生物质灰对水泥硬化浆体抗压强度影响的试验研究

对比研究了生物质灰与普通粉煤灰在粒度分布、颗粒形态、化学组成、活性指数等方面的不同,并开展了不同掺量生物质灰对水泥硬化浆体抗压强度的影响研究.结果表明:生物质灰颗粒形状不规则、平均粒径及粒径分布范围较大,具有特有的细长纤维状颗粒,且其活性组分Al2O3不足普通粉煤灰的三分之一;生物质灰的火山灰活性小于普通粉煤灰;相同掺量下,生物质灰-水泥复合胶砂各龄期的抗压强度均小于普通粉煤灰-水泥复合胶砂,生物质灰掺量越大,复合胶砂的强度相比纯水泥组下降程度越大;与普通粉煤灰相比,掺加生物质灰的硬化水泥浆体微观结构更为疏松多孔,特别是其特有的细长纤维状颗粒的存在.     

Characteristics and pozzolanic reactivity of glass powders

This paper deals with the morphology, fineness and pozzolanic activity of four glass powders: one (GP-fine) from the screening of crushed waste glasses, one (GP-dust) from a dust collector for the glass crushing process and two (GP-4000 and GP-6000) from further grinding of the powder from the dust collector in a ball mill. GP-fine and GP-dust consist mainly of large flaky particles, while GP-4000 and GP-6000 consist mainly of small angular particles. The finenesses of these glass powders are measured by particle size distribution and Blaine fineness method. For a similar particle size distribution, ground glass powder has a higher Blaine specific surface area than Portland cement due to the angular morphology of glass particles. Finely ground glass powders exhibited very high pozzolanic activity. The finer the glass powder is, the higher its pozzolanic reactivity is. An increase in curing temperature accelerates the activation of pozzolanic reactivity of both glass powder and coal fly ash in terms of strength development rate. Mortar cube strength results (ASTM C109) indicated that curing temperature has a greater influence on the glass powder than on fly ash. The rapid mortar bar expansion test (ASTM C1260) results indicate that the replacement of Portland cement with ground glass powder also reduces the expansion due to alkali-aggregate reactions, although it is not as effective as coal fly ash.     

Use of ground coarse fly ash as a replacement of condensed silica fume in producing high-strength concrete

This paper presents a method of improving coarse fly ash in order to replace condensed silica fume in making high-strength concrete. The coarse fly ash, having the average median diameter about 90-100 μm, yields a very low pozzolanic reaction and should not be used in concrete. In order to improve its quality, the coarse fly ash was ground until the average particle size was reduced to 3.8 μm. Then, it was used to replace Portland cement type I by weights of 0%, 15%, 25%, 35%, and 50% to produce high-strength concrete. It was found that concrete containing the ground coarse fly ash (FAG) replacement between 15% and 50% can produce high-strength concrete and 25% cement replacement gave the highest compressive strength. In addition, the concrete containing FAG of 15-35% as cement replacement exhibited equal or higher compressive strengths after 60 days than those of condensed silica fume concretes. The results, therefore, suggest that the FAG with high fineness is suitable to use to replace condensed silica fume in producing high-strength concrete.     

Ultrafine grinding of sugar cane bagasse ash for application as pozzolanic admixture in concrete

Sugar cane bagasse ash, a byproduct of sugar and alcohol production, is a potential pozzolanic material. However, its effective application in mortar and concrete requires first the controlled use of grinding and classification processes to allow it to achieve the fineness and homogeneity that are required to meet industry standards. The present paper investigates the role of mill type and grinding circuit configuration in grinding in laboratory- and pilot plant-scale on the particle size, specific surface area and pozzolanic activity of the produced ashes. It was observed that, although different size distributions were produced by the different mills and milling configurations, the pozzolanic activity of the ground ash was directly correlated to its fineness, characterized by its 80% passing size or Blaine specific surface area. From a low pozzolanic activity of less than 50% of the as-received ash, values above 100% could be reached after prolonged grinding times. Electric power requirements to reach the minimum pozzolanic activity were estimated to be in the order of 42 kWh/t in an industrial ball mill. Incorporation of an ultrafinely-ground ash in a high-performance concrete in partial replacement of Portland cement (10, 15 and 20% by mass) resulted in no measurable change in mechanical behavior, but improved rheology and resistance to penetration of chloride ions.     

