低价氯化铝分解的热力学分析

对一氯化铝分解得到液态的金属铝和气态的三氯化铝的反应进行了热力学研究,经过热力学计算得到:在常压下,该反应发生的起点温度为1683.31K,当系统压力下降时,该反应的起点温度也会下降,任何压力下,温度越低越有利于本反应的发生;经过计算得到了该反应起点温度与系统压力间的关系.也得到了不同系统压力下反应吉布斯自由能与系统温度间的关系.     

Mg-6Zn-1Mn镁合金中MgZn相析出的热力学计算

以Miedema生成热模型和Toop模型为基础,参考三元合金溶体中金属间化合物析出行为的热力学模型,计算Mg-6Zn-1Mn(质量分数,下同)三元合金体系中Mg和Zn的活度,进而求出重要强化相MgZn析出反应的Gibbs自由能变化与温度的关系,并得出其析出温度为580 K.MgZn析出温度的计算结果与该合金所取均匀化处理温度相符,并得到了热分析实验的进一步验证.     

Ag/CuO复合材料反应合成热力学分析

通过对Ag/CuO复合材料在反应合成制备中各元素、亚金属氧化物与1 mol氧气反应生成金属氧化物的标准自由焓的热力学计算,绘制了标准自由焓与温度关系图;考虑到氧压力对反应进行有重要影响,在标准自由焓与温度关系图中绘制了氧压力随温度变化的直线.结果表明:Ag与O_2,Cu_2O与O_2的反应是一种可逆反应,其发生可逆转变的温度分别为586.818,667.663 K;氧的压力对金属氧化物的分解有重要影响:压力越低,金属氧化物越易分解;并通过热力学分析结果,最终确定了Ag/CuO复合材料反应合成烧结工艺.     

凝聚电子相与Wagner模型在低钛渣下钛的分配行为中的应用（英文）

为研究铁水中钛元素碳热还原反应规律,提供高炉护炉理论依据,利用高温熔炼、急速淬火、化学分析以及热力学模型计算等方法,在实验室条件下利用分析纯试剂研究在1350~1600°C间钛在低钛渣系CaO-SiO2-MgO-Al2O3-TiO2与铁水间的分配行为。研究结果表明,随着反应温度的增加,钛的分配比L(Ti)增加,但系统活度系数γsys降低,从而导致反应平衡常数升高。结合Wagner与凝聚电子相模型,通过对实验数据进行拟合,得到钛碳热还原反应的吉布斯自由能公式。最后,结合实验所得结果,给出了高炉铁水中w(Si)与w(Ti)含量的关系以及可以达到护炉效果的最小入炉钛负荷。     

滚珠丝杠副转速对温升的影响

不同的转速会导致滚珠丝杠系统产生不同的温度变化。分析滚珠丝杠副转速和温升的关系,建立了滚珠丝杠副热传递过程的微分方程,得到了滚珠丝杠副使用过程中的温度随时间变化的表达形式。进一步得到热平衡状态时滚珠丝杠副的温升计算方法。为验证该方法的有效性,对该模型计算得到的理论温升值与不同转速下试验得到的实际温升值进行对比。通过滚珠丝杠副综合性能试验装置,完成不同转速下滚珠丝杠副温升的测量试验,实际温升值与理论温升值的差值10%以内,证明该方法能很好地预测滚珠丝杠副的温升。     

氧化铝碳热还原反应机制及其热力学

研究了球磨活化后氧化铝碳热还原反应合成氮化铝的机理 ,提出了通过氧化铝碳热还原反应合成氮化铝的新机制 :氧化铝首先发生氮化反应生成AlON相 ,AlON再还原氮化生成氮化铝。通过热力学计算得到的反应平衡温度与实验得到的氮化铝开始生成温度相吻合。     

AerMet100超高强度钢的热变形行为及本构模型研究

采用Gleeble3500热模拟实验机在900~1100℃温度、0.01~10s-1应变速率条件下,对超高强度钢Aer Met100进行了热压缩实验,得到了该合金的真应力-真应变曲线。利用Jonas双曲函数模型建立了峰值应力与变形温度和应变速率的关系,确定了材料的激活能为261.2 k J/mol,应变速率敏感系数m=0.0998,温度敏感系数s=7912。通过一元线性回归法获得了不同应变量下的参数值,得到了上述条件下受到等效应变影响的流动应力本构关系模型,该模型计算相对误差小于11.3%。     

微尺度氧化铁粉还原过程的动力学模拟

用热重分析法研究中低温条件下,氢气还原不同粒度氧化铁的过程,并提出了多颗粒反应料堆动力学模型,以模拟氧化铁微粉在中低温下的还原过程.该模型包括了化学反应动力学方程和颗粒间的气体扩散方程,采用全隐式有限差分方法对控制方程进行数值求解.通过计算得到不同粒度铁矿粉组成的反应料堆在不同温度下,还原率随时间的变化规律,并根据气体浓度在反应过程中的行为得知化学反应和气体扩散在反应速率控制过程中所起的作用.数值模拟数据与试验结果基本吻合.     

