Technologies toward flexible liquid‐crystal displays

Abstract— Several leading technologies for flexible liquid‐crystal displays have been developed recently at ERSO. The roll‐to‐roll compatible techniques, polymer‐added liquid crystal, have been applied on a film‐like substrate. A flexible black‐and‐white cholesteric liquid‐crystal display was also implemented by photo‐induced phase separation. Color filters placed on a plastic substrate by a low‐temperature manufacturing process was successfully fabricated. A novel design of a wide‐viewing‐angle color plastic LCD was also proposed.     

Moving‐image‐sticking phenomenon induced by an outside force in liquid‐crystal displays

Abstract— Image deformation caused by an outside force is observed to remain for hours at high gray levels for liquid‐crystal displays (LCDs) in the multi‐domain (MD) vertical‐alignment (VA) mode. This so‐called moving‐image‐sticking phenomenon demonstrated a non‐symmetric luminance profile for the left and right viewing direction for MDVA‐mode LCDs which have original symmetric viewing‐angle characteristics. The generation of a stable reverse‐tilt domain by an outside force was assumed to be the cause of this phenomenon, and the stability of a reverse‐tilt domain under an electric fringe field was calculated by changing the electric‐fringe‐field distribution which determines the LC tilt direction. The domain of a given tilt direction is calculated to change to other tilt direction induced by a fringe field at a low gray condition, but to remain unchanged at a high gray condition. This agrees with the observed trends of duration time of the moving‐image‐sticking phenomenon.     

Field‐induced photo‐reactive alignment technology for the vertical‐alignment liquid‐crystal mode

Abstract— An advanced vertical‐alignment liquid‐crystal (VA‐LC) technology based on field‐induced photo‐reactive alignment (FPA) as an advanced alignment mode for VA is proposed. FPA realizes uniform alignment and a faster rising response time, especially at high voltage. This technology can generate a pre‐tilt angle only by using photo‐reactive alignment material so that the tact time is shorter and the long‐term reliability is higher than that of conventional photo‐reactive processes, which require additional photo‐reactive monomers. The advanced hybrid FPA was developed by adopting both the tilted alignment with a pre‐tilt angle and conventional vertical alignment. By using an advanced hybrid structure, the response time and contrast ratio can be further improved.     

Single‐cell‐gap transflective liquid‐crystal display using double‐ and single‐mode approaches

Abstract— In this paper, many popular methods to study transflective liquid‐crystal‐displays (LCDs) have been discussed, and several new transflective LCD configurations with a single‐cell gap have been proposed. The traditional double‐cell‐gap method gives the best match of the transmittance/reflectance voltage curve (TVC/RVC) and also the widest viewing angle, but also brings the highest fabrication complexity. The single‐cell‐gap transflective LCD is much easier to fabricate and also shows a good match of TVC/RVC. A new methodology has been shown to find optimal configurations for single‐cell‐gap transflective LCDs. New configurations using multimode in a single pixel include twisted nematic (TN) optically compensated bend (OCB), TN electrically controlled birefringence (ECB), and TN low‐twisted nematic (LTN). TN and hybrid‐aligned nematic (HAN) modes have been investigated for single‐mode transflective LCDs. The results exhibit high contrast ratio, a good match of TVC/RVC, as well as wide viewing angle.     

Full‐color photo‐addressable electronic paper using cholesteric liquid crystals and organic photoconductors

Abstract— Full‐color photo‐addressable electronic paper using cholesteric liquid crystals and organic photoconductors was developed. The electronic paper is comprised of two stacked photo‐addressable elements displaying blue/green and red images, respectively. Each photo‐addressable element was independently controlled by two different color‐addressing lights. Furthermore, blue and green images were selectively switched by one organic photoconductor using the threshold characteristics of cholesteric liquid crystals. A highly reflective polymer‐dispersed cholesteric liquid‐crystal (PDCLC) layer was obtained by a new formation process based on the sol‐gel transition behavior of a gelatin matrix and an agar overcoat layer. The PDCLC layer had a close‐packed honeycomb‐like monolayer structure with a flat surface. The A6‐sized prototype had paper‐like features and showed full‐color bistable images instantly written with a viewer‐type writing apparatus.     

