Optical rewritable liquid‐crystal‐alignment technology

Abstract— A new optical rewritable (ORW) liquid‐crystal‐alignment technology has been developed to create a display and to demonstrate its maturity and potential. ORW displays have no electrodes and use polarizers as substrates. The display requires no photolithography on plastic. Its simple construction secures durability and low cost for mass production. The on‐screen information is optically changed in a writing unit that consists of an LCD mask and an exposure source that is based on LEDs, low power, and low cost in comparison with Hg lamps or lasers. A high contrast image can be easily written, viewed, and rewritten through a polarizer, while the multi‐stable gray‐level image requires zero power to maintain the image. Reconfigurable LC alignment using ORW technology best suits plastic‐card displays as well as for LC photonics and various one‐mask processes of patterned LC‐alignment applications.     

Properties of azo‐dye alignment layer on plastic substrates

Abstract— The alignment properties of the azo‐dye photo‐alignment material SD‐1/SDA‐2 on plastic substrates are investigated. Important liquid‐crystal cell parameters, such as azimuthal and polar anchoring energy, pretilt angle, voltage holding ratio, and the corresponding electro‐optical properties are presented. Excellent alignment with high anchoring energy can be achieved with a polarized UV dose less than 1.0 J/cm². A reflective six‐digit flexible passive‐matrix‐driven TN‐LCD for smart‐card applications showing excellent electro‐optical properties is demonstrated.     

Polarization‐independent and electrically tunable liquid‐crystal Fresnel lenses based on photoalignment in dye‐doped liquid crystals

Abstract— This work demonstrates polarization‐independent and electrically tunable liquid‐crystal (LC) Fresnel lenses based on photoalignment in dye‐doped liquid crystals (DDLCs). The LC alignments in the adjacent odd and even zones of the LC Fresnel lens are orthogonally hybrid alignments. Those are generated by surface treatment of homeotropic and homogeneous alignment layers, and the dye‐adsorption layer onto the UV‐cured surface‐relief Fresnel zone plate. The maximum focusing efficiency (～34.14%) of the fabricated LC Fresnel lens by applying a suitable AC voltage is close to the maximal theoretical focusing efficiency of a binary phase LC Fresnel lens (～40.5%). Additionally, the focusing efficiency is polarization‐independent and electrically tunable.     

Synthesis and application of an alkylated pyrazole‐based azo dye for electrofluidic display

Electrofluidic display (EFD) is one of the most promising reflective displays for its full color and video speed. Colored EFD oil, normally formulated by soluble organic dyes in non‐polar solvent, dominates the color, electro‐optical behavior, and reliability performances for EFD devices. In this paper, a novel yellow electrofluidic dye with excellent solubility in non‐polar EFD solvent was achieved based on the introduction of long alkyl chain into pyrazole azo dye. The resulting EFD device fabricated by the dye showed excellent application properties, such as fast switching speed (17.8 ms), high aperture ratio (68.5%), low threshold voltage (24v), good light stability (240 h under accelerated conditions), and low backflow phenomenon.     

Azo‐dye aligning layers for liquid‐crystal cells

Abstract— The photo‐induced alignment of liquid crystal onto a photochemical stable azo‐dye film was studied for liquid‐crystal display (LCD) applications. The photo‐aligning of azo dye takes place due to the pure reorientation of the molecular absorption oscillators perpendicular to the UV‐light polarization. The order parameters S = ?0.4 (80% of the maximum absolute value S_m = ?0.5) was measured at a wavelength of 372 nm from the polarized absorption spectra. The temperature‐stable pretilt angle of 5.3° was obtained by a two‐step exposure of azo‐dye film using normally incident polarized light followed by oblique non‐polarized light. The azimuthal anchoring energy of the photo‐aligned substrate was A_? > 10^?4 J/m², which is of the same magnitude as the anchoring of the rubbed PI layer. The VHR value of the photo‐aligned LC cell was also found to be very high (98–99%) at room temperature and more than 95% at T=80°C. The thermal stability of the photo‐aligned azo‐dye layers is sufficiently high, while UV stability has to be improved, _e.g., by polymerization. The new LCD aligning technology based on photochemical stable azo‐dye layers is envisaged.     

