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1.
A kind of novel poly(phenylene sulfide)s (PPSs) containing a chromophore group were synthesized by the reaction of dihalogenated monomer and sodium sulfide (Na2S.xH2O) via nucleophilic substitution polymerization under high pressure. The polymers were characterized by Fourier transform infrared spectroscopy, ultraviolet spectroscopy, fluorescence spectroscopy, XRD, DSC, TGA, mechanical testing and dissolvability experiments. The intrinsic viscosity of the polymers obtained with optimum synthesis conditions was 0.22 ? 0.38 dl g?1 (measured in 1‐chloronaphthalene at 208 °C). These polymers were found to have good thermal performance with a glass transition temperature (Tg) of 90.5 ? 94.6 °C and initial degradation temperature (Td) of 475–489 °C, showing improved thermal properties compared with homo‐PPS. At the same time the resultant resins had a high tensile strength of 67.5 ? 74.1 MPa and compressive strength of 70.7 ? 85.4 MPa. Additionally, these polymers exhibited a weak UV ? visible reflectivity minimum at 450–570 nm, and the fluorescence spectra of the polymers showed maximum emission around nearly 370 nm. Also they showed excellent chemical resistance and another special property ? bright shiny colors changed into different colors in acid solution. © 2014 Society of Chemical Industry  相似文献   

2.
In this article, a novel two step synthesis of soy oil based isothiocyanate is described. Allylicaly brominated soybean oil (ABSO) was reacted first with ammonium thiocyanate in tetrahydro furan to form allylic thiocyanates. These compounds were then converted to isothiocyanated soybean oil (ITSO) by a thermal rearrangement. Conversion was found to be 70%. The structure of the ITSO was characterized by IR and 1 H‐NMR techniques. Then ITSO was reacted with ethylene glycol, glycerol, and castor oil to produce polythiourethanes and ethylene diamine and triethylene tetra amine to produce polythioureas. Thermal properties of the products were determined by DSC and TGA techniques. DSC traces showed Tg's for ethylene glycol polythiourethane at ?39 and 58°C, for glycerol polythiourethane at ?39 and 126°C, for castor oil polythiourethane at ?38°C and ?17°C, for ethylene diamine polythiourea at ?45°C, and for triethylene tetra amine poly thiourea at ?39°C. Additionally, DSC analysis of polythioureas showed an endotherm at around 100°C. All of the polymers started to decompose around 200°C. Tensile properties of the polymers were determined. Polythiourethanes showed higher tensile strength and lower elongation when compared with their urea analogs. Stress at break values of the polymers were 1.2 MPa for glycerol polythiourethane, 0.6 MPa for ethylene glycol polythiourethane, 0.5 MPa for ethylene diamine polythiourea, and 0.9 MPa for triethylene tetra amine polythiourea polymers. Unfortunately, polymers synthesized showed poor solvent resistance. All polymers swelled and disintegrated in CH2Cl2 in 5 h. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010  相似文献   

3.
A series of novel aromatic and aromatic–aliphatic diamines [isophthaloyl bis(3‐(3‐aminophenyl)thiourea), terephthaloyl bis(3‐(3‐aminophenyl)thiourea), adipoyl bis(3‐(3‐aminophenyl)thiourea), sebacoyl bis(3‐(3‐aminophenyl)thiourea)] were synthesized starting from the dinitro compounds. Spectroscopic and elemental analyses were carried out for the structure elucidation of the monomers. Three series of poly(thiourea‐amide)s (PTAMs) bearing C?S groups were prepared through the condensation of new diamines with the diacid chlorides such as isophthaloyl, terephthaloyl and adipoyl chloride. The ensuing PTAMs were characterized using FTIR, 1H‐NMR and 13C‐NMR techniques. Physical properties of the polymers such as solution miscibility, crystallinity, solution viscosity, molecular weight, and thermal properties were measured. Consequently, good organosolubility of these polymers was experiential in amide solvents as DMAc, DMF, DMSO and NMP. Moreover, PTAMs exhibited ηinh in the range of 0.92–1.56 dL/g and GPC measurements revealed Mw around 607 × 102‐851 × 102. DSC served to envisage the glass transition temperatures (Tg) of poly(thiourea‐amide)s located between 232 and 258°C and the initial decomposition temperatures (T0) probed by thermogravimetry were in the range of 305–419°C. Structure‐property relationship of these polymers was also studied. Eventually, solid?liquid extraction tests of the selected poly(thiourea‐amide)s systems revealed excellent results because these polymers show nearly 100% elimination of lead and mercury cations from water media. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012  相似文献   

