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1.
Jen‐Taut Yeh Tsong‐Wei Wu Yu‐Ching Lai Huo‐Peng Zhou Qin Zhou Qi‐Cheng Li Sheng Wen Fang‐Chang Tsai Chi‐Yuan Huang Kuo‐Shien Huang Kan‐Nan Chen 《Polymer Engineering and Science》2011,51(4):687-696
Systemic investigation of the influence of the plain and functionalized carbon nanotube (CNT) contents on the ultradrawing properties of ultrahigh molecular weight polyethylene/carbon nanotubes (UHMWPE/CNTs, FCy) and UHMWPE/functionalized CNTs (FCfx‐y) as‐prepared fibers are reported. In a way similar to those found for the orientation factor values, the achievable draw ratios (Dra) of the FCy and FCfx‐y as‐prepared fibers approached a maximum value as their CNT and/or functionalized CNT contents reached their corresponding optimum values. The maximum Dra values obtained for FCfx‐0.001 as‐prepared fiber specimens prepared at varying maleic anhydride grafted polyethylene (PE‐g‐MAH)/modified CNTs weight ratios were significantly higher that of the FC0.0015 as‐prepared fiber specimen prepared at the optimum plain CNT content. Tensile property analysis further suggested that excellent orientation and tensile properties of the drawn FCy and FCfx‐y fibers can be obtained by ultradrawing the fibers prepared at their optimum plain CNT and/or functionalized CNT contents. To understand the interesting orientation, ultradrawing and tensile properties of FCy and FCfx‐y fiber specimens, FTIR, specific surface area, and SEM morphology analysis of the plain and functionalized CNTs were performed in this study. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers 相似文献
2.
Jen‐Taut Yeh Yu‐Ching Lai Hai Liu Yao‐Chi Shu Chi‐Yuan Huang Kuo‐Shien Huang Kan‐Nan Chen 《Polymer International》2011,60(1):59-68
The influence of formation temperature on the ultradrawing properties of ultrahigh‐molecular‐weight polyethylene/carbon nanotube (UHMWPE/CNT) fiber specimens is investigated. Gel solutions of UHMWPE/CNT with various CNT contents were gel‐spun at the optimum concentration and temperature but were cooled at varying formation temperatures in order to improve the ultradrawing and tensile properties of the UHMWPE/CNT composite fibers. The achievable draw ratio (Dra) values of UHMWPE/CNT as‐prepared fibers reach a maximum when they are prepared with the optimum CNT content and formation temperature. The Dra value of UHMWPE/CNT as‐prepared fibers produced using the optimum CNT content and formation temperature is about 33% higher than that of UHMWPE as‐prepared fibers produced using the optimum concentration and formation temperature. The percentage crystallinity (Wc) and melting temperature (Tm) of UHMWPE/CNT as‐prepared fiber specimens increase significantly as the formation temperature increases. In contrast, Wc increases but Tm decreases significantly as the CNT content increases. Dynamic mechanical analysis of UHMWPE and UHMWPE/CNT fiber specimens exhibits particularly high α‐transition and low β‐transition, wherein the peak temperatures of α‐transition and β‐transition increase dramatically as the formation temperature increases and/or CNT content decreases. In order to understand these interesting drawing, thermal and dynamic mechanical properties of the UHMWPE and UHMWPE/CNT as‐prepared fiber specimens, birefringence, morphological and tensile studies of as‐prepared and drawn fibers were carried out. Possible mechanisms accounting for these interesting properties are proposed. Copyright © 2010 Society of Chemical Industry 相似文献
3.
