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《中国材料进展》2016,(4)
正October 20~24,2016,Qingdao,China Web:http://www.c-mrs.org.cn/iumrs-ica 2016Organized by:Chinese Materials Research Society(C-MRS)International Union of Materials Research Societies(IUMRS)Qingdao Science and Technology Association Co-organized by Materials Research Society-Taiwan(MRS-T)Supported by:Ministry of Science and Technology of China 相似文献
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A. M. Khoviv L. A. Malevskaya D. M. Pribytkov E. I. Zavalishin 《Inorganic Materials》2004,40(2):171-175
Thin Cu–Ti films are grown on single-crystal silicon substrates by magnetron sputtering, and their oxidation is studied between 420 and 670 K. A technique is proposed for producing Cu–Ti films of controlled composition using a composite target. The phase composition of the films oxidized in oxygen at atmospheric pressure is determined, and their microstructure is studied by scanning electron microscopy. The films are found to contain the intermetallic compounds Cu3Ti and CuTi2, which form during both magnetron sputtering and subsequent oxidation. 相似文献
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The chemical and microstructural processes induced in vanadium films by nitrogen–hydrogen plasma processing were characterized by x-ray diffraction, electron microscopy, and resistivity measurements. Conditions were identified under which vanadium nitride layers can be produced by plasma processing. 相似文献
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We review recent work on the properties of 3He–4He thin film mixtures. The subject is introduced by reviewing the contributions made by Gasparini and co-workers. In the first part of this survey, we examine a microscopic calculation of the effects that an adsorbed 3He component has on the collective excitations associated with a 4He film, third sound. The work in question computes the change in the third sound velocity due to adding 3He, and we can compare this with existing experiment. For small 3He coverage, the change in the third sound speed depends on the derivatives of the species chemical potentials with respect to the areal density. The microscopic calculation shows oscillations in the third sound speed that reflect the layered structure of the film. In the second part of this survey, we concentrate on the 3He component. An important impact of the 4He environment is to change the bare mass in the limit of zero 3He concentration to a hydrodynamic mass. Quasiparticle interactions are introduced through the Landau parameters. Our Landau parameters are determined by fitting s-wave and p-wave T-matrix components using experimental results for the effective mass and the spin susceptibility. We can then predict the thermodynamic behavior of the mixture films at finite polarization, and in addition we can predict the spectrum of zero-sound excitations at all polarizations. 相似文献
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A. M. Khoviv V. N. Khoviv E. N. Vetrova L. A. Malevskaya T. A. Myachina 《Inorganic Materials》2004,40(11):1161-1164
The oxidation kinetics of thin films of dilute Fe–Ni solid solutions (0.17, 0.54, 0.65, 0.91, and 1.87 at % Ni) on single-crystal Si substrates are studied. The oxidation rate of the films is found to decrease with increasing Ni concentration. The predominant phase in all of the oxide layers is Fe2O3, independent of the oxidation conditions. It is shown that, at an Ni content of about 1 at %, the composition dependences of the oxide thickness, refractive index, extinction coefficient, and apparent activation energy for oxidation show extrema. The mechanism of film oxidation is discussed. 相似文献
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V. N. Semenov O. V. Ostapenko A. N. Lukin E. I. Zavalishin A. Yu. Zavrazhnov 《Inorganic Materials》2000,36(12):1197-1199
Structural, electrical, and optical data are used to elucidate the mechanisms of solid-state reactions in thin CdS–Bi2S3 films prepared by spray pyrolysis. The results indicate the formation of substitutional solid solutions and a chemical compound and intercalation of Cd between layers of Bi2S3. 相似文献
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Theoretical principles underlying the photothermal method for measuring the thickness and thermal properties of a thin film
located between two optical elements (“sandwich”) are analyzed. The method is based on the irradiation of the assembly by
repetitive pulse laser radiation. Radiation is absorbed in the film and causes heating of the optical elements by heat conduction.
