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本文采用以OV-101为固定液,邻苯二甲酸二乙酸为内标物的气相色谱分析,FID检测2-叔丁基-4,5-二氯-3(2H)-哒嗪酮。该法标准偏差0.32,变异系数1.06%,该方法回收率在99.3%,该方法回收率在99.3-100.8%。 相似文献
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2,5—二巯基—1,3,4—噻二唑的催化合成 总被引:3,自引:0,他引:3
以低碳叔胺为催化剂合成了2,5-二巯基-1,3,4-噻二唑,反应收率高达99.0%,产品纯度达99.78%。讨论了催化剂处类对反应收率的影响。 相似文献
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通过2-甲基吡啶的烷基化,部分还原,Hoffman消除开环,立体选择性合成了马尾松毛虫性信息素的前体N,N-二甲基-(2Z,4E)-壬二烯胺,其全合成的总化学产率为25.4%,异构体纯度高达92.0%,并分析了NaBH4还原2-烷基吡啶的机理。 相似文献
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采用高效液相色谱法,以甲醇作流动相测定2-特丁基-4,5-二氯-3(2H)-哒嗪酮。该法标准偏差为0.17,变异系数为0.23%,平均回收率为99.85%。方法线性关系了用气相色普法相关系数为0.9999,回归方程为y/0.0082+1.3085x。 相似文献
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α相和β相氮化硅的形成机理与动力 总被引:6,自引:0,他引:6
使用气流磨粉碎的硅粉(Si)(Si99.3%,dp=5.1μm,Sg=3.2m^2/g)和氮气(N2)(纯度99.9998%)为反应物,在1300~1367℃下反应形成β-Si3N4,其反应机理与动力学参数被研究。反应产物由XRD进行定量分析,相形成的机理和它们的形态用扫描电镜(SEM)确定,我们发现α相和β相的形成机理不同,β-Si3N4在1300℃的实验数据适合于界面化学反应控制的动力学模型, 相似文献
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介绍了合成2,4-二羟基苯甲酸的改良水溶液法新工艺,循环反应收率高达90%,综合收率85%,产品纯度99.4%(化学法测定)。 相似文献
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苯乙烯—丙烯酸丁酯—丙烯酸羟乙酯共聚物的合成及其与二异氰酸 … 总被引:1,自引:0,他引:1
当混合溶剂乙酸丁酯/二甲苯质量比为1:1,过氧化苯甲酰(BPO)为1%,苯乙烯(St)/丙烯酸丁酯(BA)+丙烯酸羟乙酯(HEA)(质量比)为62:38,反应温度为133℃时,可获得卖座经率为95.3%,「η」为0.16dL/g的St-BA-HEA共聚物。该共聚物(HEA的结合量为2-4%)在同一溶剂中加入甲苯二异氰酸酯(TDI)或聚醚型二异氰酸酯(PEDI),当一NCO/-OH摩尔比为1.2-1 相似文献
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2,4-二氯甲苯经光氯化、水解、氯酰化、精馏合成2,4-二氯苯甲酰氯,总收率达90%以上,产品纯度大于99%。 相似文献
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以苯甲酰氯,甲苯为原料,在催化剂三氯化铝存在下合成了4-甲基苯基苯甲酮。物料配比为苯甲酰氯:三氯化铝:甲苯=1:1.4:6.2(摩尔比)。在反应温度100℃,反应时间8h条件下,产品收率87.5%,纯度大于99%。用色质 红外光谱证实了结构。 相似文献
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1,2-butanediol (1,2-BDO) and 1,2-propanediol (1,2-PDO) are inevitably side produced in the ethylene glycol (EG) production processes from non-petroleum routes, but are very difficult to separate by the ordinary distillation method because of the closeness of their boiling temperatures to EG, thus compromise the economy of these processes. The azeotropic distillation process using 1-octanol (CPO) as an entrainer to separate EG and 1,2-BDO mixture with or without 1,2-PDO was studied in this paper. Four binary vapour–liquid equilibrium data of EG-1,2-BDO, EG-CPO, 1,2-BDO-CPO, and 1,2-PDO-CPO were measured using an Ellis equilibrium kettle and regressed with the thermodynamic model of non-random two liquid to obtain the corresponding binary interaction parameters. On this basis, azeotropic distillations with CPO as an entrainer were designed to separate EG and 1,2-BDO with or without 1,2-PDO. The complete separation processes, including the azeotropic distillation and CPO recovery process consisting of extraction with H2O and subsequent distillation, were simulated and optimized with Aspen Plus for both the EG-1,2-BDO binary mixture and the EG-1,2-BDO-1,2-PDO ternary mixture. The simulation results show that the azeotropic distillation method with CPO as an entrainer can effectively separate the mixture of EG-1,2-BDO and EG-1,2-BDO-1,2-PDO, achieving EG of 99.90% purity with 99.98% recovery and 1,2-BDO of 99.30% purity with 99.45% recovery for the binary mixture, and achieving EG of 99.90% purity with 99.80% recovery, 1,2-BDO of 99.35% purity with 99.35% recovery, and 1,2-PDO of 90.59% purity with 94.38% recovery for the ternary mixture. These processes are promising for industrial application and can significantly improve the economy of non-petroleum EG production. 相似文献
