Photovoltaics and hydrogen: Future energy options

Solar power is destined to make a significant contribution to world energy supply for reasons of both the finite amount of fossil fuels and environmental damage consciousness. It is emphasized that the global environmental damage caused thermodynamically is more alarming to life on Earth than the risk of exhausting the finite amount of fossil fuels being consumed at the present rate. Solar power plants can be designed and constructed to convert solar radiation into some concentrated form of useful energy first and then into electricity or directly into electricity. The latter kind is comprised of photovoltaic cells. This paper discusses some of the solar energy options and also presents a historical overview, explains the rudimentary physical principles of the technology, the photovoltaic effect, the process to generate electricity in silicon solar cells, thin-film devices and high efficiency cells, and finally, the state-of-the-art of the latest developments in solar cell technology. Finally, the storing of solar energy, collected by a photovoltaic system, is recommended in the form of hydrogen as a future energy option.     

Estimation of the energetic and environmental impacts of a roof-mounted building-integrated photovoltaic systems

The production of electricity from renewable sources plays a strategic role in the future of energy because it helps to effectively manage climate change through an energy generation portfolio with lower emissions of greenhouse gases.Photovoltaic solar energy is safe and sustainable and is characterised by a growing trend with a cumulative installed capacity that has reached a total of 40 GW in 2010.In this paper, investigations are presented using multiple calculations: Energy Payback Time (EPBT), Greenhouse Gas per kilowatt hour (GHG/kWh), Energy Return on Investment (EROI), Greenhouse Gas Payback Time (GPBT) and Greenhouse Gas Return on Investment (GROI). These metrics make it possible to define the energy and environmental performances for a building-integrated photovoltaic system located in Italy.The module efficiency, the embodied energy and the annual solar irradiance are variables that play a strong role in this analysis. The key parameters include the type of solar cells (e.g., mono-crystalline silicon, polycrystalline silicon, amorphous silicon, cadmium telluride) and the location where the system is installed (Milan, Rome and Palermo).The results determine whether solar energy has a viable strategic role in the global energy market.     

Texturing,reflectivity, diffuse scattering and light trapping in silicon solar cells

Energy conversion efficiency is a critical consideration in the application of silicon solar cells. Texturing of both the front side and the backside of silicon solar cells has been used in the past to increase the absorption of infrared sun light energy in silicon solar cells. A review is given of some of the basic concepts and then a design described for the optimal textured structure that can result in improvements in conversion efficiency of up to 20% on crystalline silicon solar cells and up to 40% on thin film silicon solar cells. Some of the practical limitations are described in realizing these structures in silicon technology.     

Material constraints for thin-film solar cells

Harnessing solar energy by using photovoltaic cells has the potential to become a major CO₂-free energy source. Materials requirements for the solar cells based on four types of thin-film photovoltaics have been estimated and compared with global reserves, resources and annual refining. The use of solar cells based on Cd, Ga, Ge, In, Ru, Se and Te as a major energy-supply technology has severe resource constraints. Other systems such as a-Si without Ge and crystalline silicon do not involve such constraints. For some of these metals, there is the risk of enhanced, environmentally deleterious concentrations in the ecosphere due to leakage from manufacturing, use or waste handling.     

A new energy efficient, environment friendly and high productive texturization process of industrial multicrystalline silicon solar cells

A new texturization process based on a uniform, isotropic and slow removal of silicon, using a composition of sodium hydroxide (NaOH) and sodium hypochlorite (NaOCl) solution at an elevated temperature is developed recently for multicrystalline silicon solar cells. This process is applied in optimized condition in regular industrial production line and it immediately replaces the old popular industrial process of texturization using a combination of NaOH solution, alcoholic NaOH solution and hydrochloric acid solution in different steps at a higher temperature. Also the gain in solar cell efficiency at global AM1.5 spectrum, 1 SUN intensity condition is nearly 10% in final value. In addition, it has become finally an energy efficient and environment friendly texturization process for large area multicrystalline silicon solar cells for commercial use. In this paper the cost effectiveness and environment friendly aspects of the proposed process have been studied in detail along with the surface texture analysis of wafers with SEM and AFM micrographs to substantiate the reasons behind the above facts.     

