Roll‐to‐roll gravure printing of organic photovoltaic modules—insulation of processing defects by an interfacial layer

Gravure printing as direct patterning roll‐to‐roll (R2R) production technology can revolutionize the design of thin‐film organic photovoltaic (OPV) devices by allowing feasible manufacturing of arbitrary‐shaped modules. This makes a distinction to coating methods, such as slot die coating, in which the pattern is limited to continuous stripes. Here, we analyze the thin‐film formation and its influence on OPV module performance as the gravure printing of hole transport and photoactive layers are transferred from laboratory to R2R pilot production environment. Insertion of a 0.8‐nm layer of lithium fluoride (LiF) as an interfacial layer between the active layer and the electron contact provided insulation against the detrimental pinholes formed in the R2R printing process. Using this device configuration, we produced well‐performing R2R‐printed monolithic modules with a mean efficiency of 1.7%. In comparison, reference modules with an efficiency of 2.2% were fabricated using laboratory‐scale bench top sheet‐level process. Surface energy and tension measurements together with optical microscopy were used to analyze the printability of the materials. The pinhole insulation was investigated in detail by processing R2R‐printed OPV modules with different interfacial layer materials and performing electrical measurements under dark and AM1.5 illumination conditions. Furthermore, we analyzed the LiF distribution using X‐ray photoelectron spectroscopy. The insulating nature of the LiF layer to improve module performance was confirmed by manufacturing lithographically artificial pinholes in device structures. The results show the possibility to loosen the production environment constraints and the feasibility of fabricating well‐performing thin‐film devices by R2R gravure printing. Copyright © 2014 John Wiley & Sons, Ltd.     

Humidity‐Tolerant Roll‐to‐Roll Fabrication of Perovskite Solar Cells via Polymer‐Additive‐Assisted Hot Slot Die Deposition

Heating‐assisted deposition is an industry‐friendly scalable deposition method. This manufacturing method is employed together with slot die coating to fabricate perovskite solar cells via a roll‐to‐roll process. The feasibility of the method is demonstrated after initial testing on a rigid substrate using a benchtop slot die coater in air. The fabricated solar cells exhibit power conversion efficiencies (PCEs) up to 14.7%. A nonelectroactive polymer additive is used with the perovskite formulation and found to improve its humidity tolerance significantly. These deposition parameters are also used in the roll‐to‐roll setup. The perovskite layer and other solution‐processed layers are slot die‐coated, and the fabricated device shows PCEs up to 11.7%, which is the highest efficiency obtained from a fully roll‐to‐roll processed perovskite solar cell to date.     

A new class of multi‐bandgap high‐efficiency photovoltaics enabled by broadband diffractive optics

A semiconductor absorber with a single bandgap is unable to convert broadband sunlight into electricity efficiently. Photons with energy lower than the bandgap are not absorbed, whereas those with energy far higher than the bandgap lose energy via thermalization. In this Article, we demonstrate an approach to mitigate these losses via a thin, efficient broadband diffractive micro‐structured optic that not only spectrally separates incident light but also concentrates it onto multiple laterally separated single‐junction semiconductor absorbers. A fully integrated optoelectronic device model was applied in conjunction with a nonlinear optimization algorithm to design the optic. An experimental demonstration is presented for a dual‐bandgap design using GaInP and GaAs solar cells, where a 20% increase in the total electric power is measured compared with the same cells without the diffractive optic. Finally, we demonstrate that this framework of broadband diffractive optics allows us to independently design for the number of spectral bands and geometric concentration, thereby enabling a new class of multi‐bandgap photovoltaic devices with ultra‐high energy conversion efficiencies. Copyright © 2014 John Wiley & Sons, Ltd.     

