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1.
Pb, Cd and Hg in muscles of flathead mullet (Mugil cephalus), collected from Bocca di Magra, La Spezia (Ligurian Sea, Mediterranean Sea, Italy), were determined using graphite furnace atomic absorption spectrometry after microwave digestion for Pb and Cd and direct mercury analyser for Hg. Average Pb concentrations varied in the range 0.20–0.24 mg/kg, whereas Cd and Hg levels were negligible. None of the tested 200 samples exceeded the European regulatory limits as set by EC 1881/2006 and 420/2011. Metal concentrations in fish muscles were assessed for human consumption according to provisional tolerable weekly intake. The estimated values of Pb, Cd and Hg in M. cephalus’s edible parts in this study were below the values established by the Joint WHO/FAO Expert Committee on Food Additives. Therefore, it can be concluded that there is no health problem in human consumption.  相似文献   

2.
Farmed fish and wild fish aggregating in the vicinity of four Mediterranean fish farms with different environmental conditions were sampled. Levels of metals (including As and Se) were measured in the muscle, liver, gills, bone and intestine. The wild fish from sites with anoxic substrata accumulate metals (including As and Se) from the ambient habitat in their gills whereas those from sites with oxic substrata concentrate these elements through their diet in their intestine. Tissues of wild fish aggregating around farm cages accumulate a greater number of these elements and with higher concentrations than farmed fish. Habitat, diet, ecological needs, fat content of fish, and protein expression may play an important role in these element differences between fish species. Fe in flathead grey mullet, As in surmullet, rainbow wrasse, grey gurnard and picarel and Hg in bogue may pose a risk for human health. Farmed and wild fish are good sources of P, K, Cr and Se while flathead grey mullet, picarel and comber are excellent sources of Ca and Se.  相似文献   

3.
Mercury (Hg), cadmium (Cd), and lead (Pb) were quantified in muscle tissue of 5 species of demersal fish (european conger eel, rosefish, brown ray, blackbellied angler, and red mullet) commonly consumed in Italy. In all species studied, Hg was the most abundant element, followed by Pb and Cd, which exhibited comparable levels. Cd and Pb concentrations did not differ either within individuals of the same species or among various species examined, whereas Hg accumulation was species‐specific. Significant positive correlations between Hg concentrations and fish length for the 5 characterized species were observed. From a public health standpoint, Pb concentrations were under the legal limit for human consumption indicated by European Regulation, whereas Hg and Cd content occurred at levels exceeding the respective critical values in most of the samples examined. The estimated weekly intakes (EWIs) as well as the target hazard quotients (THQs) for Cd and Pb indicated that fish were safe for human consumption, whereas major concern was related to Hg. Fish size‐related changes in Hg concentrations determined high THQ and EWI values relatively to larger size fish consumption of these species, except for red mullet, suggesting potential health human risk. A continuous surveillance system of Hg content in fishery products, especially in certain species that for physiological reasons concentrate Hg more easily than others is crucial for consumer health protection. Practical Application : The present article deals with metal (Hg, Cd, and Pb) concentrations in commercially important demersal fish from Mediterranean Sea. The dietary intakes of these elements have been estimated and the dietary exposure assessment was calculated. This kind of study will help the consumers to make an informative choice when buying fish.  相似文献   

