加工道次对FSP制备高熵合金增强铝基复合材料组织和性能的影响

采用搅拌摩擦加工制备了以AlCoCrFeNi_2.1高熵合金为增强相的6061铝合金复合材料(AlCoCrFeNi_2.1/6061Al),重点研究了加工道次对复合材料组织均匀性、界面结合以及力学性能的影响。结果表明,随搅拌摩擦加工道次的增加,AlCoCrFeNi_2.1/6061Al复合材料组织均匀性及力学性能均得到明显改善.复合材料中基体与增强相界面结合良好,界面处扩散层厚度随加工道次增加而增大。相较于不添加增强相的6道次搅拌摩擦加工铝合金,AlCoCrFeNi_2.1增强相颗粒的引入可进一步细化晶粒并提高抗拉强度,且随着加工道次增加,复合材料抗拉强度及断后伸长率均显著升高。2,4道次下的断口存在明显的颗粒聚集区,而6道次下断口表面颗粒分布均匀且呈现大量韧窝,为典型的韧性断裂。该现象主要归因于载荷传递效应、弥散强化和细晶强化3大强化机制。     

采用FSP制备新型非晶增强铝基复合材料的组织与性能

利用搅拌摩擦加工技术获得的新型非晶增强铝基复合材料,通过金相、扫描电镜、显微硬度及拉伸试验等对其显微组织结构及力学性能进行了试验和分析.试验结果表明,复合材料主要以层状结构组成,主要由母材和非晶带交替形成.复合材料显微硬度明显高于母材,并且复合材料的抗拉强度显著提高,当旋转速度达到750 r/min,抗拉强度达到最大值...     

搅拌摩擦加工法制备铝基复合材料组织与性能研究

用搅拌摩擦加工法制备碳纳米管增强铝基复合材料,并对其组织及硬度进行了分析。结果表明:搅拌摩擦中心区晶粒尺寸与轴肩变形区相似,晶粒比较细小;搅拌摩擦区边界的晶粒组织发生了明显的塑性变形,晶粒被扭曲拉长。碳纳米管在搅拌摩擦中心区均匀分散,和基体结合良好。碳纳米管对基材有明显的强化作用,搅拌摩擦中心区硬度在55 HV左右,是纯铝的2倍。     

水下搅拌摩擦加工制备CoCrFeNiMn/6061Al复合材料组织和性能研究

采用水下搅拌摩擦加工制备CoCrFeNiMn高熵合金颗粒增强6061-T6基复合材料，研究了时效热处理对CoCrFeNiMn/6061Al复合材料微观组织、显微硬度和磨损性能的影响。采用扫描电镜和电子背散射衍射技术对复合材料的微观组织进行了表征，采用显微硬度和磨损实验对复合材料的性能进行了评价。结果表明，经5道次搅拌摩擦加工后，CoCrFeNiMn高熵合金颗粒均匀分布在Al基体中，且与基体界面结合良好，无明显扩散层。时效热处理后，CoCrFeNiMn高熵合金颗粒与基体界面出现厚度约为200 nm的扩散层，复合材料的平均显微硬度达到120.0 HV,比Al基体提高了27.7%。与Al基体相比，复合材料的平均摩擦因数从0.4491升高至0.4855。时效热处理后，复合材料的平均摩擦因数降低至0.3188,主要磨损机制为磨粒磨损。     

石墨烯对搅拌摩擦加工铝基复合材料性能的影响

采用结合粉末工艺的两步法搅拌摩擦加工制备石墨烯增强铝基复合材料,研究了石墨烯添加量对复合材料力学性能和导电性能的影响。结果表明,石墨烯的添加对铝基复合材料性能有明显的影响,随石墨烯添加量增加,复合材料的硬度逐渐提高、塑性持续下降,而抗拉强度和电导率均呈先增后减的趋势。石墨烯体积分数为3.7%时,复合材料的抗拉强度最高,达到146.5 MPa,与同等加工条件下的纯铝相比,提高了78.7%,而石墨烯体积分数为1.3%时,复合材料的电导率最高,达到30.62 MS/m,较同等加工条件下的纯铝基体提高了53.4%。     

纳米SiCw增强铝基复合材料的搅拌摩擦加工制备

用搅拌摩擦加工法制备纳米SiCw增强ZL114A铝基复合材料,并对其组织及性能进行分析.结果表明,在30 mm×6mm形成了结构致密,无明显疏松、孔洞的搅拌摩擦复合区,复合区晶粒细小,搅拌摩擦中心区SiCw分布较均匀.该复合材料经T6热处理后强化效果不明显,SiCw主要起韧化作用,搅拌摩擦中心区硬度及抗拉强度略有下降,但伸长率得到改善,比基材提高111.4％.     

