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1.
A number of lamellar structures were produced in XD TiAl alloys (Ti-45 at. pct and 47 at. pct Al-2 at. pct Nb-2 at. pct Mn+0.8 vol pct TiB2) by selected heat treatments. During creep deformation, microstructural degradation of the lamellar structure was characterized by coarsening and spheroidization, resulting in the formation of fine globular structures at the grain boundaries. Grain boundary sliding (GBS) was thought to occur in local grains with a fine grain size, further accelerating the microstructural degradation and increasing the creep rate. The initial microstructural features had a great effect on microstructural instability and creep resistance. Large amounts of equiaxed γ grains hastened dynamic recrystallization, and the presence of fine lamellae increased the susceptibility to deformation-induced spheroidization. However, the coarsening and spheroidization were suppressed by stabilization treatments, resulting in better creep resistance than the microstructures without these treatments. Furthermore, well-interlocked grain boundaries with lamellar incursions were effective in restraining the onset of GBS and microstructural degradation. In the microstructures with smooth grain boundaries, a fine lamellar spacing significantly lowered the minimum creep rate but rapidly increased the tertiary creep rate for the 45 XD alloy. For the 47 XD alloy, well-interlocked grain boundaries dramatically improved the creep resistance of nearly and fully lamellar (FL) structures, in spite of the presence of coarse lamellar spacing or equiaxed γ grains. However, it may not be feasible to produce a microstructure with both a fine lamellar spacing and well-interlocked grain boundaries. If that is the case, it is suggested that the latter feature is more beneficial for creep resistance in XD TiAl alloys with relatively fine grains.  相似文献   

2.
Creep constrained grain boundary cavitation in a fully lamellar (FL) form of a titanium aluminide intermetallic alloy has been studied using finite element (FE) techniques. Two different forms of FL models were considered. Cavitation was modeled in the presence of grain boundary sliding (GBS) for the case of straight former γ grain boundaries. Models of cavitation without GBS were also performed for a FL microstructure with serrated former γ grain boundaries. The effect of cavitating facet interaction on rupture life has been studied. A comparison between the FL forms and a dualphase equiaxed microstructure having the same phase ratio (α 2/γ) was also made to examine the relative susceptibility of these microstructures to high-temperature damage. It has been observed that the overall effect of interaction between cavitating facets increases the rupture time significantly when these facets are on adjacent grains. However, in the presence of GBS, cavitation on the facet with narrower separation effectively reduces the cavity growth rate on the facet with wider separation. This article is based on a presentation made in the symposium “Fundamentals of Gamma Titanium Aluminides,” presented at the TMS Annual Meeting, February 10–12, 1997, Orlando, Florida, under the auspices of the ASM/MSD Flow & Fracture and Phase Transformations Committees.  相似文献   

3.
The influence of microstructure on creep deformation was examined in the near-y TiAl alloy Ti-49A1-1V. Specifically, microstructures with varying volume fractions of lamellar constituent were produced through thermomechanical processing. Creep studies were conducted on these various microstructures under constant load in air at temperatures between 760 °C and 870 °C and at stresses ranging from 50 to 200 MPa. Microstructure significantly influences the creep behavior of this alloy, with a fully lamellar microstructure yielding the highest creep resistance of the microstructures examined. Creep resistance is dependent on the volume fraction of lamellar constituent, with the lowest creep resistance observed at intermediate lamellar volume fractions. Examination of the creep deformation structure revealed planar slip of dislocations in the equiaxed y microstructure, while subboundary formation was observed in the duplex microstructure. The decrease in creep resistance of the duplex microstructure, compared with the equiaxed y microstructure, is attributed to an increase in dislocation mobility within the equiaxedy constituent, that results from partitioning of oxygen from the γ phase to the α2 phase. Dislocation motion in the fully lamellar microstructure was confined to the individual lamellae, with no evidence of shearing of γ/γ or γ/α2 interfaces. This suggests that the high creep resistance of the fully lamellar microstructure is a result of the fine spacing of the lamellar structure, which results in a decreased effective slip length for dislocation motion over that found in the duplex and equiaxed y microstructures. BRIAN D. WORTH, formerly with the Department of Materials Science and Engineering, The University of Michigan  相似文献   