The carbon nanotubes (CNTs) contents, ultrahigh‐molecular‐weight polyethylene (UHMWPE) concentrations and temperatures of UHMWPE, and CNTs added gel solutions exhibited significant influence on their rheological and spinning properties and the drawability of the corresponding UHMWPE/CNTs as‐prepared fibers. Tremendously high shear viscosities (ηs) of UHMWPE gel solutions were found as the temperatures reached 140°C, at which their ηs values approached the maximum. After adding CNTs, the ηs values of UHMWPE/CNTs gel solutions increase significantly and reach a maximum value as the CNTs contents increase up to a specific value. At each spinning temperature, the achievable draw ratios obtained for UHMWPE as‐prepared fibers prepared near the optimum concentration are significantly higher than those of UHMWPE as‐prepared fibers prepared at other concentrations. After addition of CNTs, the achievable draw ratios of UHMWPE/CNTs as‐prepared fibers prepared near the optimum concentration improve consistently and reach a maximum value as their CNTs contents increase up to an optimum value. To understand these interesting drawing properties of the UHMWPE and UHMWPE/CNTs as‐prepared fibers, the birefringence, thermal, morphological, and tensile properties of the as‐prepared and drawn fibers were investigated. Possible mechanisms accounting for these interesting properties are proposed. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
4.
Ultradrawing and ultimate tensile properties of ultrahigh molecular weight polyethylene composite fibers filled with functionalized nanoalumina fillers
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Jen‐Taut Yeh Chuen‐Kai Wang Wen Yu Kuo‐Shien Huang 《Polymer Engineering and Science》2015,55(10):2205-2214
Ultradrawing and ultimate tensile properties of ultrahigh molecular weight polyethylene (UHMWPE) composite fibers were successfully improved by the addition of nanoalumina (NAL), acid treated nanoalumina (ATNAL), and/or functionalized nanoalumina (FNAL). As evidenced by FTIR and TEM analyses, maleic anhydride grafted polyethylene (PEg‐MAH) molecules were successfully grafted onto ATNAL fillers. The specific surface areas of FNAL fillers reached a maximal value at 516 m2/g, as they were modified using an optimal weight ratio of PEg‐MAH to ATNAL at 8. Achievable draw ratio (Dra) values of UHMWPE/NAL (F100Ay), UHMWPE/ATNAL (F100Ax%‐8‐y) and/or UHMWPE/FNAL (F100Ax%‐8FPEzy) as‐prepared fibers approached a maximal value as NAL, ATNAL, and/or FNAL contents reached an optimal value at 0.1, 0.1, and 0.075 phr, respectively. The maximal Dra values of F100Ax%‐8FPEz0.075 as‐prepared fiber specimens were significantly higher than those of F100A0.1 and F100Ax%‐8‐0.1 as‐prepared fiber specimens. In which, the maximal Dra values obtained for F100Ax%‐8FPEz0.075 as‐prepared fibers reached another maximal value as FNAL fillers were modified using an optimal weight ratio of PEg‐MAH to ATNAL at 8. The ultimate tensile strength value of F100A2%‐8FPE80.075 drawn fiber reached 6.4 GPa, which was about 2.4 times of that of the UHMWPE drawn fibers prepared at the same optimal UHMWPE concentration and drawing condition. POLYM. ENG. SCI., 55:2205–2214, 2015. © 2015 Society of Plastics Engineers 相似文献
5.
