Effects of micro-wedges formed between parallel surfaces on mixed lubrication – Part II: modeling

The hydrodynamic effects of micro-wedges formed by asperities on two parallel surfaces in parallel sliding have been proved to be significant on mixed lubrication in the Part I of the present research. In this part of study, a theoretical model for the concept of micro wedges is proposed and used for calculating the hydrodynamic load and friction. The results show that the main influential factor on hydrodynamic effects was the separation of the two rough surfaces. Such a separation governed by the heights of highest asperities determined the minimum gaps of the micro-wedges and so thus the hydrodynamic effects. The calculated results were consistent with experimental evidence, especially, in mixed friction.     

Nanoscale chemistry and mechanical properties of tribofilms on Al–Si alloy (A383): interaction of ZDDP,calcium detergent and molybdenum friction modifier

Abstract

The interaction of a friction modifier and a calcium phenate detergent additive, with zinc dialkyl dithiophosphates (ZDDPs) in the formation of antiwear films on A383, has been studied using synchrotron radiation and nanoindentation techniques. X-ray absorption near edge structure (XANES) spectroscopy has shown that films prepared from oils containing both ZDDP and detergent, and ZDDP and molybdenum dithiocarbamate (MoDTC), are chemically similar to, but thicker than those made from oils containing only ZDDP. In addition, wear was greatly reduced in the presence of the detergent which was correlated with the basicity and the presence of the friction modifier. The phosphorus K and L edge XANES spectra show that the tribofilms are polyphosphate glasses of similar nature to those found on steel, but characterised by a shorter chain length. The sulphur K edge shows a MoS₂ like film and under certain conditions, the presence of a sulphate species is detected. High resolution topographic images and mechanical properties were determined by atomic force microscopy and imaging nanoindentation. The films formed in the presence of the detergent exhibited similar mechanical responses independent of the conditions tested. The indentation modulus of the films on the Al matrix always appear much softer than the films formed on the Si grains whether or not the lubricant contains only ZDDP, or both ZDDP and MoDTC.     

Chemical and mechanical analysis of tribofilms from fully formulated oils Part 1 – Films on 52100 steel

Abstract

The authors report, for the first time, a comprehensive chemical and mechanical characterisation of antiwear films prepared from a fully formulated oil that is commercially available. Wear increases substantially when using the fully formulated oil compared to using ZDDP alone. X-ray absorption near edge structure (XANES) spectroscopy at the P K- and L-edges, S K-edge, Mo L-edge, B K-edge, Ca L-edge, O K-edge and Fe and Zn L-edges permits chemical characterisation of the major elements in the thin films. Ca phosphates, ZnS and MoS₂ are the main P and S species formed, contrary to previous studies involving only ZDDPs, whereby Zn phosphates are the dominant species. These findings can be accounted for by using the hard and soft acid and bases (HSAB) principle. Small amounts of CaCO₃ are present, but no B was detected, implying it does not become incorporated into the film. Atomic force microscopy (AFM) reveals continuous pads with a relatively uniform indentation moduli (125 ± 10 GPa), separated by trenches that are essentially comprised of uncovered steel substrate.     

Morphology,structure and chemistry of extracted diesel soot—Part I: Transmission electron microscopy,Raman spectroscopy,X-ray photoelectron spectroscopy and synchrotron X-ray diffraction study

Inclusion of soot in lubricating oil can result in increased wear and decreased lubricity. In this study we have attempted to gain fundamental insight into the morphology, structure and chemistry of diesel soot. Energy dispersive spectroscopy using TEM suggests interaction between lubrication additives and crankcase soot resulting in the presence of C, Ca, S, P, O and Zn. Synchrotron X-ray diffraction indicates the presence of different sulfates of calcium as well as the presence of amorphous zinc based compounds. Raman spectroscopy and selected area diffraction using TEM indicates that the turbostratic structures of the carbon in both are very similar.     