非晶硅太阳能光伏/光热空气集热器性能对比实验研究

文章设计了新型非晶硅太阳能PV/T空气集热器,该空气集热器能够解决传统太阳能PV/T热水器在高温波动情况下,晶硅电池热应力大的问题,同时避免了冬季管道发生霜冻的现象。文章通过实验对比,分析了非晶硅太阳能PV/T空气集热器、单独非晶硅光伏电池和传统太阳能空气集热器的能量效率和[火用]效率的差异。分析结果表明:非晶硅太阳能PV/T空气集热器的平均热效率为45.70%,比传统太阳能空气集热器的平均热效率降低了约25.88%;当空气质量流量增大至0.048 kg/s时,非晶硅太阳能PV/T空气集热器中的非晶硅光伏电池的平均电效率高于单独非晶硅光伏电池,它们的平均电效率分别为4.70%,4.54%;非晶硅太阳能PV/T空气集热器的总[火用]效率高于传统太阳能空气集热器的热[火用]效率和单独非晶硅光伏电池的电[火用]效率,非晶硅太阳能PV/T空气集热器总[火用]效率最大值为7.14%。文章的分析结果为非晶硅太阳能PV/T空气集热器的推广提供了参考。     

Direct energy conversion: An attractive option for developing countries

Solar energy will play a key role in direct energy conversion. The conversion efficiencies of a variety of silicon and GaAs solar cells are described. A cost comparison of silicon and GaAs hybrid solar systems shows current average costs of 4.4 ¢ and 6.75 ¢ per kWh in the U.S.A. and 11 ¢ per kWh in Nigeria.

A brief account of current developments and future prospects is given for integrated tandem solar cells (ITSC) and for electrochemical solar cells.     

Modifying the solar spectrum to enhance silicon solar cell efficiency—An overview of available materials

There are three ways in which the cell efficiency of silicon solar cells may be improved by better exploitation of the solar spectrum: down-conversion (cutting one high energy photon into two low energy photons), photoluminescence (shifting photons into wavelength regions better accepted by the solar cell) and up-conversion (combining low energy photons to one high energy photon). In this paper, we present the state of the art of these three methods and discuss the suitability of materials available today for application to silicon solar cells.     

Experimental analysis of upconversion with both coherent monochromatic irradiation and broad spectrum illumination

Upconversion of sub-band-gap photons promises to increase solar cell efficiencies by making these photons useful. In this paper, we investigate the application of β-NaYF₄:20% Er³⁺ to silicon solar cells. We determine the external quantum efficiency of an upconverter silicon solar cell, both under monochromatic excitation and, for the first time in the context of silicon solar cells, under broad spectrum illumination as it is relevant for the application to harvest solar energy. The investigated upconverter silicon solar cell responds under broad spectrum illumination with an average upconversion efficiency of 1.07±0.13% in the spectral range from 1460 to 1600 nm. The resulting efficiency increase for the used solar cell with an overall efficiency of 16.7% is calculated to be 0.014% relative.     

V-trough concentrator on a photovoltaic full tracking system in a hot desert climate

A V-trough concentrator with a two-axis tracker system to increase the performance of photovoltaics was designed by the authors and installed on the roof-top of the building of the National Research Institute of Astronomy and Geophysics at Helwan in South Cairo. The V-trough concentrator system comprises two flat mirrors with dimensions 50 cm × 18 cm. They are fixed with the reflecting surfaces facing each other with a separation of about 11 cm, on a wooden table of 50 cm axis length. A sample of polycrystalline and amorphous silicon solar cells were fixed into the system, and similar solar cells of each type were fixed separate to the system, to estimate the electrical gain. The measurements were performed daily at different air masses for one complete year. The temperature of the solar cells in and out of the system were measured for comparison. Also, measurements for beam and global solar radiation and other meteorological conditions were recorded. The optical losses of the system were analyzed and details of collectable energy calculations are presented. The energy gain from the isolated contribution of the V-trough concentrators is also evaluated.     