Jen‐Taut Yeh Chuen‐Kai Wang Alice Yeh Lu‐Kai Huang Wen‐Hung Wang Kuo‐Huang Hsieh Chi‐Yuan Huang Kan‐Nan Chen 《Polymer International》2013,62(4):591-600
Ultrahigh molecular weight polyethylene (UHMWPE)/nanosilica (F2Sy) and UHMWPE/modified nanosilica (F2Smx‐y) as‐prepared fibers were prepared by spinning of F2Sy and F2Smx‐y gel solutions, respectively. Modified nanosilica particles were prepared by grafting maleic anhydride grafted polyethylenes onto nanosilica particles. The achievable draw ratios (Dra) of F2Sy and F2Smx‐y as‐prepared fibers approached a maximal value as the original and modified nanosilica contents reached corresponding optimum values; the maximal Dra value obtained for F2Smx‐y as‐prepared fiber specimens was significantly higher than that of the F2Sy as‐prepared fiber specimens prepared at the optimum nanosilica content. The melting temperature and evaluated lamellar thickness values of F2Sy and F2Smx‐y as‐prepared fiber series specimens decrease, but crystallinity values increase significantly, as their original and modified nanosilica contents respectively increase. Similar to the achievable drawing properties of the as‐prepared fibers, the orientation factor, tensile strength (σf) and initial modulus (E) values of both drawn F2Sy and F2Smx‐y fiber series specimens with a fixed draw ratio reach a maximal value as the original and/or modified nanosilica contents approach the optimum values; the σf and E values of the drawn F2Smx‐y fiber specimens are significantly higher than those of the corresponding drawn F2Sy fiber specimens prepared at the same draw ratios and nanosilica contents but without being modified. To understand the interesting ultradrawing, thermal, orientation and tensile properties of F2Sy and F2Smx‐y fiber specimens, Fourier transform infrared, specific surface area and transmission electron microscopy analyses of the original and modified nanosilica were performed in this study. © 2012 Society of Chemical Industry 相似文献
6.
Jen‐Taut Yeh Chuen‐Kai Wang Ping Hu Yu‐Ching Lai Lu‐Kai Huang Fang‐Chang Tsai 《Polymer International》2012,61(6):982-989
An investigation of the influence of the contents of original and modified attapulgite (ATP) on the ultradrawing properties of ultrahigh‐molecular‐weight polyethylene (UHMWPE)/ATP (FAx) and UHMWPE/modified ATP (FAmx) as‐prepared fibers is reported. Similar to what is found for the orientation factor values, the achievable draw ratios (Dra) of the FAx and FAmx as‐prepared fibers approach a maximum value as the original ATP and/or modified ATP contents reach their corresponding optimum values. The maximum Dra value obtained for FAmx as‐prepared fiber specimens is significantly higher than that for FAx as‐prepared fiber specimens prepared at the optimum original ATP content. Similar to what is found for the orientation factors and achievable drawing properties, the tensile strength (σf) and initial modulus (E) of both drawn F2Ax and F2Amx fiber series specimens with a fixed draw ratio reach maximum values as the original and/or modified ATP contents approach the optimum values, respectively. The σf and E values of the F2Amx fiber specimens are always significantly higher than those of the corresponding F2Ax fiber specimens prepared at the same draw ratios and ATP contents but without being modified. To understand the interesting ultradrawing, orientation and tensile properties of FAx and FAmx fiber specimens, Fourier transform infrared spectral, specific surface area, transmission electron microscopic and elemental analyses of the original and modified ATPs were performed. Copyright © 2012 Society of Chemical Industry 相似文献
7.
Jen‐Taut Yeh Chuen‐Kai Wang Zhi‐Wei Liu Peng Li Chi‐Hui Tsou Yu‐Ching Lai Fang‐Chang Tsai 《Polymer Engineering and Science》2012,52(6):1348-1355
This study systematically investigated the drawing and ultimate tenacity properties of the Nylon 6 (NY6)/nylon 6 clay (NYC) composite fiber specimens prepared at varying NYC contents and drawing temperatures. The achievable draw ratio (Dra) values of NY6x(NYC)y as‐spun fiber specimens initially increase in conjunction with NYC content, and then approach a maximum value, as their NYC contents and drawing temperature approach the 0.5 wt% and 120°C, respectively. The percentage crystallinity (Xc) values of NY6x(NYC)y as‐spun fiber specimens increased significantly, as their NYC contents increased from 0 to 2 wt%. As revealed by high power wide angle X‐ray diffraction analysis, α form NY6 crystals grew at the expense of γ form NY6 crystals originally present in NY6x(NYC)y as‐spun fiber specimens as their draw ratios increased. The ultimate modulus, tenacity, and orientation factor values of NY6x(NYC)y fiber specimens approach a maximum value, as their NYC contents and drawing temperatures approach the 0.5 wt% and 120°C optimum values, respectively. The thermal and melt shear viscosity experiments were performed on NY6x(NYC)y resins and/or fiber specimens to determine the optimum NYC content and possible deformation mechanisms accounting for the interesting drawing, orientation, and ultimate tenacity properties found above. POLYM. ENG. SCI., 2012. © 2012 Society of Plastics Engineers 相似文献
8.
