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1.
    
Thermally‐initiated living radical graft polymerization of poly(ethylene glycol) methyl ether methacrylate (PEGMA) with ozone‐pretreated poly[N,N′‐(1,4‐phenylene)‐3,3′,4,4′‐benzophenonetetra‐carboxylic amic acid] (PAmA) via a reversible addition–fragmentation chain‐transfer (RAFT)‐mediated process was carried out. The chemical compositions and structures of the copolymers were characterized by nuclear magnetic resonance (NMR) spectroscopy, thermogravimetric analysis (TGA), X‐ray photoelectron spectroscopy (XPS), and molecular weight measurements. The “living” character of the grafted PEGMA side chains was ascertained in the subsequent extension of the PEGMA side chains. Nanoporous low‐dielectric‐constant (low‐κ) polyimide (PI) films were prepared by thermal imidization of the PAmA graft copolymers under reduced argon pressure, followed by thermal decomposition of the side chains in air. The nanoporous PI films obtained from the RAFT‐mediated graft copolymers had well‐preserved PI backbones, porosity in the range of 5–17 %, and pore size in the range of 30–50 nm. The pores were smaller and the pore‐size distribution more uniform than those of the corresponding nanoporous PI films obtained via graft copolymers from conventional free‐radical processes. Dielectric constants approaching 2 were obtained for the nanoporous PI films prepared from the RAFT‐mediated graft copolymers.  相似文献   

2.
    
Hierarchical carbon materials with functional groups residing at the surface are prepared for the first time by using nanostructured silica materials as templates in combination with hydrothermal carbonization at mild temperatures (180 °C). Different carbon morphologies (e.g., macroporous casts, hollow spheres, carbon nanoparticles, and mesoporous microspheres) can be obtained by simply altering the polarity of the silica surface. The surface functionality and hydrophilicity of the resulting materials are assessed by Fourier transform IR spectroscopy, X‐ray photoelectron analysis, and water porosimetry. Raman spectroscopy and X‐ray diffraction measurements show that the materials are of the carbon‐black type, similar to charcoal.  相似文献   

3.
    
A novel concept is proposed to synthesize a new class of composites featuring magnetic, molecular sieve and metallic nanoparticle properties. These multi‐functional materials have potential applications as recyclable catalysts, disinfectants and sorbents. The magnetic property enables effective separation of the spent composites from complex multiphase systems for regeneration and recycle, safe disposal of the waste and/or recovery of loaded valuable species. The zeolite molecular sieve provides a matrix which supports a remarkably new, simple, efficient and economical method to make stable, supported silver nanoparticles by silver ion exchange and controlled thermal reduction. The silver nanoparticles generated in this way have excellent properties such as high reactivity and good thermal stability without aggregation, which act as nano reactors for desired functionality in a wide range of applications. Magnetic component (Fe3O4), molecular sieve matrix (zeolite) and silver nanoparticles generated by ion exchange followed by controlled reduction, together form this unique novel composite with designed functions. It represents a practically operational, economical, sustainable and environmentally friendly new advanced functional material. This paper focuses on the novel synthesis and characterization of the composite, with an example of applications as sorbents for the removal of vapor‐phase mercury from the flue gas of coal‐fired power plants.  相似文献   

4.
地物介电常数测量和分析   总被引:5,自引:1,他引:5  
详细分析了基于矢量风络分析仪的同轴线探头介电常数测量系统和地物介电常数的测量方法。给出了几种典型地物(沙子、岩石、树木、棉叶)介电常数的测量和分析结果,并在模型进行了比较。本文实测数据可用于地物散射和辐射特性研究。  相似文献   

5.
    
The achievement of structural control over thioether‐bridged mesoporous organosilicas is reported. The mesoporous materials have been synthesized by co‐condensation of bis[3‐(triethoxysilyl)propyl]tetrasulfide (TESPTS) and tetramethoxysilane (TMOS) in acetic acid/sodium acetate buffer solution (HAc–NaAc, pH 4.4), using the nonionic surfactant P123 as a template. The mesostructure of the material is mainly controlled by the molar ratio of TESPTS/TMOS in the initial gel mixture. A mesophase transformation, progressing from a highly ordered 2D hexagonal structure via a vesiclelike structure to a mesostructured cellular foam, can be clearly observed when the molar ratio of TESPTS/TMOS is increased in increments. Solid‐state NMR results show that TESPTS is not completely hydrolyzed and condensed at the applied buffer conditions. At low concentrations, the unhydrolyzed TESPTS can penetrate into the core of the surfactant micelles and change the packing parameter of the P123 surfactant. Above a certain concentration, the TESPTS can form a microemulsion with P123 surfactant molecules. Therefore, the vesiclelike structure or cellular foam structure can be synthesized by simply controlling the molar ratio of TESPTS/TMOS. This approach provides a novel method for the facile synthesis of organic–inorganic hybrid materials with a controllable mesostructure under mild synthetic conditions.  相似文献   

6.
    