4.
Creep constrained grain boundary cavitation in a fully lamellar (FL) form of a titanium aluminide intermetallic alloy has been studied using finite element (FE) techniques. Two different forms of FL models were considered. Cavitation was modeled in the presence of grain boundary sliding (GBS) for the case of straight former γ grain boundaries. Models of cavitation without GBS were also performed for a FL microstructure with serrated forme γ grain boundaries. The effect of cavitating facet interaction on rupture life has been studied. A comparison between the FL forms and a dual-phase equizxed microstructure having the same phase ratio (α2/γ) was also made to examine the relative susceptibility of these microstructures to high-temperature damage. It has been observed that the overall effect of interaction between cavitating facets increases the rupture time significantly when these facets are on adjacent grains. However, in the presence of GBS, cavitation on the facet with narrower separation effectively reduces the cavity growth rate on the facet with wider separation. ANIRBAN CHAKRABORTY, formerly Graduate Student Researcher with the Chemical & Biochemical Engineering and Materials Science (CBEMS) Department, University of California, Irvine. This article is based on a presentation made in the symposium “Fundamentals of Gamma Titanium Aluminides”, presented at the TMS Annual Meeting, February 10–12, 1997, Orlando, Florida, under the auspices of the ASM/MSD Flow & Fracture and Phase Transformations Committees.  相似文献   

5.
The influence of chemical composition on the microstructure of the γ-titanium aluminide alloy Ti-48Al-2W-0.5Si (at. pct) and the accompanying tensile, low-cycle fatigue, and creep properties has been evaluated. The study showed that small variations in chemical composition and casting procedures resulted in considerable variations in the microstructure, yielding vastly different mechanical properties. Low contents of aluminum and tungsten led to a coarse-grained lamellar (γ/α 2) microstructure with high creep resistance. A composition close to the nominal one produced a duplex (γ+γ/α 2) structure with favorable strength, ductility, and low-cycle fatigue properties. By controlling the solidification and cooling rates at casting, a pseudoduplex (PS-DP) microstructure with a unique combination of high strength and high fatigue and creep resistance can be obtained. These unique properties can be explained by the diffuse boundaries between the relatively small γ grains and the neighboring lamellar colonies, combined with semicoherent interfaces between the γ and α 2 phases. At tensile and low-cycle fatigue loading, these boundaries act like high-angle boundaries, producing a virtually fine-grained material promoting strength, whereas at creep loading, grain-boundary sliding is hindered in the semicoherent interfaces leading to high creep resistance.  相似文献   

6.
The kinetics of dynamic spheroidization of the lamellar microstructure and the associated flow-softening behavior during isothermal, constant-strain-rate deformation of a gamma titanium aluminide alloy were investigated, with special emphasis on the role of the prior-alpha grain/colony size. For this purpose, fully lamellar microstructures with prior-alpha grain sizes between 80 and 900 μm were developed in a Ti-45.5Al-2Nb-2Cr alloy using a special forging and heat-treatment schedule. Isothermal hot compression tests were conducted at 1093 °C and strain rates of 0.001, 0.1, and 1.0 s−1 on specimens with different grain sizes. The flow curves from these tests showed a very strong dependence of peak flow stress and flow-softening rate on grain size; both parameters increased with alpha grain/colony size. Microstructures of the upset test specimens revealed the presence of fine, equiaxed grains of γ + α 2 + β phases resulting from the dynamic spheroidization process that initiated at and proceeded inward from the prior-alpha grain/colony boundaries. The grain interiors displayed evidence of microkinking of the lamellae. The frequency and severity of kinking increased with strain, but were also strongly dependent on the local orientation of lamellae with respect to the compression axis. The kinetics of dynamic spheroidization were found to increase as the strain rate decreased for a given alpha grain size and to decrease with increasing alpha grain size at a given strain rate. The breakdown of the lamellar structure during hot deformation occurred through a combination of events, including shear localization along grain/colony boundaries, microbuckling of the lamellae, and the formation of equiaxed particles of γ + β 2 + α 2 on grain/colony boundaries and in zones of localized high deformation within the microbuckled regions.  相似文献   

