Analysis of temperature and illumination dependencies of CIS cell performance

Cell performances of Cu(In,Ga)Se₂ (CIGS) thin-film solar cells were measured and analyzed as a function of temperature and illumination. The J_sc and V_oc were linearly changed with the temperature in the range of 10°C–70°C, and the J_sc was proportional to the illumination intensity in the range up to 130 mW/cm². It was shown that I–V curves in CIGS cells could be calibrated from the measured condition to other conditions such as the standard condition and field test ones, using the calibration method proposed for crystal Si solar cells.     

Structural and electrochemical properties of Li1+xNi0.5Mn0.5O2+δ (0 ≤ x ≤ 0.7) cathode materials for lithium-ion batteries

A comparative analysis of the properties of LiNi_0.5Mn_0.5O₂ and Li_1+xNi_0.5Mn_0.5O₂ (0.2 ≤ x ≤ 0.7) powders, obtained by the freeze drying method, was performed. Lattice parameters of Li_1+xNi_0.5Mn_0.5O₂ decreased considerably with growing amounts of Li until x = 0.3; at x > 0.5 trace amounts of Li₂MnO₃ are observed by X-ray diffraction (XRD) patterns. X-ray photoelectron spectroscopy (XPS) analysis displayed an increase of Ni³⁺/Ni²⁺ ratio at 0.3 < x < 0.5, while Mn 2p spectra were almost identical in all samples. Rechargeable capacity values (V = 2.5–4.6 V) increased systematically with x reaching its maximum (185–190 mAh g⁻¹) at x = 0.5. Samples with superstoichiometric lithium content also demonstrated good C rate characteristics.     

Urban morphology and indicators of radiation availability

Common indicators used to examine the potential for utilising natural radiation of urban forms include the sky view factor (V_s), the height to width ratio and the urban horizon angle. These indicators are conveniently related to one another. In comparing simulations of sky view factor with those of simulated solar irradiation, which itself relates well to illumination, this paper tests the effectiveness of all three – based on analysis of three existing Swiss districts. From this, it is concluded that the absence of treatment of direct solar radiation, sky anisotropy or reflected radiation seriously impairs the ability of the V_s-related indicators to offer meaningful insights regarding natural radiation potential in the localised case. Predictions of annual irradiation from aggregations of V_s also perform badly, but the aggregate V_s does correlate reasonably well with irradiation so that judgements of overall radiation availability may be made with some confidence.     

Quality control and characterization of Cu(In,Ga)Se2-based thin-film solar cells by surface photovoltage spectroscopy

Surface photovoltage spectroscopy (SPS) has been used for quality control of ZnO/CdS/ Cu(In,Ga)Se₂ (CIGS) thin-film solar cells. The results show that SPS makes it possible to detect “hard failures” following CIGS deposition, and both “hard” and “soft” failures following CdS deposition and following ZnO deposition. In addition, a semi-quantitative screening of CdS/CIGS and ZnO/CdS/CIGS samples is possible. Hence, SPS is suggested as a useful tool for in-line monitoring of CIGS-based solar cell production lines. Moreover, SPS is shown to yield important new information regarding CIGS-based solar cells: (a) A deep gap state is found in samples of superior performance. (b) As opposed to the CdS/CIGS structure, a marked decrease in the open-circuit voltage upon Na contamination in ZnO/CIGS structures is found.     

High efficiency solar energy water splitting to generate hydrogen fuel: Probing RuS2 enhancement of multiple band electrolysis

The conditions under which an oxygen photocatalyst can improve multiple band gap (semiconductor) solar energy water splitting are probed. Recently, we provided evidence that previous models significantly underestimated the magnitude of H₂ fuel which may be generated by solar energy, and demonstrated a bipolar band gap solar system electrolyzing water at V_H2O

H₂O→H₂+1/2O₂; V_H2O>E°_H2O=E°_O2−E°_H2;E°_H2O(25°C)=1.229 V

at an unprecedented 18.3% solar energy conversion efficiency. Three conditions are shown in which oxygen photocatalyst addition can further improve this process; (i) a reduction in V_H2O; (ii) at V_H2O, capability to sustain electrolysis currentsgenerated photocurrents, and (iii) catalyst activation at hν_photo-O2>hν_{photo-bipolar}. We show that RuS₂ with 1% Fe is capable of meeting these conditions.     

