Diamond‐like‐carbon LC‐alignment layers for application in LCOS microdisplays

Abstract— To improve the lifetime and yield of LCOS microdisplays, non‐contact LC alignment techniques using inorganic materials are under investigation. This report focuses on oblique ion‐beam treatment of diamond‐like carbon (DLC) layers, and in particular on the influence of the ion dose on the LC alignment on DLC, keeping the ion‐beam angle (40°) and ion‐beam energy (170 eV) the same. LC alignment on ion‐milled DLC layers is uniform if the ion dose is between 3.8 × 10^?4 C/cm² and 5.5 × 10^?3 C/cm². Above and below this ion dose range, non‐uniform alignment is observed. NEXAFS experiments show that this is caused by lack of molecular anisotropy on the surface of the ion‐milled DLC layers. By varying the ion dose between 3.8 × 10^?4 C/cm² and 5.5 × 10^?3 C/cm², LC molecules have an average pre‐tilt between 3° and 5°, which is within the desired range for application in LCOS microdisplays. The lifetime of the LCOS microdisplays with ion‐milled DLC for projection‐TV application is, however, shorter than the lifetime of microdisplays with PI layers. Ion milling probably creates a reactive surface that is unstable under the high light fluxes used in projection TVs. A solution for this problem could be chemical passivation of the ion‐milled alignment layers. Initial experiments with passivation of ion‐milled PI resulted in an increase in lifetime, but the lifetime after passivation was still lower than the lifetime of rubbed PI layers (factor 0.7). Nevertheless, ion‐milling of DLC or PI can be a good alternative LC alignment technique in other LCD applications. LC‐alignment layers based on inorganic layers such as obliquely deposited SiO₂ films would be a better option for application in LCOS microdisplays due to their higher light stability.     

Fast‐response nematic liquid‐crystal mixtures

Abstract— High birefringence and relatively low‐viscosity isothiocyanate‐based liquid‐crystal compounds and mixtures were developed. A high figure‐of‐merit (FoM), which implies a fast response time of the described liquid crystals was observed. Using the new UCF mixture in a 2‐μm cell, a submillisecond response time was obtained. The UV stability dilemma is discussed as a common concern for high‐birefringence LC materials.     

Azo‐dye aligning layers for liquid‐crystal cells

Abstract— The photo‐induced alignment of liquid crystal onto a photochemical stable azo‐dye film was studied for liquid‐crystal display (LCD) applications. The photo‐aligning of azo dye takes place due to the pure reorientation of the molecular absorption oscillators perpendicular to the UV‐light polarization. The order parameters S = ?0.4 (80% of the maximum absolute value S_m = ?0.5) was measured at a wavelength of 372 nm from the polarized absorption spectra. The temperature‐stable pretilt angle of 5.3° was obtained by a two‐step exposure of azo‐dye film using normally incident polarized light followed by oblique non‐polarized light. The azimuthal anchoring energy of the photo‐aligned substrate was A_? > 10^?4 J/m², which is of the same magnitude as the anchoring of the rubbed PI layer. The VHR value of the photo‐aligned LC cell was also found to be very high (98–99%) at room temperature and more than 95% at T=80°C. The thermal stability of the photo‐aligned azo‐dye layers is sufficiently high, while UV stability has to be improved, _e.g., by polymerization. The new LCD aligning technology based on photochemical stable azo‐dye layers is envisaged.     

Novel liquid‐crystal materials for AMLCDs

Abstract— We have developed novel liquid‐crystal (LC) materials with a difluoromethyleneoxy CF₂O) moiety as the linkage group in order to satisfy the various requirements of active‐matrix liquid‐crystal displays (AMLCDs). We measured the physical properties of the CF₂O LC materials. The novel CF₂O LC materials have excellent physical properties, that is, high dielectric anisotropy, low viscosity, a broad nematic range, high reliability, etc. It was revealed that several advantages can be obtained by the introduction of CF₂O moiety into the LC molecules. The mixture containing CF₂O LC materials for various applications indicated a decrease in rotational viscosity of about 15–25% compared with that for conventional LC mixtures. Also, these novel mixtures with CF₂O LCM demonstrated a higher voltage‐holding ratio (VHR). It was confirmed that mixtures containing CF₂O LC materials have suitable characteristics for various applications, for example, low‐driving‐voltage note‐book PCs, quick response monitors, and transflective applications.     