7.
The creep deformation and rupture behavior of annealed and overheated 7075 A1 was investigated under uniaxial, biaxial, and triaxial stress states. Examinations of samples prior to and after testing using optical microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were also performed to develop a better understanding of the microstructural mechanisms governing this behavior. These observations combined with analyses of the test data indicate that annealed 7075 A1 under present testing conditions exhibits characteristics of dislocation creep with a concomitant contribution from grain boundary sliding (GBS). By contrast, the results for overheated 7075 A1 suggest that GBS is suppressed. This hypothesis is supported by observations of large particles at grain boundaries in the overheated microstructure and few or no particles at boundaries in the annealed microstructures. Rupture times for the different stress states were also compared with respect to four multiaxial stress parameters, each of which is linked to a particular physical mechanism that can facilitate creep rupture. It was found that creep rupture in annealed 7075 A1 (regardless of sample orientation) is dominated by cavitation coupled with GBS. By contrast, the rupture behavior of overheated 7075 A1 is consistent with a model that describes cavitation constrained by relatively uniform creep deformation in the matrix. Thus, the rupture findings also indicate that GBS is prevented in the overheated microstructure, while it gives rise to significant stress redistribution in the annealed microstructure.  相似文献   

8.
A study has been made to investigate boundary sliding and its accommodation mode with respect to the variation of grain size and α/β volume fraction during superplastic deformation of a two-phase Ti-6Al-4V alloy. A load relaxation test has been performed at 600 °C and 800 °C to obtain the flow stress curves and to analyze the deformation characteristics by the theory of inelastic deformation. The results show that grain matrix deformation (GMD) is found to be dominant at 600 °C and is well described by the plastic state equation. Whereas, at 800 °C, phase/grain boundary sliding (P/GBS) becomes dominant and is fitted well with the viscous flow equation. The accommodation mode for fine-grained microstructures (3 μm) well agrees with the isostress model, while that for large-grained structures (11 μm) is a mixed mode of the isostress and isostrain-rate models. The sliding resistance analyzed for the different boundaries is lowest in the α/β boundary, and increases on the order of α/βα/αβ/β, which plays an important role in controlling the superplasticity of the alloys with various α/β phase ratios.  相似文献   

9.
Constant strain rate tests at 10-5 s-1 have been carried out in the temperature range 723 to 973 K on two 1 1/2 pct Cr · 1/2 pct V ferritic steels, the first steel with a 20 pct bainite, 80 pct ferrite microstructure and the second with a fully ferritic structure. Measurements of the quantitative strain, εgb, due to grain boundary sliding (gbs), were made and in both steels the γ values (where γ = εgbT) increased with increasing temperature. In both structures, sliding was found to occur on all boundaries. A qualitative study of cavitation damage and final fracture mechanisms was also made. It is suggested that in the mixed structure, cavities are nucleated by gbs at carbides whereas in the fully ferritic structure, cavity nucleation is by the interaction of intragranular slip with a grain boundary. Optical observations showed that the large scale cavitation behavior was superficially very similar in both steels, but scanning electron microscope observations showed remarkable differences in the fine scale cavitation damage. The implications of these results are discussed in terms of the relationship between matrix deformation, grain boundary deformation and creep fracture. Formerly of the Department of Metallurgy, University of Manchester.  相似文献   

10.
The development of microstructure and its influence on creep properties have been studied for structures including equiaxed γ, duplex, and other structures of varying α2 morphology in two Ti-48Al-2Cr-2Nb alloys. Heat treatment at 1125°C have been utilized to produce equiaxed γ microstructures in alloys with or without Mo additions. The γ→α transformation produces α2 plates with several orientation variants with γ grains during subsequent annealing of the equiaxed γ microstructures below the α transus. Formation of this α2 morphology results from rapid up-quenching (UQ), and this structure persists through annealing, cooling, and creep testing. Differences in minimum creep rates for several microstructures, containing varying amounts of multi-or single variant γ/α2 grains are shown to be minimal. The presence of Mo has also resulted in improved creep resistance in equiaxed γ and γ + α2 + B2 structures, as compared to similar microstructures in the Ti-48Al-2Cr-2Nb alloy. Deformation during creep at 760 °C at stresses between 200 and 400 MPa occurs by a combination of twinning and dislocation glide without recrystallization, resulting in power-law stress exponents in the range of 6 to 9. Only minimal strain path dependence of the minimum creep rate is detected in a comparison of creep rates in stress jump, stress drop, and single stress tests. This article is based on a presentation made in the symposium “Fundamentals of Gamma Titanium Aluminides,” presented at the TMS Annual Meeting, February 10–12, 1997, Orlandom, Florida, under the auspices of the ASM/MSD Flow & Fracture and Phase Transformations Committees.  相似文献   