Advanced liquid‐crystal materials for TFT monitor and TV applications

Notebook applications have been one of the most important driving forces behind the remarkable growth of liquid‐crystal displays (LCDs). LCDs have recently been well accepted in the monitor market and large growth is forecasted because of the replacement of CRTs. The next challenge for LCDs is the TV market. These new application areas are supported by advanced LC technologies such as film‐compensated twisted nematic (TN), in‐plane switching (IPS), and vertically aligned (VA) modes. Each TFT technology requires a corresponding LC material improvement. We will review the recent liquid‐crystal material development for these advanced LC technologies.     

Auto‐calibration of drive condition for cholesteric liquid crystal displays

Dynamic drive scheme (DDS) is known widely as passive matrix addressing that obtains both high‐speed re‐writing and a high contrast ratio in the field of cholesteric liquid crystal displays (LCDs). However, DDS has a serious problem in that the proper drive condition is very narrow and it is largely influenced by individual differences in LCDs that arise during their production. We have developed a new auto‐calibration system that adjusts both the contrast ratio and color balance automatically using capacitances of effective pixels and temperature compensation models that utilize the physical properties of cholesteric LCDs. We have managed to optimize the driving conditions between 5 and 35 °C with this method, and obtained both stable and high‐quality color images where the reflectance is 36%, contrast ratio is 8, and NTSC ratio is 20%. This auto‐calibration system has been able to greatly improve the production yield of cholesteric LCDs and made it possible to make practical use of cholesteric LCDs.     

Fast‐response study of polymer‐stabilized VA‐LCD

Abstract— Polymer stabilization is introduced in VA‐type LCDs, and fast response time can be achieved along with a high contrast ratio.¹ A small amount of reactive monomer is mixed with liquid crystal and forms a polymer layer above the alignment layer by using a UV process. The pre‐tilt angle of the liquid crystal is stabilized, and a faster response time can be realized when the bias pre‐tilt angle from 90° is increased. The properties of reactive monomers and liquid crystal and the conditions of the UV process were studied. Based on the application of the proper monomer and LC, and an optima UV process, a 65‐in. 240‐Hz full‐HD TFT‐LCD, with a faster response time and high contrast ratio, has been developed.     

A single‐substrate multicolor cholesteric liquid‐crystal display prepared through ink‐jet printing

Abstract— Ink‐jet printing was used to prepare a single‐substrate multicolor cholesteric liquid‐crystal (Ch‐LC) display incorporating three Ch‐LCs exhibiting different reflective wavelengths. A room‐temperature low‐vacuum chemical‐vapor‐deposition process was developed for coating a thin polymer film onto the Ch‐LC so that the top electrode could be coated onto the Ch‐LC layer. Herein, the successful operation of such a 10.4‐in. QVGA Ch‐LC display at 40 V will be described.     

Optical design and roll‐to‐roll fabrication process of microstructure film for wide viewing LCDs

We have developed a new microstructure film for wide viewing liquid crystal displays (LCDs). By attaching it to the surface of a conventional LCD, the viewing angle characteristics of LCD has drastically improved without causing a blur of the frontal image and a decrease in the contrast ratio under bright ambient light conditions. This film can be applied to various LC modes including twisted nematic and multidomain vertical alignment by changing its internal micrometer‐size 3D structure. Further, this film can be mass‐produced efficiently by self alignment roll‐to‐roll process.     

