The formation of disinfection by-products in water treated with chlorine dioxide

In this study, chlorine dioxide (ClO(2)) was used as an alternative disinfection agent with humic acid as the organic precursor in a natural aquatic environment. The major topics in this investigation consisted of the disinfection efficiency of ClO(2), the formation of disinfection by-products (DBPs), and the operating conditions. The results indicated that the pH value (pH 5-9) did not affect the efficiency of disinfection while the concentration of organic precursors did. The primary DBPs formed were trihalomethanes (THMs) and haloacetic acids (HAAs). The distribution of the individual species was a function of the bromide content. The higher the ClO(2) dosage, the lower the amount of DBPs produced. The amount of DBPs increased with reaction time, with chlorite ions as the primary inorganic by-product.     

Sonochemical disinfection of municipal wastewater

The application of high intensity, low frequency ultrasound for the disinfection of simulated and septic tank wastewaters is evaluated in this work. Laboratory scale experiments were conducted at 24 and 80kHz ultrasound frequency with horn-type sonicators capable of operating in continuous and pulsed irradiation modes at nominal ultrasound intensities up to 450W. For the experiments with simulated wastewaters, Escherichia coli were used as biological indicator of disinfection efficiency, while for the experiments with septic tank wastewaters, the total microbiological load was used. Complete elimination of E. coli could be achieved within 20-30min of irradiation at 24kHz and 450W with the efficiency decreasing with decreasing intensity and frequency. Moreover, continuous irradiation was more effective than intermittent treatment based on a common energy input. Irradiation of the septic tank effluent prior to biological treatment at 24kHz and 450W for 30min resulted in a three-log total microbiological load reduction, and this was nearly equal to the reduction that could be achieved during biological treatment. Bacterial cell elimination upon irradiation was irreversible as no reappearance of the microorganisms occurred after 24h.     

Evaluating the life cycle environmental performance of chlorine disinfection and ultraviolet technologies

With increasing emphasis on promoting a sustainable ecological future and concern over introducing a toxic chemical in the water, the design of the disinfection process is increasingly leaning toward technologies that destroy the pathogens while balancing the effects of this disinfected wastewater on the population of aquatic biota or a drinking water supply. Since ultraviolet (UV) irradiation is not a chemical additive, it does not leave or produce any by-product toxic compounds in the wastewater, like traditional chlorination and de-chlorination processes do. Therefore, the use of UV does not affect a drinking water supply or the aquatic biota in receiving waters. Life cycle assessment or analysis (LCA) is used to quantify the environmental benefits of using UV disinfection technology (as well as better protecting public health), instead of chlorination and de-chlorination methods. LCA tools are being used to evaluate the short and long term environmental effects of both processes, and to select the best sustainable process. The approach here combines environmental LCA with these disinfection processes incorporating economic criteria and all aspects of the environment: chemical use, electricity use, and releases to water, air, and land. The environmental, health, and economic benefits and other effects show the greater sustainability of UV technology (a "clean" ecological disinfection process) in comparison to that of traditional disinfection with chlorine. Electronic Publication     

Relationship of chlorine decay and THMs formation to NOM size

Because of increasing concern about balancing health risks for pathogen control and disinfection by-product (DBP) formation in water supplies, utilities are forced to closely examine and optimize their disinfection practices. A better understanding of the relationship between the molecular weights of the natural organic matter (NOM), chlorine decay kinetics and THMs formation can help the utilities to minimize the DBP concentrations, providing healthier and microbially safer water. The authors present data on chlorine decay kinetics and total trihalomethanes (TTHM) formation kinetics and modeling with different molecular weights NOM fractions of Mississippi River water. TTHM modeling results indicated that the TTHM formation in fractionated NOM was a function of chlorine consumption. TTHM yield coefficients ranged from 31 to 42 microg-TTHM/mg-Cl2. As the molecular weight of the fractions decreased, TTHM yield coefficients increased.     

