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1.
INCONEL 718: A solidification diagram 总被引:2,自引:0,他引:2
G. A. Knorovsky M. J. Cieslak T. J. Headley A. D. Romig W. F. Hammetter 《Metallurgical and Materials Transactions A》1989,20(10):2149-2158
As part of a program studying weldability of Ni-base superalloys, results of an integrated analytical approach are used to
generate a constitution diagram for INCONEL 718* in the temperature range associated with solidification. Differential thermal analysis of wrought material and optical and
scanning electron microscopy, electron probe microanalysis, and analytical electron microscopy of gas tungsten arc welds are
used in conjunction with solidification theory to generate data points for this diagram. The important features of the diagram
are an austenite (γ)/Laves phase eutectic which occurs at ≈19.1 wt pct Nb between austenite containing ≈9.3 wt pct Nb and
a Laves phase which contains ≈22.4 wt pct Nb. The distribution coefficient for Nb was found to be ≈0.5. The solidification
sequence of INCONEL 718 was found to be (1) proeutectic γ, followed by (2) a γ/NbC eutectic at ≈1250°C, followed by (3) continued
γ solidification, followed by (4) a γ/Laves phase eutectic at ≈1200°C. An estimate of the volume fraction eutectic is made
using the Scheil solidification model, and the fraction of each phase in the eutectic is calculatedvia the lever rule. These are compared with experimentally determined values and found to be in good agreement. 相似文献
2.
A melting and solidification study of alloy 625 总被引:1,自引:0,他引:1
M. J. Cieslak T. J. Headley A. D. Romig T. Kollie 《Metallurgical and Materials Transactions A》1988,19(9):2319-2331
The melting and solidification behavior of Alloy 625 has been investigated with differential thermal analysis (DTA) and electron
microscopy. A two-level full-factorial set of chemistries involving the elements Nb, C, and Si was studied. DTA results revealed
that all alloying additions decreased the liquidus and solidus temperatures and also increased the melting temperature range.
Terminal solidification reactions were observed in the Nb-bearing alloys. Solidification microstructures in gastungsten-arc
welds were characterized with transmission electron microscopy (TEM) techniques. All alloys solidified to an austenitic (γ)
matrix. The Nb-bearing alloys terminated solidification by forming various combinations of γ/MC(NbC), γ/Laves, and γ/M6C eutectic-like constituents. Carbon additions (0.035 wt pct) promoted the formation of the γ/MC(NbC) constituent at the expense
of the γ/Laves constituent. Silicon (0.4 wt pct) increased the formation of the yJLaves constituent and promoted formation
of the γ/M6C carbide constituent at low levels (<0.01 wt pct) of carbon. When both Si (0.4 wt pct) and C (0.035 wt pct) were present,
the γ/MC(NbC) and γ/Laves constituents were observed. Regression analysis was used to develop equations for the liquidus and
solidus temperatures as functions of alloy composition. Partial derivatives of these equations taken with respect to the alloying
variables (Nb, C, Si) yielded the liquidus and solidus slopes t(m
L
, m
S
) for these elements in the multicomponent system. Ratios of these liquidus to solidus slopes gave estimates of the distribution
coefficients (k) for these same elements in Alloy 625. 相似文献
3.
J. N. DuPont M. R. Notis A. R. Marder C. V. Robino J. R. Michael 《Metallurgical and Materials Transactions A》1998,29(11):2785-2796
The solidification reaction sequences of experimental superalloys containing systematic variations in Fe, Nb, Si, and C were
studied using differential thermal analysis (DTA) and microstructural characterization techniques. The reaction sequences
responsible for microstructural development were found to be similar to those expected in the Ni-Nb-C ternary system and commercial
superalloys of comparable composition. The solute-rich interdendritic liquid generally exhibited two eutectic-type reactions
at the terminal stages of solidification: L → (γ+NbC) and L → (γ+Laves). The Ni-base alloys with a high C/Nb ratio represented the only exception to this general solidification sequence.
This group of alloys terminated solidification with the L → (γ + NbC) reaction and did not exhibit the γ/Laves constituent. At similar levels of solute elements (Nb, Si, and C), the Fe-base alloys always formed more of the γ/Laves eutectic-type constituent than the corresponding Ni-base alloys. Silicon additions also increased the amount of the
γ/Laves constituent that formed in the assolidified microstructure, while C additions promoted formation of γ/NbC. The influence of Nb was dependent on the C content of the alloy. When the C content was low, Nb additions generally
promoted formation of γ/Laves, while Nb additions to alloys with high C led to formation of the γ/NbC constituent. The results of this work are combined with quantitative analyses for developing γ-Nb-C pseudoternary solidification diagrams in a companion article. 相似文献
4.