4.
The presence of selected toxic heavy metals, such as cadmium (Cd), lead (Pb) and mercury (Hg), was investigated in fish and seafood products, namely, blue mussel, carpet shell clam, European squid, veined squid, deep-water rose shrimp, red mullet, European seabass, gilthead seabream, Atlantic cod, European hake, Atlantic bluefin tuna and swordfish so as to assess their human exposure through diet. Metals were detected by quadrupole inductively coupled plasma mass spectrometry (Q-ICP-MS) and hydride generation atomic absorption spectrometry (Hg-AAS). Measurements of Cd, Pb and Hg were performed by means of analytical methods validated in compliance with UNI CEI EN ISO/IEC 17025 [2005. General requirements for the competence of testing and calibration laboratories. Milano (Italy): UNI Ente Nazionale Italiano di Unificazione]. The exposure assessment was undertaken matching the levels of Cd, Pb and total Hg with consumption data related to fish and seafood products selected for this purpose. In order to establish human health implications, the estimated weekly intakes (EWIs) for Cd, Pb and Hg were compared with the standard tolerable weekly intakes (TWI) for Cd and provisional tolerable weekly intakes (PTWIs) for Pb and Hg stipulated by the European Food Safety Authority (EFSA) and the Food and Agriculture Organization/World Health Organization (FAO/WHO) Joint Expert Committee on Food Additives (JECFA). The found metal concentrations were largely below the maximum levels (MLs) established at the European Union level with the exception of Cd. This metal exceeded the MLs in squid, red mullet, European hake and Atlantic cod. Squid and blue mussel showed the highest Pb concentrations which accounted for 60% and 10% of the MLs, respectively. Highest Hg levels were found in predatory fish. The concentrations of Hg in swordfish, Atlantic bluefin tuna and red mullet accounted for 50%, 30% and 30% of the MLs, respectively. The EWIs for Cd, Pb and Hg related to the consumption of fish and seafood products by the median of the Italian total population accounted for 20%, 1.5% and 10% of the standard TWI for Cd as well as PTWIs for Pb and Hg, respectively. Furthermore, the EWIs estimated using consumption data concerning Italian consumers did not exceed the standard TWI and PTWIs, except for Cd at 95th percentile.  相似文献   

5.
Pesticides constitute the major source of potential environmental hazard to man and animal as they are present and concentrated in the food chain. This study was conducted on 136 samples of water, sediment and fish for detection and determination of pesticide residues in this ecosystem. Highly significant differences were found in levels of lindan, heptachlor, endrin, dieldrin, P,P′-DDE and propoxur in River Nile water when compared with that of Manzala Lake. Levels of lindan, endrin, malathion and diazinon were significantly higher in soil sediment of Manzala Lake, while the levels of heptachlor, aldrine, P,P′-DDE, DDT, parathion, propoxur and zectran were significantly higher in soil sediment of River Nile. Boury fish of Manzala Lake contained higher levels of heptachlor, aldrin, P,P′-DDE and malathion, while boury fish of River Nile contained a higher level of zectran only. This survey, thus indicated that Manzala Lake and even the River Nile which was used as control are heavily contaminated with chlorinated hydrocarbons (lindan, heptachlor, aldrin, endrin, dieldrin, P,P′-DDE and DDT), organic phosphorus compounds (malathion, dimethoat, diazinon and parathion) and carbamate pesticides (propoxur and zectran).  相似文献   

6.
The purpose of this survey was to estimate the safety of ready-to-eat infant foods in terms of Pb and Cd content. The studied samples were ready-to-eat infant products: dinners (n = 74), soups (n = 27) and desserts (n = 82) containing components of animal origin: meat and/or milk. Cd and Pb content was determined using a GF-AAS method. The analysed products contained 1.82–3.54 µg Pb and 1.32–1.50 µg Cd per kg. The content of Pb per kg of the product can be represented as dinners > soups > desserts, whereas the content of Cd was dinners > desserts > soups. The analysed ready-to-eat products could be regarded as safe, because they supply 12-month-old infants with Pb in an amount accounting for nearly 22% BMDL01 and Cd accounting for ca. 8.6% of the total weekly intake.  相似文献   

7.
Sixty-one samples of canned tomato paste comprising seven brands originating from three countries and sold in local markets in the Kumasi Metropolis of Ghana were analysed for levels of iron (Fe), zinc (Zn), manganese (Mn), cadmium (Cd) and lead (Pb) by flame atomic absorption spectrophotometry and for levels of mercury (Hg) by direct mercury analyzer. Mean heavy metal concentrations varied by brand, ranging from below the limit of detection (Cd) to a maximum concentration range of 1.68?±?1.63 to 58.6?±?14.5?µg?g??1 (Fe). Estimated mean ranges of other heavy metals are 2.06?±?0.62 to 8.52?±?0.68?µg?g??1 (Zn), 2.62?±?0.33 to 5.75?±?0.47?µg?g??1 (Mn), 0.070?±?0.003 to 0.116?±?0.012?µg?g??1 (Pb) and 0.011?±?0.001 to 0.102?±?0.001?µg?g??1 (Hg). Assessed metal levels in five brands were below the WHO/FAO permissible levels. Results of the one-way analysis of variance (ANOVA) conducted on the data suggested no significant variations (P?>?0.05) in the concentrations of the metals in the same brands of canned tomatoes.  相似文献   

