储氢技术及其关键材料研究进展

氢能是未来能源结构中最具发展潜力的能源载体,氢的廉价制备、安全高效储送以及大规模应用是当今研究的重点,而氢能的储存是其中的关键性问题.本文综述了目前主要的储氢技术和储氢材料,如高压气态储氢、低温液态储氢、合金储氢、有机液体氢化物储氢、碳质材料储氢和金属有机骨架类聚合物储氢等,并对未来的研究方向进行了展望.     

Euromembrane 2000 highlights membrane-based water treatment technologies

The first instalment of our Euromembrane 2000 round-up, which was published in the January 2001 issue of Membrane Technology, looked at developments in liquid membranes and distillation. The conference also looked in detail at water treatment, and this article, the second in a series of three summaries covering the event that was held in Israel during September last year, considers the role which different types of membranes are now playing in this area.     

A comparison of bubble and disk storage technologies

The evolution of disk storage technology is examined along with its application in current and possible future disk files. Progress in bubble storage technology is considered, and its merits are assessed as a competing storage technology. Tradeoffs in cost and performance are studied, which can enhance the application of disks and bubbles in computer storage hierarchies. Finally, likely entry points for bubbles in storage hierarchies are identified along with the required advances in bubble storage density.     

Biomolecular optical data storage and data encryption

The use of bacteriorhodopsin (BR) as an active layer in write-once-read-many optical storage is presented. This novel feature of BR materials may be used on a wide variety of substrates, among them transparent substrates but also paper and plastics. The physical basis of the recording process is polarization-sensitive two-photon absorption. As an example for this new BR application, an identification card equipped with an optical recording strip is presented, which has a capacity of about 1 MB of data. The recording density currently used is 125 kB/cm/sup 2/, which is far from the optical limits but allows operation with cheap terminals using plastic optics. In the examples given, data are stored in blocks of 10 kB each. A special optical encryption procedure allows the stored data to be protected from unauthorized reading. The molecular basis of this property is again the polarization-sensitive recording mechanism. The unique combination of optical storage, photochromism, and traceability of the BR material is combined on the single-molecule level. BR introduces a new quality of storage capability for applications with increased security and anticounterfeiting requirements.     

Review Modern magnetic materials in data storage

The current status of the technology of magnetic recording as used in disk drives is reviewed. The emphasis is on the magnetic materials used in the application and on some of the technical problems that may limit the increase in areal density. The new technology of magnetic random access memory (MRAM), which has evolved from the magnetic recording application, is also reviewed. A wide range of magnetic materials is essential for the advance of magnetic recording and the MRAM technology. For the magnetic-recording application the requirements are for high-magnetization, soft magnetic materials for write heads, new antiferromagnetic alloys with high blocking temperatures, large coupling to ferromagnetic films and low susceptibility to corrosion for pinning films in giant magnetoresistive sensors, and for the MRAM application, the requirement is for new ferromagnetic alloys with large values of tunneling polarization ratio. A significant limitation to magnetic recording is found to be the inconsistent demands on media thickness: small media thicknesses are required for large values of signal-to-noise ratio, while large values of thickness are required to reduce the impact of the superparamagnetic effect, which results in the potential for data loss over time. Both of these requirements are discussed. Multilayer ferromagnetic films for recording surfaces are shown to allow both large signal-to-noise ratio and adequate resistance to data loss.     

Security optical data storage in Fourier holograms

We have proposed and demonstrated a holographic security storage system that is implemented with a shift multiplexing technique. The security function of this storage system is achieved by using a microdiffuser (MD) for random phase encoding of the reference beams. The apparatus of random phase encoding in this system offers an additional and flexible function during the recording processes. The system can generate holographic security memory or nonsecurity holographic memory via using the MD or not. The storage capacity and the average signal-to-noise value of the security storage system are 16 bits/μm(2) and 3.5, respectively. Lateral shifting selectivity in this holographic security storage system is theoretically analyzed and experimentally investigated.     

Identifying disruptive technologies by integrating multi-source data

Scientometrics - Identifying disruptive technologies has important value for the decision-making in technology layout and investment. The identification methods of disruptive technologies based on...     

Data storage gets to the point

Could a system that is basically mechanical, albeit micromechanical, compete with electronic and magnetic devices for storing large volumes of data? Surprisingly, recent research suggests that the answer may be yes. Stranger still, the concept being investigated by IBM and others is not too far removed from that of the phonograph and record player, the once familiar system used for writing and retrieving data to and from revolving disks. But the scale of the once familiar pick-up needle compared with what is now proposed is as an ocean compared with a drop.In the new ultra-compact system for storing digital data developed by IBM researchers, patterns on the surface of a material are traced by points so fine that the impression left by one of them would be one fifty-thousandth the size of the full stop at the end of this sentence. Using technology first developed as the atomic force microscope (AFM) to trace topography down to the scale of individual atoms and molecules can, say IBM researchers, enable data to be stored at densities as high as 1 Tb/in² — a density ten times higher than today’s most advanced disk drives.     