4.
A novel diamine monomer having pendant 4‐(quinolin‐8‐yloxy) aniline group was successfully synthesized via aromatic substitution reaction of 8‐quinolinol with p‐fluoronitrobenzene followed by Pd/C catalyzed hydrazine reduction, amidation reaction between 4‐(quinolin‐8‐yloxy) aniline and 3,5‐dinitrobenzoylcholoride followed by Pd/C catalyzed hydrazine reduction. The diamine monomer was fully characterized by using FTIR, 1H‐NMR, 13C‐NMR, and elemental analysis. The diamine monomer was polymerized with various aromatic and aliphatic dicarboxylic acids to obtain the corresponding polyamides. The polyamides had inherent viscosity in the range of 0.30–0.41 dL/g and exhibited excellent solubility in the polar aprotic solvents such as DMAc, NMP, N,N‐dimethylformamide, Pyridine, and DMSO. The glass transition temperatures (Tg) of the polymers are high (up to 313°C) and the decomposition temperatures (Ti) range between 200 and 370°C, depending on the diacids residue in the polymers backbone. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010  相似文献   

5.
Eight novel polyhydrazides (PH a4?Ch3 ) were prepared from the reaction of two novel diacids, 5-(2-(6-methyl pyridine-2-yl)-1,3-dioxo isoindoline-6-carboxamido) isophthalic acid (3) and 5-(2-(4-methyl pyridine-2-yl)-1,3-dioxo isoindoline-6-carboxamido) isophthalic acid (4), with four dihydrazides by interfacial polycondensation. These polymers have moderate inherent viscosities (0.12?C0.17?dL/g) and are readily soluble in polar aprotic solvents. They start to decompose (T 10%) above 187?°C and display glass transition temperatures in the range of 130.3?C156.3?°C. All polymers could be thermally converted into the corresponding polyoxadiazole approximately in the region of 250?°C, as evidenced by the DSC thermograms. All of the above polymers were fully characterized by FT-IR and 1HNMR spectroscopy, TGA, DSC, and inherent viscosity measurement.  相似文献   

6.
Three series of liquid‐crystalline‐cum‐photocrosslinkable polymers were synthesized from 4‐x‐phenyl‐4′‐(m‐methacryloyloxyalkyloxy)cinnamates (x = ? H, ? OCH3 and ? CN; m = 6, 8 and 10) by free radical solution polymerization using azobisisobutyronitrile as an initiator in tetrahydrofuran at 60 °C. All the monomers and polymers were characterized using intrinsic viscosity, and FTIR, 1H NMR and 13C NMR spectroscopy. The liquid crystalline behavior of these polymers was examined using a hot stage optical polarizing microscope. All the polymers exhibited liquid crystalline behavior. The hexamethylene spacer‐containing polymers exhibited grainy textures; in contrast, the octamethylene and decamethylene spacer‐containing polymers showed nematic textures. Differential scanning calorimetry data confirmed the liquid crystalline property of the polymers. Thermogravimetric analysis revealed that all the polymers were stable between 236 and 344 °C in nitrogen atmosphere and underwent degradation thereafter. As the methylene chain length increases in the polymer side‐chain, the thermal stability and char yield of the polymers decrease. The photocrosslinking property of the polymers was investigated using the technique of exposing the polymer solution to UV light and using UV spectroscopy. The crosslinking reaction proceeds via 2π–2π cycloaddition reactions of the ? CH?CH? of the pendant cinnamate ester. The polymers containing electron‐releasing substituents (? OCH3) showed faster crosslinking than the unsubstituted polymers and those containing electron‐withdrawing substituents (? CN). Copyright © 2007 Society of Chemical Industry  相似文献   