8.
As, Cd, Pb and Hg were analysed in commonly consumed spices and herbs in Malaysia. The range of As, Cd, Pb and Hg content was 0.24–2.54, 0.23–8.07, 1.54–8.94 and 0.06–0.52?µg?g–1, respectively. The highest concentration of Cd, Pb and Hg in spices and herbs exceeded the maximum permitted proportion, which are 1, 2 and 0.05?µg?g?1, respectively. This study suggests further monitoring of Cd, Pb and Hg on daily consumption of spices and herbs and its toxicological implication for consumers since only the amount of As was lower than the permitted concentration.  相似文献   

9.
Concentrations of As, Cd, Cu, Hg and Pb were measured by atomic absorption spectrometry (AAS) in muscle tissues of four fish species: anchovy (Engraulis encrasicholus), mackerel (Scomber japonicus), red mullet (Mullus surmuletus) and picarel (Spicara smaris) from the Croatian waters of the Adriatic Sea during 2008 and 2009. Metal levels measured in anchovy were in the following ranges (mg kg−1): As 0.01–54.8, Cd 0.001–0.02, Cu 0.001–6.29, Hg 0.001–0.52 and Pb 0.001–0.34 mg kg−1. Metal ranges in red mullet were (mg kg−1): As 0.01–70.9, Cd 0.002–0.85, Cu 0.001–57.3, Hg 0.001–2.07 and Pb 0.001–0.27 mg kg−1. Metal level ranges measured in mackerel were (mg kg−1): As 0.01–36.4, Cd 0.001–0.1, Cu 0.001–15.9, Hg 0.001–0.78 and Pb 0.002–0.24 mg kg−1. In picarel, metal level ranges were (mg kg−1): As 0.01–54.6, Cd 0.001–0.1, Cu 0.08–32.9, Hg 0.001–0.207 and Pb 0.001–0.46 mg kg−1. Significant differences in metal concentrations were found among fish species. The results presented on metal contents in the examined species give an indication of the environmental conditions. Concentrations of Cd, Cu, Hg and Pb obtained were far below the established values by the European Community regulations. However, arsenic levels found in red mullet were higher than the recommended legal limits for human consumption and as such may present a human health issue.  相似文献   

10.
Total concentrations of essential (Cu, Zn, Se and Cr) and non-essential (Hg, Cd, Pb and As) trace elements were measured in the flesh and hepatopancreas of Octopodidae (Eledone moschata, Eledone cirrhosa, Octopus salutii), Sepiidae (Sepia elegans, Sepia orbignyana) and Loliginidae (Illex coindeti, Loligo vulgaris) from the Mediterranean Sea. As expected, the hepatopancreas showed higher metal concentrations than flesh; the only exceptions were Hg and As, which were equally distributed in the two tissues. Regarding the edible portion, the highest toxic metal concentrations were in Octopodidae (Hg: 0.44, Cd: 0.49, Pb: 0.10 µg g?1 wet weight) and Sepiidae (Hg: 0.27, Cd: 0.50, Pb: 0.12 µg g?1 wet weight), while Loliginidae tended to accumulate less metal, especially Hg (Hg: 0.11, Cd: 0.30, Pb: 0.05 µg g?1 wet weight). The other elements showed a heterogeneous distribution among the different cephalopod families. Loliginidae showed the highest Se concentrations (1.18 µg g?1 wet weight), Octopodidae of Cu (37.37 µg g?1 wet weight) and Zn (42.00 µg g?1 wet weight) and Sepiidae of As (61.43 µg g?1 wet weight), while Cr was uniformly distributed among the various families (0.38–0.43 µg g?1 wet weight). In these seafoods, the concentrations of essential and non-essential elements were within the prescribed limits set by various authorities, except for Cu and As. Health risks posed by toxic elements to humans via dietary intake of these mollusks were assessed on the basis on Provisional Tolerable Weekly Intake (PTWI), while the estimated intakes of essential elements were compared to Dietary Reference Intakes (RDIs). A 70-g serving of these mollusks was shown to provide a large contribution to Cd intake (0.89 µg kg?1 body weight), corresponding to 35.6% of PTWI. Concerning the essential elements, the consumption of these mollusks made an important contribution to daily dietary intake of Se, Cu and Zn.  相似文献   