Performance and parameter analysis of tandem solar cells using measurements at multiple spectral conditions

The current-voltage (I–V) characteristics of monolithic tandem solar cells have been measured with different radiation spectra. Introducing a spectral metric allows the experimental results and the match between current and efficiency value to be analysed. Simultaneous analysis of the I–V characteristics allows extraction of diode parameters of the individual sub-cells.

The measurements allow an assessment of cell performance and optimisation, both for amorphous and crystalline tandem cells.     

Fill factor losses in ZnO/CdS/CuGaSe2 single-crystal solar cells

Current–voltage characteristics of ZnO/CdS/CuGaSe₂ single-crystal solar cells with solar conversion efficiency values of η=3.5%, 6.0%, 6.7% and 9.7% were analyzed using the single diode equation. The effect of each of the achieved parameters on the fill factor was calculated. The calculations revealed that the fill factor reduction due to the series resistance remained below Δff=4.4% under illumination, while this effect would have been much higher if the illumination had not reduced the series resistance markedly. The calculation furthermore revealed that the fill factor reduction due to the shunt resistance remained below Δff=3.6% under illumination. This effect would have been negligible if the illumination had not also reduced the shunt resistance in all studied cells. The increase of the saturation current density under illumination has brought about considerably high fill factor losses (at least Δff=8.3%) in all studied cells. Already the dark saturation current density and the diode ideality factor in such cells have been found to be much higher than the ones in the cells based on CuInSe₂. This seems to be the most substantial restriction to the fill factor, and thus to the performance, of solar cells based on CuGaSe₂. An explanation for this different behavior seems to lie in the different band structures of these cells.     

A novel model for photovoltaic array performance prediction

Based on the I–V curves of a photovoltaic (PV) module, a novel and simple model is proposed in this paper to predict the PV module performance for engineering applications. Five parameters are introduced in this model to account for the complex dependence of the PV module performance upon solar-irradiance intensity and PV module temperature. Accordingly, the most important parameters, i.e. the short-circuit current, open-circuit voltage, fill factor and maximum power-output of the PV module, may be determined under different solar irradiance intensities and module temperatures. To validate the developed model, field measured data from one existing building-integrated photovoltaic system (BIPV) in Hong Kong was studied, and good agreements between the simulated results and the field data are found. This model is simple and especially useful for engineers to calculate the actual performances of the PV modules under operating conditions, with limited data provided by the PV module manufacturers needed.     

On the computer simulation of the P–C isotherms of ZrFe2 type hydrogen storage materials

This paper deals with computer simulation of the P–C isotherms of some ZrFe₂ type (Zr(Fe_1−xCr_x)₂, Zr_1−xTi_xFe_1.4Cr_0.6, Zr_1−2xMm_xTi_xFe_1.4Cr_0.6 : x00.4) of hydrogen storage materials. A feasible mathematical model has been developed to simulate the P–C isotherms. The randomized variables in the model applied for simulating the P–C isotherms of the above-mentioned ZrFe₂ type hydrogen storage materials correspond to change in enthalpy (ΔH) and entropy (ΔS) of hydride formation. Several ZrFe₂ type materials as in above have been synthesized and their P–C isotherms, enthalpy and entropy change has been evaluated experimentally in order to have input data for simulation. A special software was developed to simulate the P–C isotherms using the said model. A close match between the experimentally observed and simulated P–C isotherms for the above said ZrFe₂ type alloys has been obtained.     

Performance variation of carbon counter electrode based dye-sensitized solar cell

The effect of dark and room temperature aging on the performance of carbon counter electrode based dye-sensitized solar cell (DSSC) has been investigated. Using nano size carbon as a counter electrode material, DSSC with power conversion efficiency of 7.56% was fabricated. Storing the devices in the dark at room temperature enhanced both the open-circuit voltage (V_OC) and fill-factor (FF) but reduced the short-circuit current density (J_SC). After 60 days of aging, carbon counter electrode DSSC retains 84% of its initial day efficiency (η). The variation in the current–voltage parameters was explained on the basis of electrochemical impedance spectroscopic (EIS) analysis.     

