蓝光OLED器件载流子复合区域的研究

制备了结构为ITO／NPB／BAlq／Alq/Mg：Ag的有机电致发光器件(OLED),研究了有机层厚度对器件载流子复合区域的影响。实验结果表明当改变各有机层厚度时,OLED器件的电致发光光谱将发生从绿光到蓝光的变化。经分析这是由于各有机层电场强度变化影响了空穴和电子的隧穿几率,从而导致载流子的复合区域发生改变而发射不同颜色的光。     

用高锰酸钾处理ITO表面制备的白光OLED

采用多层结构制备了色纯度很好的白光有机电致发光器件(OLED).将清洗后的ITO玻璃样片在质量分数为0.005%高锰酸钾溶液中进行超声处理15 min.将处理后的ITO玻璃样片与没有经过高锰酸钾溶液处理的ITO玻璃样片,在同一条件下,采用同样的结构制备有机电致发光器件,结果表明,处理前后所制备的器件的性能发生了明显的改变,处理后的白光器件的效率提高了16%,亮度提高了近29%.     

zns:Mn纳米颗粒在电致发光器件中应用的研究

将合成的ZnS:Mn纳米颗粒掺在有机大分子PVK中,共同作为发光层,制备了多层的电致发光器件。通过比较掺杂ZnS:Mn与未掺杂的OLED的电致发光光谱、电流密度-电压曲线、亮度-电压曲线等特性,研究了器件性能提高的机理。     

双发光层白光有机电致发光器件的研究

将DCJTB掺杂入Alq3中,作为黄光发光层,制作了一种基于新型蓝光材料PAA的白光有机电致发光器件(OLED).器件的结构为ITO/NPB/PAA/Alq3:DCJTB/Alq3/Mg:Ag,通过PAA层的蓝光与Alq3:DCJTB层的黄光混合实现了很好的白光发射.结果表明,器件在4.6V时启亮,在5.2V时达到最大...     

双发光层白色FOLED的制备及其性能研究

采用以含ITO导电层的柔性透明PET基片作为衬底,荧光材料TBPe、Rubrene分别掺杂在主体材料CBP和Balq中作为蓝色发光层和橙红色发光层,制备了双发光层白色柔性有机电致发光器件(FOLED)。通过适当调节发光层的掺杂比例和厚度,得到了发光性能理想的白光器件。测量表明,制备的器件色稳定性很好,色度随外加驱动电压在很大范围内变化很小,且其色坐标均非常接近于白色等能点。当电流密度为50mA/cm2时,器件最高外量子效率达到0.9%。通过抗弯折性能的测试证明,可以基本实现柔性显示的目的。     

一种新型蓝色有机电致发光器件及其发光机理

利用5,6,11,12-tetraphenylnaphthacene(Rubrene)超薄层制备了一种蓝光有机电致发光器件(OLED),器件结构为ITO/N,N'-diphenyl-N,N'-bis(1-naphthyl)-(1,18-biphenyl)-4,4'-diamine(NPB)(50nm)/2,9-d...     

多层结构对有机电致发光器件性能的影响

将发光层进行多次堆叠,构造出有机电致发光器件.在堆叠过程中,改变各发光层厚度的相对比例,发现在总厚度相同、结构相同,而各发光层比例不同的条件下,器件呈现不同的发光特性.器件的电致发光光谱有着明显的变化,器件颜色由蓝光到近白光改变极其明显,器件的亮度和器件的效率也有不同程度的改变.     

串联白光OLED色温调整

白光有机电致发光器件(OLED)在实际应用中根据不同的应用场景而有不同的色温要求.该白光OLED具有串联混合结构,包括荧光蓝光发射单元和以Pt磷光材料为客体的黄光发光单元.利用串联器件中存在的弱微腔效应以及所用Pt磷光材料的掺杂特性,通过改变串联结构中空穴传输层的厚度、电荷产生层中n型结构的厚度、调整Pt磷光客体材料在...     