11.
Transmission electron microscopy (TEM) and microanalytical chemistry were performed on sensitized samples of duplex welds that exhibited both skeletal ferrite microstructures and lath ferrite microstructures. The objective was to understand why welds with lath ferrite, contrary to a theoretical prediction, are not immune to sensitization. Most of the ferrite-austenite (α-γ) interphase boundaries in the welds with skeletal ferrite were curved and incoherent, while those in welds with lath ferrite were predominantly planar and semicoherent. The density of carbide precipitation on incoherent boundaries was much greater than that on semicoherent boundaries. Carbide precipitates on incoherent boundaries were typically equiaxed, while those on semicoherent boundaries had very high aspect ratios and appeared to form along ledges in the interphase boundary. During sensitizing heat treatments, the chromium-depleted zone on the ferrite side of the interphase region transformed to austenite, causing the α-γ interphase boundary to move into the ferrite region. This markedly increased the width of the chromium-depleted zone in the austenite phase and extended the time of heat treatment required to replenish the zone with chromium. It is proposed that migration of the α-γ interphase boundary, which occurs to a much greater extent in the welds with lath ferrite, is responsible for their unexpected susceptibility to sensitization at 550°C.  相似文献   

12.
Plastic deformation and fracture of binary TiAl-base alloys   总被引:4,自引:0,他引:4  
The mechanical behavior of binary TiAl alloys containing 46 to 60 at. pct Al has been studied in bulk materials preparedvia rapid solidification processing. Bending and tensile tests were carried out at room temperature as a function of Al concentration. A few alloys were also tested from liquid nitrogen temperature to ∼ 1000°C. Deformation substructures were studied by analytical transmission electron microscopy and fracture modes by scanning electron microscopy (SEM). It was found that both microstructure and composition strongly affect the mechanical behavior of TiAl-base alloys. A duplex structure, which contains both primary y grains and transformedγ/α 2 lamellar grains, is more deformable than a single-phase or a fully transformed structure. The highest plasticities are observed in duplex alloys containing 48–50 at. pct Al after heat treatment in the center of theγ + α phase field. The deformation of these duplex alloys is facilitated by 1/2[110] slip and {111} twinning, but very limited superdislocation slip occurs. The twin deformation is suggested to result from a lowered stacking fault energy due to oxygen depletion or an intrinsic change in chemical bonding. Other factors, such as grain size and grain boundary chemistry and structure, are important from a fracture point of view. The results on the deformation and fracture modes as a function of test temperature are also discussed.  相似文献   

13.
The effects of grain size and environment on creep crack growth (CCG) in Ni-base superalloy, UDIMET 520, were studied through experiments at 540 °C. Specially designed solution and aging treatments were used to produce γ′ strengthened microstructures with different grain sizes but without any M23C6 grain boundary precipitates. Five grain sizes, which fall into three groups (i.e., small, medium, and large), were employed. The creep crack growth rates (CCGRs) in specimens with small grain sizes were approximately 2.5 times lower than those with medium and large grain sizes, as a result of crack branching and the presence of some undissolved primary MC carbides at the grain boundaries. Otherwise, the CCGRs were insensitive to the grain size. Fractographic observations on the fracture surfaces and metallographic examinations on the cross sections of the interrupted CCG specimen revealed intergranular microcracks and a faceted intergranular mode of fracture in both air and argon environments. The test results suggest that the formation and propagation of intergranular cracks by grain boundary sliding (GBS) is the main micromechanism responsible for CCG in both air and argon environments at the relatively low test temperature employed. Grain boundary oxidation attack in the air environment simply accelerates the crack growth process. The present results are in agreement with the theoretical predictions of the GBS-controlled CCG model previously developed by the authors.  相似文献   