Ferroelectric liquid crystal aligned on SiO2 thin films using ion‐beam deposition

Abstract— Results for a ferroelectric‐liquid‐crystal (FLC) display cell, aligned on inorganic SiO₂ thin‐film surfaces by using oblique ion‐beam sputtering deposition on the substrates, is presented. A large deposition angle from 60° to 80° can be employed for the thin alignment layer, with thicknesses varying from 5 to 40 nm. Two types of uniform alignment, chevron (before electrical treatment) and quazi‐bookshelf (after electrical treatment), were studied. High‐quality alignment on large‐sized substrates was also easily be achieved because of the linear design of the ion‐beam sputtering source, which was previously a significant challenge for FLC on SiO_x layers.     

Comparison of organic and inorganic alignment layers for low‐power liquid‐crystal devices using low‐frequency applied‐voltage waveforms

Abstract— Bistable displays are known to have low‐power consumption, but they usually lack the ability to display full‐color video‐rate images. Operating active‐matrix liquid‐crystal displays (AMLCDs) with an ultra‐wide refresh‐rate range, down to ～1 Hz, can lower the power consumption to that of bistable devices and offer video rates as well. A SiO^x‐layer‐based liquid‐crystal (LC) alignment technique is studied here to overcome the ion problems typically encountered with low‐refresh‐rate devices. The effect of ions on the voltage‐holding ratio (VHR) and residual DC voltage (RDC) with SiO^x‐based LC alignment is compared with those for polyimide‐based LC alignment. It is found that only SiO^x alignment provides high VHR and small RDC, with good stability over time. Therefore, it is shown that SiO^x alignment is an excellent candidate for low‐power AMLCDs operated with an ultra‐wide refresh‐rate range.     

Ferroelectric nanoparticle/liquid‐crystal colloids for display applications

Abstract— A non‐synthetic approach to modify liquid crystals (LCs) by dispersing low concentrations of ferroelectric nanoparticles is reported. These dilute colloids are stable and appear similar to a pure LC. However, by changing the concentration and the type of ferroelectric particles, the physical properties of the LC materials can be tailored, including the nematic isotropic transition temperature (T_NI), the dielectric constants, the birefringence (Δn), elastic constants, and the threshold voltage. Specifically, doping low concentrations of BaTiO₃ nanoparticles (～1%) into a LC MLC‐6609 increases T_NI up to ～40°C. This giant shift of T_NI has never been previously reported and indicates strong interactions between the LC and ferroelectric nanoparticles on a molecular level. The doped LC also demonstrates significant enhancement in birefringence (by 10–30%), dielectric anisotropy (by ～50%), and the elastic constant K₃₃ (by ～20%). Ferroparticles act as molecular additives and modify the intrinsic properties of LC materials without time consuming and expensive chemical synthesis. The new LC materials are very attractive and suitable for use in displays, switchable lenses, beam steering, as well as other light‐controlling devices.     

Novel photoinduced alignment phenomenon of liquid crystals on aromatic polyamide films

The liquid‐crystal (LC) alignment properties of polyamide films exposed to ultraviolet (UV) light were investigated. It was found that the uniform and stable alignment of LC molecules was achieved on films of aromatic polyamides exposed to linearly polarized UV light, even though these polymers contained no common photoreactive group such as cinnamoyl, coumarin, or azo chromophore. The alignment was induced in the same direction, which was perpendicular to the electric‐field vector of the linearly polarized light. The change in the UV‐visible absorption spectra before and after UV exposure suggested that the photoreaction of aromatic polyamide occurred only on the film surface, and that even such a small change in the film was enough to induce uniform alignment of the LC molecules. Furthermore, it was suggested that the photoreaction of this system was accelerated in the presence of oxygen. This paper also deals with the effect of the chemical structure of polymers on their LC photoalignment characteristics, i.e., the sensitivity of the photoinduced LC alignment. As a result, polymer materials with excellent LC photoalignment sensitivity have been determined, which could induce the uniform and unidirectional LC alignment by irradiation of 0.2–0.5 J‐cm^?2 of linearly polarized 313‐nm light. In addition, the alignment of the LC cell was found to be thermally and optically stable.     

Second wind of the oblique deposition method of liquid‐crystal alignment: Ion‐beam sputtering technique

Abstract— Liquid‐crystal (LC) alignment on SiO_x films produced by ion‐beam sputtering deposition was comprehensively studied. The conditions for planar, tilted planar, homeotropic, and tilted homeotropic LC alignment of high uniformity were determined. The alignment photostability and aging issue are discussed. An original sputtering system based on the anode‐layer source excelling in high reliability and quality of sputtered coatings were used. Because this system can be easily scaled up, the alignment treatment of the large‐area alignment substrates, including those used in modern LCD manufacturing, can be realized. The advantages of the sputtering LC alignment technique, in comparison with its vapor‐deposition predecessor, are described.     