新型非晶增强铝基复合材料的制备及组织性能

利用搅拌摩擦加工技术制备了一种新型的非晶增强铝基复合材料,用金相、显微硬度计及扫描电镜等分析复合材料的显微组织、硬度以及成分组成.结果表明,复合材料主要由母材和非晶带经搅拌摩擦加工后交替形成的层状结构组成,其显微硬度与母材相比有所提高.复合材料主要由α-Al,Mg2Al3,Mnal6以及La3Al11等物相组成,原始非晶带经搅拌摩擦加工后存在一定的晶化特征,而非晶的晶化可能是摩擦热、机械搅拌力以及轴肩压力等综合因素共同作用的结果.     

搅拌摩擦加工制备纳米RE/Al2O3增强铝基复合材料

铝基复合材料因其优异的物理性能及机械性能已得到广泛应用.文中通过在2219-O铝合金内部添加不同比例的RE/Al₂O₃纳米粉末,利用搅拌摩擦加工技术,制备铝基复合材料.并对搅拌区进行金相、拉伸、硬度、SEM,EDS和XRD等试验.结果表明,搅拌区金属在搅拌头强烈的搅拌摩擦作用下发生显著的塑性变形和连续动态再结晶,形成细小的等轴晶粒,并具有明显的洋葱环组织.复合材料的抗拉强度为母材的163%、屈服强度为母材的195%,同时硬度也明显增加.但是不同稀土比例对金属基复合材料的组织形貌和力学性能影响不大.大块复合材料制备过程粉末添加及隧道型缺陷的控制是关键.     

AlxCrFeNiMn高熵合金的组织和性能

采用水冷铜坩埚悬浮熔炼与铜模吸铸相结合的方法制备了直径为3mm的Al_xCrFeNiMn(x=0、0.25、0.5、0.75)系高熵合金,通过X射线衍射、光学显微镜、扫描电镜、室温压缩试验、硬度测试等探索了不同铝含量、热处理温度和时间对AlxCrFeNiMn系高熵合金微观组织及力学性能的影响。结果表明,铸态Al_xCrFeNiMn(x=0、0.25、0.5、0.75)系合金的塑性变形基本相近,保持在34%左右,且铸态Al_(0.75)CrFeNiMn高熵合金的显微硬度、规定塑性延伸强度与抗压强度分别为524.15HV0.3、765.86MPa与3236.69MPa;不同温度和时间的热处理结果表明:Al_(0.5)CrFeNiMn具有更为细小且分布均匀的等轴晶,获得硬度最大值729.37HV0.3,并保持较大的塑性变形(30.33%),具有优良的力学性能。     

热压温度对AlFeCrCoCu/ZL109复合材料的组织与性能的影响

通过粉末冶金法制备了 AlFeCrCoCu/ZL109复合材料,采用X射线衍射仪(XRD)、扫描电镜(SEM)、热膨胀仪以及拉伸实验等研究了复合材料在不同热压温度下的组织与性能.结果表明:随着热压温度的升高,复合材料的抗拉强度和硬度先增大后减小;当热压温度为550℃时,复合材料的抗拉强度与显微硬度达到最大,分别为326...     