Synthesis and characterization of novel blue azo‐dye derivatives containing acrylate group for dye‐based color filters

Abstract— Even though dyes have a fine resolution and good chromaticities, they are not widely used as coloring materials for color filters (CFs) due to their low thermal stability and chemical resistance. A series of azo‐dye derivatives, which consist of two cross‐linkable acrylate or methacrylate groups to improve thermal and chemical properties, have been synthesized and used to fabricate color filters. The spectral properties and chemical/thermal stabilities of the fabricated CFs were investigated by comparing dye‐based CFs, without a complicated dispersion process, but with pigment‐based CFs using dispersed pigment. Also, more properties including the development test and surface morphologies lithographic properties were studied. The synthesized azo dyes were characterized by elemental analysis, UV‐visible spectra, IR, mass, and ¹H‐NMR spectra.     

A photon‐mode full‐color rewritable image using photochromic compounds

Abstract— A photon‐mode full‐color rewritable image has been demonstrated. Three types of photochromic fulgides having yellow, magenta, and cyan color were used as rewritable dyes. Photochromic fulgides were mixed and coated on a white polyethylene terephthalate film. Upon irradiation with three (red, green, and blue) visible light beams, a wide hue extent, a high white reflectance of over 80%, and a high contrast ratio of over 45:1 were attained. A full‐color image retains its colors for over 1 hour under standard‐office‐brightness conditions (700 lx). The photochemical coloration‐decoloration cycles could be repeated over 100 times without substantial losses.     

Electric and magnetic fields in photoalignment of liquid crystals

The results of investigation of slow surface dynamics (easy axis gliding), induced by secondary illumination of photoaligned substrates with linearly polarized UV or blue light in the presence of electric (magnetic) fields, are presented for the first time. The initial surface orientation of nematic liquid crystal (NLC) was provided, in accordance with the standard photoalignment technique, via preliminary UV treatment of the glass substrates coated by sulfonic azo‐dye SD1 film. The experiments fulfilled for the two geometries, A and B, corresponding to the normal (A) and parallel (B) orientation of fields relatively to liquid crystal (LC) layer, revealed different effects induced by electric (magnetic) fields. For geometry A, strong electric field applied, in combination with a linearly polarized blue light, to the planar layer in a sandwich‐like LC cell with two photoaligned substrates results in simultaneous reorientation of easy axis on both substrates. It demonstrates the possibility of an azimuthal rotation of monodomain planar samples of LCs. For geometry B, usage of “in‐plane” electric (magnetic) fields in the cell, composed of photoaligned and rubbed substrates, speeds up reorientation process of NLC easy axis respectively to pure light‐induced reorientation. It provides electric control of operating times in previously proposed optical rewritable technology.     

Bright e‐skin technology and applications: Simplified gray‐scale e‐paper

Abstract— Bright‐color electronic‐paper technology based on in‐plane electrophoresis is very suitable for application in non‐emissive digital surfaces, such as electronic skins, eco‐skins, and electronic wallpaper for atmosphere creation. Aimed at these applications, simplified electrode geometries, aperiodic cell geometries, and a novel concept for built‐in gray levels have been developed.     

Development of active‐matrix electronic‐ink displays for handheld devices

Abstract— Interest in the use of electrophoretic displays for smart handheld applications has grown tremendously over the past few years. Since the launch of the Philips and E Ink joint development effort in February 2001, material parameters, TFT backplane, electronic hardware and software and modulization skills have been developed to make this promising display concept into a real product. The first commercial launch of active‐matrix electronic‐ink display modules is planned for mid 2004.     