M. J. Cieslak T. J. Headley G. A. Knorovsky A. D. Romig T. Kollie 《Metallurgical and Materials Transactions A》1990,21(1):479-488
The solidification behavior of two commercial aerospace superalloys, INCOLOY 909 and INCONEL 718, has been examined. Specifically,
differential thermal analysis (DTA) revealed that INCOLOY 909 terminates solidification with the formation of a single minor
constituent at ≈1198 °C. INCONEL 718 terminates solidification with the formation of two minor constituents, at ≈1257 °C and
~1185 °C, respectively. Metallography performed on the DTA samples confirmed that a single minor constituent was present in
INCOLOY 909 while two minor constituents were present in INCONEL 718. Differential thermal analysis samples were also examined
by electron probe microanalysis to reveal the patterns of elemental segregation. Arc welds of these alloys were examined by
transmission and analytical electron microscopy (TEM and AEM). It was observed that the arc welds of INCOLOY 909 contained
only a y/Laves eutectic-like constituent, while the arc welds of INCONEL 718 contained both y/Laves and γ/MC eutectic-like
constituents. Compositional analyses of these minor phases revealed that all were enriched in Nb relative to the bulk alloy.
The Laves phases were also enriched in Si relative to the bulk alloy concentration. Comparisons of the observed solidification
sequences in these alloys with other Nb-bearing austenitic matrix alloys are made. 相似文献
5.
M. J. Perricone J. N. Dupont T. D. Anderson C. V. Robino J. R. Michael 《Metallurgical and Materials Transactions A》2011,42(3):700-716
A series of 31 Mo-bearing stainless steel compositions with Mo contents ranging from 0 to 10 wt pct and exhibiting primary
δ-ferrite solidification were analyzed over a range of laser welding conditions to evaluate the effect of composition and cooling
rate on the solid-state transformation to γ-austenite. Alloys exhibiting this microstructural development sequence are of particular interest to the welding community
because of their reduced susceptibility to solidification cracking and the potential reduction of microsegregation (which
can affect corrosion resistance), all while harnessing the high toughness of γ-austenite. Alloys were created using the arc button melting process, and laser welds were prepared on each alloy at constant
power and travel speeds ranging from 4.2 to 42 mm/s. The cooling rates of these processes were estimated to range from 10 K
(°C)/s for arc buttons to 105 K (°C)/s for the fastest laser welds. No shift in solidification mode from primary δ-ferrite to primary γ-austenite was observed in the range of compositions or welding conditions studied. Metastable microstructural features were
observed in many laser weld fusion zones, as well as a massive transformation from δ-ferrite to γ-austenite. Evidence of epitaxial massive growth without nucleation was also found when intercellular γ-austenite was already present from a solidification reaction. The resulting single-phase γ-austenite in both cases exhibited a homogenous distribution of Mo, Cr, Ni, and Fe at nominal levels. 相似文献
6.
A. K. Abdul Jawwad M. Strangwood C. L. Davis 《Metallurgical and Materials Transactions A》2005,36(5):1237-1247
Detailed microstructural analysis, as well as fatigue crack initiation evaluation, was carried out for electron beam (EB)
welded IN-718. Fatigue test specimens were EB welded (full penetration) along their length, and a second weld pass, incorporating
a slope-out from full to zero penetration along the gage length, was also applied. The specimens were fatigue tested at 523
°C and maximum stress (R=0) in the range 579 to 820 MPa. Early fatigue failure (<100,000 cycles at 0.25 Hz) was directly associated with the initiation
at solidification porosity formed during “spiking” in the partial penetration weld metal at the start of the slope-out. The
base metal, full penetration weld metal, and slope-out region were characterized using optical microscopy, scanning electron
microscopy (SEM), and transmission electron microscopy (TEM), which indicated that the microstructures of the base metal and
full penetration weld metal should give good fatigue resistance. The rapid solidification of the full penetration weld metal
gave an interdendritic terminal solidification product consisting of γ+NbC+Laves phase instead of the usually reported eutectic γ+Laves phase. Microstructural and chemical heterogeneities in the full penetration weld metal, combined with the sharp perturbations
in penetration and solidification conditions (spiking) in the partial penetration weld metal, resulted in locally embrittled
regions and interdendritic regions containing large numbers of fine pores as well as a higher volume fraction of mixed, hard
interdendritic phases. These features would be consistent with a lower resistance to fatigue crack propagation in the partial
penetration weld metal. 相似文献
7.