Effect of thermomechanical processing on microstructure and mechanical properties of CoCrFeNiMn high entropy alloy

The CoCrFeNiMn high entropy alloy was produced by homogenization, cold rolling and recrystallization. The effects of thermomechanical processing on microstructures and tensile properties at different temperatures were investigated using X-ray diffractometry (XRD), optical microscopy (OM), scanning electron microscopy (SEM) and multi-functional testing machine. The results show that dendritic structures in cast alloy evolve into equiaxed grains after being recrystallized, with single face-centered cubic (FCC) phase detected. The most refined alloys, stemming from the highest rolling ratio (40%), exhibit the highest strength due to the grain boundary strengthening, while the variation of elongation with temperature shows a concave feature. For the coarse-grained alloys, both the ductility and work hardening ability decrease monotonically with increasing temperature. Serrated flow observed at intermediate temperatures is attributed to the effective pinning of dislocations, which manifests the occurrence of dynamic strain hardening and results in the deterioration in ductility. Besides, dimples on the fracture surfaces indicate the typical ductile rupture mode.     

Structure formation during processing short carbon fiber- reinforced aluminum alloy matrix composites

Nickel- and copper-coated, as well as uncoated, short carbon fibers were dispersed in melts of aluminum or aluminum alloys by stirring followed by solidification of composite melts. Microstructural examina-tion of cast composites indicated extensive damage to the surface of the carbon fibers when uncoated carbon fibers were introduced into the melt under the conditions of the present investigation. When nickel- or copper-coated carbon fibers were used to make composites under similar conditions, the fibers generally did not exhibit observable amounts of fiber surface degradation at the interface, except for small islands of an Al₄C₃ phase. When nickel-coated carbon fibers were used to make composites, the coating reacted with the melt, and NiAl₃ intermetallic phase particles were observed in the matrix away from the fibers, indicating a preference for nucleation of NiAl₃ away from the fiber surfaces. Under a transmission electron microscope (TEM), the NiAl₃ phase was not observed on the surface of carbon fi-bers, except in some regions where the NiAl₃ phase engulfed the carbon fibers during growth. When cop-per-coated carbon fibers were used to make composites, the coating reacted with the melt, and particles of CuAl₂ intermetallic compound were generally dispersed in the matrix away from the fibers, except for a few locations where the CuAl₂ phase was found at the interface under TEM observation. These micro-structures are discussed in terms of nucleation of primary α aluminum and NiAl₃ or CuAl₂ phases and the interaction between short carbon fibers and these phases during growth while the composite was so-lidifying. Additionally, the role of the reaction between nickel or copper coatings and the melt on struc-ture formation is discussed; some of the differences between the nickel and copper coatings are attributed to the fact that nickel dissolves with an exothermic reaction. The differences between solidification of short fiber composites and particle or fiber composite are also discussed.     

Effect of rolling processing on microstructure and electrochemical properties of high active aluminum alloy anode

The effect of rolling processing on the microstructure,electrochemical property and anti-corrosion property of Al-Mg-Sn-Bi-Ga-In alloy anode in alkaline solution(80℃,Na2SnO3+5 mol/L NaOH)was analyzed by the chronopotentiometry (E-T curves),hydrogen collection tests and modern microstructure analysis.The results show that when the rolling temperature is 370℃,the electrochemical activity of Al anode decreases gradually with the increase of pass deformation in rolling,while the anti-corrosion property is improved in the beginning and then declined rapidly.When the pass deformation of rolling is 40%,the Al anode has good electrochemical activity as good as the anti-corrosion property and with the increase of rolling temperature,both electrochemical activity and anti-corrosion property of Al anode increase first and then decrease.When the rolling temperature is 420 ℃,the aluminum alloy anode has the most negative electrode potential of about-1.521 V(vs Hg/HgO)and the lowest hydrogen evolution rate of 0.171 6 mL/(min·cm2).The optimum comprehensive performance of Al alloy anode is obtained.     

高温退火对AlCrFeNiTi高熵合金组织和性能的影响

采用非自耗真空电弧熔炼技术制备了 AlCrFeNiTi高熵合金,并对其进行了高温退火处理.通过X射线衍射仪、扫描电镜以及往复式电化学腐蚀摩擦磨损测试仪研究了铸态及高温退火后AlCrFeNiTi高熵合金组织结构和性能.结果表明:合金经过高温退火之后,物相组成并没有发生明显变化.退火后的合金晶间区域减小,"上坡扩散"的存在导致合金成分偏析现象仍然存在.同时,高温退火导致合金的硬度从434.16 HV下降到408.00 HV,摩擦系数从0.7420下降到0.3635,体积磨损量从9.7231 mm3增加到16.9675 mm3.上述性能上的变化与合金内部的成分偏析和组织结构的转变有密切关系.     