Fang‐Chang Tsai Peng Li Zhi‐Wei Liu Gang Feng Ping Zhu Chuen‐Kai Wang Kan‐Nan Chen Chi‐Yuan Huang Jen‐taut Yeh 《应用聚合物科学杂志》2012,126(6):1906-1916
The drawing and ultimate tenacity properties of the Polyamide 6 (PA6)/Attapulgite (ATP) composite fiber specimens prepared at varying modified ATP (mATP) contents and drawing condition were systematically investigated. As evidenced by Fourier transform infrared (FTIR) and morphological analysis, demarcated translucent resins were found firmly attached on the surfaces of ATP nanofibers. The specific surface areas of the mATP specimens reached a maximum value at 381 m2/g as the weight ratios of silane coupling agents to ATP nanofibers reached an optimum value at 1.0. The percentage crystallinity and melt shear viscosity values measured at varying shear rates of PA6x(mATP)y specimens increased consistently as their mATP contents increased. In contrast, melting temperatures of PA6x(mATP)y specimens reduced slightly as their mATP contents increased. At a fixed drawing temperature and rate, the achievable draw ratio (Dra) values of PA6x(mATP)y as‐spun fiber specimens approach a maximum value, as their mATP contents are close to the 0.2 wt % optimum value. The maximum Dra values obtained for PA699.8(mATP)0.2 as‐spun fiber specimens reached another maximum, when their drawing temperatures and rates approached the optimum values at 120°C and 50 mm/min, respectively. At a fixed draw ratio, the tenacity values of PA6x(mATP)y drawn fiber specimens drawn at the optimum drawing temperature and rate reached a maximum value, as their mATP contents approached the 0.2 wt % optimum value. Possible reasons accounting for the interesting morphological, specific surface area, drawing, orientation, and ultimate tenacity properties found for the PA6x(mATP)y fiber specimens are proposed. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
9.
P. Selvin Thomas Adedigba A. Abdullateef Mamdouh A. Al‐Harthi A. A. Basfar Sri Bandyopadhyay Muataz A. Atieh S. K. De 《应用聚合物科学杂志》2012,124(3):2370-2376
This paper reports the results of studies on the effect of phenol functionalization of carbon nanotubes (CNTs) on the mechanical and dynamic mechanical properties of natural rubber (NR) composites. Fourier transform infrared spectrometry (FTIR) indicates characteristic peaks for ether and aromatic rings in the case of phenol functionalized CNT. Although differential scanning calorimetric (DSC) studies show no changes in the glass‐rubber transition temperature (Tg) of NR in the nanocomposites due to surface modification of CNT, dynamic mechanical studies show marginal shifting of Tg to higher temperature, the effect being pronounced in the case of functionalized CNT. Stress‐strain plots suggest an optimum loading of 5 phr CNT in NR formulations and the phenolic functionalization of CNT does not affect significantly the stress‐strain properties of the NR nanocomposites. The storage moduli register an increase in the presence of CNT and this increase is greater in the case of functionalized CNT. Loss tangent showed a decrease in the presence of CNT, and the effect is more pronounced in the case of phenol functionalized CNT. Transmission electron microscopy (TEM) reveals that phenol functionalization causes improvement in dispersion of CNT in NR matrix. This is corroborated by the increase in electrical resistivity in the case of phenol functionalized CNT/NR composites. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
10.