Molecular size distribution of dissolved organic matter in water of the Pearl River and trihalomethane formation characteristics with chlorine and chlorine dioxide treatments

River water sample was collected from Guangzhou section of the Pearl River to investigate soluble organic fractions and formation of trihalomethane (THMs) after chlorine and chlorine dioxide treatments. The water sample was passed through Amicon YC-05, YM-1, YM-3, YM-10, YM-30, YM-100 and ZM-500 series membranes after a pre-treatment. The molecular weight distribution and the specific ultra-violet absorbance (SUVA(254)) of each fraction obtained from membrane were analyzed, and these fractions were further disinfected with chlorine and chlorine dioxide. The results showed that reverse osmosis (RO) fraction contained mainly dissolved organic matter (DOM) from the water sample, suggesting that the water has been highly contaminated by anthropogenic activities. Meanwhile, the THMs concentration and SUVA(254) increased gradually as the molecular weight of the obtained fractions reduced, indicating that the low molecular weight DOM was the major THMs precursor in the disinfection process with chlorine and chlorine dioxide. The results suggest that THMs in source water of Pearl River could be effectively reduced when pollution of human activity is greatly controlled. Between the two disinfection processes tested, chlorine dioxide produced less THMs than chlorine in this study.     

Effects of combined UV and chlorine disinfection on corrosion and water quality within reclaimed water distribution systems

The effects of combined ultraviolet (UV) and chlorine disinfection on corrosion and water quality were assessed in a model reclaimed water distribution system (RWDS) using annular reactors (ARs). UV irradiation not only enhanced the inactivation of heterotrophic bacteria, but also reduced the required initial chlorine dose. Moreover, UV pretreatment induced less changes of corrosion products composition and decreased iron release and turbidity of effluents resulted from Larson–Skold Index (Li) of reclaimed water changing, enhancing the stability of water quality through RWDS. The corrosion bacteria within the biofilm on the corrosion scales could grow selectively with different disinfection processes. In the AR with combined UV and chlorine treatment, the iron-oxidizing bacterium (IOB) Acidovorax defluvii and the iron-reducing bacteria (IRB) uncultured Rhodoferax sp. and uncultured Geobacter sp. appeared on the biofilm. In contrast, in the AR treated with chlorine alone, the IOB Sediminibacterium salmoneum and the IRB uncultured Geobacter sp. were predominant in the biofilm. In the latter, S. salmoneum respiration predominantly contributed to the oxidization of Fe(II), whereas in the former, either Fe(II) or acetate acted as a donor for A. defluvii respiration, causing an increased depletion of oxygen by the oxidation of Fe(II). Therefore, under the former conditions, the composition of corrosion bacteria could result in lower corrosion rate, decreasing the effect of Li changes on iron release. All results indicated that UV irradiation enhanced water quality stability in the RWDS.     

Effects of mechanical activation and chlorine ion on nanoparticle forsterite formation

This paper reports the positive effects of chlorine ion on the forsterite formation rate. The influence of mechanical activation of talc and magnesium carbonate mixture on the formation of forsterite structure was studied in the presence of chlorine ion. Mechanical activation increased the contact surface area of the reacting phases as a consequence of intensively reduced particle size, which is very important in the case of diffusion-controlled reactions. Besides, the presence of chlorine ion affected the forsterite formation rate following annealing. The single-phase nanostructure forsterite powder with a crystallite size of about 20 nm was obtained by 5 h of mechanical activation and subsequent annealing at 1000 °C for 2 min in the presence of the chlorine ion.     