A seed‐induced in‐situ hydrothermal conversion technique is proposed to prepare novel hollow microspheres with zeolite/mullite composite shells from fly ash cenosphere (FAC), a solid waste with a hollow structure from coal power stations. Two groups of hollow microspheres were prepared, one with zeolite FAU/mullite composite shells and the other with zeolite LTA/mullite composite shells. The FAC in this study plays dual roles as both the template cores and the aluminosilicate nutrition contributor. The final products inherit the hollow spherical morphology of FAC and possessed bilayered shells, the outer dense shell of zeolite crystals and the inner porous shell of mullite. Such hollow zeolitic materials are expected to have many advantages in applications such as catalysis, adsorption, separation, and as releasing capsules.  相似文献   

7.
    
Direct synthesis (co‐condensation reaction) and post‐synthesis reaction (grafting) are combined for the first time to efficiently fabricate bifunctionalized ordered mesoporous materials (OMMs). Ethylenediamine‐containing OMMs (ED‐MCM‐41) were first synthesized via direct synthesis and then further modified by the phenyl (PH) group in a supercritical fluid (SCF) medium via grafting reaction, resulting in OMMs with ED and PH groups (PH‐ED‐MCM‐41). X‐ray diffraction (XRD) patterns, N2 sorption properties, transmission electron microscopy (TEM), 29Si and 13C magic angle spinning (MAS) NMR, chemical analysis, and hydrothermal treatment were used to characterize the bifunctionalized materials. Experiments show that bifunctionalized OMMs can be efficiently prepared by modifying the directly synthesized monofunctionalized OMMs via grafting reaction in a supercritical fluid medium. Both functional groups are distributed uniformly at the surfaces. The advantage of bifunctionalized OMMs over monofunctionalized OMMs was illustrated by introducing thiol groups into ED‐MCM‐41 materials and the subsequent formation of CdS nanocrystals inside thiol‐ and ED‐functionalized MCM‐41 (HS‐ED‐MC‐41). Because of the variety of the functional groups that can be introduced into OMMs by direct synthesis or post‐synthesis reaction, it is expected that the present strategy could provide a generally applicable approach to the design of OMMs with two functional groups.  相似文献   

8.
    
The catalytic activity of hybrid organic–inorganic silica glasses doped with the ruthenium species tetra‐n‐propylammonium perruthenate (TPAP) in the aerial oxidation of alcohols to carbonyl compounds, either in toluene or in dense‐phase CO2, substantially increases with time several months after the xerogels' preparation, yielding the most active ruthenium‐based aerobic‐oxidation catalysts reported thus far. The doped sol–gels are living materials, and an explanation of the observed reactivity enhancement is given, which is thought to have general validity for future applications to a wide variety of relevant heterogeneous processes.  相似文献   

9.
By using Si(HIPEs) as hard, exotemplating matrices, interconnected macro‐/microporous carbon monolith‐type materials with a surface area of around 600 m2 g?1 are synthesized and shaped. The carbonaceous foams exhibit a conductivity of 20 S cm?1, addressed with excellent mechanical properties (Young's modulus of 0.2 GPa and toughness of 13 J g?1, when the carbon core is optimized). The above‐mentioned specificities, combined with the fact that the external shape and size can be easily designed on demand, are of primary importance for applications. The functionality of these carbonaceous monoliths is tested as both an electrochemical capacitor and a lithium ion negative electrode. The electrochemical capacitors' voltage–current profiles exhibit a non‐ideal rectangular response, confirming the double‐layer behavior of the carbon studied, while the charge‐discharge current profile of the electric double‐layer capacitor is directly proportional to the scan where the current response during charge and discharge exhibits high reversibility. When acting as a lithium ion negative electrode, after initial irreversibility, a good cyclability is obtained, associated with a stable capacity of 200 mA h g?1 during the first 50 cycles at a reasonable current density (C/10).  相似文献   

10.
    