Wei Wei Liang Qiu Xin-Ling Wang Hong-Ping Chen Yu-Ching Lai Fang-Chang Tsai Ping Zhu Jen-Taut Yeh 《Journal of Polymer Research》2011,18(6):1841-1850
The influence of calcium chloride (CaCl2) contents on the drawing and tensile properties of polyamide 6 (PA6)/CaCl2 composite fibers prepared at varying drawing temperatures were investigated. At any fixed drawing temperature, the achievable
draw ratio (Dra) values of PA6x(CaCl2)y as-spun fiber specimens approach a maximum value, as their CaCl2 contents are close to the 3 wt% optimum value. The maximum Dra values obtained for PA6x(CaCl2)y as-spun fiber specimens prepared at the optimum CaCl2 content reach another maximum as their drawing temperatures approach the optimum drawing temperature at 120 °C. The initial
modulus, tensile strength and birefringence values of the PA6 and PA6x(CaCl2)y fiber specimens were found to improve consistently with Dra or with drawing temperatures when they were stretched to a fixed Dra. Similar to those found for their achievable drawing properties, the ultimate initial modulus, tensile strength and birefringence
values of PA6x(CaCl2)y fiber specimens approach a maximum value, as their CaCl2 contents and drawing temperatures approach the 3 wt% and 120 °C optimum values, respectively. Experiments including thermal,
FTIR, melt shear viscosity and wide angle X-ray diffraction experiments were performed on the PA6x(CaCl2)y resin and/or fiber specimens to clarify the possible reasons accounting for the interesting drawing, tensile and birefringence
properties found for the PA6x(CaCl2)y fiber specimens. 相似文献
11.
In order to improve the dispersion of carbon nanotubes (CNTs) in polyimide (PI) matrix and the interfacial interaction between CNTs and PI, 4,4′‐diaminodiphenyl ether (ODA)‐functionalized carbon nanotubes (CNTs‐ODA) were synthesized by oxidation and amidation reactions. The structures and morphologies of CNTs‐ODA were characterized using Fourier transform infrared spectrometer, transmission electron microscopy, and thermal gravimetric analysis. Then a series of polyimide/amino‐functionalized carbon nanotube (PI/CNT‐ODA) nanocomposites were prepared by in situ polymerization. CNTs‐ODA were homogeneously dispersed in PI matrix. The influence of CNT‐ODA content on mechanical properties of PI/CNT‐ODA nanocomposites was investigated. It was found that the mechanical properties of nanocomposites were enhanced with the increase in CNT‐ODA loading. When the content of CNTs‐ODA was 3 wt%, the tensile strength of PI/CNT‐ODA nanocomposites was up to 169.07 MPa (87.11% higher than that of neat PI). The modulus of PI/CNTs‐ODA was increased by 62.64%, while elongation at break was increased by 66.05%. The improvement of the mechanical properties of PI/CNT‐ODA nanocomposites were due to the strong chemical bond and interfacial interaction between CNTs‐ODA and PI matrix. POLYM. COMPOS., 35:1952–1959, 2014. © 2014 Society of Plastics Engineers 相似文献
12.
Jen‐Taut Yeh Chuen‐Kai Wang Qin Zhou Huo‐Peng Zhou Chih‐Chen Tsai Yu‐Ching Lai Chi‐Hui Tsou Kan‐Nan Chen Chi‐Yuan Huang Kuei‐Chi Lee 《Polymer Engineering and Science》2013,53(9):1910-1919
Dimensions of conical dies were found to have a significant influence on thermal, morphological, orientation, ultradrawing, and dynamic mechanical properties of the as‐prepared and/or drawn ultrahigh molecular weight polyethylene (UHMWPE) fiber specimens prepared in this study. Many demarcated “micro‐fibrils” were found paralleling to fiber direction of the as‐prepared UHMWPE fiber specimens. The percentage crystallinity, melting temperatures, orientation factor (fo) and achievable draw ratio (Dra) values of each as‐prepared UHMWPE fiber specimen prepared at a fixed length of outlet land reach a maximum value, as the entry angles of the conical die approach the optimum value at 75°. The maximum fo and Dra values obtained for each F2075‐y as‐prepared fiber series specimens prepared using the optimum entry angle reach another maximum value as their length of outlet land approach the optimum value of 6.5 mm. The ultimate tensile strengths and moduli of the drawn UHMWPE fibers prepared at the optimum entry angle and length of outlet land are significantly higher than those of fibers prepared at other conditions but stretched to the same draw ratio. Possible reasons accounting for the above interesting properties were discussed in this study. POLYM. ENG. SCI., 2013. © 2013 Society of Plastics Engineers 相似文献
13.
