连铸结晶器保护渣熔点影响因素的研究

以生产现场实际使用的连铸结晶器保护渣为研究对象,研究碱度、碱金属氧化物含量、Al2O3含量和F含量对保护渣熔点的影响。结果表明,保护渣熔点随Al2O3含量和碱度增大呈先略微降低后逐渐升高势态,随碱金属氧化物和F含量的增加呈先显著降低后趋于平缓趋势。     

影响亚包晶钢铸坯表面纵裂纹的因素研究

采用金相、扫描电镜、连续测温等方法对亚包晶钢铸坯表面纵裂纹产生原因进行了系统研究,研究结果表明:当钢水过热度35℃和15℃浇铸时,铸坯表面纵裂纹发生率明显提高;随着拉速的增加铸坯纵裂纹发生率呈上升趋势;在同一拉速条件下,铸坯内弧比外弧更易于生成凹陷和裂纹;结晶器铜板热流密度不均是铸坯纵裂纹产生的主要原因,并在二冷区进一步扩展。     

基于有限差分法的单晶热型连铸凝固过程的数值模拟

采用有限差分法对金属单晶热型连铸凝固过程的温度场进行数值模拟,对不同工艺组合下的液固界面曲线进行分析和比较,确定了连铸速度、冷却水流量、冷却距离、铸型温度等主要工艺参数对液固界面位置和形状的影响,其中连铸速度对凝固界面形状的影响不大,但对其位置的影响较大;改变冷却水流量和冷却距离均可调节冷却强度,相比之下,冷却距离对液固界面的影响更大;铸型温度对固液界面位置的影响较大,应进行准确控制。实际操作中可采用较小的冷却距离,同时适当提高连铸速度,保持铸型温度略高于金属熔点。     

Al2O3对中钛高炉渣冶金性能影响的实验研究

为实现高铝矿与钒钛磁铁矿的合理搭配,研究了含铝中钛高炉渣中Al2O3含量变化对炉渣黏度及熔化性温度的影响．研究结果表明,在炉渣二元碱度1.15,W（TiO2）=12％,W（MgO）=9％的条件下,实验炉渣在W（Al2O3）=14％时具有良好的流动性和最低的熔化性温度（1348℃）．为高炉实际生产提供一定的理论依据．     

Mathematical model of solidification for round CC billets

A coupled mathematical model was established to simulate the whole solidification process of round billet continuous casting for wheel steel using piecewise linear functions of heat flux density in the mold, the secondary cooling zone and the withdrawing-straightening zone. The calculated results were consistent with the measured data showing that the model accords with the practice. The surface temperature and the solidified shell thickness of round billets are more strongly influenced by casting speed than by casting temperature. The holding zones have effect on surface temperature, which is more obvious for the 450 mm round billet. The relation between casting temperature/speed and solidification end is expressed as a linear function. The solidification end is located after straightening machine.     

Na2O对连铸保护渣熔化性能的影响

实验研究了Na2O对连铸保护渣熔化性能的影响规律，测定了实验渣系的熔化温度、熔化速度和结晶温度．结果表明，在实验渣基本成分条件下，Na2O的质量分数为10％时，保护渣的熔化特性能够满足高速连铸要求．     

CSP结晶器内钢液流动及凝固的数值模拟

应用数值模拟方法,建立CSP漏斗型结晶器内钢液流动及凝固传热耦合模型。针对结晶器内铸坯角部受到强冷的特点,对结晶器内热流密度采用修正方程进行计算,分析热流密度修正系数对铸坯凝固坯壳表面温度计算精度的影响。通过比较不同拉坯速率下结晶器内钢液凝固的特点,研究凝固坯壳对结晶器内钢液流动行为的影响。结果表明,采用热流密度修正系数后,铸坯凝固坯壳角部温度的计算值与实际情况更相符;提高拉坯速率可使铸坯凝固坯壳厚度减小;拉坯速率较大时凝固坯壳厚度随铸坯距弯月面距离的增大基本呈线性增长,拉坯速率为3m/min时,凝固坯壳在生长过程中厚度的增长有短暂的停滞现象;凝固坯壳对钢液流动的影响较大,主要是由钢液有效流动区域减少及两相区额外动量阻损造成的。     