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J. L. Guil-Guerrero J. C. López-Martínez M. A. Rincón-Cervera P. Campra-Madrid 《Journal of the American Oil Chemists' Society》2007,84(4):357-361
The fatty acids (FA) eicosapentaenoic acid (20:5ω-3; EPA) and docosahexaenoic acid (22:6ω-3; DHA), which have several health
benefits, have been concentrated from mako shark liver (Isurus oxyrinchus). The process was carried out in one single step, in which fish liver oil was simultaneously extracted, saponified and concentrated.
Additionally, the polyunsaturated fatty acids (PUFA) concentrate was winterized to crystallize the remaining saturated FA,
resulting in a further increase in the concentration of DHA and EPA. Two variables, temperature and water concentration in
the saponification mixture, were optimized to increase the concentration of ω-3 PUFA. Best results were obtained at 12 °C
and 0% water content in the mixture, obtaining 17.8% purity and 77.6% yield of EPA; DHA purity and yield were 33.3 and 82.2%,
respectively. 相似文献
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双环戊二烯二甲酸的合成与表征 总被引:3,自引:0,他引:3
利用双环戊二烯加热分解制得环戊二烯,在四氢呋喃中CPD与Na反应得到CPDNa,再与干冰混合,加水溶解,中和,过滤,干燥,即得双环戊二烯二甲酸。考察了CPDNa与干冰混合反放置时间对收率和产物纯度的影响。 相似文献
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Le-Phuc Nguyen Yen Thi Hai Pham Phuong Thuy Ngo Tri Van Tran Loc Vinh Tran Nam Thi Hoai Le Luong Huu Nguyen Tung Thanh Dang Duc Anh Nguyen Marco Wenzel David Hartmann Karsten Gloe Jan J. Weigand Klaus Kretschmer 《Korean Journal of Chemical Engineering》2018,35(5):1195-1202
Acid leaching and a two-step solvent extraction procedure were developed to produce high purity mixture of La and Ce from iron-rich spent FCC catalyst discharged from Dzung Quat refinery (Vietnam). Acid leaching of the spent catalyst with 2M HNO3 and a solid-to-liquid ratio of 1/3 at 80 °C in 1 h dissolved almost 90% of La while 12% of Al and 25% of Fe were transferred to the leachate. The extraction of RE metals and main impurities such as Al and Fe by a mixture of di-2-ethylhexyl phosphoric acid (D2EHPA) and tributyl phosphate (TBP) was investigated. Experiments showed that it was necessary to remove Fe before extracting RE and the optimum extraction conditions for a high recovery of RE while 0% of Al extraction were pH-1, contact time=10min, and D2EHPA/TBP volume ratio= 4: 1. At these conditions, the extraction yields of La(III) and Ce(III) were 72% and 89%, respectively. A two-step solvent extraction was developed to achieve a high purity of RE mixture, which included (1) the removal of impurity Fe by 25% (v/v) diisooctyl phosphinic acid (DiOPA) in n-octane for 140 min, (2) the extraction of rare earths by a mixture of di-2-ethylhexyl phosphoric acid (D2EHPA) and tributyl phosphate (TBP) in n-octane for 10 min without the need for adjusting the pH of the leaching solution. 相似文献