Oxidation of various reactive dyes with in situ electro-generated active chlorine for textile dyeing industry wastewater treatment

The present investigation revealed that all the reactive dyes were degraded in chlorine mediated electrochemical oxidation. Titanium based dimensionally stable anode (DSA) was used for in situ generation of chlorine in the dye solution. All classes of reactive dyes (100 mg/L) showed a complete color removal at a supporting electrolyte concentration of 1.5 g/L NaCl and 36.1 mA/cm(2) current density. The chemical oxygen demand (COD) and total organic carbon (TOC) removals were from 39.5 to 82.8% and from 11.3 to 44.7%, respectively, for different reactive dyes. It can be concluded in general that the triazine containing higher molecular weight diazo compounds takes more time for complete de-colorization than the mono azo or anthraquinone containing dye compounds. The degradation rate of mixed dye compounds was affected by reaction temperature, current density, NaCl concentration and initial dye concentration. However, the initial pH of the dye solution ranging from 4.3 to 9.4 did not show significant effect on de-colorization. A complete color removal with 73.5% COD and 32.8% TOC removals were obtained for mixed reactive dyes (200 mg/L) at the end of 120 min of electrolysis under the optimum operating conditions of 4 g/L NaCl concentration and 72.2 mA/cm(2) current density.     

Bioremediation of 2-chlorophenol containing wastewater by aerobic granules-kinetics and toxicity

2-Chlorophenol (2-CP) degrading aerobic granules were cultivated in a sequencing batch reactor (SBR) in presence of glucose. The organic loading rate (OLR) was increased from 6.9 to 9.7 kg COD m(-3)d(-1) (1150-1617 mg L(-1)COD per cycle) during the experiment. The alkalinity (1000 mg L(-1) as CaCO(3)) was maintained throughout the experiment. The specific cell growth rate was found to be 0.013 d(-1). A COD removal efficiency of 94% was achieved after steady state at 8h HRT (hydraulic retention time). FTIR, UV, GC, GC/MS studies confirmed that the biodegradation of 2-CP occurs via chlorocatechol (modified ortho-cleavage) pathway. Biodegradation kinetics followed the Haldane model with kinetic parameters: V(max)=840 mg2-CPgMLVSS(-1)d(-1), K(s)=24.61 mg L(-1), K(i)=315.02 mg L(-1). Abiotic losses of 2-CP due to volatilization and photo degradation by sunlight were less than 3% and the results of genotoxicity showed that the degradation products are eco-friendly.     

Evaluation of disinfection by-products formation during chlorination and chloramination of dissolved natural organic matter fractions isolated from a filtered river water

Dissolved natural organic matter (DOM) in a filtered river water was isolated and fractionated into six different fractions. Trihalomethanes (THMs) and haloacetic acids (HAAs) formed from these isolated DOM fractions during chlorination and chloramination were determined. Results show that the hydrophobic acid, hydrophilic acid, hydrophilic base and hydrophobic neutral are major precursors of THMs and HAAs. There exist good correlations between the values of specific ultraviolet absorbance at 254nm of the individual DOM fractions and their disinfection by-products formation potential, indicating that aromatic moieties are responsible for disinfection by-products formation for both hydrophobic and hydrophilic DOM fractions. Chloramination of the DOM fractions yields much less THMs and HAAs than chlorination. For the dominant DOM fraction (i.e. hydrophobic acid) in the water, the yields of THMs and HAAs increase more significantly in chlorination than those in chloramination with the increase of disinfectant dosage, contact time and dissolved organic carbon content.     

Prediction of N-nitrosodimethylamine (NDMA) formation as a disinfection by-product

This study investigated the possibility of a statistical model application for the prediction of N-nitrosodimethylamine (NDMA) formation. The NDMA formation was studied as a function of monochloramine concentration (0.001-5mM) at fixed dimethylamine (DMA) concentrations of 0.01mM or 0.05mM. Excellent linear correlations were observed between the molar ratio of monochloramine to DMA and the NDMA formation on a log scale at pH 7 and 8. When a developed prediction equation was applied to a previously reported study, a good result was obtained. The statistical model appears to predict adequately NDMA concentrations if other NDMA precursors are excluded. Using the predictive tool, a simple and approximate calculation of NDMA formation can be obtained in drinking water systems.     

