏安法和小槽电镀实验研究了pH、温度和电流密度对镀层成分的影响,采用扫描电镜、能谱、X射线荧光、X射线衍射等技术对镀层形貌和微观组织进行表征,采用Tafel极化曲线和电化学阻抗谱对镀层的耐蚀性进行测试。结果表明:在不含主盐的基础镀液中,次磷酸钠的P不能被还原出来,而次磷酸钠与Zn2+、Ni2+共存时有助于Ni的沉积,对Zn的沉积无明显影响;温度升高则镀层中Zn减少,Ni和P增多;降低pH有利于锌–镍共沉积;镀层的P含量随电流密度增大而减少。P元素的掺入能完全消除锌-镍合金的裂纹,细化镀层晶粒。低P含量(P质量分数低于1%)的锌–镍–磷合金镀层具有比高P含量(P质量分数大于10%)的镀层更好的耐蚀性。 相似文献
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Electrodeposition of Ni-W-B amorphous alloys 总被引:3,自引:0,他引:3
Partial polarization curves at the glassy carbon rotating disc electrode have been used to study the electrodeposition of Ni and Ni-W alloy from citrate-containing solution. For deposition of Ni-W alloys, the partial polarization curves indicate diffusion control for nickel reduction and stoichiometric limitation for tungsten deposition by the composition of the alloy. Plating experiments show that current efficiency of the electrodeposition and composition of the resulting alloy depend on the parameters of the electrolysis. The best conditions for electrodeposition of the alloy Ni-W-B are current density of 45–50 mA cm–2, temperature of 60–70 °C, Ni(II) concentration of 20–25 mm, and pH 8.5. Pulsed galvanostatic plating at 1 Hz increased slightly the current efficiency. The concentration of Ni(II) in the solution can be self-regulated by using a nickel bipolar electrode in the cathode compartment. 相似文献
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In this paper the polarization characteristics of the processes of Ni and Co powders and Ni-Co alloy powders electrodeposition from ammonium sulfate containing supporting electrolyte are investigated as a function of Ni2+ and Co2+ ions concentrations. It is shown that the correct polarization curves for Ni and Co powders and Ni-Co alloy powders electrodeposition could be obtained only after IR drop correction, since the total current density of electrodeposition at the most negative potential of −1.4 V versus Ag|AgCl is extremely high (up to about 3-6 A cm−2) as a consequence of simultaneous hydrogen evolution which starts immediately after the beginning of metals (alloys) deposition. After determining the current density for hydrogen evolution and its subtraction from the total current density, correct polarization curves for Ni and Co powders and Ni-Co alloy powders electrodeposition are obtained. They are found to be different for each ratio of Ni2+/Co2+ ions concentration. It is also concluded that the shape of the polarization curves in all cases is practically defined by the shape of the polarization curve for hydrogen evolution. The morphology and composition of electrodeposited powders were also found to be sensitive to the ratio of Ni2+/Co2+ ions concentration. 相似文献
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Mohamed H. Fawzy Mohamed M. Ashour Abd El-Halim M. Abd El-Halim 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1996,66(2):121-130
A study was carried out on the electrodeposition of Cu Ni alloys containing inert (α-Al2O3 and TiO2) particles from a selected citrate bath. The cathodic polarization curves show that alloy deposition occurs at more noble potentials relative to either of the two parent metals and this indicated the formation of a solid solution. The addition of the inert particles into the selected bath led to a polarization-increasing effect and this increased with increases in the size and concentration of the particles in the bath. An explanation of the mechanism of codeposition of the inert particles with the alloy has been presented. On controlling the bath composition, Cu Ni alloys containing 11–40% of nickel could be deposited. The effect of the operating variables such as the concentration of the metal ions in the bath, pH and current density on the alloy composition indicated that the formation of the Cu