不锈钢高速连铸中结晶器的热流计算

在高效连铸过程中,结晶器的传热效率起着至关重要的作用。在进行加拿大国家自然科学基金资助的高速连铸的战略性研究项目时,在Ａｔｌａｓ Ｓｔｅｅｌ钢铁公司的方坯连铸机上进行了１次工业试验,目的是研究高速连铸不锈钢时结晶器的热流变化。试验中,结晶器４壁共安装了４２个热电偶。不同工艺条件下的温度信号以１０Ｈｚ的频率记录在计算机中,根据每点的平均温度,针对ＩＨＣＰ（Ｉｎｖｅｒｓｅ Ｈｅａｔ Ｃｏｎｄｕｃｔｉｏ     

宽板坯凝固前沿轻压下率模型的研究

结合连铸坯凝固规律及轻压下技术改善铸坯中心偏析的冶金原理,建立宽板坯轻压下率理论模型。根据某厂连铸宽板坯实际生产条件,以传热模型计算的铸坯凝固温度数据作为轻压下率模型计算条件,分析拉速、浇注温度、坯壳凝固收缩特性对铸坯轻压下率的影响规律。结果表明,在相同的拉速和浇注温度条件下,铸坯轻压下率沿拉坯方向的分布总体呈减小趋势;拉速较高时的起始轻压下率小于拉速较低时对应的起始轻压下率;拉速与平均轻压下率呈线性递减关系：拉速每升高0.1m/min,平均轻压下率减小0.015mm/m;浇注温度越低,轻压下区起始轻压下率的值越高;浇注温度对平均轻压下率的影响较小,浇注温度每升高10℃,平均轻压下率仅减小0.002 5mm/m;铸坯外部凝固坯壳的收缩对整个轻压下区平均轻压下率的贡献量为20.4%～22.3%。     

Solidification and crystallization properties of CaO-SiO2-Na2O based mold fluxes

Crystallization properties play an important role in keeping a smooth running of continuous casting process and high sur-face quality of cast strands. To reduce fluorine pollution in slag, a new type of CaO-SiO2-Na2O (CSN) based mold flux was studied. The solidification and crystallization properties, including crystallization temperature, crystallization ratio and solidification minera-graphy, were measured, which were compared with the CaO-SiO2-CaF2 (GF) mold flux. The results show that the crystallization performance is equal to the high fluoride mold powder and CSN can be used for peritectic steel grades sensitive to longitudinal cracking in continuous casting.     

Heat-transfer model on the improvement of continuous casting slab temperature

A heat transfer model on the solidification process has been established on the basis of the technical conditions of the slab caster in No.3 steel works of Wuhan Iron & Steel Corporation, and the temperature field in the solidifying slab was calculated which was verified by the measured slab surface temperature. The influences of the main operating factors including casting speed, spray cooling patterns, superheat of melt and slab size on the solidification process were analyzed and the means of enhancing the slab temperature was brought forward. Raising the casting speed to 1.3 m/min, controlling the flowrate of secondary cooling water and improving the cooling pattern at the lower segments of secondary cooling zone could improve the slab temperature effectively. And the increasing the superheat is adverse to the production of high temperature slab.     

高磷铁水脱磷效率影响因素的研究

试验研究CaO-CaCl2-Fe2O3系脱磷熔剂组成、温度和处理时间对高磷铁水脱磷效率的影响。结果表明,温度为1350℃时高磷铁水脱磷效果最佳;脱磷剂中当Ⅲ（CaO）／m（Fe2O3）-1、时间为15min时高磷铁水脱磷率珊达到峰值;w（CaCl2）为20％左右、脱磷熔剂光学碱度A=0．7时,高磷铁水脱磷效果最好。所有炉次的高磷铁水脱磷反应在前5min基本结束。     

拉坯速度对连铸大方坯凝固的影响

结合现场研究,利用显式有限差分法计算出不同工艺条件下的铸坯凝固情况;进行了拉坯速度对出结晶器坯壳厚度、铸坯表面温度、铸坯凝固终点位置和铸坯质量影响的模拟分析研究.模拟结果表明,拉速对铸坯表面温度和凝固终点的影响较大,随拉速的增大,表面温度升高,出结晶器坯壳厚度减薄,铸坯液相穴拉长.     