7.
A novel monomer diacid, 6,6′‐methylenebis(2‐oxo‐2H‐chromene‐3‐carboxylic acid), was synthesized and used in a direct polycondensation reaction with various aromatic diamines in N‐methyl‐2‐pyrrolidone solution containing dissolved LiCl and CaCl2, using triphenyl phosphite and pyridine as condensing agents to give a series of novel heteroaromatic polyamides containing photosensitive coumarin groups in the main chain. Polyamide properties were investigated by DSC, TGA, GPC, wide‐angle X‐ray scattering, viscosity, and solubility measurements. The copolymers were soluble in aprotic polar solvents, and their inherent viscosities varied between 0.49 and 0.78 dL g?1. The weight‐average and number‐average molecular weights, measured by gel permeation chromatography, were 27,500–43,900 g mol?1 and 46,500–66,300 g mol?1, respectively, and polydispersities in the range of 1.48–1.69. The aromatic polyamides showed glass‐transition temperatures (Tg) ranging from 283 to 329°C and good thermal properties evidenced by no significant weight loss up to 380°C and 10% weight loss recorded above 425°C in air. All the polyamides exhibited an amorphous nature as evidenced by wide‐angle X‐ray diffraction and demonstrated a film forming capability. Water uptake values up to 3.35% were observed at 65% relative humidity. These polymers exhibited strong UV‐vis absorption maxima at 357–369 nm in DMSO solution, and no discernible photoluminescence maxima were detected by exciting with 365 nm. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010  相似文献   

8.
Three novel kinds of linear silicon‐containing hybrid polymers with Si?C≡C units were synthesized by polycondensation reactions using the Grignard reagent method. All the polymers were thermosetting, highly heat‐resistant, moldable and easily soluble in common organic solvents. The structure, curing behavior, thermal and oxidative properties were characterized using Fourier transform infrared spectroscopy, 1H NMR, 13C NMR, gel permeation chromatography, differential scanning calorimetry and thermogravimetric analysis. The results obtained can provide theoretical guidance for determining the curing of the resin system. In addition, the cured polymers exhibit excellent thermal and oxidative stabilities with temperatures of 5% weight loss (Td5) above 480 °C and 450 °C in nitrogen and air respectively; the residues at 1000 °C were above 70.0% and 45.0% respectively. The thermal and oxidative stabilities of the polymers are attributed to a crosslinking reaction between the Si?H and C≡C bonds or C≡C bonds. These polymers have the potential for use as high‐temperature‐resistant resins and ceramic precursors. © 2013 Society of Chemical Industry  相似文献   

9.
BACKGROUND: Wholly aromatic polyamides (aramids) are high‐performance polymeric materials with outstanding heat resistance and excellent chemical stabilities due to chain stiffness and intermolecular hydrogen bonding of amide groups. Synthesis of structurally well‐designed monomers is an effective strategy to prepare modified forms of these aramids to overcome lack of organo‐solubility and processability limitations. RESULTS: A novel class of wholly aromatic polyamides was prepared from a new diamine, namely 2,2′‐bis(p‐phenoxyphenyl)‐4,4′‐diaminodiphenyl ether (PPAPE), and two simple aromatic dicarboxylic acids. Two reference polyamides were also prepared by reacting 4,4′‐diaminodiphenyl ether with the same comonomers under similar conditions. M?w and M?n of the resultant polymers were 8.0 × 104 and 5.5 × 104 g mol?1, respectively. Polymers resulting from PPAPE exhibited a nearly amorphous nature. These polyamides exhibited excellent organo‐solubility in a variety of polar solvents and possessed glass transition temperatures up to 200 °C. The 10% weight loss temperatures of these polymers were found to be up to 500 °C under a nitrogen atmosphere. The polymers obtained from PPAPE could be cast into transparent and flexible films from N,N‐dimethylacetamide solution. CONCLUSION: The results obtained show that the new PPAPE diamine can be considered as a good monomer to enhance the processability of its resultant aromatic polyamides while maintaining their high thermal stability. The observed characteristics of the polyamides obtained make them promising high‐performance polymeric materials. Copyright © 2009 Society of Chemical Industry  相似文献   