间隔层提高有机电致发光器件的性能

使用不同的有机材料作为间隔层,制备了基于CB P材料的一系列红绿双发光层有机 电致发光器件(OLED),其结构为ITO/MoO₃(50nm)/NPB(40nm)/TCTA(10 nm)/CBP:R-4B(20nm,2%)/ 间隔层(3nm)/CBP:GIr1(30nm,14%)/BCP(10 nm)/Alq₃(20nm)/LiF(1nm)/Al(100nm),其中间隔 层材料使用BCP、TPBi和TCTA。实验比较了加入不同间隔层后OLED的发光特性,结果显 示,对发光面积为0.8cm²的器件,当器件加入间隔层后,电流效 率和亮度有很大提高,用 TCTA作间隔层时得到器件的最大效率为39.98cd/A,最大亮度为29790cd/m²;并且使用间隔 层后OLED发光性能稳定,电致发光(EL)光谱和色坐标不随驱动电压的变化而产生变化。     

用于液晶背光源的双层掺杂白光OLED

制备了一种双层掺杂的白光有机电致发光器件(OLED),其中BAlq:TBPe掺杂层发蓝光,Zn(BTZ)2:Rubrene掺杂层发橙色光.器件在驱动电压5 V时就能发出白光,且在驱动电压5～15 V内色坐标变化较小,均在白光色域区,在15 V时亮度达到8 572 cd/m2,在电流密度50 mA/cm2时量子效率最高达到0.9%.对该白光OLED的发光和电学性能以及发光机理进行了深入的研究和探讨,进而制备了应用于液晶显示(LCD)背光源的近白光OLED,有效面积达到3 cm×3 cm,在10 V时平均亮度达到～1 300 cd/m2,发光亮度均匀性为90%,色度均匀性较好,很好地符合了LCD对背光源的要求.     

Effect of Heat Treatment on Luminescent Properties of White Organic Light Emitting Device

The white organic light emitting device (OLED) with single-structure using a polymer blend as the light emitting layer is fabricated. Heat treatment is used to control the ratio between the intensities of main electroluminescent spectral peaks. The electroluminescent spectrum of our device is quite similar to that of white inorganic LED produced by Nichia Corporation after being annealed, and its turn-on voltage can be decreased by 1V.     

Thermal annealing effect on light emission profile of polyfluorenes containing double bond subunit

We presented comprehensive photoluminescence (PL) and electroluminescence (EL) studies of polyfluorene based electroactive polymer (SF4) containing double bond side chain to investigate its characteristics as a function of temperature. Annealing treatment was conducted for thin films on glass substrates and also for the organic light emitting diodes (OLEDs) at different temperatures. While polymer thin film coated on to glass substrate annealed at < 150 °C exhibited green color emission, OLEDs that annealed at >150 °C shifted white color emission. It was implying that the emission was taking place interchain interaction. Phase modulation at higher annealing temperatures was occurred on the thin film as shown AFM images. Further, annealed polymer film with 120 °C exhibited the best performance in OLED device with luminance 5241 cd m⁻², a maximum efficiency 1.54 cd A⁻¹ and external quantum efficiency 0.54% compared to other polymer films annealed with different temperatures.     

Carrier radiation distribution in organic light-emitting diodes

This paper is based on the analysis of white organic electroluminescent device electroluminescent spectrum to explain the regular pattern of carrier radiation distribution.It has proved electron that is injected from cathode is satisfied with the regularity of radiation distribution on the organic emitting layer.This radiation distribution is related to several factors,such as electron injection capabilities,applied electrical field intensity,carrier mobility,etc.The older instruction design is ITO/2-TNATA/NPB/ADN:DCJTB:TBPe/Alq3/cathode.Get to change electron injector capabilities through using different cathode and also find electroluminescent spectrum to produce significant changes.Simultaneously,electron radiation quantity has some limitation,and electroluminescent spectrum reflects that spectral intensity does not change anymore when the ratio of cathode dopant to a saturated state on the organic emitting layer.It also shows the same spectrum variational phenomenon while changing the applied electrical field intensity.To put forward of the carrier radiation distribution is good for organic light emitting diode (OLED) luminescence properties analysis and research.     

基于MIC多晶硅薄膜阳极的微腔有机发光器件

通过对溶液法金属诱导晶化多晶硅薄膜制备工艺的优化,制备出性能良好的P型掺杂多晶硅薄膜。厚度为50nm的MICP+-Poly-Si薄膜的方块电阻可降低至400Ω左右,其光学特性表现为在红光区域具有比较高的反射率和很小的吸收率,因此用它替代ITO用作红光OLED的阳极材料。由于此薄膜对可见光比较高的反射率和阴极铝对可见光的高反射性,使之形成了一定Q值的微腔效应。结果显示该器件的最大流明效率为5.88cd/A,比用ITO作阳极制备的OLED提高了57%。进一步优化器件结构,调整发光层在腔中的最佳位置,可以大大增强发光强度,从而可以实现发光强度高、单色性好的红色微腔有机电致发光显示器件。     

Design of white tandem organic light-emitting diodes for full-color microdisplay with high current efficiency and high color gamut