14.
The microstructure of an (α + γ) duplex Fe-10.1Al-28.6Mn-0.46C alloy has been investigated by means of optical microscopy and transmission electron microscopy (TEM). In the as-quenched condition, extremely fine D03 particles could be observed within the ferrite phase. During the early stage of isothermal aging at 550 °C, the D03 particles grew rapidly, especially the D03 particles in the vicinity of the α/γ grain boundary. After prolonged aging at 550 °C, coarse K’-phase (Fe, Mn)3AlC precipitates began to appear at the regions contiguous to the D03 particles, and —Mn precipitates occurred on the α/γ and α/α grain boundaries. Subsequently, the grain boundary β-Mn precipitates grew into the adjacent austenite grains accompanied by a γ→ α + β-Mn transition. When the alloy was aged at 650 °C for short times, coarse. K-phase precipitates were formed on the α/γ grain boundary. With increasing the aging time, the α/γ grain boundary migrated into the adjacent austenite grain, owing to the heterogeneous precipitation of the Mn-enrichedK phase on the grain boundary. However, the α/γ grain boundary migrated into the adjacent ferrite grain, even though coarse K-phase precipitates were also formed on the α/γ grain boundary in the specimen aged at 750 °C.  相似文献   

15.
The hard-orientated polysynthetically twinned (PST) crystal with the lamellar plates oriented parallel to the compression axis was deformed at 1150 K under the applied stress of 158 to 316 MPa. Microstructural changes were examined quantitatively for the PST crystal during creep deformation. In the as-grown PST crystal of the present study, proportions of α 2/γ, true twin, pseudotwin, and 120 deg rotational fault interfaces were 12, 59, 12, and 17 pct, respectively. After creep deformation, lamellar coarsening by dissolution of α 2 lamellae and migration of γ/γ interfaces were observed. The acceleration of creep rate after the minimum strain rate in the creep curve was attributed to the lamellar coarsening and destruction of lamellar structure during the creep deformation. Thirty-two percent of α 2/γ interfaces, 51 pct of true twin interfaces, 74 pct of pseudotwin interfaces, and 80 pct of 120 deg rotational faults disappeared after 4 pct creep strain at 1150 K. The α 2/γ interface was more stable than γ/γ interfaces during the creep deformation. The pseudotwin interface and 120 deg rotational fault were less thermally stable than the true twin interface for γ/γ interfaces. This article is based on a presentation made in the symposium entitled “Fundamentals of Structural Intermetallics,” presented at the 2002 TMS Annual Meeting, February 21–27, 2002, in Seattle, Washington, under the auspices of the ASM and TMS Joint Committee on Mechanical Behavior of Materials.  相似文献   

16.
The development of microstructure and its influence on creep properties have been studied for structures including equiaxed γ, duplex, and other structures of varying α 2 morphology in two Ti-48Al-2Cr-2Nb alloys. Heat treatments at 1125 °C have been utilized to produce equiaxed γ microstructures in alloys with or without Mo additions. The γα transformation produces α 2 plates with several orientation variants within γ grains during subsequent annealing of the equiaxed γ microstructures below the α transus. Formation of this α 2 morphology results from rapid up-quenching (UQ), and this structure persists through annealing, cooling, and creep testing. Differences in minimum creep rates for several microstructures containing varying amounts of multi- or single variant γ/α 2 grains are shown to be minimal. The presence of Mo has also resulted in improved creep resistance in equiaxed γ and γ+α 2+B2 structures, as compared to similar microstructures in the Ti-48Al-2Cr-2Nb alloy. Deformation during creep at 760 °C at stresses between 200 and 400 MPa occurs by a combination of twinning and dislocation glide without recrystallization, resulting in power-law stress exponents in the range of 6 to 9. Only minimal strain path dependence of the minimum creep rate is detected in a comparison of creep rates in stress jump, stress drop, and single stress tests. This article is based on a presentation made in the symposium “Fundamentals of Gamma Titanium Aluminides,” presented at the TMS Annual Meeting, February 10–12, 1997, Orlando, Florida, under the auspices of the ASM/MSD Flow & Fracture and Phase Transformations Committees.  相似文献   

