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EPDM熔融接枝甲基丙烯酸缩水甘油酯及其与NR动态硫化共混物的性能 总被引:16,自引:6,他引:16
研究了三元乙丙橡胶熔融接枝甲基丙烯酸缩水甘油酯(GMA)的接枝反应温度、过氧化二异丙苯(DCP)及GIM用量对EPDM-g-GMA/NR动态硫化共混物力学性能的影响。结果表明:与直接静硫化胶相比,动态硫化胶的拉伸强度提高了48.2%;接枝反应温度8为160℃、DCP用量为0.3份、GMA用量为3 ̄5份时,动态硫化共混物的力学性能较好。另外红外光谱测试结果表明,在EPDM上已成功接枝了GMA。 相似文献
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以环氧化天然橡胶(ENR)与马来酸酐接枝聚丙烯(PPMAH)双组分相容剂改性废PP/胶粉体系,探讨了相容作用实施的条件及相容剂的最佳用量配比,并考察了胶粉用量和细度对材料力学性能的影响。结果表明,ENR与胶粉只有先通过机械剪切作用和硫化剂DCP交联作用达到物理化学结合,才能使ENR和PPMAH双组分相容剂发挥有效的增韧作用;按照最佳工艺和最佳共混条件,PP用量为100份,胶粉为20份,ENR和PPMAH均为6份时,制得复合材料的冲击强度为141kJ·m-2,拉伸强度为185MPa;冲击断面扫描电镜观察表明,双组分相容剂的加入强化了PP与胶粉的界面相容。 相似文献
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低密度聚乙烯接枝烯基双酚A醚对HDPE/PC共混体系性能的影响 总被引:6,自引:0,他引:6
本文采用烯基双酚A醚接枝低密度聚乙烯(LDPE-g-DBAE)作为高密度聚乙烯/聚碳酸酯(HDPE/PC)共混体系的增容剂,初步研究了LDPE-g-DBAE对HDPE/PC体系性能的影响。通过对共混物形态观察、耐热性能及力学性能测试,发现LDPE-g-DBAE对HDPE/PC体系有良好的增容效果;并发现了增容剂的最佳用量质量比大致为10%,提高增容剂的接枝率更有利于改善共混物的性能。65/35HDPE/PC共混物的HDT为92℃,拉伸强度302MPa,冲击强度298kJ/m2,分别比未加增容剂时的82℃,273MPa和155kJ/m2有较大提高。 相似文献
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聚丙烯熔融接枝马来酸二丁酯增容聚丙烯/尼龙6的研究 总被引:13,自引:1,他引:12
研究了聚丙烯(PP)与马来酸二丁酯(DBM)的接枝共聚物PPgDBM对聚丙烯/尼龙6(PP/PA6)共混物的增容作用。研究表明,PPgDBM是PP/PA6共混体系的有效增容剂,由于共混过程中就地生成PPgPA6,改善了共混物的相容性,增加了两相界面的粘合,使分散相粒径减小,分散更均匀,提高了共混物的力学性能。增容剂接枝率的高低对增容效果有一定影响,接枝物中残留单体不影响增容效果 相似文献
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在氯化聚乙烯(CPE)和NBR中加入促进剂NA22首先对CPE进行动态硫化,然后加入硫黄对NBR进行静态硫化制备了CPE/NBR共混物。考察了促进剂NA22用量、CPE/NBR共混比以及动态硫化温度对共混物性能的影响。结果表明,动态硫化是解决CPE与NBR相容性问题的有效手段;促进剂NA22存在饱和点,用量以2份为宜;CPE用量增大,动态硫化共混物交联密度则略有升高;动态硫化温度提高(160~180℃),交联密度增大。 相似文献
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采用有机过氧化物硫化体系,通过动态硫化方法制备高聚合度聚氯乙烯(HPVC)/SBR共混型热塑性弹性体,测试共混物硫化胶的力学性能。结果表明,当HPVC/SBR并用比为80/20,过氧化二异丙苯(硫化剂DCP)用量为15份时,加入1~3份不同种类的相容剂,可改善共混物的力学性能,其中以氯化聚乙烯(CPE)的作用效果最好;返炼次数对共混物力学性能没有明显影响 相似文献
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M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
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Cheng-Le Zhao Shane Porzio Alan Smith Haiyan Ge H. T. Davis L. E. Scriven 《Journal of Coatings Technology and Research》2006,3(2):109-115
Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively.
There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized.
High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without
the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of
fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to
achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic
SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve
F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender
particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing,
and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing
or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually
preserves suspension stability during freezing.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago,
IL. Tied for first place in The John A. Gordon Best Paper Competition. 相似文献
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Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae
and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted
in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures
(release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species
(Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species
to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were
exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of
separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles
from the southeastern region of the US. 相似文献
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Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed. 相似文献
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中蓝晨光化工研究院有限公司《塑料工业》编辑部 《塑料工业》2009,37(3)
收集了2007年7月~2008年6月世界塑料工业的相关资料,介绍了2007~2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍. 相似文献
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中蓝晨光化工研究院《塑料工业》编辑部 《塑料工业》2007,35(3):1-25,67
收集了2005年7月~2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、通用热固性树脂(酚醛、聚氨酯、不饱和树脂、环氧树脂)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。 相似文献