Amorphous solar cells, the micromorph concept and the role of VHF-GD deposition technique

During the last two decades, the Institute of Microtechnology (IMT) has contributed in two important fields to future thin-film silicon solar cell processing and design:

(1) In 1987, IMT introduced the so-called “very high frequency glow discharge (VHF-GD)” technique, a method that leads to a considerable enhancement in the deposition rate of amorphous and microcrystalline silicon layers. As a direct consequence of reduced plasma impedances at higher plasma excitation frequencies, silane dissociation is enhanced and the maximum energy of ions bombarding the growing surface is reduced. Due to softer ion bombardment on the growing surface, the VHF process also favours the formation of microcrystalline silicon. Based on these beneficial properties of VHF plasmas, for the growth of thin silicon films, plasma excitation frequencies f_exc in the range 30–300 MHz, i.e. clearly higher than the standard 13.56 MHz, are indeed scheduled to play an important role in future production equipment.

(2) In 1994, IMT pioneered a novel thin-film solar cell, the microcrystalline silicon solar cell. This new type of thin-film absorber material––a form of crystalline silicon––opens up the way for a new concept, the so-called “micromorph” tandem solar cell concept. This term stands for the combination of a microcrystalline silicon bottom cell and an amorphous silicon top cell. Thanks to the lower band gap and to the stability of microcrystalline silicon solar cells, a better use of the full solar spectrum is possible, leading, thereby, to higher efficiencies than those obtained with solar cells based solely on amorphous silicon.

Both the VHF-GD deposition technique and the “micromorph” tandem solar cell concept are considered to be essential for future thin-film PV modules, as they bear the potential for combining high-efficiency devices with low-cost manufacturing processes.     

Stability of some ternary and quaternary CeNi5-based and PrNi5-based hydride systems

The Ce_1−xR_xNi_2.5Cu_2.5 (R = La,Pr; 0.8 x 0.3) and PrNi_5−xM_x (M = Cu, Fe; 0.5 x 2.5) alloys were investigated for their hydriding characteristics in the temperature range 0–70°C and hydrogen pressure range 0.01–50 atm. The nonlinear behaviour of unit cell volume vs x in Ce_1–xLa_xNi_2.5Cu_2.5 suggests that both size and electronic effects are involved. The partial replacement of Ce by La and Ni by Cu in CeNi₅ causes a substantial reduction in the hydrogen sorption pressures without significantly impairing its hydrogen capacity. It was observed that Fe is more effective than Cu in stabilizing PrNi₅-H₂. The high values of the molar entropy of hydrogen of the β-hydrides studied, S^β_H, are attributed to extensive hydrogen disorder in the interstitial sites of the host lattice. A linear correlation between the hydride decomposition pressures (or free energy) and the unit cell volume. V_c, of the host alloys was observed. This behavior is helpful in predicting the stabilities of new hydrides in a given substitutional alloy series.     

Novel device structure for Cu(In,Ga)Se2 thin film solar cells using transparent conducting oxide back and front contacts

Cu(In_1−xGa_x)Se₂ (CIGS)-based thin film solar cells fabricated using transparent conducting oxide (TCO) front and back contacts were investigated. The cell performance of substrate-type CIGS devices using TCO back contacts was almost the same as that of conventional CIGS solar cells with metallic Mo back contacts when the CIGS deposition temperatures were below 500 °C for SnO₂:F and 520 °C for ITO. CIGS thin film solar cells fabricated with ITO back contacts had an efficiency of 15.2% without anti-reflection coatings. However, the cell performance deteriorated at deposition temperatures above 520 °C. This is attributed to the increased resistivity of the TCO’s due to the removal of fluorine from SnO₂ or undesirable formation of a Ga₂O₃ thin layer at the CIGS/ITO interface. The formation of Ga₂O₃ was eliminated by inserting an intermediate layer such as Mo between ITO and CIGS. Furthermore, bifacial CIGS thin film solar cells were demonstrated as being one of the applications of semi-transparent CIGS devices. The cell performance of bifacial devices was improved by controlling the thickness of the CIGS absorber layer. Superstrate-type CIGS thin film solar cells with an efficiency of 12.8% were fabricated using a ZnO:Al front contact. Key techniques include the use of a graded band gap Cu(In,Ga)₃Se₅ phase absorber layer and a ZnO buffer layer along with the inclusion of Na₂S during CIGS deposition.     

