共查询到20条相似文献,搜索用时 15 毫秒
1.
SynthesisandStructuralInvestigationof(LaO)_3BO_3withEu~(3+)asLuminescentProbePengYi'an(彭夷安);LiQihua(李其华)(HunanMedicalCollege,C?.. 相似文献
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Synthesis,Characterization,CrystalStructureandQuantumChemistryCalculationoftheMixedLigandComplexes[Ln(CF_3COO)_3·(Phen)_2·(H_2O... 相似文献
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SynthesisandCrystalStructureofaHeteronuclearComplex[MnSc(DTPA)(H_2O)_2]·2H_2OZhangYi;LiBiaoguo;GaoSong;JinTianzhu;XuGuangxian(?.. 相似文献
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Viscosities were measured for the ternary systems Y(NO3)3+La(NO3)3+H2O, La(NO3)3+Ce(NO3)3+H2O, and La(NO3)3+Nd(NO3)3+ H2O and their binary subsystems Y(NO3)3+H2O, La(NO3)3+H2O, Ce(NO3)3+H2O, and Nd(NO3)3+H2O at 293.15, 298.15 and 308.15 K. The results were used to test the applicability of simple equations for the viscosity of the mixed solutions. The predictions agreed well with measured values, implying that the viscosities of the examined electrolyte solutions could be related to those of their constituent binary solutions using these simple equations. 相似文献
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SynthesisandCharacterizationofWater-SolubleMono(tetrapyridylporphyrinato)Gadolinium(Ⅲ)[Gd(tpyp)OH·DMSO·23H_2O]¥JiangJian-Zhua?.. 相似文献
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Eu3+ doped Gd2WO6 and Gd2(WO4)3 nanophosphors with different concentrations were prepared via a co-precipitation method. The structure and morphology of the nanocrystal samples were characterized by using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM), respectively. The emission spectra and excitation spectra of samples were measured. J-O parameters and quantum efficiencies of Eu3+ 5D0 energy level were calculated, and the concentration quenching of Eu3+ luminescence in different matrixes were studied. The results indicated that effective Eu3+:5D0-7F2 red luminescence could be achieved while excited by 395 nm near-UV light and 465 nm blue light in Gd2WO6 host, which was similar to the familiar Gd2(WO4)3:Eu. Therefore, the Gd2WO6:Eu red phosphors might have a potential application for white LED. 相似文献
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The samples of YVO4·xTa2O5:Eu3+ (x=0.45,0.35,0.25,0.15,0.05)were synthesized by the conventional solid state reaction. The structure of the prepared sample was checked by the X-ray diffraction. XRD measurements at room temperature were confirmed that the prepared YVO4·xTa2O5:Eu3+ consisted of two phases. One phase was YVO4, which is tetragonal according with the JCPDS-Card (17-0341); the other phase was YTaO4, which is according with the JCPDS-Card (72-2018). The spectrum property of the sample was studied under the VUV. The effects of Ta doped on the luminescent properties of sample were investigated and it was found that some Ta doped could highlight the absorption of matrix in VUV region. The emission spectrum was dominated by the red peaks at 613 and 619 nm due to the electric dipole transition 5D0→7F2 of Eu3+. It indicated that Eu3+ occupied a site lacking inversion symmetry. There was one band peaked at 155 nm in the excitation spectrum of the sample, it could be assigned to the absorption of the host. 相似文献
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CrystalStructureandLuminescenceSpectraofTernaryEuropium(Ⅲ)Complex[Eu(DBM)_3(2,2'-BIPY)](HDBM)¥WangMing-Zhao;JinLin-Pei(Depart?.. 相似文献