Influence of fly ash fineness on strength, drying shrinkage and sulfate resistance of blended cement mortar

In this paper, the influence of fineness of fly ash on water demand and some of the properties of hardened mortar are examined. In addition to the original fly ash (OFA), five different fineness values of fly ash were obtained by sieving and by using an air separator. Two sieves, Nos. 200 and 325, were used to obtain two lots of graded fine fly ash. For the classification using air separator, the OFA was separated into fine, medium and coarse portions. The fly ash dosage of 40% by weight of binder was used throughout the experiment. From the tests, it was found that the compressive strength of mortar depended on the fineness of fly ash. The strength of mortar containing fine fly ash was better than that of OFA mortar at all ages with the very fine fly ash giving the highest strength. The use of all fly ashes resulted in significant improvement in drying shrinkage with the coarse fly ash showing the least improvement owing primarily to the high water to binder ratio (W/B) of the mix. Significant improvement of resistance to sulfate expansion was obtained for all fineness values except for the coarse fly ash where greater expansion was observed. The resistance to sulfuric acid attack was also improved with the incorporation of all fly ashes. In this case the coarse fly ash gave the best performance with the lowest rate of the weight loss owing probably to the better bonding of the coarse fly ash particles to the cement matrix and less hydration products. It is suggested that the fine fly ash is more reactive and its use resulted in a denser cement matrix and better mechanical properties of mortar.     

燃煤灰渣活性差异及来源研究

粉煤灰、沸腾炉渣和固硫灰渣是三种具有代表性的燃煤灰渣,因生成方式与生成温度不同,火山灰活性存在较大差异。本文采用改进的28 d抗压强度比方法研究其活性差异,并在矿物组成及颗粒形貌等方面探讨活性差异来源。研究结果显示:沸腾炉渣和固硫灰渣活性相近,明显高于粉煤灰;不同种类燃煤灰渣的活性差异主要来源于其矿物组成及颗粒形貌差异。     

三乙醇胺助磨剂对蔗渣灰颗粒特性及蔗渣灰砂浆性能的影响

为研究不同质量掺量三乙醇胺(TEA)作助磨剂对蔗渣灰颗粒特性的影响,通过方孔筛筛余量、粒径分布、比表面积和颗粒形貌测试对蔗渣灰颗粒特性进行表征,研究蔗渣灰颗粒特性对蔗渣灰砂浆强度及抗氯盐侵蚀性的影响。结果表明,TEA可优化蔗渣灰颗粒粒径分布,在最佳质量掺量0.08%条件下,＜32 μm的颗粒占比增加8.2个百分点,比表面积可提升至5.503 5 m²/g,颗粒形貌更趋于圆球状。同时,蔗渣灰砂浆的强度和抗氯盐侵蚀性能随着TEA掺量的增加呈现先增后降的变化规律,TEA在0.08%(质量分数)最佳掺量时,蔗渣灰砂浆的抗压强度相比于普通水泥砂浆提升19.88%,氯离子扩散系数下降79.63%。通过X射线衍射和压汞孔分析测试揭示了蔗渣灰颗粒特性对蔗渣灰砂浆性能的影响机理,研究表明:经过TEA助磨剂优化后的蔗渣灰火山灰反应活性得到提升,蔗渣灰砂浆基体中生成更多水化产物,提高了密实度;优化后的蔗渣灰颗粒充分发挥了填充效应,降低蔗渣灰砂浆的孔隙率,提高了蔗渣灰砂浆的强度和抗氯盐侵蚀性能。     