We examine the effects of controlling nanoscale architecture on the tensile properties of honeycomb‐structured silica/polymer composite films. The hexagonal films are produced using evaporation‐induced self‐assembly and uniaxially strained using a home‐built tensile testing apparatus. Significant differences in the yield strain, failure strain, and tensile moduli between the axes parallel and perpendicular to the film‐deposition direction are observed for the thinnest films examined and are attributed to anisotropy in the film nanostructure that is further characterized with transmission electron microscopy and atomic force microscopy. For properly oriented composites, these films have tensile moduli comparable to the Young's modulus of bulk silica but exhibit failure strains that are about an order of magnitude larger than those seen in typical bulk‐silica systems. The yielding and failure processes are explored using X‐ray diffraction and optical microscopy and are characterized by irreversible changes in the nanoscale architecture. We show that tuning the nanoscale architecture can provide control over the tensile properties of composites, allowing for materials with combinations of stiffness and elasticity unachievable in the analogous bulk systems.  相似文献   

11.
    
This study demonstrates a novel approach towards the development of advanced protein assay systems based on physically functionalized, magnetic‐core/porous‐shell CoFe2O4/SiO2 composite nanoparticles. The preparation, characterization, and measurement of the relevant properties of the protein assay system is discussed, and the system is used for the detection of cancer antigen 15‐3 (CA 15‐3, used as a model here) in clinical immunoassays. The protein assay system, based on nanometer‐sized magnetic cores and silica shells, shows good adsorption properties for the selective attachment of CA 15‐3 antibodies specific to CA 15‐3. The core/shell nanostructures exhibit good magnetic properties, which enables their integration into a quartz crystal microbalance (QCM) detection cell with the help of a permanent magnet. Under optimal conditions, the resulting immunoassay system presents a good QCM response for the detection of CA 15‐3, and allows the detection of CA 15‐3 at concentrations as low as 1.5 U mL–1 (U: units). Importantly, the proposed protein assay system can be extended to the detection of other antigens and biological compounds.  相似文献   

12.
    
The synthesis of a faujasite–Metglas composite material that can be used in gas‐sensing applications is presented. A continuous faujasite film was synthesized on a Metglas magnetoelastic strip using the secondary growth method. The ability of the new composite to remotely sense carbon dioxide in a nitrogen atmosphere at room temperature over a wide range of concentrations is demonstrated by monitoring the changes in the resonance frequency of the strip. The novel sensor combines the electromagnetic properties of the magnetoelastic material with the adsorption properties of the faujasite crystals. Experiments performed over a period of a few months showed that the composite sensor remained fully operational, thus indicating its long‐term stability. Furthermore, the present work demonstrates that a zeolite–Metglas composite can be used as a sensor of an analyte in a mixture as long as it adsorbs selectively larger amounts of the particular analyte than other compounds present in the mixture.  相似文献   

13.
    
A type of all‐polymer percolative composite is introduced which exhibits a very high dielectric constant (> 7000). The experimental results also show that the dielectric behavior of this new class of percolative composites follows the predictions of the percolation theory and the analysis of conductive percolation phenomena. The very high dielectric constant of the all‐polymer composites, which are also very flexible and possesses an elastic modulus close to that of the insulation polymer matrix, makes it possible to induce a high electromechanical response under a very reduced electric field (a strain of 2.65 % with an elastic energy density of 0.18 J cm–3 can be achieved under a field of 16 MV m–1). Data analysis also suggests that within the composites, the non‐uniform local field distribution as well as interface effects can significantly enhance the strain responses. Furthermore, the experimental data as well as the data analysis indicate that conduction loss in the composites will not affect the strain hysteresis.  相似文献   

14.
    
Two novel porous nitrosamine traps have been synthesized in order to eliminate carcinogens from the environment. A functional mesoporous material, CuO/SBA‐15, has been synthesized by using an in‐situ coating method, with the addition of a guest salt to the reaction system to modify the porous materials before the particles of SBA‐15 were incubated; the synthesis and modification processes were performed in a single step. The resulting mesoporous composites selectively adsorb N‐nitrosopyrrolidine (NPYR), a typical volatile nitrosamine, and are potential cigarette additives that can be used for the removal of nitrosamines from cigarette smoke, thereby protecting public health and the environment. In another reaction, silica gel is modified by being coated with magnesia and then corroded by NaOH solution.The magnesia is dispersed onto the silica by impregnating it with a magnesium acetate solution, followed by calcination. After corrosion of the calcined sample with caustic soda, only the silica particles that are completely covered by magnesia remain. This material exhibits a similar ability to SBA‐15 and zeolite NaY in its selective adsorption of NPYR.  相似文献   

15.
    