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Coordination compounds of lanthanide trichloroacetates with 1,10-phenanthroline weresynthesized and characterized as Ln(CCl_3COO)_3·(phen)_2·2H_2O(phen=1,10-phenanthroline,Ln=Tb~Lu)by chemical analysis,IR spectra,thermal analysis and crystal X-ray structural analysis.The crystal ofEr(CCl_3COO)_3·(phen)_2·2H_2O belongs to monoclinic system,with space group P2_1/c,a=1.6969(6)nm,b=1.3776(5)nm,c=1.7563(9)nm,β=114.79(9)°,V=3.727(1)nm~3,Z=4. 相似文献
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Synthesis,CharacterizationandCrystalStructureofCyclotetramerofEuropium(Ⅱ)-areneComplex:[Eu(C_6Me_6)(AlCl_4)_2l_4·Me_4C_6H_2LiangH... 相似文献
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StudiesonCoordinationsReactionbetweenEu(NO_3)_3·3H_2OandCrownEther18C6inAnhydrousAcetonitrileLiuShichang;ZhangQiang(Department?.. 相似文献
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Luminescence Properties and Site Substitution of Eu~(3+)and Bi~(3+) in Me_2Y_8(SiO_4)_6O_2 总被引:1,自引:0,他引:1
LuminescencePropertiesandSiteSubstitutionofEu~(3+)andBi~(3+)inMe_2Y_8(SiO_4)_6O_2LinJun(林君);LiBin(李彬)(InstituteofMaterialsScienc?.. 相似文献
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2 Hydroxydiphenylaceticacid (HD PHA) ,agoodplantgrowthregulator ,canformstableaqueousbinarycomplexeswithrareearths .TointroducePhen ( 1 ,1 0 Phenanthro line) ,theniceligandtorareearths ,intothesystem ,aternarycomplexEu(DPHA) 3·Phen·2H2 Owassynthesizedanditsphotophysic… 相似文献
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[HoAl(CF_3COO)_2(CF_3CHOO)(C_2H_5)_2(C_4H_8O)_2]_2,Mr=1468.7,monoclinic,P 2_1/n,a=1.0084(4),b=1.8453(6),c=1.4501(6)nm,β=102.40(3)°,V=2.6355(1)nm~3,Z=2,D_c=1.81gcm~(-3),F(000)=1511,T=233K,Mo Kα radiation(λ=0.071069nm).R=0.052 for 6176 unique reflections[Ⅰ≥36(Ⅰ)].The structuralunits consist of dimeric molecules with the mixed ligand and central bimetallic atoms,which are polynuclearlanthanoid complexes containing aluminium.Ho-Ho'distance is 0.3619(1)nm.The coordination polyhedron ofHo can be described in terms of a distored bicap-prism. 相似文献
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Reaction of (C_5H_5)_2NdCl·2LiCl with n-Butyllithium: Formation and Crystal Structure of [Li(DME)_3][(C_5H_5)_3Nd(μ-H)Nd(C_5H_5)_3] 相似文献
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采用水热法合成了稀土配位聚合物{[Nd2(C2O4)3(H2O)6].3CH3OH}n(1),得到该配合物的粉红色块状晶体,并对其进行了元素分析。用单晶x射线衍射法测得其晶体结构,属单斜晶系,空间群为P21/c,晶胞参数为:a=1.1200(2)nm,b=0.96325(17)nm,c=1.02580(18)nm,α=90°,β=114.278(3)°,γ=90°,Z=4,V=1.0088(3)nm3。配合物中钕离子为九配位,与配体结合生成蜂窝状二维层,通过氢键的连接形成了三维超分子配合物。 相似文献
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Inthepastfewyears ,themagneticprop ertiesofcomplexescomprisinglanthanideandtransitionmetalionshaveattractedincreasinginterest[1~ 6 ] .Thesecomplexesareimportantinthestudiesofmagneticexchangeinteractionbetweenlanthanideandd transitionmetalions,andtheycanpro… 相似文献
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we developed a new silicate-based full-color phosphor Ba3Lu2(SiO4)3:Eu2+ through solid state reaction.The host crystal structure was isostructural with Ca3Y2(SiO4)3 instead of garnet-type.The phosphor absorbed near-ultraviolet light from 250 to 400 nm,which was very suitable for a color converter of white LED that used UV-LED as the primary light source.The photoluminescence peak wavelength of Ba3Lu2(SiO4)3:Eu2+ was about 461 nm and a shoulder peak was around 522 nm,which resulted from the 5d-4f transition ... 相似文献