Polyimide‐free LCD by dissolving dendrimers

Vertical alignment (VA) and in‐plane switching modes have been widely used for liquid crystal displays (LCDs). They require a polyimide (PI) alignment layer in the pixel structure. PI‐free LCDs have been proposed to exploit the VA of liquid crystals (LCs) obtained by dissolving dendrimers without PI. In this paper, we report a new PI‐free VA mode with a pixel structure that has in‐plane electrodes. The PI‐free VA is achieved by dissolving an LC dendrimer in a positive LC mixture. We measured the test cell properties and obtained a lower voltage and a higher brightness in the voltage–brightness curve. In addition, we analyzed the alignment surface of LC dendrimer by time‐of‐flight secondary ion mass spectrometry and scanning electron microscopy observations. We found that dendrimer molecules are uniformly adsorbed on the glass surface and that the layer was generally one molecule thick. These properties are responsible for the lower voltage and higher brightness of the PI‐free VA mode. The use of dendrimers allows the PI process to be omitted and reduces the power consumption of the VA mode. It is thus possible to reduce the high manufacturing costs and improve the performance of the VA mode.     

Luminescent dichroic‐dye‐doped cholesteric liquid‐crystal displays

Abstract— LCDs based on a luminescent dichroic‐dye‐doped non‐absorbing cholesteric LC with positive dielectric anisotropy is proposed. In the initial state, the orientation of the dye molecules provides effective light absorption and irradiation. By applying an electric field to the cell, the absorption and thus the luminescence is absent. A two‐color luminescence could be achieved by sandwiching two cells: the upper cell consists of a cholesteric LC with two dyes (sensitizer and emitter) and is used with an applied voltage (active cell); the lower cell consists of a cholesteric LC doped with one dye and works without applying a voltage (passive cell). The performance characteristics of luminescent dye‐doped cholesteric‐LCDs were investigated.     

Birefringent light‐shaping films for mini‐LED backlights

Birefringent light‐shaping films (BLSFs) for mini‐LED backlit liquid crystal displays (LCDs) are proposed and experimentally demonstrated by passive polymer‐dispersed liquid crystal (PDLC) films. Such films show angle‐selective scattering properties, achieved by proper material engineering and good vertical alignment of liquid crystals. They only respond to angles rather than spatial locations. By directly adhering the BLSF onto a LED, the angular intensity distribution of light can be tailored from Lambertian‐like to batwing‐like. Further simulation proves that by engineering the angular distribution, a fewer number of LEDs or equivalently a shorter light‐spreading distance is required to maintain good uniformity. These BLSFs are expected to find widespread applications in emerging mini‐LED backlit LCDs and shed light on designing other light‐shaping films in the future.     

A rugged display: Recent results of flexible cholesteric liquid‐crystal displays

Abstract— A 3‐m‐long rugged flexible display having a novel single‐plastic‐substrate structure has been demonstrated with a coated cholesteric liquid‐crystal mixture. The display is designed to be fabricated by a roll‐to‐roll process to increase productivity at a competitive cost. It has the advantage of having almost no limitation in display length. The high‐resolution (300‐dpi) monochrome cholesteric liquid‐crystal display (ChLCD) can be achieved by using a photo‐addressing method. A single‐layered 10.4‐in. color ChLCD also has been developed with good color and contrast.     

High‐speed nonchiral‐smectic‐C liquid‐crystal modes for display applications

Abstract— Three nonchiral‐smectic‐C (NSC) liquid‐crystal (LC) modes having fast‐response and wide‐viewing characteristics applicable for next‐generation LCDs are described. In the NSC LC modes, fast analog optical modulation is achieved by means of a coupling with an external electric field in a dielectrically driving scheme. The fast response results intrinsically from no interlayer interferences during molecular rotation in the layered structure of the NSC LC. Moreover, the self‐formation of two domains and the in‐plane variations of the optic axis produce the wide‐viewing properties. A step‐wise temperature annealing process is employed for a stable and well‐aligned smectic layer structure in a time‐efficient manner.     

Photoalignment and photo‐patterning of planar and homeotropic liquid‐crystal‐display configurations

Abstract— Optical alignment and micro‐patterning of the alignment of liquid‐crystal displays (LCDs) by linear photopolymerization (LPP) technology renders high‐quality multi‐domain twisted‐nematic (TN) and supertwisted‐nematic (STN) displays with broad fields of view over wide temperature ranges feasible. The prerequisites are the generation of photo‐induced high‐resolution azimuthal alignment patterns with defined bias‐tilt angles 0° ≤ θ ≤ 90°. For the first time, LPP‐aligned single‐ and dual‐domain vertically aligned nematic LCDs (VAN‐LCDs) are presented. Dual‐domain VAN‐LCDs are shown to exhibit broad fields of view which are further broadened by combining the displays with LPP‐aligned optical compensators made of liquid‐crystal polymers.     