Thin-film silicon solar cells: A review and selected trends

A case is developed for considering silicon as the prime medium-term candidate for semiconductor photovoltaic cells; the argumentation is based on other materials not being abundantly available, highly toxic and/or very expensive. Crystalline silicon solar cells have excellent efficiencies, however, according to data presented by the authors on material fluxes and energy consumption there are serious bottlenecks for this technique with respect to future large-scale applications both from an economical as well as from an ecological point of view. Thus, the authors consider thin-film silicon solar cells as the main option for large-scale energy applications in the foreseeable future. Thin-film silicon solar cells are either polycrystalline or amorphous. The first category is gaining in interest at this moment, but major technological problems remain unresolved, e.g., growth of a high-quality crystalline structure on foreign (low-cost) substrates, reduction of deposition temperature and increase of deposition rate. The second category has so far yielded only limited stable efficiencies, although progress has been recently achieved in improving the stability of solar cells using stacked or tandem/triple structures. Novel approaches to further improve the stable efficiencies, such as using low-level doping profiles within the i-layer of the p-i-n solar cell, are listed. Entirely microcrystalline p-i-n solar cells that are stable and can be deposited at low temperatures (220° C) with rates up to 1 å/s by the VHF plasma deposition technique are described as further, recent contribution to thin-film silicon photovoltaic technology.     

Output variation of photovoltaic modules with environmental factors—I. The effect of spectral solar radiation on photovoltaic module output

In this study, it was investigated how changes in spectral solar radiation effects the output of photovoltaic modules. First, there was a precise examination of the seasonal changes in spectral solar radiation. Consequently, it was found that the ratio of spectral solar radiation available for solar cell utilization, to global solar radiation, changes from season to season. It varied, from 5% for polycrystalline silicon cells, to 14% for amorphous silicon cells, throughout one year. Obviously a cell made from amorphous silicon is more severely effected by seasonal variations.

Next, the seasonal changes of photovoltaic module output were examined. The output was calculated by the conventional output evaluation method using irradiance and cell temperature. This calculated value and the subsequently measured value were accumulated and the two values compared. As a result, the accumulated output of photovoltaic modules was confirmed as changing seasonally in the same way as spectral solar radiation. The output ratio of polycrystalline silicon was found to change by 4%, while that of amorphous silicon varied by 20%. Hence the seasonal variations in spectral solar radiation should be taken into account for optimum photovoltaic power system design.     

Commercial white paint as back surface reflector for thin-film solar cells

In this work, commercially available white paint is applied as a pigmented diffuse reflector (PDR) on the rear surface of thin-film crystalline silicon (c-Si) solar cells with a silicon thickness in the 1–2 μm range. We show that white paint increases the short-circuit current density of the solar cells enormously, with a boost of 41% observed for very thin planar solar cells illuminated with the global AM1.5 solar spectrum. We also show that white paint is a better back surface reflector (BSR) than aluminium, air, a transparent conductive oxide (TCO)/aluminium stack, and even a detached aluminium mirror. While previous studies have investigated the influence of PDRs on silicon solar cells with thicknesses of over 27 μm, this work closes the gap that has existed for much thinner cells.     

Annual available radiation for fixed and tracking collectors

Single crystal silicon solar cells are potential elements of large scale solar energy conversion systems. Current costs of these cells are too high at least in part because current production methods require single crystal wafers obtained by slicing cylindrical single crystal ingots. This paper reviews a U.S. research program aimed at reducing the cost of silicon cells by developing new methods of growing silicon ribbons and sheets from which high efficiency solar cells can be fabricated. The paper also describes novel techniques for lower cost processes for ingot growth and wafer slicing which are included in this research and development program.     

Development of low-cost silicon crystal growth techniques for terrestrial photovoltaic solar energy conversion

Single crystal silicon solar cells are potential elements of large scale solar energy conversion systems. Current costs of these cells are too high at least in part because current production methods require single crystal wafers obtained by slicing cylindrical single crystal ingots. This paper reviews a U.S. research program aimed at reducing the cost of silicon cells by developing new methods of growing silicon ribbons and sheets from which high efficiency solar cells can be fabricated. The paper also describes novel techniques for lower cost processes for ingot growth and wafer slicing which are included in this research and development program.     