Javed Alam Manawwer Alam Lawrence Arockiasamy Dass A. M. Shanmugharaj Mohan Raja 《Polymer Composites》2014,35(11):2129-2136
A polymer nanocomposite system comprising epoxidized soya oil plasticized‐polylactic acid (PLA) and amine functionalized carbon nanotubes (NH2 functionalized‐CNTs) has been prepared with the aim of producing electrically conductive PLA products suitable for shape memory (SM) applications. An influence of the addition of NH2 functionalized‐CNTs on thermal, mechanical properties, and morphology development of plasticized PLA/NH2 functionalized‐CNTs nanocomposite was investigated by differential scanning calorimetry, tensile tests, scanning electron microscope, and atomic force microscopy, respectively. In addition, electroactive SM behavior in resulting nanocomposite was evaluated by a bending test, and the recovery process was recorded with video camera. The results showed that SM behavior in nanocomposite was influenced by NH2 functionalized‐CNTs weight percent in matrix. Nanocomposite with 5 wt% NH2 functionalized‐CNTs showed optimum values of shape recovery due to its relatively high electrical conductivity, and an adequate degree of crosslinking between NH2 functionalized‐CNTs and plasticized PLA matrix. However, more than 5 wt% loading of NH2 functionalized‐CNTs dropped down an elongation at break, while tensile at break increased with the increasing of CNTs weight percent in matrix. Interesting point in this study is that all improvements in the properties of resulting PLA/NH2 functionalized‐CNTs nanocomposite sheet were observed at very low filler content, while other literature reports where large quantities of CNTs were used. POLYM. COMPOS., 35:2129–2136, 2014. © 2014 Society of Plastics Engineers 相似文献
14.
Richard L. Thompson Amilcar Pillay Narrainen Stuart M. Eggleston Imtiyaz A. Ansari Lian R. Hutchings Nigel Clarke 《应用聚合物科学杂志》2007,105(2):623-628
Dendritically fluorocarbon‐functionalized poly(methyl methacrylate) (PMMA) has been explored as a robust surface‐modifying additive in PMMA blends. These functionalized materials, denoted FxPMMAy, where x is the number of C8F17 fluorocarbon groups per dendron connected to a PMMA chain of y kg/mol, have been synthesized by living radical polymerization. These materials adsorb efficiently to the surfaces of their blends with unfunctionalized PMMA, resulting in increased hydrophobicity and lipophobicity. Contact‐angle goniometry has indicated a substantial reduction in the surface energy toward polytetrafluoroethylene‐like surface properties in the case of pure F4PMMA8.6 and substantial, but incomplete fluorocarbon surface coverage at a lower FxPMMAy concentration. The partial coverage has been confirmed by Rutherford backscattering and, together with the weak dependence of the surface modification on the FxPMMAy structure, indicates incomplete equilibrium of the surface adsorption. The modified surfaces are quite durable with respect to abrasion under water but are progressively eroded when the double‐wipe test is carried out with acetone. FxPMMAy, dispersed in the remaining film, acts as a reservoir of spare functional groups, from which the damaged surface may be replenished, leading to the recovery of the modified surface properties. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
15.