The element is monitored by a narrow beam of a second low-power laser propagating through the heated region. The beam is deflected
due to the spatial variation of the refractive index, and the magnitude of the deflection angle as a function of time contains
the relaxation and “wave” components. It is shown that the phase of the “wave” component depends on the thickness and thermophysical
properties of the film. The thermophysical properties of the film can be determined, provided that the analogous properties
of the optical element are measured previously or otherwise known, by comparing experimentally measured values of the phase
shift with theoretical values obtained from the analytical solution of the non-stationary two-dimensional heat conduction
equation. 相似文献
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A. Antonakos E. Liarokapis M. Filippi W. Prellier G. H. Aydogdu H.-U. Habermeier 《Journal of Superconductivity and Novel Magnetism》2009,22(2):109-113
We have measured the reflectivity infrared (IR) spectra of R1−x
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MnO3 (R = La, Pr) manganite thin films grown on different substrates (SrTiO3 (STO), LaAlO3 (LAO) and SrLaGaO4 (SLGO)) manganites over a wide frequency (50–5000 cm−1) range. In the Far IR (FIR) region the substrates dominate over the manganite spectrum. However, the previously observed
infrared active modes or mode pairs could be identified. In the mid-IR (MIR) region, a characteristic insulating gap at ∼700 cm−1 is always present for all thin film studied, which shows substrate and thickness dependence. 相似文献
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B. Nagy Y. N. Khaydukov L. F. Kiss S. Sajti D. G. Merkel F. Tanczikó A. S. Vasenko R. O. Tsaregorodsev A. Rühm T. Keller L. Bottyán 《Journal of Superconductivity and Novel Magnetism》2013,26(5):1957-1961
The thickness (d F) and concentration (x) dependence of the Curie temperature of Ni x Cu1?x (d F) ferromagnetic alloy layers (x=0.55, 0.65, d F=[4.5 nm÷12 nm]) in contact with a vanadium layer was studied. The Curie temperature of the ferromagnetic layers depends on the thickness when it is comparable with the transition layer between the F and the vanadium layers, which is attributed to the proximity coupling of the interface region with the rest of the F layer. The present study provides valuable information for fabrication of samples with controlled exchange coupling strength for studies of superconductor/ferromagnet proximity effects. 相似文献
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The thermal stability of high-K dielectrics on Si is critical in avoiding the malfunction of metal oxide field effect transistors(MOSFET) in devices.Series of annealing experiments have been performed to investigate the thermal stability of atomic layer deposited(ALD) lanthanum aluminate(LAO) thin films,a promising amorphous high-K candidate.The abrupt interface between LAO and Si remains intact at temperatures below 600 C.Above this temperature,a SiO_2-rich interfacial layer begins to appear and thickens at higher temperatures.At900 ℃,the interface is roughened due to the formation of nano sized crystal nuclei above the interfacial layer,which indicates the interfacial reactions with the Si substrate.The thermal stability of ALD Al_2O_3 thin films on Si have also been studied under similar conditions.The Al_2O_3/Si interface retains its smoothness even after full crystallization.This comparison suggests that the rare earth element may catalyze the interfacial reactions.Further annealing experiments on LAO films with different thickness and with a capping layer show that the oxygen source of the interfacial layer mainly comes from the ALD oxide films. 相似文献
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Thomas Brede Michel Kuhfuß Reiner Kirchheim Cynthia A. Volkert 《Advanced Engineering Materials》2023,25(18):2201914
Herein, it is demonstrated that high DC electric current densities can be used to tailor the microstructure of iron–carbon thin films. Specifically, elongated ferrite grains can be formed in a nanocrystalline matrix via a process involving electromigration-induced carbide migration. Herein this article, the parameters that are required to produce and control elongated grain formation in the Fe(C) system are mapped out and they are interpreted in terms of carbon electromigration, and the flux divergences need to reach a critical carbon concentration for precipitate growth and migration. Possible approaches to allow more precise control of the elongated grains are discussed, as are the requirements for material systems where microstructure control through electromigration should be feasible. 相似文献
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M. M. Abdelhadi 《Journal of Superconductivity and Novel Magnetism》2011,24(1-2):741-746
Careful investigation of the angular dependence of resistivity ??(??) (?? is the angle between the magnetic field and the ab-planes) as a function of the temperature within the superconducting transition in an applied magnetic field B up to 1 T for a series of YBa2Cu3O7??? (YBCO) thin films revealed a large variation in the shape and width of the minimum displayed in the vicinity of ??=0??, from a flat to a very sharp behavior. The series of films studied included both optimally doped and underdoped samples of different T c , critical current density?J c , film thickness, and preparation techniques. ??(??) measured for B close to ??=0?? (B parallel to ab-planes) for both B??J and B??J (J is the applied current density) showed two classes of samples; class of samples where ??(??) is independent of the direction of B relative to J and the other class where ??(??) depends on the orientation B relative to?J. This unusual unique behavior motivated us to investigate its origin by looking at the scaling of ??(??) as a function of the reduced field. Scaling of ??(??)) with the reduced field B(?? ?2cos?2 ??+sin?2)1/2 allowed a quantitative determination of the value of ?? (intrinsic anisotropy) which varies between 7 and 400, and is independent of film thickness and J c . Analysis of the microstructure though XRD of the films studied showed that the anisotropy is related to microstrain of the films. 相似文献
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W. Cui P. Mikheenko L. M. Yu T. W. Button J. S. Abell A. Crisan 《Journal of Superconductivity and Novel Magnetism》2009,22(8):811-815
A new fluorine-free chemical solution deposition route has been developed for YBa2Cu3O7−x
(YBCO) thin films. The precursor was formed by dissolving metal nitrates and citric acid in ethylene glycol. Polyethyleneimine
was used to modify the solution. The preparation of YBCO thin films consisted of repeated dip coating, drying, heat-treating
in air and annealing in flowing argon with a small addition of oxygen and with final treatment in pure oxygen. The films were
characterized by XRD and SEM and show dominating and well-textured YBCO phase. The AC susceptibility and magnetization measurements
reveal a critical temperature about 90 K and a high critical current density, comparable with that of pulse laser deposited
films. The simplicity and high performance of the method may be attractive for large-scale superconducting applications. 相似文献