8.
S. M. Seo J. H. Lee Y. S. Yoo C. Y. Jo H. Miyahara K. Ogi 《Metallurgical and Materials Transactions A》2011,42(10):3150-3159
The evolution of γ/γ′ eutectic during the solidification of Ni-base superalloys CMSX-10 and CMSX-4 was investigated over a wide range of cooling
rates. The microsegregation behavior during solidification was also quantitatively examined to clarify the influence of elemental
segregation on the evolution of γ/γ′ eutectic. In the cooling rate ranges investigated (0.9 to 138.4 K/min (0.9 to 138.4 °C/min)), the γ/γ′ eutectic fraction in CMSX-10 was found to be more than 2 times higher than that in CMSX-4 at a given cooling rate. However,
the dependence of the γ/γ′ eutectic fraction on the cooling rate in both alloys showed a similar tendency; i.e., the γ/γ′ eutectic fraction increased with increasing the cooling rate and then exhibited a maximum plateau at and above the certain
critical cooling rate in both alloys. This critical cooling rate was found to be dependent on the alloy composition and was
estimated to be about 12 K/min (12 °C/min) and 25 K/min (25 °C/min) for CMSX-10 and CMSX-4, respectively. The calculated solid
compositions based on the modified Scheil model revealed that even a small compositional difference of total γ′ forming elements in the initial composition of the alloy can play a significant role in the as-cast eutectic fraction during
the solidification of Ni-base superalloys. The evolution of the γ/γ′ eutectic fraction with respect to the cooling rate could be rationalized by taking into account the effects of back-diffusion
in solid and dendrite arm coarsening on decreasing the extent of microsegregation. 相似文献
9.
M. J. Cieslak J. J. Stephens M. J. Carr 《Metallurgical and Materials Transactions A》1988,19(3):657-667
The weldability and weld metal microstructure of Cabot Alloy 214 have been investigated with a variety of experimental and
analytical techniques. These include Varestraint hot crack testing, hot ductility testing, pulsed Nd:YAG laser welding, scanning
and analytical electron microscopy, electron microprobe analysis, and X-ray diffraction. A heat of Alloy 214 containing intentionally
alloyed B (0.003 wt pct) and Zr (0.07 wt pct) was much more sensitive to both fusion zone hot cracking as quantified by the
Varestraint test and to simulated heat-affected-zone (HAZ) cracking as quantified by hot ductility testing than a heat of
Alloy 214 containing no intentionally added B (0.0002 wt pct) or Zr (0.02 wt pct). Scanning electron microscopy of the high
B and Zr alloy showed the presence of dendritically-shaped, Zr-rich constituents in interdendritic regions in the gas-tungsten-arc
(GTA) welds. Electron microprobe analysis of these welds revealed a segregation pattern of Cr, Al, Mn, and Zr enrichment in
interdendritic regions and Ni and Fe enrichment in dendrite core regions. Analytical electron microscopy revealed the presence
of ZrX (X = B, C, N, O), M23C6, andγ′ in the fusion zone of GTA weld specimens,γ′ was also found in the as-received base metal and in the GTA weld HAZ. X-ray diffraction analysis of extractions from the
high B and Zr GTA weld metal also indicated the presence of a ZrX-type constituent. The results of this study are in qualitative
agreement with earlier work performed on alloys such as NIMONIC 90 and INCONEL 718∗ relative to the detrimental effect of B and Zr additions on fusion zone and HAZ hot cracking susceptibility.
Formerly with Sandia National Laboratories, Albuquerque, NM 相似文献
10.
The response of as-cast structures of 12 alloys in the Ti-Al-Mo system containing 44 to 50 at. pct Al and 2 to 6 at. pct Mo
to simple single step heat treatments in the temperature range 1373 to 1673 K is described. The microsegregation patterns
present in the cast structure persist to a large extent after heat treatment, especially below 1673 K. However, tentative
conclusions regarding phase equilibria in this temperature and composition range are drawn from the results. High-temperature
equilibria are dominated by the β, α+β, and α+γ phase fields, while the β+γ phase field dominates equilibrium below 1473 K. Three major types of transformation behavior are observed: a massive α to γ transformation, which occurs within the α phase on quenching from 1673 and 1573 K in alloys centered around the 48 pct Al composition; a eutectoid transformation from
α to B2+γ mixtures, which occurs at 1473 K and below in alloys centered around the 48Al-4Mo and 46Al-6Mo compositions; direct
γ precipitation in β, which occurs primarily in the 44Al-6Mo composition at 1273 K and below; and finally growth of γ lamellae in α+γ lamellar structures with B2 precipitation on lamellar interfaces, which occurs over a broad range of alloy compositions and
temperatures. 相似文献
11.