10.
The microwave assisted polycondensation of two polyimides were studied using pyromellitic dianhydride (PMDA), and 4,4′‐(hexafluoroisopropyliden)diphthalic anhydride (6FDA) as dianhydride monomers and 2,4,6‐trimethyl‐m‐phenylenediamine (TrmPD), as diamine monomer, under microwave irradiation in DMF and DMSO solvents. The structure and performance of polymers were characterized by Fourier Transform Infrared Spectroscopy (FTIR), viscosity, density, and Thermogravimetric Analysis (TGA). The results show that the polyimides can be obtained in a short reaction time with high intrinsic viscosity and high yield. The effect of the presence of a bridging group, ? C(CF3)2? , in the monomer structure is apparent in the permeability parameters of the macromolecules as polymer (6FDA‐TrmPD) always presents better results than polymer (PMDA‐TrmPD). Properties as density and Tg increases with the time exposition to the microwave irradiation. Polyimides obtained present good thermal properties because they began to lose weight in a range of 8–16% at high temperature as 450°C. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010  相似文献   

11.
Resins containing plant oil‐based cross‐linkers were studied with two reactive diluents: a styrene and an acrylated fatty acid methyl ester‐based (AFAME) monomer. Acrylated epoxidized soybean oil and maleinated castor oil monoglyceride were bio‐based cross‐linkers used. The viscosity and mechanical properties of the resulting polymers were measured and analyzed. Both bio‐based cross‐linkers prepared using the modified AFAME as diluent had a fairly high viscosity, so blends of AFAME and styrene were needed to meet the viscosity requirements established by the composite industry (<1000 cP at room temperature). In addition, the glass transition temperature (Tg) and stiffness of bio‐based cross‐linker/AFAME polymers were significantly lower than the resin/styrene polymers. Ternary blends of maleinated castor oil monoglyceride with AFAME and styrene improved the mechanical properties to acceptable comparable values (storage modulus at 30°C ~ 1200 MPa and Tg ~ 100°C). The addition of 5 wt% of chemically modified lignin led to an improvement in the mechanical properties of the polymeric matrix but caused an increase in the viscosity. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers  相似文献   

12.
Novel optically active polyurethanes (BPUs) based on chiral 1,1′‐binaphthol were synthesized via direct hydrogen transfer addition polymerization. The polymers were analyzed by FTIR, 1H NMR, DSC‐TGA, CD spectra.The results showed that the specific rotation [α]25D were ?78.0° and +54.6° for the S‐BPU and R‐BPU respectively, and these polymers showed better thermal stability. The circular dichroism spectra of the chiral polymers were almost identical except that they gave opposite signals at each wavelength, and the infrared emissivity values of the S‐BPU and R‐BPU were 0.618 and 0.682, they displayed low infrared emissivity. Meantime the polymers implanted with PEG group exhibit better solubility, however thermal stability reduced to some extent. Some properties of the new optically active polyurethanes were reported. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010  相似文献   

13.
Our interest in the fabrication of high‐performance polyimides has led to thiourea‐substituted poly(thiourea‐ether‐imide)s (PTEIs) with good retention of thermal properties along with flame retardancy. A new aromatic monomer, 4,4′‐oxydiphenyl‐bis(thiourea) (ODPBT), was efficiently synthesized and polymerized with various dianhydrides (pyromellitic dianhydride, 3,3′,4,4′‐benzophenonetetracarboxylic dianhydride and 4,4′‐(hexafluoroisopropylidene)diphthalic dianhydride) via two‐stage chemical imidization to fabricate a series of PTEIs. The structural characterization of ODPBT and the polymers was carried out using Fourier transform infrared, 1H NMR and 13C NMR spectral techniques along with crystallinity, organosolubility, inherent viscosity and gel permeation chromatographic measurements. PTEIs bearing C?S and ? O? moieties in the backbone demonstrated an amorphous nature and were readily soluble in various amide solvents. The novel polymers had inherent viscosities of 1.16–1.23 dL g?1 and molecular weights of ca 90 783–96 927 g mol?1. Their thermal stability was substantiated via 10% weight loss in the temperature range 516–530 °C under inert atmosphere. The polyimides had glass transition temperatures of 260–265 °C. Incorporation of thiourea functionalities into polymer backbones is demonstrated to be an effective way to enhance their thermal properties and flame retardancy. Thus, ODPBT can be considered as an excellent candidate for use in the synthesis of high‐performance polymeric materials. Copyright © 2010 Society of Chemical Industry  相似文献   