11.
This article shows the concentrations of ten metals (Cd, Pb, Ni, Cr, Cu, Co, Fe, Mn, Zn and Al) measured in 30 different brands of nail polish in the Nigerian market in order to provide some relevant information on the safe levels of these products for consumers. The metal concentrations in the nail polish samples ranged from <0.15 µg/g Cd, <0.03 to 7.25 µg/g Pb, <0.03 to 40 µg/g Ni, <0.1 to 8.25 µg/g Cr, <0.03 to 590 µg/g Cu, <0.03 to 3.00 µg/g Co, <0.1 to 15,200 µg/g Fe, <0.05 to 458 µg/g Mn, <0.03 to 595 µg/g Zn and <0.25 to 13,600 µg/g Al. The concentrations of Ni, Cr, and Co were found above the suggested allergenic limit of 1 µg/g in 56, 33 and 17 % of the 30 brands, respectively, whereas Cd and Pb were detected at levels below their permissible limits as impurities in cosmetics as specified by Health Canada. The brands made in Nigeria contained lower concentrations of Ni, Cr, Cu, Co, Pb and Al than the imported brands.  相似文献   

12.
The fatty acid profile of crevalle jack was compared with that of Atlantic bluefin tuna, Atlantic Spanish mackerel, red snapper, and Nile tilapia. Crevalle jack and Atlantic Spanish mackerel showed similarities in their fatty acid profiles, with the saturated fatty acid > monounsaturated fatty acid > polyunsaturated fatty acid pattern. Atlantic bluefin tuna and red snapper followed a similar pattern to each other, with the polyunsaturated fatty acid > saturated fatty acid > monounsaturated fatty acid pattern, and the pattern for Nile tilapia was saturated fatty acid > monounsaturated fatty acid ≈ polyunsaturated fatty acid. In winter, the DHA+EPA content of crevalle jack (493.2 mg/100 g fillet) was 37% lower than Atlantic bluefin tuna and Atlantic Spanish mackerel, 35% higher than for the red snapper, and 2.8 fold higher than for the Nile tilapia. The best nutritional indices were for Atlantic bluefin tuna > red snapper > Atlantic Spanish mackerel > crevalle jack > Nile tilapia.  相似文献   

13.
ABSTRACT

Approximately 3000 food samples from the Slovenian market and 2500 drinking (tap) water samples in the period 2011 ? 2016 were evaluated for the presence of toxic elements lead (Pb) and cadmium (Cd) and the overall chronic dietary exposure was assessed for each element. The highest mean concentrations were found for Pb in products for special nutritional use – dietary supplements (0.383 mg/kg) and for Cd in fish and seafood (0.117 mg/kg). The consumption data were obtained from the national study of the household budget and from the European Food Safety Authority (EFSA) summary statistics. Chronic dietary exposure was estimated deterministically. The average Pb and Cd intakes from food and drinking (tap) water ranged for children from 0.90 to 1.021 µg/kg bw/day and 4.65 to 5.65 µg/kg bw/week, respectively, and for adults, including adolescents, from 0.40 to 0.53 µg/kg bw/day and 1.98 to 2.82 µg/kg bw/week, respectively. The high consumption of cereal-based foods and vegetables contributed most to overall Pb and Cd intake in the majority of the age groups. The exposure to Pb was generally lower and that to Cd was higher compared to the average EU values. The most exposed were children, as the health-based guidance values were exceeded for both elements, which indicates a health concern. An important contribution to Cd exposure can be attributed to grains and potatoes grown in Slovenia, where the soil contains more Cd than that in other EU countries. Further efforts to reduce Pb and Cd intake are required to minimize potential health risks.  相似文献   

14.
Results are presented for the determination of levels of Ca, Cd, Ni, Cr, Cu, Pb, Mn, Zn Fe, Co and Mg in candies and chocolates consumed in southern Nigeria. Mean concentrations of metals in both confectionaries ranged 7.7–1405.2?µg/g1 for Ca, <0.001–0.2?µg/g for Cd, 1.4–7.9?µg/g for Ni, 0.4–3.0?µg/g for Cr, <0.08–2.3?µg/g for Pb, 0.4–12.6?µg/g for Mn, 0.6–8.0?µg/g for Zn, 1.7–12.3?µg/g for Fe, <0.05–1.49?µg/g for Co, and 8.4–576.1µg/g for Mg. The data showed that that these metals are not present at harmful levels. Concentrations of nickel and chromium were slightly elevated but were comparable to levels reported in similar food items elsewhere in the world.  相似文献   