New Roll‐to‐Roll Processable PEDOT‐Based Polymer with Colorless Bleached State for Flexible Electrochromic Devices

Conjugated electrochromic (EC) polymers for flexible EC devices (ECDs) generally lack a fully colorless bleached state. A strategy to overcome this drawback is the implementation of a new sidechain‐modified poly(3,4‐ethylene dioxythiophene) derivative that can be deposited in thin‐film form in a customized high‐throughput and large‐area roll‐to‐roll polymerization process. The sidechain modification provides enhanced EC properties in terms of visible light transmittance change, Δτ_v = 59% (ΔL* = 54.1), contrast ratio (CR = 15.8), coloration efficiency (η = 530 cm² C^?1), and color neutrality (L* = 83.8, a* = ?4.3, b* = ?4.1) in the bleached state. The intense blue‐colored polymer thin films exhibit high cycle stability (10 000 cycles) and fast response times. The design, synthesis, and polymerization of the modified 3,4‐ethylene dioxythiophene derivative are discussed along with a detailed optical, electrochemical, and spectroelectrochemical characterization of the resulting EC thin films. Finally, a flexible see‐through ECD with a visible light transmittance change of Δτ_v = 47% (ΔL* = 51.9) and a neutral‐colored bleached state is developed.     

Synergistic Roll‐to‐Roll Transfer and Doping of CVD‐Graphene Using Parylene for Ambient‐Stable and Ultra‐Lightweight Photovoltaics

A roll‐to‐roll (R2R) transfer technique is employed to improve the electrical properties of transferred graphene on flexible substrates using parylene as an interfacial layer. A layer of parylene is deposited on graphene/copper (Cu) foils grown by chemical vapor deposition and are laminated onto ethylene vinyl acetate (EVA)/poly(ethylene terephthalate). Then, the samples are delaminated from the Cu using an electrochemical transfer process, resulting in flexible and conductive substrates with sheet resistances of below 300 Ω sq^?1, which is significantly better (fourfold) than the sample transferred by R2R without parylene (1200 Ω sq^?1). The characterization results indicate that parylene C and D dope graphene due to the presence of chlorine atoms in their structure, resulting in higher carrier density and thus lower sheet resistance. Density functional theory calculations reveal that the binding energy between parylene and graphene is stronger than that of EVA and graphene, which may lead to less tear in graphene during the R2R transfer. Finally, organic solar cells are fabricated on the ultrathin and flexible parylene/graphene substrates and an ultra‐lightweight device is achieved with a power conversion efficiency of 5.86%. Additionally, the device shows a high power per weight of 6.46 W g^?1 with superior air stability.     

High Performance Roll‐to‐Roll Produced Fullerene‐Free Organic Photovoltaic Devices via Temperature‐Controlled Slot Die Coating

Solution‐processed organic photovoltaics (OPVs) have continued to show their potential as a low‐cost power generation technology; however, there has been a significant gap between device efficiencies fabricated with lab‐scale techniques—i.e., spin coating—and scalable deposition methods. Herein, temperature‐controlled slot die deposition is developed for the photoactive layer of OPVs. The influence of solution and substrate temperatures on photoactive films and their effects on power conversion efficiency (PCE) in slot die coated OPVs using a 3D printer‐based slot die coater are studied on the basis of device performance, molecular structure, film morphology, and carrier transport behavior. These studies clearly demonstrate that both substrate and solution temperatures during slot die coating can influence device performance, and the combination of hot substrate (120 °C) and hot solution (90 °C) conditions result in mechanically robust films with PCE values up to 10.0% using this scalable deposition method in air. The efficiency is close to that of state‐of‐the‐art devices fabricated by spin coating. The deposition condition is translated to roll‐to‐roll processing without further modification and results in flexible OPVs with PCE values above 7%. The results underscore the promising potential of temperature‐controlled slot die coating for roll‐to‐roll manufacturing of high performance OPVs.     

Experimental demonstration of high‐concentration photovoltaics on a parabolic trough using tracking secondary optics

A new approach to high‐concentration photovoltaics (HCPV) based on a parabolic trough primary concentrator is presented. The design diverges from the standard HCPV arrangement of a two‐axis tracking point‐focus concentrator, and rather employs a simpler parabolic trough primary concentrator to reduce cost. To break the 2D limit of concentration, and bring the system into the realm of HCPV, the system employs an array of rotating secondary concentrators is arranged along the focal line of the parabolic trough. The resulting line‐to‐point (LTP) focus geometry allows the system to achieve a geometric concentration of 590×, yet still maintains the advantages of having a linear trough primary concentrator, namely manufacturability, economy, and scalability. A full‐scale prototype of the system was constructed in Biasca, Switzerland. During on‐sun tests a flux concentration of 364 suns was measured at the exit of the secondary concentrator, the highest reported concentration for any parabolic‐trough‐based system. Moreover, the system reached a peak efficiency of 20.2%, the highest measured solar‐to‐DC efficiency for a parabolic trough‐based solar collector. Long‐term performance is estimated by means of a coupled optical‐electrical model validated vis‐à‐vis the experimental results. This work serves as an experimental proof‐of‐concept for high‐concentration trough‐based collectors, thereby opening new avenues for reducing the cost of HCPV systems. Copyright © 2016 John Wiley & Sons, Ltd.     