Ji‐Hoon Lee John Kathi Kyong Yop Rhee Joong Hee Lee 《Polymer Engineering and Science》2010,50(7):1433-1439
Ultra high molecular weight polyethylene (UHMWPE) is extensively used as a material in various high‐end applications with superior mechanical properties. Carbon nanotubes (CNTs) reinforced UHMWPE (CNT/UHMWPE) nanocomposite is a promising material that can compensate for the weak durability of UHMWPE. In this study, multiwalled carbon nanotubes were oxidized and silanized using acid mixture and 3‐aminopropyltriethoxysilane, respectively, to improve the interfacial strength between CNTs and UHMWPE. The CNT/UHMWPE nanocomposite was fabricated using these oxidized and silanized CNTs. The treatment effect of CNTs on the wear behavior of the CNT/UHMWPE nanocomposites was investigated through wear tests. The oxidization and silanization of CNTs were confirmed by infrared spectroscopy. Scanning electron microscope analysis showed that the silane‐treated CNT/UHMWPE nanocomposites showed better dispersion and interfacial adhesion between UHMWPE and CNTs becaue of the newly formed functional groups on the CNTs. The friction coefficient and wear rate of silanized CNT/UHMWPE nanocomposite were also found to be lower than those of raw UHMWPE and oxidized CNT/UHMWPE nanocomposite. CNTs were functionalized using oxidation and silanization methods to improve the interfacial adhesion between CNTs and UHMWPE. POLYM. ENG. SCI., 2010. © 2010 Society of Plastics Engineers 相似文献
16.
Xulin Yang Zicheng Wang Yingqing Zhan Jian Yang Yanke Zou Rui Zhao Xiaobo Liu 《Polymer International》2013,62(4):629-637
The different filler effects of identical nitrile‐functionalized carbon nanotubes (CNTs) and graphene nanoplatelets (GNs) in a poly(arylene ether nitrile) (PEEN) matrix were investigated. PEEN/CNT and PEEN/GN composites were prepared by a facile solution‐casting method and systematically investigated for their differences in morphological, thermal and rheological properties. In the PEEN matrix GNs contact one another in a plane‐to‐plane manner, while CNTs are separated. Compared with PEEN/CNT composites, PEEN/GN composites below 2 wt% filler content exhibited higher thermal stability. Rheological properties of the resulting composites indicated that PEEN/GN composites were more sensitive to strain and exhibited higher η*, G′ and G″ than PEEN/CNT composites. The rheological percolation for CNTs is over 2 wt%, higher than that for GNs (around 1 wt%). All these differences originate from the different dimensions and structures of CNTs and GNs: GNs with a flake‐like structure and larger surface area can have stronger physical and interfacial interactions with the polymer matrix. This work gives a comparative view of the different filler effects that functionalized CNTs and GNs can have in the polymer host. With identical processing technology, GNs can show a stronger filler effect than CNTs. © 2012 Society of Chemical Industry 相似文献
17.
《Journal of Adhesion Science and Technology》2013,27(10):1073-1086
Two series of waterborne polyurethane (WBPU)/carbon nanotube (CNT) nanocomposites were prepared with various CNT contents (0–1.50 wt%). We used a metal-hydroxide (copper hydroxide, Cu(OH)2) and amine (triethylamine, TEA) as the countercation in the nanocomposites. The interaction of the countercations with the CNTs in the nanocomposite was characterized by TEM, and the interaction effects on the properties, such as the glass transition temperature (Tg), storage modulus, tensile strength, Young's modulus and adhesive strength, were investigated. The CNTs were homogeneously (optimum) dispersed at concentrations of up to 1.25 and 1.00 wt% for the metal-hydroxide and amine series, respectively. At the optimum CNT content, the tensile strength and adhesive strength were maximized in each series. However, the adhesive strength of the WBPU/CNT nanocomposite with the metal-hydroxide countercation was less affected than with the amine-countercation after immersing the adhesive bonded nylon fabrics in water (for up to 48 h). 相似文献
18.