Chemical and mechanical analysis of tribofilms formed from fully formulated oils Part 2 – Films on Al–Si alloy (A383)

Abstract

The interactions of a commercially available fully formulated oil on an Al–Si alloy have been studied, and a chemical and mechanical characterisation of the resulting surface films has been undertaken to compare with the results found on 52100 steel. ZnS and Ca phosphate are the primary species found. No Mo species were found in the film, but B was detected; the latter observation contrasts with the results found for 52100 steel. A surprisingly consistent indentation modulus was found for the films formed on A383, considering the complex microstructure of the alloy, which has been shown previously to influence the mechanical response of the film produced from zinc dialkyl dithiophosphates (ZDDPs) in oil. The stiffness of the films on A383 is statistically indistinguishable from that found on 52100 steel, and the topography of the film also looks unchanged compared to the steel study.     

Effect of heat treatment on the structure,cavitation erosion and erosion–corrosion behavior of Fe-based amorphous coatings

In this study, high-velocity oxygen-fuel sprayed amorphous coatings have been heat treated at various temperatures to form microstructures with crystalline phases. The structure, micro-hardness, cavitation erosion resistance and erosion–corrosion resistance of these coatings are compared. Crystalline phases are discovered in the coatings after heat treatments at 650 °C and 750 °C. The coating heat treated at 750 °C exhibits the poorest cavitation erosion resistance in 3.5 wt% NaCl solution among all coatings due to the degraded corrosion resistance. However, the hardness of the crystallized coating can reach 1000 Hv and the erosion–corrosion resistance of the heat treated coating is better than the untreated one.     

Analysis of Double-Row Tapered Roller Bearings,Part II – Results: Prediction of Fatigue Life and Heat Dissipation

The model developed to predict the performance of double-row tapered roller bearings (DRTRB) and described in the first part of the paper is now exemplified. For a given example results on the internal load distribution, bearing fatigue life and hear generation are presented and discussed for various operating conditions including the mounting preload. It is revealed that some sliding occurs at the contact between the rollers and the cone that contributes significantly to the total power dissipated within the bearing. It is also shown that an optimum axial compression (or mounting preload) may be found in terms of fatigue life and heat dissipated. As the main conclusion the initial compression between bearing rows was found to play a major role upon the bearing behavior and therefore should be considered carefully for each application.     

Effect of Mo and Ag on the friction and wear behavior of ZrO2 (Y2O3)–Ag–CaF2–Mo composites from 20 °C to 1000 °C

In this paper, a series of ZrO₂ matrix high-temperature self-lubricating composites were prepared by hot-press technique. The effect of Mo and Ag on the friction and wear behavior of the ZrO₂(Y₂O₃)–Ag–CaF₂–Mo composites in a wide temperature range was investigated. The XRD results showed that CaMoO₄ formed on the worn surface above 400 °C. The excellent lubrication performance of CaMoO₄ endowed the low coefficient of friction of the ZrO₂(Y₂O₃)–Ag–CaF₂–Mo composites at high temperatures. The ZrO₂(Y₂O₃)–10Ag–10CaF₂–10Mo composites showed favorable wear resistance at all the tested temperatures which was attributed to the combined action of hardness and phase transformation.     

Antiwear Film Formation by ZnDTP,Detergent, and Dispersant Components of Passenger Car Motor Oils—Part II: Effects of Low-Molecular-Weight Dispersant on Film Formation

Passenger car motor oils (PCMOs) are undergoing a rapid evolution. Studies have found that some exhaust emission catalysts may be deactivated by phosphorus, largely derived from zinc dialkyldithiophosphate (ZnDTP), the mainstay antiwear and antioxidant agent in PCMO formulations for the past 50 years. Consequently, future engine oils will contain significantly reduced phosphorus levels. Since ZnDTP is the dominant antiwear and antioxidant in current PCMOs, lower phosphorus content will impact engine oil formulation strategies.

To better understand the effects of ZnDTP reduction on wear control, electrical contact resistance (ECR) studies have been carried out on blends containing ZnDTP, detergent, and low-molecular-weight (LMW) succinimide dispersant. In contrast to previous results obtained with high-molecular-weight (HMW) dispersant, the combination of ZnDTP and LMW dispersant gave an ECR trace closely resembling that of ZnDTP alone. Thus, the chemical structure of the succinimide dispersant can have a profound effect on ZnDTP antiwear film formation. ECR experiments on three-way combinations of ZnDTP + LMW succinimide dispersant + overbased phenate detergent provided a much better film than that from a similar formulation using an HMW succinimide dispersant. This study demonstrates that the ECR experiment is sensitive to the chemical structures of components controlling the function of modern PCMOs, making ECR a convenient tool to optimize the performance of the remaining ZnDTP in lower phosphorus PCMO formulations.     