14.
Two polyphosphonates having multiple flame‐retardant actions were synthesized by interfacial polycondensation of a bisphenol and dichlorophenylphosphine oxide using cetyl trimethyl ammonium chloride as a phase transfer catalyst (PTC) at 0°C. The polyphosphanates thus prepared were characterized by viscometry, elemental analysis, IR, 1H‐NMR, 31P‐NMR, and X‐ray diffraction studies. These polymers are highly soluble in polar solvents such as DMF, DMAc, DMSO, etc., as well as in chlorinated hydrocarbon solvents such as CH2Cl2, CHCl3, etc. The thermal study of polymers was carried out by TGA and DTA analyses. The flammability of the polymers was studied by the limiting oxygen index measurements. The polymers are self‐extinguishing, and begin to lose weight at around 252°C. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 785–792, 2001  相似文献   

15.
Vinyl‐addition polymerization of norbornene was accomplished by two novel dinuclear diimine nickel dichloride complexes in combination with methylaluminoxane (MAO). The activities were moderate. The catalyst structure, Al/Ni molar ratio, solvents, and polymerization temperature all affected the catalytic activities. The obtained polynorbornenes were characterized by 1H‐NMR, 13C‐NMR, FTIR, DSC, WAXD, and intrinsic viscosity measurements. The vinyl‐addition polymers were amorphous but with a short‐range order and high packing density. The polynorbornenes showed glass transition temperatures (Tg) above 240°C and decomposed above 400°C. The catalyst structure and polymerization conditions have effects on the molecular weight and the microstructure of the polymers. The nickel complex with bulkier substituents in the ligand produced polynorbornene with a higher packing density and higher regularity and, therefore, with higher Tg. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 3273–3278, 2003  相似文献   

16.
Polyamides (PAs) containing fluorene, oxyether, and diphenyl‐silane moieties in the repeating unit were synthesized in > 85% yield by direct polycondesation between a diamine and four dicarboxylic acids. Alternatively, one PA was synthesized from an acid dichloride. The diamine 4‐[4‐[9‐[4‐(4‐aminophenoxy)‐3‐methyl‐phenyl]fluoren‐9‐yl]‐2‐methyl‐phenoxy]aniline ( 3 ) was obtained from the corresponding dinitro compound, which was synthesized by nucleophilic aromatic halogen displacement from p‐chloronitrobenzene and 9,9‐bis (4‐hydroxy‐3‐methyl‐phenyl)fluorene ( 1 ). Monomers and polymers were characterized by FTIR and 1H, 13C, and 29Si‐NMR spectroscopy and the results were in agreement with the proposed structures. PAs showed inherent viscosity values between 0.14 and 0.43 dL/g, indicative of low molecular weight species, probably of oligomeric nature. The glass transition temperature (Tg) values were observed in the 188–211°C range by DSC analysis. Thermal decomposition temperature (TDT10%) values were above 400°C due to the presence of the aromatic rings in the diamine. All PAs showed good transparency in the visible region (>88% at 400 nm) due to the incorporation of the fluorene moiety. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011  相似文献   

17.
3,6‐bi(4‐fluorobenzoyl)‐N‐methylcarbazole and 3,6‐bi(4‐fluorobenzoyl)‐N‐ethylcarbazole were synthesized and used to prepare poly(arylene ether ketone)s (PAEKs) with high glass transition temperatures (Tg) and good solubility. High molecular weight amorphous PAEKs were prepared from these two difluoroketones with hydroquinone, phenolphthalein, 9,9‐bis(4‐hydroxyphenyl)fluorene and 4‐(4‐hydroxylphenyl)‐2,3‐phthalazin‐1‐one, respectively. All these polymers presented high thermal stability with glass transition temperatures being in the range 239–303 °C and a 5% thermal weight loss temperature above 460 °C. Compared with the Tg of phenolphthalein‐based PAEK (PEK‐C), fluorene‐based PAEK (BFEK) and phthalazinone‐based PAEK (DPEK) not containing a carbazole unit, these polymers presented a 30–50 °C increase in Tg. Meanwhile, PAEKs prepared from N‐ethylcarbazole difluoroketone showed good solubility in ordinary organic solvents, and all polymers exhibited excellent resistance to hydrochloric acid (36.5 wt%) and sodium hydroxide (50 wt%) solutions. In particular, phthalazinone‐based PAEK bearing N‐ethylcarbazole afforded simultaneously a Tg of 301 °C with good solubility. Tensile tests of films showed that these polymers have desirable mechanical properties. The carbazole‐based difluoroketones play an important role in preparing soluble PAEKs with high Tg by coordinating the relationship between chain rigidity resulting from the carbazole unit and chain distance from the side alkyl. © 2014 Society of Chemical Industry  相似文献   