The assessment of major hazards: The lethal toxicity of chlorine: Part 1, review of information on toxicity

Measures for the control of hazardous installations include the assessment of the hazard and the setting of separation distances between the installation and the public. For installations handling toxic materials this creates a requirement for data on toxicity. One of the toxic materials handled industrially in large quantities is chlorine. There is a considerable literature on chlorine which yields a number of different values for the toxicity to animals and man, often of obscure origin. The literature is reviewed and the information evaluated. The results of this evaluation are used in a complementary paper to derive a model of the lethal toxicity of chlorine to man.     

The assessment of major hazards: The lethal toxicity of chlorine: Part 2, model of toxicity to man

The information available on the lethal toxicity of chlorine to animals and man has been reviewed in a previous paper. In the present paper this information is used to derive a revised estimate for the lethal toxicity to man. A distinction is made between less vulnerable and more vulnerable populations and between different levels of physical activity, with a standard level defined which is applicable to most daytime activity. Mortality is expressed in terms of a lethal toxic load which is a function of concentration and time. The concentrations lethal at the 50% level for a 10 min exposure with standard level of activity are estimated as 433, 173 and 364 ppm for the regular, vulnerable and average population, respectively, and those for a 30 min exposure as 250, 100 and 210, respectively. The probit equation derived for the regular population at the standard level of activity is Y = ?8.29 + 0.92 ln L* with L* = Σ C²T where C is concentration (ppm), L* toxic load (ppm² min), T time (min) and Y the probit. A methodology for the application of the toxicity relationships in hazard assessment is given.

T001. List of symbols

     

14.

Evaporation and air-stripping to assess and reduce ethanolamines toxicity in oily wastewater   总被引：1，自引：0，他引：1  

Libralato G  Ghirardini AV  Avezzù F 《Journal of hazardous materials》2008,153(3):928-936

Toxicity from industrial oily wastewater remains a problem even after conventional activated sludge treatment process, because of the persistence of some toxicant compounds. This work verified the removal efficiency of organic and inorganic pollutants and the effects of evaporation and air-stripping techniques on oily wastewater toxicity reduction. In a lab-scale plant, a vacuum evaporation procedure at three different temperatures and an air-stripping stage were tested on oily wastewater. Toxicity reduction/removal was observed at each treatment step via Microtox bioassay. A case study monitoring real scale evaporation was also done in a full-size wastewater treatment plant (WWTP). To implement part of a general project of toxicity reduction evaluation, additional investigations took into account the monoethanolamine (MEA), diethanolamine (DEA) and triethanolamine (TEA) role in toxicity definition after the evaporation phase, both as pure substances and mixtures. Only MEA and TEA appeared to contribute towards effluent toxicity.     

15.

Elimination of polyphenols toxicity from olive mill wastewater sludge by its co-composting with sesame bark     

Hachicha S  Cegarra J  Sellami F  Hachicha R  Drira N  Medhioub K  Ammar E 《Journal of hazardous materials》2009,161(2-3):1131-1139

Olive mill wastes represent a significant environmental problem in Mediterranean areas where they are generated in huge quantities in a short period of time. Their high phenol, lipid and organic acid concentrations turn them into phytotoxic materials, but these wastes also contain valuable resources such as a large proportion of organic matter and a wide range of nutrients that could be recycled. Composting is one of the technologies used for the valorization of this effluent, producing a fertilizer useful for poor soils.The present work deals with the changes that occur in the content of phenolic compounds and the biotoxicity of the oxidized substrate which result from the composting of olive mill wastewater (OMW) sludge with sesame bark. The total organic matter decreased 52.72% while water-soluble phenol degradation decreased 72% after 7 months of processing. Gas chromatography coupled with mass spectroscopy was used to confirm the elimination of polyphenols during composting. Initially, the analysis showed three abundant polyphenolic compounds, one of which was identified as the 4-hydroxyphenyl-ethanol (tyrosol), a well-known antioxidant in OMW. After 7 months of composting, all of the phenolic compounds disappeared. The phytotoxic effects of OMW sludge, assessed by the plant index germination, increased during the composting to reach 80% after 210 days. This trend was confirmed by the correlation between physico-chemical and toxicity parameters. The results obtained confirmed the stability of the compost prepared from OMW sludge with sesame bark and indicated a gradual detoxification as the compost matured.     

