共查询到19条相似文献,搜索用时 78 毫秒
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在无水乙醇溶液中,以邻菲啰啉(Phen)、柠檬酸(H3Cit)为配体,合成了7种稀土三元固体配合物.通过元素分析、摩尔电导率测定、红外光谱和热重差热分析等手段确定配合物的组成为RE(Cit)·Phen·2H2O(RE=La3+,Pr3+,Nd3+,Sm3+, Eu3+,Tb3+,Dy3+). 相似文献
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在无水乙醇溶液中,以邻菲哆啉(Phen)、柠檬酸(H3Cit)为配体,合成了7种稀土三元固体配合物。通过元素分析、摩尔电导率测定、红外光谱和热重差热分析等手段确定配合物的组成为RE(Cit)·Phen·2H2O(RE=La^3+,Pr^3+,Nd^3+,Sm^3+,Eu^3+,Tb^3+,Dy^3+)。 相似文献
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在无水乙醇溶液中 ,以邻菲啉 ( Phen) ,水杨酸 ( HSal)为配体 ,合成了 7种稀土三元固体配合物。通过元素分析 ,红外光谱、紫外光谱、摩尔电导确定了配合物的化学组成为 RE( Phen) 2 ( Sal) 2 Cl· H2 O( RE=La3+ ,Nd3+ ,Sm3+ ,Eu3+ ,Gd3+ ,Tb3+ ,Dy3+ ) ,红外光谱表明稀土配合物中存在 RE— O和 RE— N配位键 相似文献
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合成了邻菲啰啉(Phen)-对苯二甲酸(p-Phtha)铜(Ⅱ)的混配配合物并获得晶体。X-射线单晶衍射、红外光谱分析表明该配合物组成为[Cu(Phen)2(p-Phtha)]·5H2O,晶体属单斜晶系,C2/C空间群,晶胞参数为:α=11.623(7)A,b=32.51(2)A,c=16.341(10)A,β=95.022(9)°,V=6150(7)A^3。Cu(Ⅱ)采取5配位方式,处于一个变形的四方锥配位环境中。 相似文献
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A novel fully conjugated polymer containing 1,10‐phenanthroline (DAPcDOD) was first synthesized by the polycondensation of 2,7‐dimethyl‐2,4,6‐octatriene‐1,8‐dial with 5,6‐diamine‐1,10‐phenanthroline. Three polymeric complexes were first prepared by the reaction of DAPcDOD with NiSO4, CoCl2, and FeSO4, respectively. The structures of the polymer and the complexes were characterized by IR, 1H‐NMR, and elemental analysis. The magnetic behaviors of these complexes were measured as a function of magnetic field strength (0–50 kOe) at 5 K and as a function of temperature (5–300 K) at a magnetic field strength of 30 kOe. The results show that DAPcDOD–Ni2+ and DAPcDOD–Co2+ were soft ferromagnets, whereas DAPcDOD–Fe2+ exhibited the features of an antiferromagnet. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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4-酰基吡唑啉酮配合物的合成方法与结构 总被引:3,自引:0,他引:3
综述了4-酰基吡唑啉酮及其配合物的合成方法和结构特征,介绍了非水溶剂法、水相合成法、固相合成法等合成方法适用的体系。分析评价了4-酰基吡唑啉酮以烯醇双氧、共轭双酮氧参与中心离子包含主族金属元素、副族金属元素、稀土金属元素等配位成键,形成6配位、8配位、单核、双核和多核配合物的结构关系。 相似文献
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《Inorganic chemistry communications》2007,10(4):404-406
Six new transition metal complexes (1–6) with Schiff base were synthesized and crystallographically characterized. Their urease inhibitory activities were evaluated. Three of them showed potent inhibitions against jack bean urease. Mn(II) complex (2) possessed the best jbU inhibitory activity with IC50 of 8.30 ± 0.93 μM, which was much better than those of the corresponding ligand and control ion. The investigation on the stability constants and the structure-activity relationships of the complexes indicated that the complexes interacted with the enzyme in the whole complex forms rather than the free ions. 相似文献
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A series of novel polymer‐supported mixed ligand complexes were synthesized and studied. Two percent divinyl benzene (DVB)‐crosslinked polystyrene supports were synthesized by the suspension copolymerization technique. An ethylene diamine group was anchored onto the support and the corresponding copper complexes were prepared. The ligating functions like phthalate, acetate, and oxalate groups were introduced, and mixed ligands complexes were synthesized. The resultant polymer supported mixed ligand complexes were characterized by UV‐Vis, IR, and EPR methods. The stability constants dictate the formation of these complexes on polymer support. Spectral results gave information about the structure, stability, and geometry of the mixed ligand complexes. These factors were discussed in detail. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2684–2690, 2003 相似文献
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Synthesis,characterization and molecular structure of Re(III) complexes containing 2-benzoylpyridine
The paper presents a combined experimental and computational study of Re(III) complexes containing 2-benzoylpyridine (bopy). Two novel complexes [ReX3(bopy)(PPh3)] (X = Cl, Br) have been obtained in the reactions of [ReX3(MeCN)(PPh3)2] with 2-benzoylpyridine in dichloromethane and have been studied by IR, UV–Vis spectroscopy and X-ray crystallography. The electronic structure of [ReCl3(bopy)(PPh3)] has been calculated with the density functional theory (DFT) method. The spin-allowed electronic transitions of [ReCl3(bopy)(PPh3)] have been calculated with the time-dependent DFT method and the UV–Vis spectrum has been discussed on this basis. 相似文献
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Guofu Zi Li Xiang Xue Liu Qiuwen Wang Haibin Song 《Inorganic chemistry communications》2010,13(3):445-448
The chiral biaryl-based N4-ligands, (R)-5,5′,6,6′,7,7′,8,8′-octahydro-2,2′-bis(pyrrol-2-ylmethyleneamino)-1,1′-binaphthyl (1H2) and (S)-2,2′-bis(pyrrol-2-ylmethyleneamino)-6,6′-dimethyl-1,1′-biphenyl (2H2), can effectively stabilize the chiral rare earth metal chloride complexes such as 1-YCl(dme) (3) and 2-YCl(dme) (4), which offers important intermediates for the preparation of chiral rare earth catalysts containing the M–C or M–X (X = heteroatom) bonds. For example, treatment of 3 with half equiv of 1Na2 in THF gives the binuclear complex 1-Y(thf)-1-Y(thf)-1 (5) in 70% yield. These complexes have been characterized by various spectroscopic techniques, elemental analyses, and X-ray diffraction analyses. The complex 5 is an active catalyst for the ring-opening polymerization of rac-lactide, affording isotactic-rich polylactides. 相似文献