18.
Unsymmetrical α‐diimine ligand 1 was successfully synthesized via condensation of trimethylaluminum (TMA) metalated 2‐methyl‐6‐isopropyl‐aniline with rigid bicyclic aliphatic diketone camphorquinone. Syn‐ and anti‐stereoisomers were detected by 13C NMR in the condensation product. The corresponding α‐diimine nickel (II) complex 1 was prepared from the exchange reaction of (DME)NiBr2 with the ligand 1 , and displayed high activity for ethylene polymerization in the presence of diethylaluminum chloride (AlEt2Cl). The resultant polymers were confirmed by gel permeation chromatography and 13C NMR characterization to be broad molecular weight distribution polyethylene with various branches, and high degree of branching, even at low polymerization temperature ?10°C. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   

19.
Mixed‐substituent fluoroalkoxyphosphazene polymers bearing ~15% 1H,1H,2H,2H‐perfluorooctan‐1‐oxy or 1H,1H,2H,2H‐perfluorodecan‐1‐oxy side groups together with trifluoroethoxy cosubstituent groups were synthesized. The low reactivity of the long‐chain fluoroalkoxides and their limited solubility in organic solvents prevented higher levels of substitution. Moreover, the sodium alkoxides with two methylene residues adjacent to the oxygen proved to be unstable in solution due to elimination of NaF and precipitation of side products, and this limited the time available for chlorine replacement reactions. The resulting cosubstituent polymers were characterized by proton nuclear magnetic resonance (1H‐NMR), 31P‐NMR, 19F‐NMR, gel‐permeation chromatography, and differential scanning calorimetry. Unlike homo‐ or mixed‐substituent fluoroalkoxyphosphazene polymers, such as [NP(OCH2CF3)2]n (a microcrystalline thermoplastic, Tg ~ ?63°C, Tm ~ 242°C) or [NP(OCH2CF3)(OCH2(CF2)xCF2H)]n (PN‐F, a rubbery elastomer, Tg ~ ?60°C, but no detectable Tm), the new polymers are gums (Tg ~ ?50°C, but no detectable Tm) with molecular weights in the 105 g/mol rather than the 106 g/mol range. POLYM. ENG. SCI., 54:1827–1832, 2014. © 2013 Society of Plastics Engineers  相似文献   

20.
The diamine 2‐methyl‐1,3‐bis(4‐aminophenyloxy)benzene was prepared via a nucleophilic substitution reaction and was characterized with Fourier transform infrared, elemental analysis, and 1H‐ and 13C‐NMR spectroscopy. The prepared diamine was also characterized with single‐crystal analysis. The geometric parameters of C19H18N2O2 were in the usual ranges. The dihedral angles between the central phenyl ring and the two terminal aromatic rings were 88.9 and 91.6°. The crystal structure was stabilized by N? H···N hydrogen bonds. The diamine was then polymerized with 3,3′,4,4′‐benzophenone tetracarboxylic acid dianhydride, 4,4′‐(hexafluoroisopropylidene)diphthalic anhydride, 3,4,9,10‐perylenetetracarboxylic acid dianhydride, and pyromellitic dianhydride by either a one‐step solution polymerization reaction or a two‐step procedure. These polymers had inherent viscosities ranging from 0.61 to 0.85 dL/gm. Some of the polymers were soluble in most common organic solvents even at room temperature, and some were soluble on heating. The degradation temperatures of the resultant polymers fell in the range of 260–500°C in nitrogen (with only 10% weight loss). The specific heat capacity at 200°C ranged from 1.0 to 2.21 J g?1 K?1. The temperatures at which the maximum degradation of the polymer occurred ranged from 510 to 610°C. The glass‐transition temperatures of the polyimides ranged from 182 to 191°C. The activation energy and enthalpy of the polyimides ranged from 44.44 to 73.91 kJ/mol and from 42.58 to 72.08 kJ/mol K, respectively. The moisture absorption was found in the range of 0.23–0.71%. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009  相似文献   

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