M. J. Cieslak G. A. Knorovsky T. J. Headley A. D. Romig 《Metallurgical and Materials Transactions A》1986,17(12):2107-2116
The weld metal microstructures of five commercial nickel base alloys (HASTELLOYS* C-4, C-22, and C-276, and INCONELS* 625
and 718) have been examined by electron probe microanalysis and analytical electron microscopy. It has been found that solidification
terminates in many of these alloys with the formation of a constituent containing a topologically-close-packed (TCP) intermetallic
phase(i.e., σ, P, Laves). Electron microprobe examination of gas-tungsten-arc welds revealed a solidification segregation pattern of Ni
depletion and solute enrichment in interdendritic volumes. New PHACOMP calculations performed on these segregation profiles
revealed a pattern of increasingM
d (metal-d levels) in traversing from a dendrite core to an adjacent interdendritic volume. In alloys forming a terminal solidification
TCP constituent, the calculatedM
d values in interdendritic regions were greater than the criticalM
d values for formation ofσ as stated by Morinagaet al. Implications of the correlation between TCP phase formation andM
d in the prediction of weld metal solidification microstructure, prediction of potential hot-cracking behavior, and applications
in future alloy design endeavors are discussed. 相似文献
12.
In order to provide the necessary phase equilibria data for understanding the development of the Widmanstatten pattern in
iron meteorites, we have redetermined the Fe-Ni-P phase diagram from 0 to 100 pct Ni, 0 to 16.5 wt pct P, in the temperature
range 1100° to 550°C. Long term heat treatments and 130 selected alloys were used. The electron microprobe was employed to
measure the composition of the coexisting phases directly. We found that the fourphase reaction isotherm, where α+ liq ⇌ γ+ Ph, occurs at 1000° ± 5°C. Above this temperature the ternary fields α+ Ph + liq and α+ γ+ liq are stable and below 1000°C, the ternary fields ⇌+ γ + Ph and γ + Ph + liq are stable. Below 875°C a eutectic reaction, liq → γ + Ph, occurs at the Ni-P edge of the diagram.
Altogether nineteen isotherms were determined in this study. The phase boundary compositions of the two-and three-phase fields
are listed and are compared with the three binary diagrams. The α + γ + Ph field expands in area in each isotherm as the temperature
decreases from 1000°C. Below 800°C the nickel content in all three phases increases with decreasing temperature. The phosphorus
solubility in α and γ decreases from 2.7 and 1.4 wt pct at 1000°C to 0.25 and 0.08 wt pct at 550°C. The addition of phosphorus
to binary Fe-Ni greatly affects the α/α + γ and γ/α + γ boundaries below 900°C. It stabilizes the α phase by increasing the
solubility of nickel (α/α +γ boundary) and above 700°C, it decreases the stability field of the γ phase by decreasing the
solubility of nickel(@#@ γ/α + γ boundary). However below 700°C, phosphorus reverses its role in γ and acts as a γ stabilizer, increasing the nickel
solubility range. The addition of phosphorus to Fe-Ni caused significant changes in the nucleation and growth processes. Phosphorus
contents of 0.1 wt pct or more allow the direct precipitation ofa from the parent γ phase by the reaction γ ⇌ α + γ. The growth rate of the α phase is substantially higher than that predicted
from the binary diffusion coefficients.
Formerly at Planetology Branch, Goddard Space Flight Center 相似文献
13.
O. A. Ojo N. L. Richards M. C. Chaturvedi 《Metallurgical and Materials Transactions A》2006,37(2):421-433
The fusion zone and heat-affected zone (HAZ) microstructures obtained during tungsten inert gas (TIG) welding of a commercial
superalloy IN 738LC were examined. The microsegregation observed during solidification in the fusion zone indicated that while
Co, Cr, and W segregated to the γ dendrites, Nb, Ti, Ta, Mo, Al, and Zr were rejected into the interdendritic liquid. Electron
diffraction and energy-dispersive X-ray microanalyses using a transmission electron microscope (TEM) of secondary phases,
extracted from the fusion zone on carbon replicas, and of those in thin foils prepared from the fusion zone showed that the
major secondary solidification constituents, formed from the interdendritic liquid, were cubic MC-type carbides and γ-γ’ eutectic.
