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Polyvinyl fluoride (PVF) shows a strong crystal interference caused by the lateral distances of the chains, and is highly crystalline. Over the temperature range 0—100°C the degree of crystallinity is about 86%. Gelation of PVF in γ-butyrolactone was studied over practically the whole range of concentrations (from pure PVF to 1% solution). Gel temperatures were found practically independent of concentration (174°C). Gelation is coupled with crystallization. The swollen samples showed no differences in degree of crystallinity and quality of the crystals compared with the pure polymer at the same temperature. Therefore the degree of crystallinity of the gels is solely a function of temperature. The crosslinks of the network are formed by crystalline regions. Only the amorphous regions in the gels can take up solvent. Caused by the high crystallinity the gels have a crumb-like nature. 相似文献
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Humic acids from four coals, varying in rank from peat to subbituminous coal, have been characterized by elemental analysis, acidic groups, molecular weight, electrophoresis and visible, FT-i.r. and CP/MAS 13C n.m.r. spectroscopy. The humic acids increase in carbon content, molecular weight, condensation degree and aromaticity (fa) with increasing maturation of the parent coals, while the oxygen content decreases with a loss of oxygen functional groups. The presence of lignin-like polymers, poly-saccharides and peptidic materials in humic acids from peat was established using i.r. and 13C n.m.r. spectroscopy. The structural changes observed in humic acids are in agreement with the recognized coalification theory and tend to support the hypothesis of condensation of humic acids into insoluble humin of coal. 相似文献
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Conclusions The stress in polyacrylonitrile yarns of various chemical structures and of various linear densities has been studied under isometric heat-treatment under static and dynamic conditions.Limits of the relaxation states have been determined over a wide range of temperature and rate (or duration) of yarn heating, in the contact and convective methods of heating.Translated from Khimicheskie Volokna, No. 6, pp. 29–30, November–December, 1989. 相似文献
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The chemical changes occurring during mild oxidation of petroleum and coal tar pitch were studied by elementary analysis, solubility measurements, IR and nuclear magnetic resonance spectroscopy and chromatography. The oxidized pitches were compared with pitches which were distilled to give similar softening points. A mild oxidation was shown to induce dehydrogenative polymerization of the pitch components without introducing appreciable amounts of oxygen into the products. The greater reactivity of the petroleum pitch constituents to oxygen is attributed to the presence of alkyl substituents. Study of the mesophase formation and X-ray analysis of the derived graphites showed that mild air oxidation did not affect the subsequent graphitic development. 相似文献
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Aytaç Saygin Gümüşkesen Temel Çakaloz 《Journal of the American Oil Chemists' Society》1992,69(4):392-393
The effects of deodorization time and temperature on the physical and chemical properties of cottonseed oil were investigated.
Higher temperatures and longer times lead to increases in free fatty acids, peroxide value, viscosity and refractive index
while iodine value, unsaponifiable matter and induction period decreased. 相似文献
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N. Gopalakrishnan Geetha Cherian J. S. Sim 《European Journal of Lipid Science and Technology》1996,98(5):168-171
The changes in acid value (AV), peroxide value (PV), anisidine value (AnV), tocopherols and fatty acid composition in crushed flax, canola seeds or commercial poultry feed during a 60-day storage period in room temperature (RT) or cold room (CR) were examined. Storage at RT or CR increased AV, PV and AnV of flax and canola seeds. Regardless of storage condition, a 50% reduction in the content of tocopherols was observed in flax, canola and commercial feed samples at day-30 of storage. The changes in the content of polyunsaturated fatty acids were negligible during storage. These results may have implication in the storage and handling of animal feeds containing n-3-polyunsaturated fatty acid-rich oil seeds. 相似文献
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Israel Sifuentes-Nieves Jose F. Hernandez-Gamez Pamela C. Flores-Silva Pablo Gonzalez-Morones Roberto Yáñez-Macías Eduardo Ramirez-Vargas Ernesto Hernández-Hernández 《应用聚合物科学杂志》2023,140(4):e53354
This study aims to investigate changes in the structural properties of alkali/acid-ultrasound modified Agave fibers and their performance immersed on a polyvinyl alcohol (PVA) matrix with plasticizer during melt mixing processing. Structural analysis revealed that ultrasound enhances the effectiveness of the conventional alkaline/acid treatments to modify fibers since the simultaneous treatment increased the partial removal of lignocellulosic components, water molecules, and amorphous regions which improved their processability on a PVA matrix. Specific energy consumption values indicated that during melt mixing the modified fibers required more energy to expose the chains of cellulose fraction to function as an interaction site for PVA chains. Once the mixture was homogenized, the fiber-matrix interactions promoted high viscosity, friction, and mechanical stress in the chamber. Therefore, the modified fibers restricted the interaction between plasticizer and PVA in the obtained films, resulting in a highly structured, and reinforced network, increasing the storage modulus as dynamic mechanical analysis indicated. These findings highlight a feasible way to valorize Agave fibers and allow the understanding of the matrix-fiber interactions during melt mixing processing, useful to predict the structural and mechanical properties of the films. 相似文献
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采用凝胶纺丝,添加硼酸和助剂生产高强高模聚乙烯醇(PVA)纤维,探讨了其生产工艺。结果表明:控制纺丝原液PVA质量分数16%,添加硼酸质量分数1.0%~1.1%;采用Na_2SO_4/NaOH凝固浴体系,其中Na_2SO_4质量浓度为300g/L,NaOH质量浓度为80~100g/L,凝固浴温度45℃,凝固时间25s;选择4段拉伸,湿热拉伸倍数为6,总拉伸倍数为14;生产稳定,得到的高强高模PVA纤维断裂强度达15cN/dtex,模量达320cN/dtex。 相似文献
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V. D. Fikhman L. S. Krasil'nikova G. A. Kulagina V. B. Shalaev Yu. V. Zaitsev V. P. Zadorozhnaya 《Fibre Chemistry》1988,20(1):32-34
Conclusions The effect of spinning solution preparation parameters on the fibre preparation process and on the properties of polyvinyl chloride fibre have been studied using the experiment planning method.It has been found that the concentration and holding time of the spinning solution exert the greatest effect on the process of washing the fibre free of dimethylformamide.An optimization of the parameters of preparing a solution for polyvinyl chloride fibre production under manufacturing conditions has been carried out.Translated from Khimicheskie Volokna, No. 1, pp. 24–25, January–February, 1988. 相似文献