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对比在普通浓度(1.5GM/L)H_2SO_4溶液中ADC12试验片阳极氧化试验过程及生成的氧化膜的部份性能,叙述了在较高浓度(13G/L)H_2SO_4溶液中 ADC12电解过程及生成的氧化膜的某些差异及特点。 相似文献
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在测定微量的氯离子时,一般用比色法、重量法、容量法分析。现采用碳酸钠中和硫酸,碳酸氢钠沉淀分离铜后,以铬酸为指示剂,用硝酸银滴定终点的方法进行分析。其手续简便,容易掌握,取得了满意的结果。其反应式如下: H_2,SO_4+Na_2CO_3→Na_2SO_4+H_2CO_3 H_2CO_3→CO_2(?)+H_2O 按实际椎算碳酸钠的重量恰好是硫酸重量的1.08倍。 2CuSO_4+4NaHCO_3 →CaCO_3Cu(OH)_2(?)+2Na_2S0_4+3CO_2(?)+H_2O 按实际推算、碳酸氢钠的重量正好为硫酸铜的1.05倍。但这一分离只须调到偏碱、近中性。加碳酸氢钠是为了形成碱式碳酸铜的粗晶粒沉淀,便于过滤。根据实际测试,沉淀铜离子,碳酸氢钠只需加入所取试样体积内硫酸铜含量的85%,就能完全沉淀碱式碳酸铜。 相似文献
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用多步感应熔覆法在HT300灰铸铁表面制备Ni60A镍基合金熔覆层,研究了熔覆层的显微组织、物相组成及其在H_2SO_4溶液中的腐蚀行为。结果表明:熔覆层与基体形成了良好的冶金结合;熔覆层主要由γ-Ni以及Ni_3Si、Cr_(1.12)Ni_(2.88)、Ni_3B、Cr_(15.58)Fe_(7.42)C_6等物相组成;熔覆层的电化学腐蚀存在钝化过程,自腐蚀电流密度和腐蚀速率远低于灰铸铁的,熔覆层/H_2SO_4溶液腐蚀体系的总阻抗值更高;在H_2SO_4溶液中熔覆层表面生成了具有钝化效果的Ni_2O_3,显著提高了其耐腐蚀性能。 相似文献
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采用高温固相法、溶胶-凝胶法制备了NASICON固体电解质材料,并利用XRD、IR、Raman、SEM等现代分析手段对NASICON材料进行了分析表征,优选出NASICON材料制备的工艺条件.对制备不同检测气体所需的敏感电极材料组份及制备方法进行了比较系统的研究.并以NASICON为离子导电层,以BaCO3-Li_2CO_3、Na_2SO_4-Li_2SO_4等复合盐以及单一或复合金属氧化物为敏感电极材料,制作出了具有良好性能的CO_2、CO、SO_2、NO_2、H_2S、Cl_2、NH_3等分立器件和集成一体化的CO-C_7H_8(甲苯)、NH_3-C_7H_8两种双功能器件. 相似文献
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建立了一种用离子色谱法同时测定Na_3PO_4·12H_2O中的Cl~-和SO_4~(2-)的分析方法。该方法采用分离时间20min,分离度为3.02的Metrosep A Supp 4 250/4.0型色谱柱,柱温为35℃,流速为0.8mL/min。两种离子的标准曲线的相关系数达到了0.9999。Cl~-和SO_4~(2-)的稀释液的测定结果的相对标准偏差分别为1.02%,2.26%;检出限分别为0.010mg/L,0.011mg/L;加标回收率分别96.0%,94.0%。与HG/T 2517-2009中Cl~-和SO_4~(2-)的测定方法相比,该方法的相对误差仅为分别为2.78%和0.00%。因此,该方法具有较高的精密度和准确度,且分析时间短,方法简单,可作为缓蚀阻垢剂Na_3PO_4·12H_2O中的Cl~-和SO_4~(2-)含量分析的常规方法。 相似文献
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温秉谋 《机械工人(冷加工)》1979,(1)
前年,我厂试制了可控硅快速充电装置。用它对DG232,40伏电瓶充电50分钟,便可代替常规充电16小时,并满足电瓶车的使用要求,初步达到高工效、低消耗的目的。一、快速充电的基本原理铅酸蓄电池在充放电过程中的化学反应可用下式来表示:充电时,在外电场的作用下,PbSO_4、H_2O电离成Pb~++、SO_4~--、H~+、OH~-分别向正、负极板运动,并生成PbO_2、Pb、H_2SO_4。由于电离速度远大于化 相似文献
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镀铬在工业生产中已广泛采用着。60年代以前,工艺方法一直沿用所谓“普通电解液”。CrO_3150~350克/升。H_2SO_41.5~3.5克/升。而以CrO_3350克/升较优,人们常采用CrO_3 220~250克/升,H_2SO_42.2~2.5克/升。但这种溶液成份, 相似文献
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Abstract An integrated swatch testing system for precisely quantifying the resistance of chemical protective materials to permeation and penetration by a chemical weapons agent (CWA) simulant is described. The analytical variability of methodologies currently used by Department of Defense testing laboratories was dramatically reduced by modifying the test cell and experimental procedures while maintaining compatibility with military testing specifications. Utilizing an on-line calibration system, cryogen-free preconcentrator, and flame ionization detector, the integrated system has demonstrated excellent repeatability, reproducibility, and high sampling frequency for a variety of non-porous and air-penetrable swatch samples challenged with methyl salicylate. 相似文献