Energy‐efficient liquid‐crystal displays (e2‐LCDs) using a photonic‐crystal backlight system

Abstract— Cholesteric liquid crystals automatically form one‐dimensional photonic crystals. For a photonic crystal in which light‐emitting moieties are embedded, unique properties such as microcavity effects and simultaneous light emission and light reflection can be expected. Three primary‐color photonic‐crystal films were prepared based on cholesteric liquid crystal in which fluorescent dye is incorporated. Microcavity effects, i.e., emission enhancement and spectrum narrowing, were observed. Two types of demonstration liquid‐crystal displays (LCDs) were fabricated using the prepared photonic‐crystal films in a backlight system. One is an area‐color LCD in which a single photonic‐crystal layer is used for each color pixel and the other is a full‐color TFT‐LCD in which three stacked photonic‐crystal layers are used as light‐conversion layers. The area‐color LCD was excited by using 365‐nm UV light, and the full‐color TFT‐LCD was excited by using 470‐nm blue LED light. Because of the photonic crystal's unique features that allow it to work as light‐emitting and light‐reflecting layers simultaneously, both LCDs demonstrate clear readable images even under strong ambient light, such as direct‐sunlight conditions, under which conventional displays including LCDs and OLED displays cannot demonstrate clear images. In particular, an area‐color LCD, which eliminated color filters, gives clear images under bright ambient light conditions even without backlight illumination. This fact suggests that a backlight system using novel photonic‐crystal layers will be suitable for energy‐efficient LCDs (e²‐LCDs), especially for displays designed for outdoor usage.     

Analysis of the dependence of optical response time of liquid‐crystal displays on the viewing direction

Abstract— The optical response time of liquid‐crystal displays (LCDs) has recently been observed to be dependent on the viewing direction. For the vertically aligned LC mode, response time increased as the viewing angle increased when the final state is the zero gray level of the minimum luminance. This change in response time is analyzed to relate to the deformation of the normalized luminance curve of LCDs for different viewing directions. The dependency trends of the optical response time for the oblique direction can be estimated from the temporal luminance measurement data along the normal direction and the normalized luminance curve for oblique viewing directions.     

Electro‐optical characteristics of ion‐beam‐aligned FFS‐LCDs on diamond‐like‐carbon thin film

Abstract— A fringe‐field‐switching (FFS) mode cell having LC alignment has been developed by using a non‐rubbing method, a ion‐beam‐alignment method on a‐C:H thin film, to analyze the electro‐optical characteristics of this cell. The suitable inorganic thin film for FFS‐LCDs and the alignment capabilities of nematic liquid crystal (NLC) have been studied. An excellent voltage‐transmittance (V‐T) and response‐time curve for the ion‐beam‐aligned FFS‐LCDs were observed using oblique ion‐beam exposure on DLC thin films.     

Aggregate‐induced emission in light‐emitting liquid crystal display technology

Nowadays, liquid crystal displays (LCDs) with light‐emission are considered as energy‐efficient devices and are promising alternatives to conventional LCDs. To realize such possibility, strong fluorescent materials with a dichroic properties are required. Aggregate‐induced emission (AIE) is an unusual photophysical phenomenon shown by some luminogenic materials that will be highly emissive in their aggregate state. In this work, we studied the AIE effect of a luminescent liquid crystalline molecule TPE‐PPE in our LC system as a luminophore dopant. The result showed the excellent AIE effect that higher concentration of luminogen in the nematic LC host induced stronger luminescent intensity. Through exposure of a photoisomeriable alignment material sulfonic‐dye‐1, the photopatterning of a light‐emitting LC device was achieved with the use of the TPE‐PPE/nematic LC mixture.