16.

The formation of excited chlorine atoms in a low-pressure transverse volume discharge     

A. K. Shuaibov  A. I. Dashchenko  I. V. Shevera 《Technical Physics Letters》2002,28(4):330-332

The characteristics of a transverse volume discharge (TVD) in chlorine at low pressures (P(Cl₂)=0.1–1.5 kPa) were studied. The excited chlorine atoms were formed in a 18×2.2× (0.5–1.0) cm volume using relatively low values of the capacitor bank charging voltage (U _ch ≤ 10 kV) in the pulsed discharge voltage source. The optical emission from plasma was studied in a spectral range from 500 to 900 nm. Homogeneous TVD pulses of short duration (τ; ≤ 100 ns) obtained under these conditions are of interest for use in UV-VUV lamps employed in pulsed plasmachemical reactors for dry etching of thin films. The density of excited atomic chlorine radicals can be monitored on medium-resolution spectrometers using the ClI emission lines with λ=725, 754, and 821 (2) nm.     

17.

Investigation of bromide ion effects on disinfection by-products formation and speciation in an Istanbul water supply   总被引：6，自引：0，他引：6  

Uyak V  Toroz I 《Journal of hazardous materials》2007,149(2):445-451

Recent epidemiological studies reported that brominated DBPs may be more carcinogenic than their chlorinated analogs. Thus, this research was designed to investigate the role of bromide ion in the formation and speciation of disinfection by-products (DBPs) during chlorination of Buyukcekmece Lake Water (BLW) in Istanbul. Chlorination of BLW samples was carried out at pH 7.0 with 5 and 12 mg/l chlorine dosages. For each chlorine dosage, six bromide concentrations ranging from 0.05 to 4.0mg/l were added to form a 2 x 6 experimental matrix. In general, increasing bromide concentration gradually shifted trihalomethanes (THMs) and haloacetic acids (HAAs) speciation from chlorinated species to the mixed bromochloro species during chlorination. The halogen substitution ability of HOBr and HOCl during the formation of THMs and HAAs can be estimated through the use of probability theory. It was concluded that, in both halogen substitution for THM and dihalogenated HAA formation, HOBr was found to be 20 times more reactive than HOCl.     

18.

Occurrence and removal of NDMA and NDMA formation potential in wastewater treatment plants   总被引：1，自引：0，他引：1  

Yoon S  Nakada N  Tanaka H 《Journal of hazardous materials》2011,190(1-3):897-902

N-Nitrosodimethylamine (NDMA) is a potent carcinogen that is formed during disinfection by chlorination or ozonation in wastewater treatment plants (WWTPs). At present, little is known about the occurrence and fate of NDMA and its formation potential (FP) during wastewater treatment. We investigated the fate of NDMA and NDMA FP in 12 WWTPs. NDMA occurred in the influents at a concentration ranging from below the limit of quantification (LOQ <10 ng/L) to 80 ng/L, and in the final discharges from below the LOQ to 73 ng/L. In three WWTPs located in industrial areas, the influent had a high NDMA FP (up to 8230 ng/L). The rate of NDMA FP reduction from influent to secondary effluent varied between 85 and 98%, regardless of treatment process. The rate of NDMA removal is due more to the influent properties than to the type of biological treatment process.     

19.

