往复旋转管式陶瓷膜超滤脱脂奶水溶液的研究

往复旋转管式陶瓷膜过滤系统通过膜组件往复旋转在膜表面反复产生高剪切率,达到减缓膜污染的效果。在相同操作条件下,与单向旋转过滤和死端过滤相比较,往复旋转过滤具有更好的减缓膜污染的作用。本实验利用往复旋转膜过滤装置超滤脱脂奶水溶液,考察了各种参数对该膜系统过滤特性的影响。实验结果表明,料液浓度增大,膜通量减小;过高的操作压差将会抑制膜通量增加;旋转速度增大,膜表面剪切强化作用增强,膜通量相应增大;膜稳态通量随往复旋转周期增大呈现先增大后减小的趋势。当料液速度达到膜组件转速时,瞬时反方向旋转膜组件,膜表面产生最大的剪切率,膜稳态通量也达到最大值。能耗分析表明,往复旋转过滤较单向旋转过滤单位通量能耗低。     

旋转流强化膜过滤的研究与应用

通过流场测定 ,探明了旋转流膜过滤器内的流态全貌 ,为认识旋转流强化膜过滤的机理与膜器设计提供了理论依据。建立了旋转流膜微滤通量数学模型 ,探明了渗透通量的三个主要影响因素。应用研究证明 ,此种膜器是一种结构不复杂、通量大、分离质量好、能量利用率高的新颖膜器结构 ,其应用前景十分宽广。     

锯齿形湍流促进膜过滤器处理SiC废水性能研究

为提高平板膜过滤器的过滤性能,设计了一种新型的锯齿形湍流促进膜过滤器。以含有不同浓度的Si C颗粒废水为研究对象,通过错流微滤实验对促进器强化过滤性能进行了研究,分析了促进器作用下膜组件的流动阻力和能量利用率。结果表明,锯齿形促进器可使常规过滤渗透通量提高3.46倍,尤其是在低进料流量、低雷诺数下能有效地强化膜通道内的湍动能,提高能量利用率。锯齿形促进器的强化作用与锯齿的疏密有关,当锯齿的疏密程度增加50%时,单齿强化过滤效率可提高3.7倍。     

往复旋转式中空纤维超滤膜处理大豆乳清

采用往复旋转式中空纤维超滤膜装置处理大豆乳清液,实验结果表明,该装置利用膜的旋转速度与料液的流动速度之间的矢量叠加,形成较高的速度梯度,从而很好地延缓膜通量的衰减。增大旋转速度或缩短往复周期均会在膜表面形成更大的流体速度梯度,进而产生更好的剪切强化效果,延缓膜通量的衰减。当旋转速度较高时,改变往复周期对膜过滤通量的影响更明显。回归分析表明,膜总透过液量与速度梯度之间存在一个幂函数关系。能耗分析的结果表明,单位通量能耗率随膜表面流体速度梯度的增大而增大,二者之间的关系接近于一个多项式。     

往复旋转中空纤维膜处理脱脂奶水溶液

采用一种往复旋转中空纤维膜超滤装置处理脱脂奶水溶液,考察了该膜过滤装置的结构参数、膜组件旋转参数以及料液的特征参数等对膜渗透通量衰减的影响。结果表明,旋转角速度越大,膜丝距中空轴轴心越远,往复旋转中空纤维膜的剪切强化作用越好;往复旋转周期的优化则需考虑如何使料液流场流速与膜丝转速之间的矢量迭加在膜表面产生的速度梯度更大,单纯增大或减小旋转周期均会弱化剪切强化的效果。在同样操作参数下,往复旋转方式比死端过滤及单向旋转方式的膜过滤更利于延缓膜通量衰减。     

膜微滤强化技术国内研究进展

概述了国内膜微滤强化技术研究进展,分析了附加场、设置湍流促进器或脉动进料方法,以及旋转横流强化、旋转动态膜强化、组合强化等方法的特点。     

膜振动过滤通量的实验研究

针对膜过滤过程中,因污染造成膜渗透通量下降等问题,提出了全新的将膜过滤与机械振动结合的膜振动过滤方式;用粘土悬浮液做正交实验,对比了在相同操作条件下,膜振动过滤及无振动膜过滤的膜过滤通量随时间的变化情况,表明膜振动过滤通量比无振动膜过滤通量大,并验证膜振动过滤方式的可行性;通过对影响因素的分析明确了振动频率适中、振动振幅较大时,膜过滤通量越大的原因。     