Microdisplays based on organic light-emitting diodes (OLEDs) have a small form factor, and this can be a great advantage when applied to augmented reality and virtual reality devices. In addition, a high-resolution microdisplay of 3000 ppi or more can be achieved when applying a white OLED structure and a color filter. However, low luminance is the weakness of an OLED-based microdisplay as compared with other microdisplay technologies. By applying a tandem structure consisting of two separate emission layers, the efficiency of the OLED device is increased, and higher luminance can be achieved. The efficiency and white spectrum of the OLED device are affected by the position of the emitting layer in the tandem structure and calculated via optical simulation. Each white OLED device with optimized efficiency is fabricated according to the position of the emitting layer, and red, green, and blue spectrum and efficiency are confirmed after passing through color filters. The optimized white OLED device with color filters reaches 97.8% of the National Television Standards Committee standard.     

Voltage independent white emission from all solution processed polymer light-emitting diode with dual emitting layers spaced by an alcohol soluble conjugated polymer as interlayer

Spatial control of recombination zone in multilayer white polymer light emitting diode (WPLED) is highly desirable for stable white-light emission. In this work, the utilization of 18-crown-6 (Cn6)-grafted polyfluorene (PFCn6) as an interlayer in between two emitting layers is demonstrated to control the recombination zones for the multilayer WPLED with β-phase and rubrene doped poly(9,9-di-n-octylfluorene) (PFO) as blue- and yellow-emitting layers, respectively. The device gives the maximum brightness of 15,695 cd/m² and maximum efficiency 5.43 cd/A, accompanying with voltage-independent electroluminescence spectrum having invariant Commission Internationale de L’Eclairage (CIE) coordinates of (0.32, 0.36). The performance with the luminance efficiency 5.43 cd/A and voltage independent white emission is the highest record among the reported multilayer WPLED.     

多孔硅发光器件的设计与试验

设计了多孔硅电致发光器件，讨论了工艺条件对器件Ｉ—Ｖ特性影响。试验中已观察到微弱的电致发光。认为利用多孔硅制备可见光发光器件是可行的。     

一种有机发光二极管的电路仿真宏模型

文章介绍了一种有机发光二极管的电路仿真宏模型及其元件参数数值的提取方法。该电路仿真宏模型不但表征了有机发光二极管的全固态多层结构,而且表征有机发光二极管发光的物理过程。同时还提出了采用交流阻抗法提取该有机发光二极管电路仿真宏模型的元件参数的方法。该有机发光二极管的电路仿真宏模型可用于有源二极管显示器的背板电路设计过程中,背板电路与有机发光二极管器件的联合电路功能仿真,从而实现更准确的背板电路性能评估。     

绿色亚单层结合磷光掺杂层的白色有机发光器件

采用10-(2-benzothiazolyl)-2,3,6,7-tetrahydro-1,1,7,7-tetramethy l-1H,5H,11H(1)-benzopyroyran-o(6,7-8-i,j)quinolizin-11-one (C545T)作为亚单层材料,在蓝光层和红光层间引入亚单层C545T,制备了三种亚单层结构的有机发光器件,通过对各器件的电致发光谱、发光强度和发光效率的对比研究,发现可以通过改变C545T层的厚度,获得高效率的白色有机发光器件.     

White Organic LED with a Luminous Efficacy Exceeding 100 lm W−1 without Light Out‐Coupling Enhancement Techniques

Luminous efficacy (LE), which is given by the ratio of luminous flux to power, is commonly used to measure the power consumption of a light source. Unfortunately, the LE of white organic light‐emitting diodes (OLEDs) still lags behind those of inorganic LED for practically used (>100 lm W^?1). In this paper, an ultraefficient white OLED is discussed based on a newly designed thermally activated delayed fluorescent exciplex host. The resulting white OLED delivers an unusually high forward‐viewing LE of 105.0 lm W^?1 and external quantum efficiency (EQE) η_ext of ≈30% (without using any optical out‐coupling techniques). As far as it is known, specifically, these efficiencies are the highest values among the published white OLEDs to date. Two‐color warm white emission is realized with Commission International de I'Eclairage coordinates of (0.40, 0.48) at a brightness of 1000 cd m^?2. Furthermore, the well‐matched energy alignment endows the device with an extremely low turn‐on voltage (≈2.5 V). Such high efficiencies and excellent device performance should benefit from the advantages of exciplex material solely used as the host. Therefore, this study anticipates that the findings have great potential to boost the LE of OLEDs, and more importantly, fulfill the power efficacy requirement for lighting applications.