The terminal solidification reaction product was found to consist of M3B2 and Ni7Zr2 formed in front of the interdendritic γ-γ’ eutectic. Based on the knowledge of the Ni-Ti-C ternary system, a pseudoternary
solidification diagram was adapted for IN 738 superalloy, which adequately explained the as-solidified microstructure. The
HAZ microfissuring was observed in regions surrounding the fusion zone. Closer and careful microstructural examination by
analytical scanning electron microscopy revealed formation of re-solidified constituents along the microfissured HAZ grain
boundaries, which suggest that HAZ cracking in this alloy involves liquation cracking. Liquation of various phases present
in preweld alloy as well as characteristics of the intergranular liquid film contributing to the alloy’s low resistance to
HAZ cracking were identified and are discussed. 相似文献
14.
M. J. Cieslak T. J. Headley A. D. Romig 《Metallurgical and Materials Transactions A》1986,17(11):2035-2047
The welding metallurgy (solidification and solid state transformations) of HASTELLOY* Alloys C-4, C-22, and C-276 has been
determined. Varestraint hot-cracking tests performed on commercial alloys revealed a weldability ranking as follows: C-4 >
C-22 > C-276. All alloys would be expected to have good weldability, with Alloy C-4 having a very low hot-cracking tendency,
comparable to 304L stainless steel. Microstructures of gas-tungsten-arc welds of these alloys have been characterized by scanning
electron microscopy and analytical electron microscopy. Intermetallic secondary solidification constituents have been found
associated with weld metal hot cracks in Alloys C-276 and C-22. In Alloy C-276, this constituent is a combination ofP and ώ phases, and in Alloy C-22, this constituent is composed of σ,P, and ώ phases. With phase composition data obtained by AEM techniques and available ternary (Ni-Cr-Mo) phase diagrams, an
equivalent chemistry model is proposed to account for the microstructures observed in each alloy's weld metal. 相似文献
15.
16.
S. Nourbakhsh O. Sahin W. H. Rhee H. Margolin 《Metallurgical and Materials Transactions A》1996,27(2):451-458
Composites of INCONEL 718 alloy reinforced with either single-crystal (SAPHIKON) or polycrys-talline (Du Pont's FP) A12O3 fiber were fabricated by pressure casting. Optical and transmission electron microscopy were used to characterize the microstructure
of the composites and to determine the nature of the fiber/matrix reaction. The widely dispersed fibers in the SAPHIKON-fiber-reinforced
composite had no influence on the solidification of the matrix. Six phases, γ-Ni3Al, γ'-Ni3Nb, δ-Ni3Nb, TiC, NbC, and Laves, were present in the matrix of the composite. The last three phases were formed during solidification
and the others precipitated during subsequent cooling. The high density of fibers in the FP-fiber-reinforced composite led
to a more uniform microstructure within the matrix. Only three phases,γ″-Ni3Nb, NbC, and Laves, were identified. Diffusion of Ti into the A12O3 fiber resulted in preferential grain growth in the FP fiber in areas adjacent to the fiber/matrix interface. The fiber/matrix
bond strength in shear in the SAPHIKON-fiber-reinforced composite was in excess of 150 MPa. 相似文献
17.
Spatially resolved X-ray diffraction (SRXRD) experiments have been performed during gas tungstenarc (GTA) welding of AISI
1045 C-Mn steel at input powers ranging from 1000 to 3750 W. In-situ diffraction patterns taken at discreet locations across the width of the heat-affected zone (HAZ) near the peak of the heating
cycle in each weld show regions containing austenite (γ), ferrite and austenite (α+γ), and ferrite (α). Changes in input power have a demonstrated effect on the resulting sizes of these regions. The largest effect is on the
γ phase region, which nearly triples in width with increasing input power, while the width of the surrounding two-phase α+γ region remains relatively constant. An analysis of the diffraction patterns obtained across this range of locations allows
the formation of austenite from the base-metal microstructure to be monitored. After the completion of the α → γ transformation, a splitting of the austenite peaks is observed at temperatures between approximately 860 °C and 1290 °C.
This splitting in the austenite peaks results from the dissolution of cementite laths originally present in the base-metal
pearlite, which remain after the completion of the α → γ transformation, and represents the formation of a second more highly alloyed austenite constituent. With increasing temperatures,
carbon, originally present in the cementite laths, diffuses from the second newly formed austenite constituent to the original
austenite constituent. Eventually, a homogeneous austenitic microstructure is produced at temperatures of approximately 1300
°C and above, depending on the weld input power. 相似文献
18.