Novel liquid‐crystal materials with negative dielectric anisotropy for TV application

Abstract— The development of materials for vertically aligned (VA) active‐matrix display technology is briefly reviewed and the newest generation of liquid crystals for this application is disclosed. These new materials possess a unique combination of high dielectric anisotropy Δε and low rotational viscosity γ₁ with good clearing temperatures T_NI for fast‐switching LC mixtures targeted for TV application.     

High‐performance organic‐inorganic hybrid plastic substrate for flexible displays and electronics

Abstract— An inorganic‐dominated silica/polyimide (PI) hybrid film has been successfully developed for the fabrication of flexible AMOLEDs. The existence of networks between silica particles in the PI matrix have been confirmed by 3‐D tomography, respectively. The inorganic—organic hybrid film was achieved by roll‐type processing with a variety of attractive properties, such as low coefficient of thermal expansion (CTE, 20 ppm/°C), high transmittance (within the wavelength range of 400–700 nm), excellent flexibility, and high Young's modulus. Additionally, a flexible color‐filter, an AMEPD, and a flexible touch film were fabricated on hybrid film.     

Inorganic EL devices with high‐performance blue phosphor and application to 34‐in. flat‐panel televisions

Abstract— A high‐performance inorganic electroluminescence (EL) device has been successfully developed by using an EL structure with a thick dielectric layer (TDEL) and sputtered BaAl₂S₄:Eu blue phosphor. The luminance and efficacy were higher than 2300 cd/m² and 2.5 lm/W at L⁶⁰, 120 Hz, respectively. Furthermore, the luminance at L⁶⁰, 1.2 kHz was more than 23,000 cd/m². The phosphor layer has a single‐phase and a highly oriented crystalline structure. The phosphor also shows high stability in air. A 34‐in. high‐definition television (HDTV) has been developed by combining a TDEL structure and color‐conversion materials. The panels with an optimized color filter demonstrated a peak luminance of 350 cd/m², a color gamut of more than 100% NTSC, and a wide viewing angle similar to that of plasma‐display panels. The high reproducibility of the 34‐in. panels using our pilot line has been confirmed.     

Analysis of image sticking on a real MVA Cell

Abstract— Image‐sticking phenomenon is one of the most important issues affecting LCDs, especially LCD TV. It is known that image sticking is caused by residual DC voltage. An analysis of the cause that induces image sticking on a real LCD cell is very difficult to perform and is rarely reported. In this paper, the impurities that cause boundary image sticking on a real MVA cell was analyzed by examining a cross section of a cell, the bulk LC layer, the vicinity of the LC layer, the LC layer/PI alignment film interface using microanalysis methods such as infrared micro‐spectroscopy (μ‐IR) and micro‐sampling mass spectrometry (μ‐MS). It is clarified that there is quite a bit of aromatic acid at the boundary of the image‐sticking area than in the normal area at the LC/PI alignment film interface on the color‐filter side, not the TFT side, and it is assumed that aromatic carboxylic acid, a negative charged material, is condensed at the LC/PI alignment film interface on the color filter side by an electrically driven DC component inducing an electric‐condenser residual DC voltage.     

Progress in fabrication technologies of polycrystalline‐silicon thin‐film transistors at low temperatures

Abstract— The development of fabrication processes for polycrystalline‐silicon thin‐film transistors (poly‐Si TFTs) at low temperatures will be discussed. Rapid crystallization of silicon films through laser‐induced melt regrowth has the advantage of having a low thermal budget. Solid‐phase crystallization techniques have also been improved for low‐temperature processing. Passivation of the SiO₂/Si interface and crystalline grain boundaries is important in achieving high‐carrier‐transport properties. Oxygen‐plasma and H₂O‐vapor heat treatments are proposed for the effective reduction of the density of defect states. TFTs with high performances will be reported.     

Single‐layered retardation films with negative wavelength dispersion birefringence made from liquid‐crystalline monomers

Organic light‐emitting diode displays have a cathode composed of a layer of highly reflective metal. Reflection of external light from this layer can be suppressed with a broadband quarter‐wave plate. Although various types of quarter‐wave plate retardation films have been prepared by copolymerizing, mixing, or laminating multiple polymers, ideal wavelength dispersion has not been achieved with thin retardation films because of their relatively low birefringence and the complexity of the procedure required manufacturing them. In this study, we developed (i) new liquid‐crystalline monomers with negative wavelength dispersion birefringence that we used to obtain thin, single‐layered retardation films suitable for coating and (ii) retardation films with different molecular alignments. We found that the monomers showed high solubility and high regularity of molecular alignment, with less damage to the substrate and alignment films. We also investigated the wavelength dispersion and thermal stability of the films. We succeeded in developing retardation films that had a homeotropic alignment or a hybrid alignment with negative wavelength dispersion. These alignments can be used to obtain antireflection films with an improved viewing angle for organic light‐emitting diode displays or next‐generation thin displays.     