Properties of fly ash-modified cement mortar-aggregate interfaces

This paper investigates the effect of fly ash on strength and fracture properties of the interfaces between the cement mortar and aggregates. The mortars were prepared at a water-to-binder ratio of 0.3, with fly ash replacements from 15 to 55%. Notched mortar beams were tested to determine the flexural strength, fracture toughness, and fracture energy of the plain cement and fly-ash modified cement mortars. Another set of notched beams with mortar-aggregate interface above the notch was tested to determine the flexural strength, fracture toughness, and fracture energy of the interface. Mortar-aggregate interface cubes were tested to determine the splitting strength of the interface. It was found that a 15% fly ash replacement increased the interfacial bond strength and fracture toughness. Fly ash replacements at the levels of 45 and 55% reduced the interfacial bond strength and fracture toughness at 28 days, but recovered almost all the reduction at 90 days. Fly ash replacement at all levels studied increased the interfacial fracture energy. Fly ash contributed to the interfacial properties mainly through the pozzolanic effect. For higher percentages of replacement, the development of interfacial bond strength initially fell behind the development of compressive strength. But at later ages, the former surpassed the latter. Strengthening of the interfaces leads to higher long-term strength increases and excellent durability for high-volume fly ash concrete.     

Prediction model of compressive strength development of fly-ash concrete

Based on experimental results concerning the compressive strength development of concrete containing fly ash, the authors derived an estimation equation for compressive strength development. The equation can express coefficient , which indicates the activity of fly ash as a binder, in the form of a function of age, fly-ash content, and Blaine specific surface area of fly ash.

This equation is capable of explaining the increases in the early strength due to fly ash in place of part of fine aggregate, the decreases in the early strength due to fly ash in place of part of cement, the increases in the long-term strength due to pozzolanic reaction, the relationship between the fly-ash replacement ratio and the ratio of strength increase/decrease, and the effect of fly ash's Blaine specific surface area on the strength.     

砂浆中粉煤灰的最佳掺量

分别以砂浆抗压强度、粉煤灰单位强度因子为指标研究了砂浆体系中粉煤灰的最佳掺量范围.并结合实验探讨了充分水化条件下,水胶比、粉煤灰种类等因素对砂浆体系中粉煤灰最佳掺量的影响规律.结果表明:水胶比、粉煤灰种类对砂浆中粉煤灰的最佳掺量存在较大影响.在所调查的实验条件下,粉煤灰的最佳掺量范围为20%～30%(质量分数).砂浆抗压强度最高值和粉煤灰单位强度因子最大值处分别所对应的粉煤灰最佳掺量并不相同.     

Influence of fly ash and its mean particle size on certain engineering properties of cement composite mortars

An experimental investigation on the effects of incorporating large volumes of fly ash on the early engineering properties and long-term strength of masonry mortars is reported. The effect of fly ash and its mean particle size (PD) on the variation of workability and strength has been studied. It was found that fly ash and its mean particle size play a very significant role on the strength of masonry mortars. It has been observed that the early-term strength, except the mortars incorporating coarse fly ash (CFA), was slightly influenced by the replacement with fly ash. The long-term strength (both the bond strength and the compressive strength) will significantly increase, especially for the bond strength of mortars incorporating coarse fly ash. It was also found that the bond strength significantly increased as the mean particle size of fly ash decreases after 28 days curing. However, the 7-day strength was little influenced by fly ash particle size. The fluidity of composite mortar enhanced due to replace cement and lime with fly ash, and the mean PD of fly ash significantly influenced the workability.     