Roll‐to‐Roll Printed Silver Nanowire Semitransparent Electrodes for Fully Ambient Solution‐Processed Tandem Polymer Solar Cells

Silver nanowires (AgNWs) and zinc oxide (ZnO) are deposited on flexible substrates using fast roll‐to‐roll (R2R) processing. The AgNW film on polyethylene terephthalate (PET) shows >80% uniform optical transmission in the range of 550–900 nm. This electrode is compared to the previously reported and currently widely produced indium‐tin‐oxide (ITO) replacement comprising polyethylene terephthalate (PET)|silver grid|poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS)|ZnO known as Flextrode. The AgNW/ZnO electrode shows higher transmission than Flextrode above 490 nm in the electromagnetic spectrum reaching up to 40% increased transmission at 750 nm in comparison to Flextrode. The functionality of AgNW electrodes is demonstrated in single and tandem polymer solar cells and compared with parallel devices on traditional Flextrode. All layers, apart from the semitransparent electrodes which are large‐scale R2R produced, are fabricated in ambient conditions on a laboratory roll‐coater using printing and coating methods which are directly transferrable to large‐scale R2R processing upon availability of materials. In a single cell structure, Flextrode is preferable with active layers based on poly‐3‐hexylthiophene(P3HT):phenyl‐C61‐butyric acid methylester (PCBM) and donor polymers of similar absorption characteristics while AgNW/ZnO electrodes are more compatible with low band gap polymer‐based single cells. In tandem devices, AgNW/ZnO is more preferable resulting in up to 80% improvement in PCE compared to parallel devices on Flextrode.     

Anodized Aluminum Oxide/Polydimethylsiloxane Hybrid Mold for Roll‐to‐Roll Nanoimprinting

Two types (hard and soft) of the molds are widely used in nanoimprint lithography for a high throughput over a large area, and high‐resolution parallel patterning. Although hard molds have proven excellent resolutions and can be used at high temperatures, cracks often occur in the mold in addition to the requirement of high imprinting pressure. On the other hand, though soft molds can operate at lower pressures, they give poor pattern resolution. Here, a novel hybrid mold of anodized aluminum oxide (AAO) template attached to a flexible polydimethylsiloxane (PDMS) plate is introduced. Due to the flexible nature of PDMS, various polymer nanostructures are obtained on flat and curved substrates without crack formation on the AAO mold surface. Furthermore, the hybrid mold is successfully used for roll‐to‐roll imprinting for the fabrication of high density array of various shaped polymeric nanostructures over a large area.     

A monolithically integrated high‐efficiency Cu(In,Ga)Se2 mini‐module structured solely by laser

Monolithically integrated Cu(In,Ga)Se₂ mini‐modules were fabricated in order to reduce the width of patterning related dead area. The Cu(In,Ga)Se₂ layers were prepared on soda‐lime glasses using the multistage process at low substrate temperature below 500 °C. A picosecond laser with a wavelength of 532 nm was used for all of the structuring processes (P1, P2, and P3) for the monolithic integration. A “lift‐off” type structuring was applied for P1 and P3, and an “ablation” type was for P2. The laser structuring was optimized to be minimizing the dead area width, and the width of about 70 µm was successfully achieved. A mini‐module, in which the optimized structuring processes were applied for the integration, demonstrated a certified efficiency of 16.6%. Copyright © 2015 John Wiley & Sons, Ltd.     