Inactivation of Chironomid larvae with chlorine dioxide     

Sun XB  Cui FY  Zhang JS  Xu F  Liu LJ 《Journal of hazardous materials》2007,142(1-2):348-353

In this paper, comparative experiments on the inactivation of Chironomid larvae by chlorine dioxide and chlorine were conducted. In addition, batch experiments were performed in order to analyze the influence of pH value, organic precursor concentration and temperature on the inactivation efficiency of Chironomid larvae with chlorine dioxide. Based on it, removal effect of different pre-oxidation followed by coagulation process on Chironomid larvae in raw water was evaluated. The results showed that chlorine dioxide possessed better inactivation performance than chlorine, and complete inactivation of Chironomid larvae was obtained at CT value of 37.5 mg min/L (dose of 1.5mg/L and exposure time of 25 min). The pH in the range of 6-8 did not affect the inactivation efficiency of chlorine dioxide, whereas pH 10 resulted in around 10% decrease in inactivation rate. Meanwhile, the organic precursor had negative effects on inactivation, indicated by the decreased inactivation rate from 100% at TOC concentration of 0mg/L to 62.2% at 8 mg/L when the CT value was 45 mg min/L. With regard to the temperature, the inactivation efficiency of Chironomid larvae was significantly improved with the temperature increasing within the range investigated of 10-25 degrees C. The inactivation rate was reduced by 68.9% when temperature reduced from 25 degrees C to 10 degrees C. The coagulation jar test showed that Chironomid larvae in the raw water could be completely removed by chlorine dioxide pre-oxidation in combination with the coagulation process at CT value of 24.8 mg min/L.     

20.

Optimizing of ANFIS for estimating INS error during GPS outages     

Ahmed Mudheher Hasan  Khairulmizam Samsudin  Abdul Rahman Ramli 《中国工程学刊》2013,36(7):967-982

Global positioning system (GPS) has been extensively used for land vehicle navigation systems. However, GPS is incapable of providing permanent and reliable navigation solutions in the presence of signal evaporation or blockage. On the other hand, navigation systems, in particular, inertial navigation systems (INSs), have become important components in different military and civil applications due to the recent advent of micro-electro-mechanical systems (MEMS). Both INS and GPS systems are often paired together to provide a reliable navigation solution by integrating the long-term GPS accuracy with the short-term INS accuracy. This article presents an alternative method to integrate GPS and INS systems and provide a robust navigation solution. This alternative approach to Kalman filtering (KF) utilizes artificial intelligence based on adaptive neuro-fuzzy inference system (ANFIS) to fuse data from both systems and estimate position and velocity errors. The KF is usually criticized for working only under predefined models and for its observability problem of hidden state variables, sensor error models, immunity to noise, sensor dependency, and linearization dependency. The training and updating of ANFIS parameters is one of the main problems. Therefore, the challenges encountered implementing an ANFIS module in real time have been overcome using particle swarm optimization (PSO) to optimize the ANFIS learning parameters since PSO involves less complexity and has fast convergence. The proposed alternative method uses GPS with INS data and PSO to update the intelligent PANFIS navigator using GPS/INS error as a fitness function to be minimized. Three methods of optimization have been tested and compared to estimate the INS error. Finally, the performance of the proposed alternative method has been examined using real field test data of MEMS grade INS integrated with GPS for different GPS outage periods. The results obtained outperform KF, particularly during long GPS signal blockage.     

The symbols used are as in Reference [1] plus
k	constant
Pa	probability of acute death
ψ1	inhalation rate factor
ψ2	medical treatment factor

Evaporation and air-stripping to assess and reduce ethanolamines toxicity in oily wastewater

Toxicity from industrial oily wastewater remains a problem even after conventional activated sludge treatment process, because of the persistence of some toxicant compounds. This work verified the removal efficiency of organic and inorganic pollutants and the effects of evaporation and air-stripping techniques on oily wastewater toxicity reduction. In a lab-scale plant, a vacuum evaporation procedure at three different temperatures and an air-stripping stage were tested on oily wastewater. Toxicity reduction/removal was observed at each treatment step via Microtox bioassay. A case study monitoring real scale evaporation was also done in a full-size wastewater treatment plant (WWTP). To implement part of a general project of toxicity reduction evaluation, additional investigations took into account the monoethanolamine (MEA), diethanolamine (DEA) and triethanolamine (TEA) role in toxicity definition after the evaporation phase, both as pure substances and mixtures. Only MEA and TEA appeared to contribute towards effluent toxicity.     