集成反应器微滤过程中湍流促进器的研究

采用湍流促进器对陶瓷膜分离TiO2超细粒子悬浆液微滤过程进行了强化研究。考察了湍流促进器结构参数对强化过程的影响,确定了合适的湍流促进器为螺旋式湍流促进器,其结构参数为螺杆直径2 mm,螺距20 mm;探讨了湍流促进器的强化机理,同时对湍流促进器的有效性进行了实验考察。研究表明,采用这种方法提高了渗透通量。     

旋转流管式微滤膜的流场探测及分离性能研究

利用水力旋流器原理采用切向进料使膜器环隙产生旋转流,为探明旋转流场的特征,应用PIV(粒子图像测速技术)测试系统进行了实测,结果表明环隙中存在起强化过滤作用的类Taylor涡。在此基础上对旋转流场进行了过滤分离实验,以探讨旋转流场中的进料方式、悬浮液质量分数和操作压力对过滤的影响。研究发现由于存在旋转流和二次涡流的剪切强化作用使得在相同工况下旋转流过滤的稳定通量达到普通轴向流的4—10倍,这表明旋转流过滤是一种有效的膜过滤强化方法之一,由此为进一步探讨旋转流膜过滤强化机理,减少浓差极化和膜污染提供实验依据。     

探究滤膜的振动过滤方法

借鉴大量国内外关于膜过滤分离先进技术研究成果并结合膜过滤生产实际,发现随过滤时间增加,膜污染加重导致过滤通量减小的问题。为此提出了一种新型的将膜过滤与机械振动相结合的膜振动过滤分离方式,即膜振动过滤,使之达到在保证膜过滤通量的基础上,又能有效防止膜阻塞的目的。从理论上分析证明膜振动过滤可行性,并应用自行设计、制造的具有控制振动振幅和频率的膜振动过滤装置进行过滤实验。通过实验测定膜过滤通量随过滤时间变化情况和过滤液体的透光值,证明了在合理操作条件下膜振动过滤的有效性和可行性。     

Experimental Investigation on the Separation of Bentonite using Ceramic Membranes: Effect of Turbulence Promoters

Abstract

The static turbulence promoters presented in this work are designed to enhance filtration within tubular ceramic membranes of 0.5 micron pore size. Permeate flux enhancement still remains a topical problem during tangential crossflow filtration. The decline in flux with time is due to the usual phenomena of concentration polarization and membrane fouling, operating parameters including the system pressures, feed composition, membrane type and configuration, and the hydrodynamics within the membrane module. Solute accumulates on the membrane surface and forms a high concentration gel layer, thus increasing the effective membrane thickness and reduces its hydraulic permeability. Turbulence promoters of varying pitch lengths have been incorporated into the work to ultimately reduce the deposition of bentonite particles on the membrane surface during microfiltration. Yeast suspensions have previously been used as feed suspensions in order to compare the effectiveness of the turbulence promoters with an organic foulant. The objective of this work was to investigate the influence of static promoter geometry on flux sustainability enhancement during bentonite suspension filtration. All experiments have been conducted on a tubular ceramic membrane and the experimental membrane rig as shown in this paper. The effects of feed concentration, feed temperature, system pressures, and crossflow rates on the membrane flux sustainability were investigated. It was found that the promoters greatly improved flux sustainability and membrane efficiency over time and in some cases, a loss of 3% in membrane efficiency was realized with turbulence promoters at higher feed temperatures. The use of the turbulence promoter caused a large scouring of the membrane surface and membrane cleaning was significantly improved compared to the experiments without the promoters.     