A slot‐based BS scheduling with maximum latency guarantee and capacity first in 802.16e networks

The IEEE 802.16e standard specifies the QoS support at the MAC level for wireless broadband access network. To meet the QoS requirements, an efficient scheduling algorithm at base station (BS), which is not defined in the standard, is necessary for slots allocation. In this paper, a Slot‐based BS scheduling algorithm with Maximum Latency Guarantee and Capacity First (SMLG‐CF) is proposed. With SMLG‐CF, the connection request is satisfied with highest slot capacity first. Together with the use of dynamic sub‐frame adjustment, the overall system transmission can be efficiently improved. Through the finer slots calculation and accurate transmission time scheduling, the maximum latency guarantee can be better achieved for urgent requests. In the simulation, we compare the proposed mechanism with the deficit fair priority queue scheduling algorithm and the Highest Urgency First scheduling algorithm. The simulation results reveal that SMLG‐CF outperforms both algorithms from the aspect of maximum latency violation rate and average transmission rate. Copyright © 2011 John Wiley & Sons, Ltd.     

Cu2ZnSnS4 photovoltaic cell with improved efficiency fabricated by high‐temperature annealing after CdS buffer‐layer deposition

To improve the photovoltaic properties of Cu₂ZnSnS₄ (CZTS) cells, we investigated the effect of both the thickness of the deposited CdS layers and the post‐annealing temperature following CdS deposition on the photovoltaic properties of CZTS cells using a two‐layer CZTS structure. By depositing a thin CdS layer (40 nm) followed by high temperature annealing (603 K), we observed a remarkable increase in the short‐circuit current density because of the enhancement of the external quantum efficiency in the wavelength range of 400–800 nm. The best CZTS cell exhibited a conversion efficiency of 9.4% in the active area (9.1% in the designated area). In addition, we also fabricated a CZTS cell with open‐circuit voltage of 0.80 V by appropriately tuning the composition of the CZTS layers. Copyright © 2016 John Wiley & Sons, Ltd.     

A reconstructing approach to end‐to‐end network traffic based on multifractal wavelet model

This paper studies the reconstructing method of end‐to‐end network traffic. Due to the development of current communication networks, our networks become more complex and heterogeneous. Meanwhile, because of time‐varying nature and spatio‐temporal correlations of the end‐to‐end network traffic, to obtain it accurately is a great challenge. We propose to exploit discrete wavelet transforms and multifractal analysis to reconstruct the end‐to‐end network traffic from time–frequency domain. First, its time–frequency properties can be characterized in detail by discrete wavelet transforms. And then, we combine discrete wavelet transforms and multifractal analysis to reconstruct end‐to‐end network traffic from link loads. Furthermore, our method needs to measure end‐to‐end network traffic to build the statistical model named multifractal wavelet model. Finally, simulation results from the real backbone networks suggest that our method can reconstruct the end‐to‐end network traffic more accurately than previous methods. Copyright © 2013 John Wiley & Sons, Ltd.     

A location‐aware peer‐to‐peer overlay network

This work describes a novel location‐aware, self‐organizing, fault‐tolerant peer‐to‐peer (P2P) overlay network, referred to as Laptop. Network locality‐aware considerations are a very important metric for designing a P2P overlay network. Several network proximity schemes have been proposed to enhance the routing efficiency of existing DHT‐based overlay networks. However, these schemes have some drawbacks such as high overlay network and routing table maintenance overhead, or not being completely self‐organizing. As a result, they may result in poor scalability as the number of nodes in the system grows. Laptop constructs a location‐aware overlay network without pre‐determined landmarks and adopts a routing cache scheme to avoid maintaining the routing table periodically. In addition, Laptop significantly reduces the overlay maintenance overhead by making each node maintain only the connectivity between parent and itself. Mathematical analysis and simulations are conducted to evaluate the efficiency, scalability, and robustness of Laptop. Our mathematical analysis shows that the routing path length is bounded by log_d N, and the joining and leaving overhead is bounded by d log_d N, where N is the number of nodes in the system, and d is the maximum degree of each node on the overlay tree. Our simulation results show that the average latency stretch is 1.6 and the average routing path length is only about three in 10 000 Laptop nodes, and the maximum degree of a node is bounded by 32. Copyright © 2006 John Wiley & Sons, Ltd.     