MATCHING OF SEPARATELY EXCITED DC MOTORS TO PHOTOVOLTAIC GENERATORS FOR MAXIMUM POWER OUTPUT

This paper addresses the matching of separately excited dc motors to photovoltaic generators (PVG) for maximum power output. The dc motor is used to drive a centrifugal water pump. A PVG is a nonlinear device having insolation dependent I–V (current–voltage) characteristic, and hence a natural mismatch exists between the motor loads and the PVG. Therefore, considering the high initial cost of PVG, it is of vital importance to develop an appropriate matching process, to utilize PVG efficiently. In this article a procedure is developed to express the field current of the motor directly in terms of the maximum power point current and voltage of the PVG. It is shown that by adjusting the field current according to the developed relation, the motor is forced to follow the maximum power trajectory of the PVG, i.e. the input power of the motor is always equal to the maximum output power of the PVG at any available solar insolation. The effect of temperature on the I–V characteristic of the PVG is neglected at this stage. Finally a general expression is proposed relating the optimum field current directly to the available insolation level, which may be used as base for best matching.     

Interfacial oxide layer mechanisms in the generation of electricity and hydrogen by solar photoelectrochemical cells

The effect of an oxide layer of tunneling dimensions, together with localized interface states at the optically-illuminated semiconductor-electrolyte interface, on the transport of electrons and holes from the semiconductor bands into the redox levels in solution is calculated analytically. The interface states are considered to affect the charge transport primarily in an electrostatic manner, by adjusting their charge with changes in the semiconductor surface potential.

A photovoltage, V, is developed in the oxidized semiconductor electrode, which divides between the space-charge region of the semiconductor V_s and the oxide layer V_ox. The majority-carrier current for a given total photovoltage depends primarily on V_s, and is therefore reduced from its value without an oxide layer. This has the effect of substantially increasing the open-circuit voltage and the photovoltaic conversion efficiency of a photo-electrochemical solar cell. The oxide layer is also expected to reduce, or in some cases to eliminate, the requirement for a supplementary external bias voltage in the production of hydrogen or other fuels from solar energy, using photosynthetic devices of this type.     

Quasi-solid-state dye-sensitized solar cells employing ternary component polymer-gel electrolytes

Ternary component polymer-gel electrolytes are designed to facilitate ion transport in a highly viscous medium and utilize incident light more efficiently in dye-sensitized solar cells (DSSCs). Polyethers with multiple molecular size distributions are employed as solvents and TiO₂ nanoparticles as a filler to prepare the polymer-gel electrolytes. The ion transport properties of the electrolytes are systematically investigated using electrochemical analyses such as ion conductivity and diffusion coefficient measurements. The influences of the electrolyte components on the electron transport in photoanodes are also investigated by measuring the laser-induced photovoltage and photocurrent transient response, incident photon-to-current efficiency (IPCE), and current–voltage (J–V) curves. The optimized polymer-gel electrolyte results in greatly enhanced energy conversion efficiency (i.e., 7.2% at 1 sun) due to the significantly improved ion transport and good light-scattering effect of the nanofillers.     