Study of the photon down‐conversion effect produced by thin silicon‐rich oxide films on silicon solar cells

In the present work, we studied the photon down‐conversion effect produced by thin films of silicon oxide with embedded silicon nanocrystals also called silicon‐rich oxide (SRO). These films have been used to absorb high energy light and the re‐emission of two or more low energy photons (~1.1 eV) with the goal of improving the external quantum efficiency and consequently the conversion efficiency of silicon solar cells. According to our results, the incorporation of a thin SRO film on the solar cell surface increases the short circuit current and the FF of the silicon solar cells; the enhancement of spectral response is due to the high photoluminescence intensity of the SRO in the visible region when irradiated with UV light. An improvement of 38% in the solar cell efficiency has been observed in our particular solar cell fabrication process by the use of an SRO film with high photoluminescence intensity, which replaces the conventional silicon dioxide film. Copyright © 2016 John Wiley & Sons, Ltd.     

Role of hydrazine monohydrate during texturization of large-area crystalline silicon solar cell fabrication

Reduction of optical losses in monocrystalline silicon solar cells by surface texturing is one of the important issues of modern silicon photovoltaic. For texturization during commercial monocrystalline silicon solar cell fabrication, a mixture of NaOH or KOH and isopropyl alcohol (IPA) is generally used in order to achieve good uniformity of pyramidal structure on the silicon surface. The interfacial energy between silicon and electrolyte should be reduced in order to achieve sufficient wettability for the silicon surface which in turn will enhance the pyramid nucleation. In this work, we have investigated the role of hydrazine monohydrate as a surface-active additive, which supplies OH⁻ ions after dissociation. This cuts down the IPA consumption during texturing without any loss of uniformity of textured pyramid. We are probably the first group to report such a novel idea of using hydrazine monohydrate addition in NaOH solution for texturization of solar cell. We were able to fabricate monocrystalline silicon solar cells with more than 85% yield in the range of 14–15% efficiency.     

整形激光掺杂制备PERC电池选择性发射极研究

研究整形激光掺杂制备选择性发射极(SE)对p型单晶硅钝化发射极局域背接触(PERC)太阳电池的表面金字塔形貌、掺杂分布及电池性能的影响。整形激光具有能量分布均匀、对硅片损伤小等优点。通过改变激光的功率以及激光划线速度在p型单晶硅PERC太阳电池制备了不同掺杂分布的发射极。结合3D激光显微镜、扫描电子显微镜、EDS能谱分析、四探针方阻测试仪、电化学电容法等测试分析方法表征了样品的表面形貌、方阻变化、掺杂浓度曲线和电学性能。本文结合光斑重叠率将不同激光功率和激光划线速度采用公式统一转化为激光能量密度,从而得出制备选择性发射极的最佳激光能量密度。研究结果表明,当激光能量密度为0.97 J/cm2时,电池效率可以稳定提升0.25%以上,体现了整形激光SE技术应用于PERC电池的应用潜力。     

A new strategy for the fabrication of cost-effective silicon solar cells

Fabrication of solar cells with very high efficiencies currently requires extremely complex processing. In order to make photovoltaics an economical large scale source of energy, very high efficiencies have to be achieved by low-cost processing. The innovative approach for the cost-effective production of highly efficient silicon solar cells presented in this paper is characterised by only four simple and environmentally safe large-area fabrication steps. The basic processing sequence consists of: (i) mechanical surface grooving, (ii) simple diffusion or inversion, (iii) shallow angle metal evaporation, and (iv) plasma silicon nitride deposition. Cell design, fabrication techniques and processing sequences for metal-insulator-semiconductor contacted diffused n⁺-p junction (MIS-n⁺p) and MIS-inversion-layer (MIS-IL) silicon solar cells are outlined. The new simple approach turned out to be most successful, as demonstrated by mechanically grooved MIS-n⁺p silicon solar cells with efficiencies above 21% using exclusively aluminium as metallisation.     

China’s photovoltaic industry policy performance from the perspective of global value chain

China’s solar energy capacity has enhanced significantly over the past two decades, and this source of energy is playing increasingly vital role in China’s power generation. This study first explained the mechanism of the global value chain and its uses, and then a photovoltaic (PV) system was investigated. We also studied China’s potential and economic viability of solar photovoltaic power, because the most significant problem solar PV systems is currently facing is to finance and find an investor to carry out the projects. It was found that the cost of manufacturing and purifying silicon in all solar panel producers (USA, China, Taiwan, and Malaysia) is nearly equal, because silicon is found to be abundant in all countries, and its purification method (polycrystalline method) is almost similar in all four countries.