Acrylamide-based photopolymer for microholographic data storage

The application of an acrylamide-based holographic photopolymer for bit-format holographic data storage is investigated. Holographic reflection gratings with a spatial frequency of 5640 lines/mm and micrometer radius were recorded at 532 nm wavelength using 1 μJ write energy. A diffraction efficiency of up to 0.2% was measured.     

Inorganic materials for optical data storage

Recyclable holographic (optical) storage in inorganic materials is nowadays possible due to the advent of laser. Various performance parameters of the state-of-the-art of optical storage are discussed in detail with reference to the well-established case of ferroelectric lithium niobate (LiNbO₃). Various physicochemical techniques are employed in understanding the microscopic mechanisms responsible for optical storage in LiNbO₃. A short summary of other inorganic materials capable of holographic storage is also presented.     

The emergence of spin electronics in data storage

Electrons have a charge and a spin, but until recently these were considered separately. In classical electronics, charges are moved by electric fields to transmit information and are stored in a capacitor to save it. In magnetic recording, magnetic fields have been used to read or write the information stored on the magnetization, which 'measures' the local orientation of spins in ferromagnets. The picture started to change in 1988, when the discovery of giant magnetoresistance opened the way to efficient control of charge transport through magnetization. The recent expansion of hard-disk recording owes much to this development. We are starting to see a new paradigm where magnetization dynamics and charge currents act on each other in nanostructured artificial materials. Ultimately, 'spin currents' could even replace charge currents for the transfer and treatment of information, allowing faster, low-energy operations: spin electronics is on its way.     

Nanophase change for data storage applications

Phase change materials are widely used for date storage. The most widespread and important applications are rewritable optical disc and Phase Change Random Access Memory (PCRAM), which utilizes the light and electric induced phase change respectively. For decades, miniaturization has been the major driving force to increase the density. Now the working unit area of the current data storage media is in the order of nano-scale. On the nano-scale, extreme dimensional and nano-structural constraints and the large proportion of interfaces will cause the deviation of the phase change behavior from that of bulk. Hence an in-depth understanding of nanophase change and the related issues has become more and more important. Nanophase change can be defined as: phase change at the scale within nano range of 100 nm, which is size-dependent, interface-dominated and surrounding materials related. Nanophase change can be classified into two groups, thin film related and structure related. Film thickness and clapping materials are key factors for thin film type, while structure shape, size and surrounding materials are critical parameters for structure type. In this paper, the recent development of nanophase change is reviewed, including crystallization of small element at nano size, thickness dependence of crystallization, effect of clapping layer on the phase change of phase change thin film and so on. The applications of nanophase change technology on data storage is introduced, including optical recording such as super lattice like optical disc, initialization free disc, near field, super-RENS, dual layer, multi level, probe storage, and PCRAM including, superlattice-like structure, side edge structure, and line type structure. Future key research issues of nanophase change are also discussed.     

Microholographic multilayer optical disk data storage

Micrometer-sized reflection holograms can be written into a rapidly rotating homogeneous photopolymer disk at the focus of a high-numerical-aperture beam and its retroreflection to implement high-capacity multilayer digital data storage. This retroreflection is generated by an optical system with positive unity magnification to ensure passive alignment of the counterpropagating beam. Analysis reveals that the storage capacity and transfer rate of this bit-based holographic storage system compare favorably with traditional page-based systems but at a fraction of the system complexity and cost. The analysis is experimentally validated at 532 nm by writing and reading 12 layers of microholograms in a 125-microm photopolymer disk continuously rotating at 3600 rpm. The experimental results predict a capacity limit of 140 Gbytes in a millimeter-thick disk or over 1 Tbyte with the wavelength and numerical aperture of Blu-Ray.     

Phase-change materials for rewriteable data storage

Phase-change materials are some of the most promising materials for data-storage applications. They are already used in rewriteable optical data storage and offer great potential as an emerging non-volatile electronic memory. This review looks at the unique property combination that characterizes phase-change materials. The crystalline state often shows an octahedral-like atomic arrangement, frequently accompanied by pronounced lattice distortions and huge vacancy concentrations. This can be attributed to the chemical bonding in phase-change alloys, which is promoted by p-orbitals. From this insight, phase-change alloys with desired properties can be designed. This is demonstrated for the optical properties of phase-change alloys, in particular the contrast between the amorphous and crystalline states. The origin of the fast crystallization kinetics is also discussed.     

Modeling of multilayer microholographic data storage

We focus on the investigation of multilayer recording in microholographic data storage. We have developed a numerical model for calculating the electromagnetic scattering from thick microholographic gratings using the Born approximation and the direct volume integral. The signal-to-noise ratio and bit error rate were calculated to estimate the noise arising from interlayer and interhologram cross talk. Measurements were done to prove the validity of the model. The results of our calculations and the measurements show good agreement. We present the application of the model to the investigation of confocal filtering at the image plane and to the evaluation of positioning and wavelength tolerances.