共查询到20条相似文献,搜索用时 46 毫秒
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用Devnathan-Stachurski双电解池技术,对16Mn钢表面干湿循环时氢渗透现象进行了研究,结果表明不同表面液膜下,都有氢渗透电流的存在.氢离子渗透量与试样腐蚀失重之间存在线性关系.利用此线性关系制作的实时监测氢渗透电流的传感器,用以记录实际海洋大气中氢渗透电流,并根据氢离子渗透量与腐蚀失重之间的线性关系对海洋大气中钢材的腐蚀速率进行预测.结果表明,实际海洋大气中,氢渗透电流与环境湿度存在着对应关系,环境湿度由大变小时,氢渗透电流由小变大.环境湿度交替变化,在试样表面完成干湿循环,促进了氢的渗透,实际海洋大气与摸拟海洋大气失重取得了较好的一致性.可以用氢渗透电流传感器实时监测海洋用钢在大气中的氢渗透情况及腐蚀失重情况. 相似文献
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目前,就SO_2大气环境下杂散电流对碳钢腐蚀影响的报道较少。采用户外暴露、室内周期浸泡加速腐蚀并结合表面滴加腐蚀溶液的方法,研究了施加不同强度直流杂散电流后的Q235钢在SO_2大气环境下的腐蚀行为,计算了腐蚀失重,对不同阶段腐蚀后的试样进行了交流阻抗和锈层X射线衍射分析。结果表明:只有在较高SO_2浓度的户外大气环境和室内加速腐蚀条件下,并且表面通入至少30 m A直流杂散电流时,才能引起Q235钢腐蚀行为的轻微变化,在这种条件下,腐蚀初期试样表面因电解作用形成较多的亚稳相造成腐蚀加速,后期则由于较多亚稳相转变为稳态相提高了锈层致密性,使得腐蚀相对放缓。 相似文献
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为了弄清埋地钢管阴极保护下交流电流干扰腐蚀的性能及机制,建立了交流回路和直流回路的模拟试验装置,研究了阴极保护对于埋地管线交流电流干扰腐蚀行为的影响。利用失重法测量了有、无阴极保护条件下交流电流干扰腐蚀速率,并用扫描电镜(SEM)观察了腐蚀产物的微观形貌及去除腐蚀产物后试样表面腐蚀形貌,测量了腐蚀电流随时间的变化规律。结果表明:施加阴极保护后,腐蚀向均匀腐蚀发展,且阴极保护可能改变腐蚀产物的沉积状况和致密度;阴极保护对于交流电流干扰腐蚀的作用,主要集中在析氢反应和气体逸出上;阴极保护对于交流电流腐蚀严重程度的影响,根据不同的腐蚀体系,其规律也不尽相同。 相似文献
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7A04-T6铝合金被广泛应用于航空领域,目前对其大气腐蚀初期行为的报道较少。对7A04-T6铝合金进行了4~48 h的连续中性盐雾腐蚀,采用失重法和动电位极化曲线法对其初期腐蚀规律和行为进行了研究,利用扫描电镜(SEM)对腐蚀初期的表面形貌进行了观察,并对不同腐蚀时间的试样进行了拉伸。结果表明:7A04-T6铝合金盐雾腐蚀初期,从点蚀开始,随着腐蚀时间的延长逐渐发展为剥蚀;腐蚀动力学遵循指数增长规律;盐雾腐蚀后抗拉强度降低,腐蚀时间越长,抗拉强度下降越明显。 相似文献
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A method is proposed for estimating the parameters of a mixture of exponential and Weibull distributions for which the accuracy of preliminary estimates obtained by graphical analysis is refined in accordance with the criterion of maximum likelihood. The efficiency of the proposed method is supported by the results of statistical modeling. 相似文献
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An approximate analytical expression is derived for the velocity of the front of the wave of change of boiling modes on a
rod and on a plate. The impact of the Thomson effect and of the heater orientation in the gravity field is included. Adequate
agreement is demonstrated between the derived relations and experimental data. 相似文献
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Liebert A Wabnitz H Grosenick D Möller M Macdonald R Rinneberg H 《Applied optics》2003,42(28):5785-5792
A novel method for the determination of the optical properties of tissue from time-domain measurements is presented. The data analysis is based on the evaluation of the first moment and the second centralized moment, i.e., the mean time of flight and the variance of the measured distribution of times of flight (DTOF) of photons injected by short (picosecond) laser pulses. Analytical expressions are derived for calculation of absorption and of reduced scattering coefficients from these moments by application of diffusion theory for infinite and semi-infinite homogeneous media. The proposed method was tested on experimental data obtained with phantoms, and results for absorption and reduced scattering coefficients obtained by the proposed method are compared with those obtained by fitting of the same data with analytical solutions of the diffusion equation. Furthermore, the accuracy of the moment analysis was investigated for a range of integration limits of the DTOF. The moment analysis may serve as a comparatively fast method for evaluating optical properties with sufficient accuracy and can be used, e.g., for on-line monitoring of optical properties of biological tissue. 相似文献
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水三相点是开尔文热力学温度的唯一基准点,也是ITS-90国际温标重要的定义固定点。因此,水三相点不确定度分析对整个温标的建立、温度量值传递起着至关重要的作用。近3年来,中国计量科学研究院研制出一系列高质量的水三相点容器,加强了水三相点的研究,为不确定度的分析提供了更为可靠的实验依据。同时,不确定度的分析也是客观评价新研制容器性能的一个重要指标。因此,根据实验结果对新研制容器所复现的水三相点进行了不确定度评定。评定结果表明,其扩展不确定度为0.16mK(k=2.69,P=0.99)。 相似文献
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