Condensing heat exchangers onboard manned spacecraft require hydrophilic fin surfaces to facilitate wetting and wicking of condensate to achieve gravity‐independent water separation in the zero‐ or micro‐gravity environment of space. In order to prevent the proliferation of microbes, the coating must also be biocidal. Here we show for the first time that zeolite A and ZSM‐5 coatings deposited via in‐situ crystallization on stainless steel and aluminum alloys have excellent hydrophilicity, biocidal properties, and adhesion. Water contact angles below 5° were obtained on most substrates tested. When silver‐ion exchange is carried out on the zeolite A coating, it becomes highly antibacterial. This biocidal capability of zeolite A is regenerative by repeated ion exchange. All coatings exhibit the highest rating of 5B as determined by adhesion test ASTM D‐3359‐02 (American Society for Testing and Materials). These properties, in addition to zeolite coating's low‐temperature crystallization process and demonstrated corrosion resistance, make zeolite coatings advantageous over the current sol–gel coatings and well suited for use in condensing heat exchangers onboard manned spacecraft.  相似文献   

16.
    
Nature has evolved mechanisms to create a diversity of specialized materials through nanoscale organization. Inspired by nature, hybrid materials are designed with highly tailorable properties, which are achieved through careful control of their nanoscale interactions. These novel materials, based on a silica‐gelatin hybrid system, have the potential to serve as a platform technology for human tissue regeneration. Covalent interactions between the inorganic and organic constituents of the hybrid are essential to enable the precise control of mechanical and dissolution properties. Furthermore, hybrid scaffold porosity is found to highly influence mechanical properties, to the extent where scaffolds of particular strength could be specified based on their porosity. The hybrids also demonstrate a non‐cytotoxic effect when mesenchymal stem cells are cultured on the material. Cytoskeletal proteins of the cells are imaged using actin and vimentin staining. It is envisaged these hybrid materials will find a diverse application in both hard and soft tissue regenerating scaffolds.  相似文献   

17.
    
Nature has evolved mechanisms to create a diversity of specialized materials through nanoscale organization. Inspired by nature, hybrid materials are designed with highly tailorable properties, which are achieved through careful control of their nanoscale interactions. These novel materials, based on a silica‐gelatin hybrid system, have the potential to serve as a platform technology for human tissue regeneration. Covalent interactions between the inorganic and organic constituents of the hybrid are essential to enable the precise control of mechanical and dissolution properties. Furthermore, hybrid scaffold porosity is found to highly influence mechanical properties, to the extent where scaffolds of particular strength could be specified based on their porosity. The hybrids also demonstrate a non‐cytotoxic effect when mesenchymal stem cells are cultured on the material. Cytoskeletal proteins of the cells are imaged using actin and vimentin staining. It is envisaged these hybrid materials will find a diverse application in both hard and soft tissue regenerating scaffolds.  相似文献   

18.
Several important materials have been used for the electron injection layer (EIL) of the organic light-emitting devices (OLEDs), such as LiF, NaCl, NaF, Al2O3, SiO2, Si3N4, MgO, etc. LiF is the most usually used in OLED among these materials for its performance in OLED. The dielectric constant of LiF, NaCl, NaF is 9.036, 5.895 and 5.072, respectively, at 300 K [J. Fontanella, C. Andeen, D. Schuele, Phys. Rev. B 6 (1972) 582]. The thin film of these insulting layers here supply a very strong electric field to enhance the electrons injection and limit the holes injection to the emitting layer (EL). Then we kept the balance of the injected electrons and the holes, and then we got the excellent performing OLEDs.  相似文献   

19.
Hydrogenated amorphous silicon carbon (a-SiC:H) films were deposited by hot wire chemical vapor deposition. The evolution of microscopic properties like network bonding, disorder, density and chemical composition are studied as a function of H2 dilution. The sp2 and sp3 carbon clusters, hydrogen content and the density of the material has significant effect on the dielectric properties like the leakage current of M/a-SiC:H/〈Si〉 MIS structures made with both Cu and Al metal electrode. A higher leakage current is observed in the case of Cu electrode. These changes are important for its applicability as a low dielectric constant barrier material in microelectronic devices.  相似文献   

20.
    
Polyetherimides are versatile melt‐processable engineering resins. A series of fluoro‐polyetherimides compositions based on diether‐containing diamines were designed on paper and their dielectric constants (ϵ′) estimated before their synthesis. Experimentally determined ϵ′ values were compared with the estimated values. The amorphous polyetherimides containing bis‐trifluoromethyl groups exhibited not only low dielectric constants—lower than those of the commercially available polyetherimide ULTEM 1000 and polyimide Kapton H at 1 kHz—but also excellent long‐term thermo‐oxidative stability and reduced water absorption relative to non‐fluorinated polyimides.  相似文献   

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