Ni alloy belongs to the regular alloy deposition system. The current efficiency of the alloy deposition is relatively lower than for either of the two parent metals, from similar baths, and ranges between 76 and 84%. The microhardness of the deposited Cu Ni alloy improved from 170 to 248 kfg mm−2 as a result of codeposition of 1–2% of the inert particles. A direct correlation between the surface morphology of the deposited Cu Ni alloy, as revealed by SEM, and its microhardness could be detected. X-ray diffraction studies confirmed the dispersion of the α-Al2O3 and TiO2 phases in the Cu Ni alloy phase. 相似文献
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为进一步提高镍基电极的析氢性能,采用恒电位沉积法,通过改变镀液中各合金的质量浓度比、沉积电位、沉积时间等条件,制备出一种高活性的镍钴铁三元合金电极。通过测定电极在1 mol/L的NaOH溶液中的极化曲线,得到最佳的沉积工艺条件为:36.25 g/L NiSO_4·6H_2O,1.25 g/L NiCl_2·6H_2O,5 g/L CoSO_4·7H_2O,7.5 g/L FeSO_4·7H_2O,10 g/L H_3BO_3,0.5 g/L抗坏血酸,1 g/L十二烷基硫酸钠,pH=4.0,电沉积电位-1.45 V,电沉积时间300 s。阴极极化曲线测试结果表明在5 A/dm^2的条件下,镍钴铁三元合金电极的析氢过电位降低至121 mV,相比于纯镍电极过电位降低近50%,相比于镍钴电极过电位降低近35%。 相似文献
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采用循环伏安曲线、电化学阻抗谱、扫描电镜、能谱仪等手段,研究了pH值对Ni-Cr-Mo合金电沉积机制的影响。结果表明:当pH值为3.0时,循环伏安曲线的共沉积还原峰最正,电化学阻抗谱的极化电阻最小,Ni-Cr-Mo合金的电沉积最容易发生。当pH值不大于3.0时,Ni-Cr-Mo合金的电沉积受动力学和扩散混合控制;当pH值大于3.0时,Ni-Cr-Mo合金的电沉积受动力学过程控制。随着pH值的增大,Ni-Cr-Mo合金的晶粒尺寸逐渐增大,Cr的质量分数先增大后减小,Ni、Mo的质量分数均先减小后增大。 相似文献
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The electrodeposition of the Fe-Ni powders from citrate containing electrolytes for different Ni/Fe ions concentration ratios, using Fe(III) and Fe(II) salts at pH 4.5 and pH 4.0 respectively was investigated by the polarization measurements and cyclic voltammetry. The morphology and composition of the electrodeposited powders were investigated by SEM and EDS analysis. The EDS analysis of the alloy powders confirmed anomalous co-deposition of Fe and Ni from both solutions, with the one obtained using Fe(III) salt being more pronounced. The morphology of electrodeposited powders was found to depend on the Ni/Fe ions concentration ratio, as well as on the valence of Fe ions used. A common characteristic for all powder samples was the presence of cone shaped cavities and nodules, while for the ratio Ni/Fe = 9/1 in both electrolytes pagoda like crystals, corresponding to the FeNi3 single crystal, have been detected. In the case of Fe(III) containing electrolytes current efficiency for powder electrodeposition was very small (about 1-2%) due to the first step in the electrochemical reaction being reduction of Fe(III) into Fe(II), while in the case of Fe(II) containing electrolytes current efficiency for powder electrodeposition varied between about 15% and 8% depending on the Ni/Fe ratio. 相似文献
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M. M. Kamel 《Journal of Applied Electrochemistry》2007,37(4):483-489
Thin films of cobalt–nickel alloys were galvanostatically deposited onto steel substrates from gluconate baths. Cathodic polarization
curves were determined for the parent metals and Co–Ni alloy. The effects of bath composition, current density and temperature
on cathodic current efficiency (CCE) and alloy composition were studied. The deposition of Co–Ni alloy is of anomalous type,
in which the less noble metal (Co) is preferentially deposited. The CCE of codeposition is high and increases with increase
in temperature and current density, but it decreases as the [Co2+]/[Ni2+] ratio in the bath increases. The percentage of Co in the deposit increases with increasing cathodic current density, temperature
and increasing Co2+ ion concentration. The structure and surface morphology of the deposit were studied by XRD, ALSV and SEM. The results showed
that the alloys consisted of a single solid solution phase with a hexagonal close packed structure. 相似文献