Effect of low-frequency rotary electromagnetic-field on solidification structure of continuous casting austenitic stainless steel

To understand the solidification behavior of austenitic stainless steel in rotary electromagnetic-field, the influence of low-frequency rotary electromagnetic-field on solidification structure of austenitic stainless steel in horizontal continuous casting was investigated based on industrial experiments. The results show that the solidification structure of austenitic stainless steel can be remarkably refined, the central porosity and shrinkage cavity can be remarkably decreased, and the equiaxed grains zone are enlarged by means of application of appropriate low-frequency electromagnetic-field parameters. The industrial trials verify that the stirring intensity of austenitic stainless steel should be higher compared with that of plain carbon steel. Electromagnetic stirring affects the macrostructure even if the average magnetic flux density of the electromagnetic stirring reaches 90 mT (amplitude reaches 141 mT) with the frequency of 3–4 Hz. Due to a higher viscosity, rotating speed of molten stainless steel is 20%–30% lower than that of molten carbon steel in the same magnetic flux density. Foundation item: Project(CSTC2007BB4216) supported by the Natural Science Foundation of Chongqing, China     

小方坯连铸二冷配水对凝固与传热的影响

研究小方坯连铸在二次冷却过程中的坯壳凝固情况,建立了传热过程的二维非稳态数学模型,计算出在整个连铸过程中温度变化和温度场分布,并得出在二冷区铸坯凝固速度与换热系数的关系.     

Simulation of thermomechanical behavior during continuous casting process based on MiLE method

A new method called mixed Lagrangian and Eulerian method(MiLE method) was used to simulate the thermomechanical behavior during continuous casting process of steel YF45MnV.The simulation results are basically in agreement with the measured data.The delaying period at the beginning of solidification is about 0.1 in square root of solidification time which is agreement with the data in literatures,and shell thickness increases in linear relation to square root of solidification time.The bloom surface temperature decreases gradually as the casting proceeds.The effective stress in the corner is much larger than that in the mid-face.The corner area is the dangerous zone of cracking.The effects of mold flux break temperature on the air gap and hot tearing indicator were also modeled.The model predicts that the bloom surface temperature increases with the increase of the mold flux break temperature,but the heat flux decreases with the increase of the mold flux break temperature.The hot tearing indicator is much smaller when the mold flux break temperature is higher.     

Effects of Suspension Casting on Solidification Process of GCr15 Steel Ingot

The mechanism of inoculation in the case of suspension casting process has been studied through solidification kinetics. The effect of suspension casting process on temperature field, solidification rate, temperature gap of crystallization, effective distribution coefficient of solute and nucleation frequency during solidification process in steel ingot were discussed on the base of experiments. It has been found that the suspension casting process can increase both cooling at and solidification rate of steel ingot, improve the temperature field and solute distribution, narrow the temperature gap of crystallication, and increase the nucleation frequency. Thus, the solidification time can be shorten, the solute can be well distributied, the shrinkage porosity can be reduced and the grain of crystallization can be fined.     

Al-Si合金(A357)重力铸造充型及凝固过程模拟

利用多通道数据采集系统对铸件特定部位的温度进行测量,以掌握该点的凝固和补缩,并利用O lym pu s金相显微镜观察铸件关键部位的宏观组织,进而分析其凝固方式.用商业化模拟软件Z-C ast对铝合金拉伸试棒充型及凝固过程进行模拟,对实际浇注实验中测试点的温度场进行模拟,并将模拟结果与实验结果进行比较.结果表明,当金属铸型的预热温度较低时,必须采用较高的浇注温度才能够使铸型充满,试棒在凝固过程能够得到有效补缩,从而消除了由于糊状凝固造成的显微缩松.铸造模拟软件Z-CA ST能够准确的模拟铝合金铸件充型凝固过程,提供较准确的流场、温度场信息,预测缺陷及其出现位置.     

4145H钢的电炉连铸工艺生产

4145H钢是石油钻铤用钢,对钢水纯净度、非金属夹杂物含量、钢材的晶粒度、中心碳偏析等指标要求严格。采用电炉连铸工艺开展了4145H钻铤用钢的制备研究。结果表明,化学成分调整合格后,连铸过热度为25—35℃、铸速为0．4～0．6m／min、冷却水量为180m3／h时可以拉出280mm×280mm合格方坯。当加热炉出炉温度1160～1170℃、入轧温度965—975℃、缓冷时间46h、出坑温度100～150℃时,可以获得质量合格的西130的4145H轧制材。     

金属间化合物NiAl的合金化与凝固技术

详细介绍和评述了金属间化合物NiAl的合金化与凝固技术的研究现状，并重点介绍了合金化对NiAl合金的塑性、韧性和强度的影响，以及定向凝固，普通铸造和单晶制备技术对NiAl合金强韧化的影响。其中，定向凝固技术制备的NiAl基与难熔金属相组成的共晶合金具有良好的综合力学性能，既具有较高的高温强度，又具有较好的室温韧性。