The composition and pozzolanic properties of pulverised fuel ashes

The pozzolanic activities of the fly ashes and other materials examined in previous papers^1,2 have been determined by two chemical methods based on estimating the amount of acid-soluble material that is produced when a pozzolan reacts with lime. The conclusions reached from these results, on the relative importance of the factors that determine the activity of an ash, agree with those previously based on the crushing strengths of fly ash mortars, as already presented. There was a close relation between the amount of chemical reaction taking place in a mortar and the strength it developed, but short-term chemical assessments showed no relation to long-term crushing strengths. It was concluded that chemical methods were unlikely to have any practical value for predicting the long-term strength of a mortar in the field.     

Hydration of Portland cement with high replacement by siliceous fly ash

The effects of two different low calcium fly ashes on the hydration of ordinary Portland cement (OPC) pastes containing 50 wt.% of fly ash were investigated over a hydration time of 550 days. The results were compared with a reference blend of OPC containing 50 wt.% of inert quartz powder allowing the distinction between "filler effect" and pozzolanic reaction.Until 2 days, no evidence of fly ash reaction was measured and its influence on the hydration is mainly related to the “filler effect”. From 7 days on, the effects of the pozzolanic reaction were observed by the consumption of portlandite, the change of the pore solution chemistry, the formation of a presumably water-rich inner hydration product and the change of the C–S–H composition towards higher Al/Si ratio compared to the C–S–H of neat OPC. Additional strength due to the pozzolanic reaction developed after 28 days of hydration.     

公路粉煤灰水泥的研制（一）

文中研究了熟料掺量、复合激发剂、石膏掺量、水泥颗粒粒度对公路粉煤灰水泥的影响.获得了公路粉煤灰水泥的最佳配料方案和工艺参数.与粉煤灰硅酸盐水泥性能相比,公路粉煤灰水泥早期强度略低于粉煤灰硅酸盐水泥,凝结时间较长,但其7d～28d水化龄期内的强度增长率较高,28d强度已赶上或超过粉煤灰硅酸盐水泥,胶砂流动度好.     

颗粒级配对高掺量粉煤灰干混砂浆性能影响的研究

依据颗粒紧密堆积理论,一般采用Andreasen方程计算粉体紧密堆积用于表征粉体颗粒的级配作用.通过研究不同粒径粉煤灰对高粉煤灰掺量干混砂浆的性能影响,研究得出:颗粒太细的粉煤灰,会更加偏离原来的紧密堆积状态,不但不能充分发挥其微观填充的补强作用,反而大大降低强度.因此,使用粉煤灰与水泥复合掺配时,特别是高粉煤灰掺量,需要考虑颗粒与颗粒之间的相互补充作用,使胶凝材料的颗粒粒径分布更趋近于紧密堆积,从而提高基体材料的密实度,保持较高干混砂浆性能.     

聚合硫酸铝改性低碱度水泥性能研究

以水泥、硅灰和粉煤灰为主要胶凝材料制备的低碱度水泥可应用于放射性焚烧灰的固化,但其存在早期强度发展慢、后期强度不高的问题。本文以聚合硫酸铝作为添加剂激发火山灰材料反应活性,通过测定不同掺量聚合硫酸铝加入后固化体的抗压强度、孔隙率及pH值变化,并结合水化产物组成与含量、水化放热特性等表征手段,分析了聚合硫酸铝对低碱度水泥早期水化过程的影响规律和作用机理。结果表明:掺入聚合硫酸铝可以显著提高低碱度水泥固化体的早期抗压强度,使水化放热峰提前,促进了火山灰反应的发生,提高了水化产物的生成量,使微观结构更加密实,同时有效降低试样的早期碱度,有利于抑制焚烧灰中活性铝的腐蚀反应。     

Use of zeolite, coal bottom ash and fly ash as replacement materials in cement production

In this research, the effects of zeolite, coal bottom ash and fly ash as Portland cement replacement materials on the properties of cement are investigated through three different combinations of tests. These materials are substituted for Portland cement in different proportions, and physical properties such as setting time, volume expansion, compressive strength and water consistency of the mortar are determined. Then, these physical properties are compared with those of PC 42.5. The results showed that replacement materials have some effects on the mechanical properties of the cement. The inclusion of zeolite up to the level of 15% resulted in an increase in compressive strength at early ages, but resulted in a decrease in compressive strength when used in combination with fly ash. Also, setting time was decreased when zeolite was substituted. The results obtained were compared with Turkish Standards (TS), and it was found that they are above the minimum requirements.     