Elimination of polyphenols toxicity from olive mill wastewater sludge by its co-composting with sesame bark

Olive mill wastes represent a significant environmental problem in Mediterranean areas where they are generated in huge quantities in a short period of time. Their high phenol, lipid and organic acid concentrations turn them into phytotoxic materials, but these wastes also contain valuable resources such as a large proportion of organic matter and a wide range of nutrients that could be recycled. Composting is one of the technologies used for the valorization of this effluent, producing a fertilizer useful for poor soils.The present work deals with the changes that occur in the content of phenolic compounds and the biotoxicity of the oxidized substrate which result from the composting of olive mill wastewater (OMW) sludge with sesame bark. The total organic matter decreased 52.72% while water-soluble phenol degradation decreased 72% after 7 months of processing. Gas chromatography coupled with mass spectroscopy was used to confirm the elimination of polyphenols during composting. Initially, the analysis showed three abundant polyphenolic compounds, one of which was identified as the 4-hydroxyphenyl-ethanol (tyrosol), a well-known antioxidant in OMW. After 7 months of composting, all of the phenolic compounds disappeared. The phytotoxic effects of OMW sludge, assessed by the plant index germination, increased during the composting to reach 80% after 210 days. This trend was confirmed by the correlation between physico-chemical and toxicity parameters. The results obtained confirmed the stability of the compost prepared from OMW sludge with sesame bark and indicated a gradual detoxification as the compost matured.     

The formation of excited chlorine atoms in a low-pressure transverse volume discharge

The characteristics of a transverse volume discharge (TVD) in chlorine at low pressures (P(Cl₂)=0.1–1.5 kPa) were studied. The excited chlorine atoms were formed in a 18×2.2× (0.5–1.0) cm volume using relatively low values of the capacitor bank charging voltage (U _ch ≤ 10 kV) in the pulsed discharge voltage source. The optical emission from plasma was studied in a spectral range from 500 to 900 nm. Homogeneous TVD pulses of short duration (τ; ≤ 100 ns) obtained under these conditions are of interest for use in UV-VUV lamps employed in pulsed plasmachemical reactors for dry etching of thin films. The density of excited atomic chlorine radicals can be monitored on medium-resolution spectrometers using the ClI emission lines with λ=725, 754, and 821 (2) nm.     

Investigation of bromide ion effects on disinfection by-products formation and speciation in an Istanbul water supply

Recent epidemiological studies reported that brominated DBPs may be more carcinogenic than their chlorinated analogs. Thus, this research was designed to investigate the role of bromide ion in the formation and speciation of disinfection by-products (DBPs) during chlorination of Buyukcekmece Lake Water (BLW) in Istanbul. Chlorination of BLW samples was carried out at pH 7.0 with 5 and 12 mg/l chlorine dosages. For each chlorine dosage, six bromide concentrations ranging from 0.05 to 4.0mg/l were added to form a 2 x 6 experimental matrix. In general, increasing bromide concentration gradually shifted trihalomethanes (THMs) and haloacetic acids (HAAs) speciation from chlorinated species to the mixed bromochloro species during chlorination. The halogen substitution ability of HOBr and HOCl during the formation of THMs and HAAs can be estimated through the use of probability theory. It was concluded that, in both halogen substitution for THM and dihalogenated HAA formation, HOBr was found to be 20 times more reactive than HOCl.     