00Cr25Ni7M04N超级双相不锈钢的热变形行为

采用Gleeble-3800热模拟机研究了铸态00Cr25Ni7:Mo4N双相不锈钢在应变速率为0.1s-1～10s-1,变形温度为1000～1200℃下的热变形行为,分析了流变应力与应变速率以及变形温度之间的关系.结果发现在同一应变速率下随温度的升高峰值应力值σp减小;在同一温度下随着应变速率的减小峰值应力值σp也减小,并获得了在热变形条件下该双相不锈钢的热变形方程以及其它热变形参数,计算出该双相不锈钢的热变形激活能为433kJ/mol.     

00Cr25Ni7Mo4N超级双相不锈钢的热变形行为

采用Gleeble．3800热模拟机研究了铸态00Cr25Ni7Mo4N双相不锈钢在应变速率为0．1s^-1。10s^-1,变形温度为1000,1200℃下的热变形行为,分析了流变应力与应变速率以及变形温度之间的关系。结果发现在同一应变速率下随温度的升高峰值应力值σp。减小;在同一温度下随着应变速率的减小峰值应力值σp也减小,并获得了在热变形条件下该双相不锈钢的热变形方程以及其它热变形参数,计算出该双相不锈钢的热变形激活能为433kJ／mol。     

自蔓延高温合成TiC-Ni金属陶瓷的热力学编程计算与分析

根据热力学原理对Ti、C、Ni三元体系进行热力学编程计算,绘出了标准反应自由焓随温度变化的曲线、绝热温度随Ni含量变化的曲线以及绝热温度随预热温度变化的曲线,通过对曲线进行分析认为：Ti、C、Ni三元体系的主反应是Ti C=TiC;体系的绝热温度随Ni含量的增加而下降,当预热温度为600K时,最佳的理论Ni含量约40％;体系的绝热温度随预热温度的升高而升高,当Ni含量过大,体系的绝热温度小于1800K时,可以适当提高预热温度,来确保反应的自发进行。     

静高压作用下纯铝凝固过程温度场的数值模拟

采用数值模拟的方法,研究了纯铝在静高压作用下凝固过程温度场的变化情况。首先建立了温度场的数学模型,根据压力与金属熔点的关系,将压力作用到凝固过程的温度场上。模拟结果表明:压力越大,纯Al开始凝固的时间越早;在凝固过程中,压力越大,对应的温度变化速度越快。     

Thermodynamic assessment of the Aluminum-Manganese (Al-Mn) binary phase diagram

A thermodynamic calculation of the Al-Mn binary system that takes into account recent experimental results and includes five intermetallic compounds and all the solid-solution phases is presented. The Gibbs energy of the body-centered cubic (bcc) phase has been described on the basis of the two-sublattice model that includes the second-order A2/B2 ordering reaction as well. A consistent set of optimized thermodynamic parameters has been arrived at for describing the Gibbs energy of each phase in this system leading to a better fit between calculation and experiments.     

Thermodynamic assessment of the Aluminum-Manganese (Al-Mn) binary phase diagram

A thermodynamic calculation of the Al-Mn binary system that takes into account recent experimental results and includes five intermetallic compounds and all the solid-solution phases is presented. The Gibbs energy of the body-centered cubic (bcc) phase has been described on the basis of the two-sublattice model that includes the second-order A2/B2 ordering reaction as well. A consistent set of optimized thermodynamic parameters has been arrived at for describing the Gibbs energy of each phase in this system leading to a better fit between calculation and experiments.     

Experimental Investigation and Thermodynamic Calculation of the Phase Equilibria in the Al-Bi-Sn Ternary System

This work first deals with the experimental investigation and thermodynamic calculation in the Al-Bi-Sn ternary system. The phase equilibria at 400 and 500 °C in the Al-Bi-Sn ternary system have been experimentally determined by electron probe microanalysis (EPMA) on the equilibrated alloys. Based on the experimental data determined in the present work, the phase equilibria in the Al-Bi-Sn ternary system have been thermodynamically assessed by using the CALPHAD (CALculation of PHAse Diagrams) method, and a consistent set of thermodynamic parameters leading to reasonable agreement between the calculated results and experimental data was obtained. The additions of Sn can effectively reduce the stable liquid miscibility gap in the Al-Bi binary system and gradually decrease its critical temperature. And the additions of Bi can significantly stabilize the metastable liquid miscibility gap in the Al-Sn binary system. This is shown by an initial decrease in critical temperature with increasing Bi additions.     

Thermographic detection of fatigue damage of reactor pressure vessel (RPV) steels

An IR (IR) thermography technique, as a nondestructive evaluation technique, was applied to investigate the fatigue damage of reactor pressure vessel (RPV) steels during 20 Hz and 1000 Hz fatigue testing. Five stages of temperature profile were observed: an initial increase of the average specimen temperature, a region of temperature decrease, an equilibrium (steady-state) temperature region, an abrupt increase of the temperature, and a drop of temperature following specimen failure. The relationship between the temperature, stress-strain state, and fatigue behavior is discussed. Both thermodynamic and heat-transfer theories are applied to model the observed temperature variation during fatigue. The stress-strain state of the material has been back-calculated from the observed temperature profiles. The predicted and measured temperature evolutions and mechanical behavior during fatigue were found to be in good agreement. Thermography appears to provide a useful method of investigating the stress-strain behavior during fatigue.     

Modeling for thermal contact resistance of frictional interface under high temperature and high pressure

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