Development and Manufacture of Polymer‐Based Electrochromic Devices

The field of organic electrochromics is reviewed here, with particular focus on how the “electrochromic” as a functional material can be brought from the current level of accurate laboratory synthesis and characterization to the device and application level through a number of suited roll‐to‐roll methods compatible with upscaling and manufacture. The successful approaches to operational devices are presented in detail, as well as areas where future research would have a high impact and accelerate the development such as highly conducting and transparent substrates, electrolytes adapted for multilayer application and morphologically stable conjugated polymers.     

Energy efficiency optimization for device‐to‐device communication underlaying cellular networks in millimeter‐wave

This paper studies energy efficiency maximization in device‐to‐device (D2D) communications underlaying cellular networks in millimeter‐wave (mm‐wave) band. A stochastic geometry framework has been used to extract the results. First, cellular and D2D users are modeled by independent homogeneous Poisson point process; then, exact expressions for successful transmission probability of D2D and cellular users have been derived. Furthermore, the average sum rate and energy efficiency for a typical D2D scenario have been presented. An optimization problem subject to transmission power and quality of service constraints for both cellular and D2D users has been defined, and energy efficiency of D2D communication is maximized. Simulation results reveal that by working in millimeter‐wave, significant energy efficiency improvement can be attained, e.g., 20% energy efficiency improvement compared with Rayleigh distribution in the practical scenarios by considering circuit power. Finally, to verify our analytical expressions, the simulation studies are carried out, and the excellent agreements have been achieved.     

Service‐oriented 5G network architecture: an end‐to‐end software defining approach

With the ever‐increasing mobile demands and proliferation of mobile services, mobile Internet has penetrated into every aspect of human life. Although the 4G mobile communication system is now being deployed worldwide, simply evolving or incrementally improving the current mobile networks can no longer keep the pace with the proliferation of mobile services. Against this background, aiming to achieve service‐oriented 5G mobile networks, this article proposes an end‐to‐end software defining architecture, which introduces a logically centralized control plane and dramatically simplifies the data‐plane. The control plane decomposes the diversified mobile service requirements and, correspondingly, controls the functions and behaviors of data‐plane devices. Consequently, the network directly orients towards services, and the devices are dynamically operated according to the service requirements. Therefore, the proposed architecture efficiently guarantees the end‐to‐end QoS and quality of experience. The challenges and key technologies of our architecture are also discussed in this article. Real traces‐based simulations validate the performance advantages of proposed architecture, including energy efficiency and the whole performance. Copyright © 2015 John Wiley & Sons, Ltd.     

End‐to‐end response time with fixed priority scheduling: trajectory approach versus holistic approach

In this paper, we are interested in providing deterministic end‐to‐end guarantees to real‐time flows in a distributed system. We focus on the end‐to‐end response time, quality of service (QoS) parameter of the utmost importance for such flows. We assume that each node uses a Fixed Priority scheduling. We determine a bound on the end‐to‐end response time of any real‐time flow with a worst case analysis using the trajectory approach. We establish new results that we compare with those provided by the classical holistic approach for flows visiting the same sequence of nodes. These results show that the trajectory approach is less pessimistic than the holistic one. Moreover, the bound provided by our worst‐case analysis is reached in various configurations, as shown in the examples presented. Copyright © 2004 John Wiley & Sons, Ltd.     

Toward high‐efficiency dye‐sensitized solar cells with a photoanode fabricated via a simple water‐based formulation

An aqueous formulation containing commercially available P25 nanoparticles and a water‐soluble precursor—titanium (IV) bis(ammonium lactato)dihydroxide (TALH) has been developed and optimized for fabricating photoanodes in dye‐sensitized solar cells. An optimal formulation achieved a power conversion efficiency of 9.2%. Solar cell performance is significantly influenced by precursor concentration impacting the porosity and electron transport of the thin film. The use of TALH during processing is shown to enhance the electron transport in the resulting titanium dioxide nanoparticle network using transient decay measurements. Bridging between neighboring nanoparticles is confirmed using transmission electron microscopy explaining the enhanced electron transport. The developed formulation has several advantages, as it is water‐based, composed of inexpensive, non‐hazardous components, is easy to make, and does not require special handling. The formulation has great potential for industrial applications, in particular for DSC manufacturing using roll‐to‐roll technology. Copyright © 2014 John Wiley & Sons, Ltd.