Numerical and experimental research of the characteristics of concentration solar cells

The development of automatic tracking solar concentrator photovoltaic systems is currently attracting growing interest. High concentration photovoltaic systems (HCPVs) combining triple-junction InGaP/lnGaAs/Ge solar cells with a concentrator provide high conversion efficiencies. The mathematical model for triple-junction solar cells, having a higher efficiency and superior temperature characteristics, was established based on the one-diode equivalent circuit cell model. A paraboloidal concentrator with a secondary optic system and a concentration ratio in the range of 100X–150X along with a sun tracking system was developed in this study. The GaInP/GalnAs/Ge triple-junction solar cell, produced by AZUR SPACE Solar Power, was also used in this study. The solar cells produced by Shanghai Solar Youth Energy (SY) and Shenzhen Yinshengsheng Technology Co. Ltd. (YXS) were used as comparison samples in a further comparative study at different concentration ratios (200X–1000X). A detailed analysis on the factors that influence the electrical output characteristics of the InGaP/lnGaAs/Ge solar cell was conducted with a dish-style concentrating photovoltaic system. The results show that the short-circuit current (I_sc) and the open-circuit voltage (V_oc) of multi-junction solar cells increases with the increasing concentration ratio, while the cell efficiency (η_c) of the solar cells increases first and then decreases with increasing concentration ratio. With increasing solar cell temperature, I_sc increases, while V_oc and η_c decrease. A comparison of the experimental and simulation results indicate that the maximum root mean square error is less than 10%, which provides a certain theoretical basis for the study of the characteristics of triple-junction solar cell that can be applied in the analysis and discussion regarding the influence of the relevant parameters on the performance of high concentration photovoltaic systems.     

Numerical prediction of InGaAs/GaAs MQW solar cell characteristics under concentrated sunlight

The characteristics of InGaAs/GaAs multi-quantum well (MQW) solar cells under concentrated sunlight were analyzed by self-consistent numerical calculation and were compared with GaAs p-i-n cells that have the same structure except for the QWs. Prior to the calculations, the absorption coefficients of the InGaAs MQW cell were determined by fitting the calculated quantum efficiencies to experimental ones. In the simulation, mainly the influences of concentrated sunlight and temperature were investigated. Results of the simulation showed that the rate of the conversion efficiency and open-circuit voltage (V_oc) of MQW cells increased faster than that of p-i-n cells as the light intensity increased, while the rate of efficiency of the MQW cell decreased a little slower than that of the p-i-n cell with the temperature increase. MQW cells compensate for the disadvantage of lower efficiency and V_oc than p-i-n cells in a concentrated sunlight system.     

Effect of temperature on the morphological and photovoltaic stability of bulk heterojunction polymer:fullerene solar cells

In high performance polymer:fullerene bulk heterojunction solar cells the nanoscale morphology of interpenetrating acceptor:donor materials is optimized through appropriate preparation conditions such as annealing and choice of solvent, but this initial state-of-the-art morphology will not remain stable during long-term operation. We report the effects of prolonged storage at elevated temperatures on both the morphology and the photovoltaic performance for the model systems MDMO-PPV:PCBM and P3HT:PCBM as compared to ‘High T_g PPV’:PCBM based solar cells, where the ‘High T_g PPV’ is characterized by its high glass transition temperature (138 °C). In situ monitoring of the photocurrent–voltage characteristics at elevated temperatures, in combination with a systematic transmission electron microscopy (TEM) study and complementary optical spectroscopy, reveals distinct degradation kinetics and morphological changes that indicate the occurrence of different underlying physico-chemical mechanisms.     

Conditional probabilities of daily relative sunshine data and the dependence on the weather of the previous day

In this paper, the conditional probabilities p₁₁(m, x) and p₀₁(m, x) of the daily relative sunshine (DRS) are estimated for each month m, using available data for 30 years. p₁₁(m, x) (p₀₁(m, x)) is the probability that the DRS of a day for a certain month is greater than x, (o < x < 1), given that the DRS of the previous day is greater (smaller) than x. The empirical curves for p₁₁(m, x) and p₀₁(m, x) are fitted and the fitting parameters are estimated for each month. The results show a good agreement between the empirical and the calculated values. The vertical distance between the curves p₁₁(m, x) and p₀₁(m, x) shows a strong dependence of the weather on that of the previous day. A method to estimate a sequence of k consecutive days of “good” or “bad” weather is also given.