Asad Hameed Mohammad Islam Iftikhar ahmad Nasir Mahmood Shaukat Saeed Hassan Javed 《Polymer Composites》2015,36(10):1891-1898
In this study, the effects of functionalization and weight fraction of mutliwalled carbon nanotubes (CNTs) were investigated on mechanical and thermomechanical properties of CNT/Epoxy composite. Epoxy resin was used as matrix material with pristine‐, COOH‐, and NH2‐functionalized CNTs as reinforcements in weight fractions of 0.1, 0.5, and 1.0%. Varying (increasing) the weight fraction and changing type (pristine or functionalized) of CNTs caused increment in Young's modulus and tensile strength as observed during mechanical tests. CNT reinforcement improved thermal stability of the nanocomposites as observed by thermogravimetric analysis. Thermomechanical analysis showed a slight reduction in free volume of the polymer, that is a drop in coefficient of thermal expansion, prior to glass transition temperature (Tg) beside a slight increase in Tg value. Dynamic mechanical analysis indicated an increase in storage modulus and Tg owing to the strength addition of CNT to the matrix alongside the hardener. Scanning electron microscopy analysis of the fractured surface(s) revealed that CNTs were well dispersed with no agglomeration and resulted in reinforcing the matrix. POLYM. COMPOS., 36:1891–1898, 2015. © 2014 Society of Plastics Engineers 相似文献
19.
Improvements in carbon nanotube (CNT) dispersion and subsequent mechanical properties of CNT/poly(phenylsulfone) (PPSF) composites were obtained by applying the supercritical CO2 (scCO2)‐aided melt‐blending technique that has been used in our laboratory for nanoclay/polymer composite preparation. The preparation process relied on rapid expansion of the CNTs followed by melt blending using a single‐screw extruder. Scanning electronic microscopy results revealed that the CNTs exposed to scCO2 at certain pressures, temperatures, exposure time, and depressurization rates have a more dispersed structure. Microscopy results showed improved CNT dispersion in the polymer matrix and more uniform networks formed with the use of scCO2, which indicated that CO2‐expanded CNTs are easier to disperse into the polymer matrix during the blending procedure. The CNT/PPSF composites prepared with scCO2‐aided melt blending and conventional melt blending showed similar tensile strength and elongation at break. The Young's modulus of the composite prepared by means of conventional direct melt blending failed to increase beyond the addition of 1 wt% CNT, but the scCO2‐aided melt‐blending method provided continuous improvements in Young's modulus up to the addition of 7 wt% CNT. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers 相似文献
20.
Morphology,mechanical properties and electromagnetic shielding effectiveness of poly(styrene‐b‐ethylene‐ran‐butylene‐b‐styrene)/carbon nanotube nanocomposites: effects of maleic anhydride,carbon nanotube loading and processing method
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Nanocomposites based on poly(styrene‐b‐ethylene‐ran‐butylene‐b‐styrene) (SEBS) and carbon nanotubes (CNTs) (SEBS/CNT) as well as SEBS grafted with maleic anhydride (SEBS‐MA)/CNT were successfully prepared for electromagnetic shielding applications. Both SEBS/CNT and SEBS‐MA/CNT nanocomposites were prepared by melt compounding and were post‐processed using two different techniques: tape extrusion and compression moulding. The different nanocomposites were characterized by Raman spectroscopy and rheological analysis. Their mechanical properties, electrical properties (10-2–105 Hz) and electromagnetic shielding effectiveness (8.2–12.4 GHz) were also evaluated. The results showed that the CNT loading amount, the presence of MA in the matrix and the shaping technique used strongly influence the final morphologies and properties of the nanocomposites. Whilst the nanocomposite containing 8 wt% CNTs prepared by compression moulding presented the highest electromagnetic shielding effectiveness (with a value of 56.73 dB, which corresponds to an attenuation of 99.9996% of the incident radiation), the nanocomposite containing 5 wt% CNTs prepared by tape extrusion presented the best balance between electromagnetic and mechanical properties and was a good candidate to be used as an efficient flexible electromagnetic interference shielding material. © 2018 Society of Chemical Industry 相似文献