Laser‐addressed full‐color photo‐quality rewritable sheets based on thermochromic systems with leuco dyes

We have developed a laser‐addressed full‐color photographic quality rewritable sheet. The sheet was composed of a vertically stacked Cyan/Magenta/Yellow‐thermochromic system with a mixture of leuco dyes, developers and photothermal conversion agents in a polymer matrix. The sheet was simply manufactured by roll‐to‐roll (R2R) processes. Writing and erasing were performed by scan of near‐infrared laser light. It achieved full‐color photographic quality images with a wide color gamut with 70% coverage of the Specifications for Web Offset Publications (SWOP) standards and a high resolution of 426 ppi. Clear rewritability has also been confirmed. Non‐contact laser writing has other advantages in that it can create an image under a protection film, and it has form factor flexibility. We have developed a reliability model for high‐temperature storage and a light fastness test. This model showed a good agreement with experimental data, and the lifetime of an image was estimated to be over 8 years under ambient conditions. This technology will create applications for on‐demand rewritable image design while saving power and reducing the use of paper, which will eventually contribute to a sustainable society.     

Photoalignment dynamics of azo dyes series with different coordination metals

There are many photoaligned azo dyes that can be used for orientation of liquid crystals in various display devices. However, the structure of these compounds needs to be optimized to increase the rate of the process of molecule photoalignment, as well as to spread the application of these compounds. The main coordination metal that presents in the molecules of azo dyes is sodium derivatives. The use of other alkali metals remains an open question. We used quantum‐chemical computation methods and reversible intermolecular bonding model to determine the effect of metal coordination on the velocity of photoalignment. The theoretical predictions were experimentally verified using sodium, potassium, lithium, and cesium salts of the model azo dye synthesized by us. We conclude that potassium azo derivatives are the fastest, ceteris paribus.     

Aggregate‐induced emission in light‐emitting liquid crystal display technology

Nowadays, liquid crystal displays (LCDs) with light‐emission are considered as energy‐efficient devices and are promising alternatives to conventional LCDs. To realize such possibility, strong fluorescent materials with a dichroic properties are required. Aggregate‐induced emission (AIE) is an unusual photophysical phenomenon shown by some luminogenic materials that will be highly emissive in their aggregate state. In this work, we studied the AIE effect of a luminescent liquid crystalline molecule TPE‐PPE in our LC system as a luminophore dopant. The result showed the excellent AIE effect that higher concentration of luminogen in the nematic LC host induced stronger luminescent intensity. Through exposure of a photoisomeriable alignment material sulfonic‐dye‐1, the photopatterning of a light‐emitting LC device was achieved with the use of the TPE‐PPE/nematic LC mixture.     

Memory Effect Canceling and Novel Driving Scheme of Twisting‐ball Display via Space‐charge Polarization

In this paper, characteristics of memory effect cancelling method for twisting‐ball display utilizing space‐charge polarization were examined. Response speed of the display to voltage removal became slow with increasing resistance value of resistors connected in parallel to the display. Memory effect canceling was effective with the resistance value at least up to 1 GΩ. Polarization and depolarization of space‐charges in a twisting‐ball display were completed in 60 s at 50 V and space‐charge polarization was induced under 1 Hz. The strength of space‐charge polarization can be controlled by the extent of progress of polymerization of the silicone rubber sheet, which means unpolymerized silicone rubber molecules or cross‐linker molecules can be charge careers in the display. Also, we proposed and demonstrated a novel driving scheme for the twisting‐ball display utilizing space‐charge polarization, which achieved simple structure, fast response and low energy consumption.     