Invited Paper: New technology for HTPS‐LCD panels for projection systems

Abstract— A new technology has been developed for high‐temperature‐polysilicon (HTPS) TFT liquid‐crystal panels employed in projection systems. It consists of vertically aligned nematic (VAN) liquid‐crystal, inorganic alignment layers, and a new driving technique. Full‐HD (1080p) resolution was realized in a 0.7‐in.‐diagonal device with high contrast and low power consumption.     

New properties and applications of rewritable azo‐dye photoalignment

Abstract— The rewritable azo‐dye photoalignment (ORW) of liquid crystals (LCs) for application in optical rewritable electronic paper has been investigated. It was observed that a periodic change in the azimuthal aligning direction with polarized UV light (365 nm) brings about homeotropic alignment, while utilization of visible light (450 nm) does not affect the LC tilt angle. The wavelength dependence of the ORW photoalignment result and the behavior of the photoinduced anisotropy was explored. The dark amplification of film anisotropy after exposure was observed, which is believed to be the relaxation process related to hydrogen bonding in azo‐dye film. New material, CD1, for azo‐dye rotation photoalignement that possesses a high azimuthal anchoring energy (about 2 × 10^?4 J/m²) was found.     

Polymer‐stabilized pretilt angle on the surface of nanoparticle‐induced vertical‐alignment surface for multi‐domain vertical‐alignment liquid‐crystal display

Abstract— By introducing polyhedral oligomeric silsesquioxane (POSS) nanoparticles along with a controlled amount of UV‐curable reactive mesogen (RM) into a liquid‐crystalline (LC) medium, a multi‐domain vertical‐alignment LC device was successfully demonstrated. The device, possessing a vertically aligned LC director in four different azimuthal directions, exhibited a fast response time and wide‐viewing‐angle characteristics, in the absence of conventional polymer‐type vertical‐alignment layers. Electro‐optic characteristics of the fabricated device, before and after UV curing of the cell, were studied. The surface morphology of the substrate surfaces were analyzed by using field‐emission scanning electron microscopy (FESEM). The experimental results show that the technology will possibly be applicable to cost‐effective vertical‐alignment liquid‐crystal devices and is suitable for green‐technology liquid‐crystal displays.     

EO characteristics for a photoaligned VA‐1/4 π cell on a photopolymer layer

The generation of a liquid‐crystal (LC) tilt angle on a copolymer with chalconyl and cholesteryl moiety characteristics was performed, and the electro‐optical (EO) performance of the photoaligned vertical‐alignment (VA) 1/4 π cell by polarized UV exposure on a homeotropic photopolymer surfaces was studied. The LC tilt angles decreased as UV exposure time increased on the copolymer surfaces. A tilt angle of 87° in NLC was observed with an UV exposure of 3 min on the photoalignment‐2 surface. The LC tilt angle is attributed to increased chalcone moiety with increasing UV exposure time. Excellent voltage‐transmittance (V‐T) curves of the photoaligned VA 1/4 π cell by polarized UV exposure on the photopolymer surface for 3 min containing a cholesteryl moiety of 8% were obtained. The V‐T and response‐time characteristics can be improved by the presence of a cholesteryl moiety in the photopolymer.     

Physical interpretation of the characteristics of LCDs embedded with MgO and SiO2 nanoparticles

Abstract— The electro‐optical characteristics of TN‐LCD and ECB‐LCD cells, both of which were embedded with of MgO and SiO₂ nanoparticles at a low concentration of about or below 1 wt.%, were investigated. The threshold voltage and operating voltage of these LCD cells were found to decrease by 5–16%, depending on the materials and the concentration of nanoparticles. Measurements of the physical properties of nanoparticle‐embedded NLCs, such as the order parameter, clearing point, birefringence, dielectric anisotropy, elastic constants, and rotational viscosity on the nanoparticle‐doped NLC sample cells, were performed. Through these measurements, it is shown that the decrease in the threshold voltage and the operating voltage may be attributed to the decrease in the order parameter by 10–30% due to the existence of these nanoparticles.