15.
The concentrations of cadmium, copper, mercury and lead in fish from the Neretva river have been investigated in order to assess safety for consumers and the level of contamination. Samples of muscle and liver from six fish species (brown trout, common carp, prussian carp, chub, rudd and gray mullet) were collected at six locations upstream and downstream from the three largest towns along the Neretva river. Metal concentrations were determined by inductively coupled plasma mass spectrometry after microwave-assisted acid mineralisation. Accumulation of metals in fish tissues was species-dependent. The average content of metals in fish muscle samples was 0.013-0.055, 0.068-16.059, 0.050-0.401 and 0.055-0.703 mg/kg for Cd, Cu, Hg and Pb, respectively. Health effects due to fish consumption could not be excluded. Further investigation is recommended, including a survey of fish consumption frequency among the local inhabitants and sports fishermen.  相似文献   

16.
Concentrations of cadmium, chromium, lead and vanadium were determined in samples of six fish species collected along the coast of the Adriatic Sea. The concentrations of the elements studied were generally low, often below the detection limits of the analytical methods. The highest values (μg kg-1 fresh weight) were observed, mainly in the central area of the Adriatic Sea, for anchovy (Cd 20.2, Cr 82.9, Pb 45.9, V 89.9), red mullet (Cd 3.1, Cr 31.0, Pb 36.0, V 79.1) and mackerel (Cd 7.7, Cr 28.0, Pb 11.4, V 43.5). The concentrations of cadmium and lead in all the species examined were below the maximum levels indicated by the European Community for these two elements in seafood, and also would lead to exposure levels lower than the provisional tolerable daily intakes suggested by the FAO/WHO for Cd (420 μg week-1 for a 60-kg person) and Pb (1500 μg week-1 for a 60-kg person). The concentration of chromium was lower than the recommended daily amount (50-200 μg day-1 for a 60-kg person) indicated by the US National Research Council. An 11-34% contribution to the daily vanadium ingestion with fish was calculated for the population of the Adriatic coast.  相似文献   

17.
Food and environmental safety concerns as well as ecotoxicology considerations require investigation of the metal content of certain types of edible fungi. Thus, we conducted inductively coupled plasma optical emission spectrometry to obtain the metal content profiles of Cr, Mn, Fe, Ni, Cu, Zn, Pb, and Cd in Armillaria mellea (Vahl ex Fr.) Quel from nine zones in the Tumen River Basin. Statistical analysis showed that the characteristics of Yanji (Zone 1) differed from those of the other eight zones. Compared with the levels in the reference site (0.20 ± 0.01, 0.07 ± 0.02 µg/g for Pb and Cd), the Cd and Pb levels in three zones (1.2 ± 0.1, 8.5 ± 0.4 µg/g for Yanji; 0.35 ± 0.01, 0.73 ± 0.03 µg/g for Longjing; and 6.2 ± 0.4, 0.039 ± 0.000 µg/g for Hunchun) were higher than those listed in the Chinese Industrial Standards (WM/T2-2004; Pb ≤ 5.0 µg/g, Cd ≤ 0.3 µg/g). The present study can contribute data related to pollution control and food safety in the Tumen River Basin.  相似文献   