电场强化错流膜过滤的研究

电场强化错流膜过滤技术可有效改善膜污染和浓差极化对错流过滤带来的不利影响。就电场膜过滤装置、机理、外加电场及影响渗透通量的因素这4个方面进行综述。目前研制的新型附加电场中空纤维膜组件克服了传统膜过滤组件的缺点,显示出很大的工程应用前景。电场强化错流膜过滤中会发生电泳和电渗等电动力学效应以及电化学效应。电泳是减缓膜污染一个主要因素,电泳和电渗两者共同作用,可以大幅提高过滤通量。采用脉冲电场可以减缓过滤速率的衰减幅度,节省单位体积滤液的电功率比耗。当颗粒具有较高Zeta电位、外加场强及跨膜压力接近临界值、错流速率较高时,过滤通量极限值将会得到提高。     

湍流促进器强化微滤过程的实验与CFD模拟研究(英文)

This paper reports experimental and computational fluid dynamics(CFD) studies on the performance of microfiltration enhanced by a helical screw insert.The experimental results show that the use of turbulence pro-moter can improve the permeate flux of membrane in the crossflow microfiltration of calcium carbonate suspension,and flux improvement efficiency is strongly influenced by operation conditions.The energy consumption analysis indicates that the enhanced membrane system is more energy saving at higher feed concentrations.To explore the intrinsic mechanism of flux enhancement by a helical screw insert,three-dimensional CFD simulation of fluid flow was implemented.It reveals that hydrodynamic characteristics of fluid flow inside the channel are entirely changed by the turbulence promoter.The rotational flow pattern increases the scouring effect on the tube wall,reducing the particle deposition on the membrane surface.The absence of stagnant regions and high wall shear stress are respon-sible for the enhanced filtration performance.No secondary flow is generated in the channel,owing to the streamline shape of helical screw insert,so that the enhanced performance is achieved at relatively low energy consumption.     

Comparison of Different Pitch Lengths on Static Promoters for Flux Enhancement in Tubular Ceramic Membrane

Abstract

The use of turbulence promoters in membrane based processes have been investigated and are increasingly been used in industrial applications to minimize fouling and enhance the membrane flux. The efficiency of crossflow microfiltration is limited by membrane fouling and concentration polarization leading to flux decline during operation. A detailed study was carried out in the microfiltration of yeast suspensions using an in‐house rig and three different static turbulence promoters of varying pitch lengths. The design of the promoters incorporates a helical thread around the length of the insert, which induces turbulent flow through the membrane. This promotes good mixing of the feed fluid and minimizes concentration polarization effects. The testing of tubular membranes with the static inserts has been carried out and the results are included in the report. The pitch lengths used were 7 mm, 10 mm, and 14 mm and the parameters investigated included temperature, CFV, concentration of feed suspension and pressure. The flux decline data was recorded over a 50 minute filtration cycle and the cleaning protocol was employed after every cycle to restore the permeability of the membrane. A comparison of the membrane performance and efficiency of the three swirls inserts of varying pitch lengths together with a comparison of the degree of total, reversible, and irreversible fouling data amongst others are reported and discussed. The results obtained during the investigations of flux enhancement via static turbulence promoters into the tubular membranes are presented and are selected to differentiate the efficiency of the inserts and the degree of fouling associated with them.     

附加湍流器强化陶瓷膜微滤过程的研究

通过在管式陶瓷膜内设置不同结构形式的湍流器，试验和比较了不同主体流速和膜滤压差等工艺条件下的膜滤速率及能耗，分析了湍流器所产生的强化膜滤过程的效果以及试验条件下的一般规律。     

Flux enhancement with glass ball inserted membrane module for the ultrafiltration of dextran solution

The glass-ball-inserted membrane module has been designed to enhance the filtration of a flat-sheet membrane. Three different modes of filtration experiments were conducted and compared to demonstrate the flux enhancement due to the presence of glass balls: normal dead-end filtration, vortex flow filtration, and enhanced vortex flow filtration using glass balls. In the case of enhanced vortex flow filtration, the permeate flux was found to be three times as large as that of dead-end filtration and two times larger than vortex flow filtration. In addition, the flux decline was observed to be relatively low. The effect of the amount of glass balls on the permeate flux was also investigated by changing the glass ball volume fraction from 0.059 to 0.356. It has been observed that the permeate flux shows a maximum value of the volume fraction of 0.119. For the glass-ball-inserted membrane module, the permeate flux tends to increase with the feed flow rate.