Activation of Pozzolanic Reaction of Hydrated Portland Cement Fly Ash Pastes in Sulfate Solution

The activation of the pozzolanic reaction of fly ash in portland cement paste immersed in sulfate solution has been studied. Mixtures of two Spanish fly ashes (ASTM class F) with 0%, 15%, and 35% replacement of portland cement by fly ash were immersed in Na₂SO₄ solution, of 2880 ppm SO₄²⁻ concentration, for a period of 90 days. The resistance of the different mixtures to the sulfate attack was evaluated using the Koch-Steinegger test. The results showed that all of the mixtures were sulfate resistant, despite the high Al₂O₃ content of the fly ash. The diffusion of SO₄²⁻ and Na⁺ ions through the pore solution activated the pozzolanic reactivity of the fly ashes, causing microstructural changes, which were characterized by X-ray diffraction (XRD), mercury intrusion porosimetry (MIP), and scanning electron microscopy (SEM). As a result, the flexural strength of the mixtures increased, principally for the fly ash of a lower particle size and 35% of addition.     

磨细矿物掺合料对水泥硬化浆体孔结构及砂浆强度的影响

采用压汞法研究了钢渣、矿渣、粉煤灰单掺或复掺对水泥硬化浆体孔结构的影响.同时还研究了掺合料单掺或复掺对水泥砂浆抗压强度的影响.结果表明:掺合料单掺或复掺对早期水泥硬化浆体的孔结构有一定的劣化作用;水化后期,矿渣与钢渣均明显降低了水泥硬化浆体的孔隙率,矿渣与粉煤灰均明显降低了水泥硬化浆体的中值孔径并改善了水泥石的孔径分布,掺合料复掺对改善水泥硬化浆体的孔结构有积极作用,尤其是掺合料三元复合可取得最佳的效果.3种掺合料降低水泥硬化浆体孔隙率能力的大小顺序为:矿渣>钢渣>粉煤灰.3种掺合料降低水泥硬化浆体孔径并改善孔径分布能力的大小顺序为:矿渣>粉煤灰>钢渣.掺合料降低了水泥砂浆早期的抗压强度,却增加了水泥砂浆90 d的抗压强度.掺合料的活性大小顺序为:矿渣>钢渣>粉煤灰.     

Use of recycled copper slag for blended cements

Copper slag is a by‐product generated during smelting to extract copper metal from the ore. The copper slag obtained may exhibit pozzolanic activity and may therefore be used in the manufacture of addition‐containing cements. In this paper the effect of the incorporation of the copper slag in cement is measured. Blends of copper slag with Portland cement generally possess properties equivalent to Portland cement containing fly ash, but very different to the silica fume incorporation. Copper slag and fly ash reduce the heat of hydration more effectively than silica fume in mortars. The replacement of 30% cement by copper slag reduces the flexural and compressive strength in a similar way to fly ash; however, after 28 days, the reduction is less than the percentage of substitution. Hydrated calcium aluminate phases were analysed using scanning electron microscopy (SEM) and X‐ray diffraction (XRD) techniques. The pozzolanic activity of copper slag is similar to that of fly ash and higher than silica fume. In the presence of low water/cement ratios, certain pozzolanic materials produce a very compact cement paste that limits the space available for hydration products, a determining factor in the formation of hydrated calcium aluminates. SEM was found to be a useful analytical technique when aluminates are formed and can be clearly detected by XRD. Copyright © 2008 Society of Chemical Industry