Occurrence and removal of NDMA and NDMA formation potential in wastewater treatment plants

N-Nitrosodimethylamine (NDMA) is a potent carcinogen that is formed during disinfection by chlorination or ozonation in wastewater treatment plants (WWTPs). At present, little is known about the occurrence and fate of NDMA and its formation potential (FP) during wastewater treatment. We investigated the fate of NDMA and NDMA FP in 12 WWTPs. NDMA occurred in the influents at a concentration ranging from below the limit of quantification (LOQ <10 ng/L) to 80 ng/L, and in the final discharges from below the LOQ to 73 ng/L. In three WWTPs located in industrial areas, the influent had a high NDMA FP (up to 8230 ng/L). The rate of NDMA FP reduction from influent to secondary effluent varied between 85 and 98%, regardless of treatment process. The rate of NDMA removal is due more to the influent properties than to the type of biological treatment process.     

Inactivation of Chironomid larvae with chlorine dioxide

In this paper, comparative experiments on the inactivation of Chironomid larvae by chlorine dioxide and chlorine were conducted. In addition, batch experiments were performed in order to analyze the influence of pH value, organic precursor concentration and temperature on the inactivation efficiency of Chironomid larvae with chlorine dioxide. Based on it, removal effect of different pre-oxidation followed by coagulation process on Chironomid larvae in raw water was evaluated. The results showed that chlorine dioxide possessed better inactivation performance than chlorine, and complete inactivation of Chironomid larvae was obtained at CT value of 37.5 mg min/L (dose of 1.5mg/L and exposure time of 25 min). The pH in the range of 6-8 did not affect the inactivation efficiency of chlorine dioxide, whereas pH 10 resulted in around 10% decrease in inactivation rate. Meanwhile, the organic precursor had negative effects on inactivation, indicated by the decreased inactivation rate from 100% at TOC concentration of 0mg/L to 62.2% at 8 mg/L when the CT value was 45 mg min/L. With regard to the temperature, the inactivation efficiency of Chironomid larvae was significantly improved with the temperature increasing within the range investigated of 10-25 degrees C. The inactivation rate was reduced by 68.9% when temperature reduced from 25 degrees C to 10 degrees C. The coagulation jar test showed that Chironomid larvae in the raw water could be completely removed by chlorine dioxide pre-oxidation in combination with the coagulation process at CT value of 24.8 mg min/L.     

Optimizing of ANFIS for estimating INS error during GPS outages

Global positioning system (GPS) has been extensively used for land vehicle navigation systems. However, GPS is incapable of providing permanent and reliable navigation solutions in the presence of signal evaporation or blockage. On the other hand, navigation systems, in particular, inertial navigation systems (INSs), have become important components in different military and civil applications due to the recent advent of micro-electro-mechanical systems (MEMS). Both INS and GPS systems are often paired together to provide a reliable navigation solution by integrating the long-term GPS accuracy with the short-term INS accuracy. This article presents an alternative method to integrate GPS and INS systems and provide a robust navigation solution. This alternative approach to Kalman filtering (KF) utilizes artificial intelligence based on adaptive neuro-fuzzy inference system (ANFIS) to fuse data from both systems and estimate position and velocity errors. The KF is usually criticized for working only under predefined models and for its observability problem of hidden state variables, sensor error models, immunity to noise, sensor dependency, and linearization dependency. The training and updating of ANFIS parameters is one of the main problems. Therefore, the challenges encountered implementing an ANFIS module in real time have been overcome using particle swarm optimization (PSO) to optimize the ANFIS learning parameters since PSO involves less complexity and has fast convergence. The proposed alternative method uses GPS with INS data and PSO to update the intelligent PANFIS navigator using GPS/INS error as a fitness function to be minimized. Three methods of optimization have been tested and compared to estimate the INS error. Finally, the performance of the proposed alternative method has been examined using real field test data of MEMS grade INS integrated with GPS for different GPS outage periods. The results obtained outperform KF, particularly during long GPS signal blockage.