A. D. Romig J. C. Lippold M. J. Cieslak 《Metallurgical and Materials Transactions A》1988,19(1):35-50
The heat-affected zone (HAZ) hot-cracking behavior of Alloy 800 was investigated with hot ductility (Gleeble) testing during
a simulated HAZ thermal cycle. Microstructural analyses were performed by optical metallography, fractography, electron microprobe
analysis, and analytical electron microscopy on specimens that were water quenched from selected temperatures during this
thermal cycle. Analysis of analytical electron microscopy (AEM) and Auger electron spectroscopy (AES) data suggests that incipient
melting of the grain boundaries occurs at temperatures of 1300 °C and above. The HAZ hot-cracking mechanism was consistent
with aspects of a constitutional liquation phenomenon involving a nonequilibrium eutectic-type reaction between grain boundary
Ti(C, N) and the austenitic matrix. The extent of expected HAZ cracking would be low as the liquation of Ti(C, N) was localized
and no lower melting intermetallic solidification products(e.g., Laves) were observed. The mechanistic observations were consistent with classical thermodynamic and solid state diffusion
models. 相似文献
19.
C. D. Anderson W. H. Hofmeister R. J. Bayuzick 《Metallurgical and Materials Transactions A》1992,23(10):2699-2714
Near-equiatomic alloys of Ti-Al were solidified at various bulk undercoolings using electromagnetic levitation. Detailed thermal
histories were acquired during experiments using optical pyrometry with sampling rates as fast as 500 KHz. Solidification
and other high-temperature transformation pathways were deduced from the thermal data and microstructural analysis. Re- calescence
rise times were used to determine semiquantitative primary solidification kinetics for the different phases. Primary β solidification
was observed at compositions well into the equi- librium α regime; this is presented as part of a near-equiatomic nucleation
domain diagram mat shows the primary solidification phase (β, α, ordered γ, or disordered γ) that results for each combination
of nucleation temperature and composition. Solidification kinetics are faster for primary β (Vmax ≈ 15 to 18 m s-1) than they are for primary α (Vmax ≈ 10 to 12 m s-1). For undercoolings less than about 150 K, the primary solidification kinetics are about an order of magnitude slower for
γ than for α. However, at an undercooling of about 150 K, the solidi- fication kinetics for γ increase discontinuously. This
discontinuity is associated with a change in the primary solidification phase from ordered γ (Vmax ≈ 0.5 m s-1) to disordered γ (Vmax ≈ 10 m s-1).
formerly Doctoral Student, Vanderbilt
formerly Doctoral Student, Vanderbilt
formerly Doctoral Student, Vanderbilt 相似文献
20.
The [001] oriented single crystals of nickel-base superalloy NASAIR 100 with the planar, cellular, coarse-dendritic, and fine-dendritic
solid/liquid (S/L) interfaces were prepared, respectively, and their microstructure and stress-rupture behavior at 1050 °C
were investigated in both as-cast and solution heat-treated conditions. It was found that in as-cast single crystals of NASAIR
100, microsegregation and γ/γ′ eutectic produced in the solidification process increased, γ′ size decreased, and γ′ shape tended progressively to be cuboidal, with the successive transition of the S/L interface from planar to cellular, then
to coarse-dendritic, and finally to fine-dendritic morphology. Furthermore, the solution temperature required to dissolve
all as-cast γ′ and most of the γ/γ′ eutectic increased with the aforementioned successive transition of S/L interfaces. The reprecipitated γ′, after solution heat treatment (SHT), was usually fine and cuboidal. However, some W-rich phase was present in the heat-treated
dendritic single crystals. Both the planar and the cellular single crystals of NASAIR 100 exhibited no superiority in stress-rupture
life, irrespective of the heat-treatment conditions. Instead, the single crystals with dendritic morphology possessed excellent
stress-rupture lives, after heat treatment at 1320 °C for 4 hours, followed by air cooling (AC). Perfect γ′ rafts with high-average aspect ratios formed during the stress-rupture tests of dendritic single crystals; in contrast, irregularly
coarsening structures appeared in both the planar and cellular single crystals. The microstructure and solution behavior were
illustrated in detail. Furthermore, the microstructural factors to affect the high-temperature stress-rupture life of the
single crystals of NASAIR 100 were also analyzed. 相似文献