New multicolor and rewritable holographic polymer film for three‐dimensional holographic display

We have developed a new multicolor holographic polymer film. Our holographic polymer film contains 3‐[(2,4,6‐trichloro)azo]‐9H‐carbazole‐9‐ethanol (A‐1) and poly(methyl methacrylate). The holographic polymer film can be recorded with a holographic image without applying an external electric field. The diffraction efficiency was 57% at A‐1 with a 20 wt% of dope ratio. The writable holographic image writing for the holographic polymer film step used the silver halide photographic emulsion master plate 532‐nm laser beam under the nonelectric field. After the copy hologram is formed, our holographic polymer film can be displayed in red and green holographic images. Even though our holographic polymer film is rewritten over 200 times, the diffraction efficiency does not fall. As the holographic polymer film is manufactured using roll‐to‐roll techniques, although still in a laboratory scale in this study, it has a strong possibility of being manufactured in larger sizes with lower cost.     

A controller design for micro‐cup active‐matrix electrophoretic displays

Abstract— The active‐matrix electrophoretic display (AMEPD) has been commonly used for the applications of smart handheld reading devices such as e‐books and e‐newspapers. This paper presents a controller IC design for the AMEPD backend system which reduces the total hardware cost compared to that of the conventional design. By contrast, this study also provides a driving method for image displays. The prototyped controller is connected to a 6‐in. AMEPD panel, and good display quality has demonstrated the effectiveness of the proposed controller design.     

Full‐color photo‐addressable electronic paper using cholesteric liquid crystals and organic photoconductors

Abstract— Full‐color photo‐addressable electronic paper using cholesteric liquid crystals and organic photoconductors was developed. The electronic paper is comprised of two stacked photo‐addressable elements displaying blue/green and red images, respectively. Each photo‐addressable element was independently controlled by two different color‐addressing lights. Furthermore, blue and green images were selectively switched by one organic photoconductor using the threshold characteristics of cholesteric liquid crystals. A highly reflective polymer‐dispersed cholesteric liquid‐crystal (PDCLC) layer was obtained by a new formation process based on the sol‐gel transition behavior of a gelatin matrix and an agar overcoat layer. The PDCLC layer had a close‐packed honeycomb‐like monolayer structure with a flat surface. The A6‐sized prototype had paper‐like features and showed full‐color bistable images instantly written with a viewer‐type writing apparatus.     

Flexible electronic‐paper active‐matrix displays

Abstract— A QVGA active‐matrix backplane was produced on a 25‐μm thin plastic substrate. A four‐mask photolithographic process was used. The insulator layer and the semiconductor layer were organic material processed from solution. This backplane was a combination of the electrophoretic display effects supplied by SiPix and E‐Ink Corp., resulting in electronic‐paper displays with a thickness of 150 and 100 μm, respectively; this is the world's thinnest active‐matrix display ever made.     

Single‐cell‐gap transflective liquid‐crystal display and the use of photoalignment technology

Abstract— In this paper, transflective liquid‐crystal‐display (LCD) technology will be reviewed, and several new single‐cell‐gap transflective LCD configurations are proposed. Photoalignment technology is studied especially for transflective‐LCD applications. In order to realize the optimal performance of the display as well as a matched transmittance/reflectance voltage curve (TVC/RVC) for the transflective configurations, two different single‐cell‐gap transflective‐LCD approaches will be discussed. The first one is the dual‐mode single‐cell‐gap approach, in which different liquid‐crystal modes are applied to the transmissive and reflective subpixels of the transflective LCD. The other approach is the single‐mode s ingle‐cell‐gap approach, in which an in‐cell retardation film is applied to adjust the performance and TVC/RVC matching of a transflective LCD. Photoalignment technology is used to fabricate the dual‐mode liquid‐crystal cell in the first approach and also the in‐cell retardation film in the second approach. Prototypes of the proposed configurations have been fabricated, which show good performance and a matched TVC/RVC.     

Flexible electronic‐paper active‐matrix displays

Abstract— A100‐μm‐thick 320 × 240‐pixel active‐matrix display integrated into a functional‐device prototype is presented. The active matrix is composed of alternating layers of organic materials and gold. A six‐mask photolithographic process is used. An electrophoretic electronic imaging film is laminated on top of the active matrix. The display is bendable to a radius of 7.5 mm for more than 30,000 repetitions.