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Mauro M. Dal‐Cin Ashwani Kumar Deepak M. Kirpalani Linda Layton Emmanuelle Daligaux Damien Jubely 《仪器科学与技术》2013,41(3):257-272
Abstract An apparatus is described for the automated characterization of ultrafiltration membranes using solute permeation in cross flow mode. The automated characterization approach described in this work lends itself well for the purpose of increased productivity and reducing operator fatigue/error. The operational, control, and data acquisition aspects of an automated membrane cross flow test unit, which are accomplished using LabVIEW 5.0? are described. The interpretation of the flux and separation data is independent of the apparatus and depends on the filtration regime and various theoretical models available. The apparatus can be used for reverse osmosis, nanofiltration, or ultrafiltration experiments, with appropriate selection of test cells and pumps. 相似文献
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块体纳米晶工业纯铁在室温硫酸溶液中的腐蚀电化学行为 总被引:2,自引:0,他引:2
通过动电位极化曲线、电化学阻抗谱(EIS)试验,研究了块体纳米工业纯铁(BNIPI)和粗晶工业纯铁棒(CGIPIR)在室温0.05mol/L H2SO4 0.25mol/L Na2SO4溶液中的腐蚀行为,用SEM对极化测试后的试样形貌进行了观察。结果表明:BNIPI与CGPIR相比,平均腐蚀速度和腐蚀电流密度Ic较小,极化电阻Rp较大,抗氧化性酸的腐蚀能力有所增强。两种试样表面形貌有明显差别,粗晶试样的晶界明显外露。纳米试样各向同性对其抗腐蚀性能的提高有很大帮助。 相似文献
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Inductively coupled plasma mass spectrometry (ICP-MS) was used to detect trace metal impurities in reagents such as H2O2, HNO3and H2SO4. The limit of detection to metal elements can be down to 2-20 ng/L in H2O2 and HNO3 and 0.1-1.0 ng/L in H2SO4. 相似文献
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M K Dutt 《Microscopica acta》1981,84(3):239-243
This paper describes a method for the preparation of Schiff's reagent as well as a Schiff-type dye-reagent, toluidine blue O-SO2 for use in Feulgen procedure. The method involves replacement of the usual N HCl by N H2SO4 and the usual amount of potassium metabisulphite. Following this method of preparation, an extra-sensitive Schiff's reagent is obtained which requires only 4-5 min for optimum nuclear colouration even when staining is performed at 5 degrees C. This Schiff's reagent produces perfect Feulgen staining up to 6 months after preparation. Toluidine blue O-SO2, prepared with N H2SO4 and potassium metabisulphite, also produces perfect Feulgen type staining of the DNA-aldehyde molecules of acid-hydrolysed mammalian tissue sections. Toluidine blue O-SO2 when shaken with activated charcoal and filtered produces very satisfactory result. The shell-life of this dye-reagent is just a week. The suitability of the use of N H2SO4 for the preparation of Schiff's reagent as well as a Schiff-type dye-reagent, toluidine blue O-SO2, has been discussed. 相似文献
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