增强体形貌对高熵合金增强铸铝合金组织及性能的影响

本文采用机械合金化工艺制备了两种不同形貌特征的高熵合金（Al0.25Cu0.75FeCoNi）颗粒,一种为椭球状颗粒（平均粒径为53μm,无过程控制剂）;另一种为片状颗粒（平均粒径15μm,有过程控制剂）。采用挤压铸造工艺制备了低体积分数（颗粒含量为5 vol.%）的高熵合金颗粒增强铸造铝合金材料,重点分析了不同增强相形貌对复合材料的组织和力学性能的影响规律。结果表明：在复合材料预制块制备过程中,椭球状高熵合金粉体与铝粉容易混合均匀,而片状高熵合金粉体之间易发生团聚。椭球状颗粒与片状颗粒增强的复合材料的抗拉强度分别达到162MPa和174MPa,比铸铝合金实验基体分别提升了12.5%和 20.8%,但伸长率较铸铝合金基体却发生了明显下降。断口分析表明,椭球状颗粒增强复合材料的断裂以基体的撕裂为主;而片状颗粒增强复合材料则以团聚颗粒的破裂为主。     

原位生成制备Al2O3增强铝基复合材料

研究了综合搅拌铸造法和原位反应制备ＡＩ２Ｏ３增强铝基复合材料,向熔体中直接加入制备高纯ＡＩ２Ｏ３的原料ＡＩ２（ＳＯ４）３粉体,由反应分解的ＳＯ３可以对熔体进行精炼、除气。结果表明：ＡＩ２Ｏ３颗凿和基体结合良好,没发现气孔、团聚、集聚、偏析,克服了传统搅拌铸造所带来的铸造缺陷;ＡＩ２Ｏ３弥散增强铝基复合材料具有良好的冲击韧性和耐磨损性能;分解的ＳＯ３对熔体进行精炼、除气;被认为是颗 增强铝基得合材料     

Effect of laser remelting on microstructure and mechanical properties of CrMnFeCoNi high entropy alloy

Equiatomic CrMnFeCoNi high entropy alloy prepared by powder metallurgy was remelted by laser. The relative density and microstructure of fusion zone are evaluated. The nanoindentation tests are conducted to reveal the hardness difference of dendrite arms and interdendritic areas. Tensile tests are conducted to assess the mechanical properties of remelted HEA. After laser remelting, the number and morphology of voids changed significantly. Dendritic structure with face-centered cubic phase form in the fusion zone. Fe, Cr and Co are enriched in dendrite arm, while Mn and Ni are enriched in interdendritic area. Elements segregation led to a nanohardness difference between dendrite arm and interdendritic area. Local deformation occurs in interdendritic area during tensile tests and results in a fracture with directionality.     

氮元素对CrFeMnVTi6高熵合金显微组织和力学性能的影响

为了评估氮元素的间隙固溶强化机制对高熵合金性能的影响,采用机械冶金化和放电等离子体烧结工艺制备N掺杂CrFeMnVTi6高熵合金,并利用XRD、SEM、TEM和FIB检测手段对合金的相组成及显微组织进行表征.实验结果显示,CrMnFeVTi6合金组织由TiNx、BCC、Laves相和B2有序相组成.因此,合金在低温区域...     

退火温度对CrFeCoNiTi1.5高熵合金微结构与性能的影响

为研究中低温热处理对CrFeCoNiTi_1.5高熵合金性能的影响,分别在200、400及600 ℃下对高熵合金进行10 h退火处理。通过X射线衍射仪、扫描电镜(SEM)、能谱仪(EDS)、显微硬度计和电化学工作站对高熵合金的组织结构、表面形貌以及元素的偏析程度进行分析,并测试了高熵合金的动电位极化曲线以及维氏硬度。结果表明:退火温度的提高有利于CrFeCoNiTi_1.5高熵合金中HCP结构相的析出;随着温度的升高Cr、Fe、Co和Ni逐渐向晶内聚集分布,Ti逐渐向晶间聚集。600 ℃中低温退火处理时合金耐腐蚀性能最好,硬度为914 HV0.5。