17.
The steady-state creep deformation behavior of a cast two phase gamma TiAl alloy having the composition Ti48Al1Nb (at.%) has been studied. Tension creep tests using the stress increment technique (θθ2θ3) were conducted over the temperature range of 704–850°C at constant initial applied stress level of 103.4–241.3 MPa. The activation energy for creep over the temperature and stress regime of this study varied 317.5 kJ/mol (137.8 MPa) up to 341.0 kJ/mol (206.8 MPa) with an average value of 326.4 kJ/mol. This is well within the range of values previously measured for gamma TiAl alloys where creep controlled by volume diffusion has been suggested as rate controlling. The stress exponents meaured were 5.0 at 704°C, 4.9 at 750°C, 4.7 at 800°C and 4.46 at 850°C. Using the activation energy of 326.4 kJ/mol, the temperature compensated steady-state creep rate was plotted against long stress with all temperatures collapsing onto a single line having a slope equal to 4.95. Using conventional creep analysis, this value of the stress exponent can be taken as suggestive of dislocation climb controlled power law creep as the operative deformation mechanism within the stress and temperature regime of the present study. The boundary separating the lamellar grains in two phase gamma TiAl alloys having the duplex microstructure may be a very important aspect of this microstructure with respect to creep deformation resistance. The interlocking γ/α2 laths making up these boundaries are expected to be very resistant to grain boundary sliding which may contribute to creep deformation in the dislocation creep regime. Finally, some previous observations along with a comparison of the creep behavior of the Ti48Al1Nb alloy to that of a Tiz.sbnd;50.3Al binary have been discussed in terms of the pre-exponential constant A in the power law creep equation. TiAl alloys having similar stress and temperature dependencies but differing steady-state strain rates over comparable stress-temperature regimes may be rationalized on the basis of differing power law creep constants which may reflect differences in stacking fault energies.  相似文献   

18.
Creep of a TiAl/Ti3Al alloy with a lamellar microstructure causes progressive spheroidization of the lamellar microstructure. Microstructural observations reveal that deformation-induced spheroidization (DIS) occurs by deformation and fragmentation of lamellae in localized shear zones at interpacket boundaries and within lamellar packets. Deformation-induced spheroidization substantially increases the interphase interfacial area per unit volume, demonstrating that DIS is not a coarsening process driven by reduction of interfacial energy per unit volume. Creep experiments reveal that DIS increases the minimum creep rate (εmin) during creep at constant stress and temperature; the activation energy (Q c ) and stress exponent (n) for creep are both reduced as a result of DIS. Values ofn andQ c for the lamellar microstructure are typical of a dislocation creep mechanism, while estimated values ofn andQ c for the completely spheroidized microstructure are characteristic of a diffusional creep mechanism. The increase in (εmin) associated with DIS is thus attributed primarily to a change of creep mechanism resulting from microstructural refinement.  相似文献   

19.
A γ-base TiAl alloy with duplex microstructure of lamellar colonies and equiaxed γ grains was prepared with a reactive sintering method. Tensile tests and fracture toughness tests at loading velocities up to 12 m/s (strain rate for tensile tests up to 3.2×102/s) were carried out. The micro-structure of the alloy before and after tensile deformation was carefully examined with a scanning electron microscope (SEM) and a transmission electron microscope (TEM). The fractography of the tensile specimens and fracture toughness specimens was studied. The experimental results demonstrated that the ultimate tensile strength (UTS) and yield strength (YS) increase with increasing strain rate up to 10/s and subsequently level off. The UTS and YS exhibited similar strain rate sensitivity. The strain rate sensitivity exponent at strain rates lower than 10/s is about 1.5×10−2 and at higher strain rates is almost zero. In this study, fracture toughness was found to be less sensitive to the loading velocity, having values of around 25 MPa √m, which is believed to be attributed to the high strain rate experienced at the crack tip. The predominant deformation mechanism for the strain rates used in this study was found to be twinning. However, in the low strain rate range, the dislocation motion mechanism was operative at the initial deformation stage and twinning dominated the later stage of the deformation process. In the high strain rate range, the entire deformation process was dominated by twinning. The interaction between deformation twinning and grain boundaries resulted in intergranular fracture in the γ grains and delamination of α 2/γ interfaces in the lamellar colonies.  相似文献   

20.
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