Design of a five-axis ultra-precision micro-milling machine—UltraMill. Part 2: integrated dynamic modelling, design optimisation and analysis

Using computer models to predict the dynamic performance of ultra-precision machine tools can help manufacturers to substantially reduce the lead time and cost of developing new machines. However, the use of electronic drives on such machines is becoming widespread, the machine dynamic performance depending not only on the mechanical structure and components but also on the control system and electronic drives. Bench-top ultra-precision machine tools are highly desirable for the micro-manufacturing of high-accuracy micro-mechanical components. However, the development is still at the nascent stage and hence lacks standardised guidelines. Part 2 of this two-part paper proposes an integrated approach, which permits analysis and optimisation of the entire machine dynamic performance at the early design stage. Based on the proposed approach, the modelling and simulation process of a novel five-axis bench-top ultra-precision micro-milling machine tool—UltraMill—is presented. The modelling and simulation cover the dynamics of the machine structure, the moving components, the control system and the machining process and are used to predict the entire machine performance of two typical configurations.     

Ionic Liquids as Lubricants of Titanium–Steel Contact. Part 2: Friction, Wear and Surface Interactions at High Temperature

The tribological behaviour and surface interactions of titanium sliding against AISI 52100 steel have been studied at 200 and 300 °C in the presence of two commercial imidazolium room temperature ionic liquid (ILs): 1-octyl-3-methylimidazolium tetrafluoroborate (L108) and 1-hexyl-3-methylimidazolium hexafluorophosphate (LP106). L108 presents the higher thermal stability but gives higher friction coefficients and wear rates than LP106, with long running-in periods and high friction values, both at 200 and 300 °C. Friction and wear rates for LP106 are lower and decrease as the temperature increases from 25 to 200 °C. At 200 °C, LP106 shows a constant friction coefficient, without running-in, produces a mild wear on titanium and no surface damage on steel. LP106 fails at 300 °C, close to its degradation temperature, due to tribochemical decomposition through partial dissociation of the hexafluorophosphate anion, with formation of a phosphorus-rich layer on the steel ball, while the titanium wear track surface is heterogeneous, showing regions with the presence of fluoride and others with the presence of phosphate. When the steel ball is substituted for a ruby sphere under the same conditions at 300 °C, a low friction coefficient and mild wear is observed, due to the higher stability of the LP106 lubricant at the ruby–titanium interface. The friction coefficients, wear mechanisms and surface interactions have been studied by means of friction-distance records, SEM, EDX and XPS.     

Microstructure,chemical composition,wear, and corrosion resistance of FeB–Fe<Subscript>2</Subscript>B–Fe<Subscript>3</Subscript>B surface layers produced on Vanadis-6 steel using CO<Subscript>2</Subscript> laser

The paper presents the study results of laser modification of FeB–Fe₂B surface layers produced on Vanadis-6 steel using pack cementation method. Microstructure, x-ray phase analysis, chemical composition study using wave dispersive spectrometry method, microhardness, corrosion resistance as well as surface condition, roughness, and wear resistance were investigated. The diffusion boronizing processes were performed at 900 °C for 5 h in the EKabor® powder mixture. The boronized layers had a dual-phase microstructure composed of two types of iron borides, FeB and Fe₂B, and their microhardness ranged from 1800 to 1400 HV. The laser surface modification was carried out on specimens after diffusion boronizing process using CO₂ laser with a nominal power of 2600 W. Laser beam power used in this experiment was equal to 1040 W and was constant. While the three values of scanning speed were used: 19, 48, and 75 mm/s. During laser modification, the multiple tracks were made where distance between of axis tracks was equal to 0.5 mm. As a result of this process, microstructure consisted of remelted zone, heat-affected zone, and substrate was obtained. In remelted zone, the boron-martensite eutectic was observed. Boronized layers after laser modification were characterized by the mild gradient of microhardness from surface to the substrate and their value was dependent on the scanning speed used and was between 1700 and 1100 HV. Corrosion resistance tests revealed reducing the current of corrosion in case of laser modification process. Wear resistance of laser modified specimens was improved in comparison to diffusion boronized layers.