18.
BACKGROUND: It is important to determine the concentrations of essential and non‐essential metals in fish for human health. The essential elements and contaminants (Pb and Cd) were determined seasonally in the muscle and liver of some pelagic fish species round herring (Etrumeus teres), chub mackerel (Scomber japonicus), golden grey mullet (Liza aurata) and Mediterranean horse mackerel (Trachurus mediterraneus) from the Iskenderun Bay, Eastern Mediterranean Sea. RESULTS: The Na, K, Ca and Mg were the most abundant elements in muscle and liver tissues. The Na, K, Ca and Mg concentrations in fish tissues were between 51.7 and 3426 mg kg?1. Muscle accumulated the lowest levels of elements. Trace element and contaminant levels in muscle were highest in spring and summer. The Cu, Zn and Cr concentrations were highest in summer. The Ni, Mn and Fe concentrations were highest in spring. The maximum Pb concentrations in the muscle and liver of fish species was 0.39 and 0.80 mg kg?1 in autumn. The maximum Cd concentration in the muscle of fish was 0.27 mg kg?1 in spring and the maximum Cd concentration in the liver was 0.78 mg kg?1 in summer. CONCLUSION: The Cr, Pb, Cd, Cu and Zn levels in muscle were found to be lower than permissible limits reported by various authorities. Estimated weekly and daily intake for Pb and Cd by consumption of fish muscle were far below the PTWI and PTDI values established by FAO/WHO. Copyright © 2009 Society of Chemical Industry  相似文献   

19.
Total mercury (Hg), cadmium (Cd) and lead (Pb) levels were determined in the muscle of four commercialised exported fish species Thunnus albacares (yellowfin tuna), Xiphias gladius (swordfish), Makaira indica (black marlin) and Lutjanus sp (red snapper) collected from the Indian Ocean, Sri Lanka, during July 2009–March 2010 and measured by atomic absorption spectrophotometry. Results show that swordfish (n = 176) contained the highest total Hg (0.90 ± 0.51 mg/kg) and Cd (0.09 ± 0.13 mg/kg) levels, whereas yellowfin tuna (n = 140) contained the highest Pb levels (0.11 ± 0.16 mg/kg). The lowest total Hg (0.16 ± 0.11 mg/kg), Cd (0.01 ± 0.01 mg/kg) and Pb (0.04 ± 0.04 mg/kg) levels were found in red snapper (n = 28). Black marlin (n = 24) contained moderate levels of total Hg (0.49 ± 0.37), Cd (0.02 ± 0.02) and Pb (0.05 ± 0.05). Even though there are some concerns during certain months of the year, this study demonstrates the safety of main export fish varieties in terms of total Hg, Cd and Pb.  相似文献   

20.
Five commercially available common fish species: catfish (Chsysichthyes nigrodigitatus), tilapia (Oreochromis nilotichus), ilisha (Ilisha africana), bonga (Ethmalosa fimbriata) and mudskipper (Periophthalmus koelreuteri) in Oron Local Government Area were evaluated for their content of heavy metals and the effects of salting on nutrient contents, oxidative stability and fatty acid profiles of smoke-dried fish cakes. Concentrations of heavy metals in edible muscle, liver and gill tissues were determined while the oxidative rancidities in unsalted and salted smoke-dried fish cakes, packed in low-density polyethylene (LDPE) bags and stored at 30 ± 1 °C were assessed using peroxide value (POV), thiobarbituric acid (TBA) value, free fatty acid (FFA) contents and sensory evaluation techniques. Generally the analytical data for Cu, Zn and Pb in the muscle, gills and liver of test samples were significantly low. Similarly, insignificant concentrations (<0.001 mg/100 g) of Hg, As, Cr and Cd were obtained in the fish tissues. The protein and lipid contents of the fish cakes ranged from 60.8–63.9% to 7.3–9.1%, respectively. Salting caused minimal reductions in the nutrient contents of the dried fish cakes. The POV, TBA, FFA and taste panel scores were highest during the first week of storage and declined thereafter. Salted smoke-dried samples had higher POV, TBA and FFA values than unsalted samples. Panel preference ratings for flavour/aroma and desirability characteristics of the fish cakes were in the order: C. nigrodigitatus > O. nilotichus > E. fimbriata > I. africana > P. keolreuteri. Palmitic acid (C16:0) was the predominant saturated fatty acid in the test samples. The eicosapentaenoic acid (EPA) contents of unsalted smoke-dried C. nigrodigitatus was 4.9%, Oreochromis niloticus 6.5%, Ilisha africana 2.6%, E. fimbriata 5.6% and P. koelreuteri 7.64%. The docosahexaenoic acid (DHA) contents of salted smoked dried fish were 1.8% (C. nigrodigitatus), 4.8% (O. niloticus), 9.5% (I. africana), 5.5% (E. fimbriata) and 12.3% (P. koelreuteri).  相似文献   

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